CN109053028A - A kind of fire-retardant quartzite slate and its manufacturing method - Google Patents
A kind of fire-retardant quartzite slate and its manufacturing method Download PDFInfo
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- CN109053028A CN109053028A CN201810982565.2A CN201810982565A CN109053028A CN 109053028 A CN109053028 A CN 109053028A CN 201810982565 A CN201810982565 A CN 201810982565A CN 109053028 A CN109053028 A CN 109053028A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
- C04B26/122—Phenol-formaldehyde condensation polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Building Environments (AREA)
Abstract
The invention discloses a kind of fire-retardant quartzite slates, each component including following mass percentage: silica flour 25-30%, particulate material 40-45%, ceramic powder 10-15%, silane coupling agent 1-2%, curing agent 1-2%, iron ammonium sulfate 0.5-1%, tert-butyl hydroquinone 0.5-1%, fire retardant 1-3%, unsaturated polyester resin 10-15%.Iron ammonium sulfate and tert-butyl hydroquinone is added in the present invention, the compatibility between inorganic fire retardants and unsaturated-resin can be improved, so that being uniformly mixed between each raw material, interface adhesion is strong, internal gap is smaller, and in conjunction with even closer, obtained flame-retardant quartzite slate has excellent wearability, also there is excellent mechanical property, higher bending strength, while there is good flame retardant effect and lower water absorption rate again.
Description
Technical field
The invention belongs to building material technical fields, and in particular to a kind of fire-retardant quartzite slate and its manufacturing method.
Background technique
Artificial quartz stone is to be process using natural siliceous sand, silica flour, resin and pigment mixing through special equipment
A kind of new polymeric materials.Quartz is glued by the colorant of 80% or more natural quartz and 10% or so, resin and other adjust
The additive composition connect, solidify etc. is formed by negative-pressure vacuum, high-frequency vibration, and (temperature height is according to solidification for heating cure
The plate that production method depending on the type of agent is process.Its quality hard (Mohs' hardness 5-7), compact structure (density
2.3-2.5g/ cubic centimetres) with incomparable wear-resisting, the pressure-resistant, high temperature resistant of other ornament materials, anticorrosive, impermeable etc.
Characteristic.Quartz product is mainly in kitchen countertop, toilet table top, bar desk, tea table, ground and inner-outer wall head etc. at present,
Since its is rich in color, the advantages that product pattern enriches, lithotome, high-grade ceramic, timber, metal class decoration material can be substituted
Material.
Nevertheless, there is also certain drawbacks, such as fire protecting performance are bad for quartzite slate.In the mistake of quartz production
Cheng Zhong, the content of resin is all 6% or more, and since resin is inflammable substance, resin content was more than in quartzite slate at that time
When 3%, fire protecting performance is poor, limits quartzite slate in the application of complex condition.It is therefore desirable to be carried out to it fire-retardant
Processing.Frequently with fire retardant be inorganic fire retardants, halogen containing flame-retardant and phosphonium flame retardant etc..When due to halogen containing flame-retardant burning
The gas of a large amount of poisonous and harmful strong and stimulatings can be generated, health and environment to people cause direct, potential and permanent
Harm.Therefore great attention of the halogen-free flameproof by people.But the compatibility of halogen-free flame retardants and resin is poor, in resin
In be not easy to disperse, even if dispersion, affinity is also bad, therefore the performance of finally obtained fire-retardant quartzite slate drops significantly
It is low.
Summary of the invention
The purpose of the present invention is overcome the deficiencies of the prior art and provide a kind of fire-retardant quartzite slate and its manufacturing method.
The present invention provides a kind of fire-retardant quartzite slate, each component including following mass percentage: silica flour 25-
30%, particulate material 40-45%, ceramic powder 10-15%, silane coupling agent 1-2%, curing agent 1-2%, iron ammonium sulfate 0.5-
1%, tert-butyl hydroquinone 0.5-1%, fire retardant 1-3%, unsaturated polyester resin 10-15%.
Preferably, each component including following mass percentage: silica flour 28%, particulate material 42%, ceramic powder
10%, silane coupling agent 2%, curing agent 1%, iron ammonium sulfate 1%, tert-butyl hydroquinone 1%, fire retardant 3%, unsaturation
Polyester resin 12%.
Preferably, the particulate material is quartz particles or glass particle.
Preferably, the partial size of the ceramic powder is 150-300 mesh.
Preferably, the curing agent is in methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate or dibenzoyl peroxide
One kind.
Preferably, the unsaturated polyester resin is one of epoxy resin, phenolic resin or acrylic resin or more
Kind.
Preferably, the fire retardant is aluminium hydroxide or magnesium hydroxide.
The present invention also provides a kind of manufacturing methods of fire-retardant quartzite slate, comprising the following steps:
1) glass particle, silane coupling agent and fire retardant are uniformly mixing to obtain under the mixing speed of 300-400r/min
Mixture；
2) curing agent, iron ammonium sulfate, tert-butyl hydroquinone and unsaturated polyester resin are then added into mixture,
It is uniformly mixed under the mixing speed of 50-80r/min, is eventually adding silica flour and ceramic powder, after adding, increase mixing speed extremely
500-600r/min continues to stir 5-10min, obtains mixture after mixing；Mixture is poured into mold, then in vacuum item
Compression moulding under part, plate after molding curing reaction at 80-100 DEG C are cooling to get resistance after reaction by demoulding
Fire quartzite slate.
Preferably, the vacuum degree under the step 2) vacuum condition is -0.1~-0.08MPa.
The partial size of silica flour of the present invention is 150-200 mesh.
The partial size of particulate material of the present invention is 20-40 mesh.
Silane coupling agent of the present invention is vinyltriethoxysilane (A151) or γ-aminopropyl-triethoxy silicon
Alkane (KH550).
Currently, fire retardant usually is added during preparation, in order to meet to make quartzite slate that there is anti-flammability
The requirement of environmental protection and human health, through frequently with halogen-free flame retardants, but the compatibility of halogen-free flame retardants and resin is poor, is setting
It is not easy to disperse in rouge, even if dispersion, affinity is also bad, so that the structure inside quartzite slate is not close, finally obtains
The performance of fire-retardant quartzite slate substantially reduce.
Ceramic powder is added to replace part halogen-free flame retardants in the present invention, reduces the dosage of fire retardant, and production cost reduces,
And the compatibility that can improve halogen-free flame retardants and resin is poor, and the main ingredient of ceramic powder is silica and aluminium oxide,
Fumed silica and silica dioxide gel can be used as the surface that thermal barrier layer is gathered in melting plate, reduce plate and burning
The contact of flame achievees the effect that fire-retardant.And the particle size of silica is small, large specific surface area, surface physical chemistry
It is active big, two alternate binding forces can be improved, to improve the mechanical property of material in conjunction with macromolecular chain generation physical chemistry
Energy.
Iron ammonium sulfate and tert-butyl hydroquinone is added in the present invention, can improve inorganic fire retardants and unsaturated-resin it
Between compatibility so that between each raw material be uniformly mixed, interface adhesion is strong, and internal gap is smaller, in conjunction with even closer, institute
Obtaining fire-retardant quartzite slate has excellent wearability, also has excellent mechanical property, higher bending strength, while having again
There are good flame retardant effect and lower water absorption rate.
Using raw material of the invention and the sequence of each raw material addition and the mixing speed of day part are controlled, each raw material can be made
Between uniformly mix, by the excellent physical properties for the quartzite slate that such manufacturing method obtains, compression strength is higher.
The beneficial effects of the present invention are:
1, ceramic powder is added to replace part halogen-free flame retardants in the present invention, reduces the dosage of fire retardant, production cost drop
It is low, and the compatibility that can improve halogen-free flame retardants and resin is poor, and the main ingredient of ceramic powder is silica and oxidation
Aluminium, fumed silica and silica dioxide gel can be used as thermal barrier layer be gathered in melting plate surface, reduce plate with
The contact of combustion flame achievees the effect that fire-retardant.And the particle size of silica is small, large specific surface area, surface physics
Chemical activity is big, can improve two alternate binding forces, to improve the mechanics of material in conjunction with macromolecular chain generation physical chemistry
Performance.
2, iron ammonium sulfate and tert-butyl hydroquinone is added in the present invention, can improve inorganic fire retardants and unsaturated-resin
Between compatibility so that being uniformly mixed between each raw material, interface adhesion is strong, and internal gap is smaller, in conjunction with even closer,
Obtained flame-retardant quartzite slate has excellent wearability, also has excellent mechanical property, higher bending strength, while again
With good flame retardant effect and lower water absorption rate.
3, using raw material of the invention and the mixing speed of sequence and day part that each raw material is added is controlled, each original can be made
It is uniformly mixed between material, the excellent physical properties of obtained fire-retardant quartzite slate, compression strength is higher.
Specific embodiment
A specific embodiment of the invention is described further below with reference to embodiment, is not therefore limited the invention to
Within the scope of the embodiment described.
Embodiment 1
A kind of fire-retardant quartzite slate, each component including following mass percentage: the silica flour 25% of 200 mesh, 20
Purpose quartz particles 45%, the ceramic powder 15% of 300 mesh, silane coupling agent γ-aminopropyl triethoxysilane (KH550)
1%, curing agent peroxidized t-butyl perbenzoate 1.5%, iron ammonium sulfate 0.5%, tert-butyl hydroquinone 1%, fire retardant hydrogen
Aluminium oxide 1%, epoxy resin 10%.
Its manufacturing method is as follows:
1) glass particle, silane coupling agent and fire retardant are uniformly mixing to obtain mixing under the mixing speed of 350r/min
Object；
2) curing agent, iron ammonium sulfate, tert-butyl hydroquinone and unsaturated polyester resin are then added into mixture,
It is uniformly mixed under the mixing speed of 80r/min, is eventually adding silica flour and ceramic powder, after adding, increase mixing speed extremely
600r/min continues to stir 10min, obtains mixture after mixing；Mixture is poured into mold, is then pressed under vacuum conditions
Type is made, vacuum degree is -0.8MPa, and plate after molding curing reaction at 80 DEG C is cooling after reaction by demoulding,
Up to fire-retardant quartzite slate.
Embodiment 2
A kind of fire-retardant quartzite slate, each component including following mass percentage: the silica flour 28% of 150 mesh, 40
Purpose glass particle 42%, the ceramic powder 10% of 150 mesh, silane coupling agent vinyl triethoxysilane (A151) 2%, solidification
Agent methyl ethyl ketone peroxide 1%, iron ammonium sulfate 1%, tert-butyl hydroquinone 1%, fire retardant aluminium hydroxide or magnesium hydroxide
3%, phenolic resin 12%.
Its manufacturing method is as follows:
1) glass particle, silane coupling agent and fire retardant are uniformly mixing to obtain mixing under the mixing speed of 400r/min
Object；
2) curing agent, iron ammonium sulfate, tert-butyl hydroquinone and unsaturated polyester resin are then added into mixture,
It is uniformly mixed under the mixing speed of 60r/min, is eventually adding silica flour and ceramic powder, after adding, increase mixing speed extremely
500r/min continues to stir 5min, obtains mixture after mixing；Mixture is poured into mold, is then pressed under vacuum conditions
Type is made, vacuum degree is -0.1MPa, and plate after molding curing reaction at 90 DEG C is cooling after reaction by demoulding,
Up to fire-retardant quartzite slate.
Embodiment 3
A kind of fire-retardant quartzite slate, each component including following mass percentage: the silica flour 30% of 200 mesh, 30
Purpose quartz particles 40%, the ceramic powder 10% of 200 mesh, silane coupling agent γ-aminopropyl triethoxysilane (KH550)
1%, curing agent dibenzoyl peroxide 2%, iron ammonium sulfate 0.5%, tert-butyl hydroquinone 0.5%, fire retardant hydroxide
Aluminium 1%, acrylic resin 15%.
Its manufacturing method is as follows:
1) glass particle, silane coupling agent and fire retardant are uniformly mixing to obtain mixing under the mixing speed of 300r/min
Object；
2) curing agent, iron ammonium sulfate, tert-butyl hydroquinone and unsaturated polyester resin are then added into mixture,
It is uniformly mixed under the mixing speed of 50r/min, is eventually adding silica flour and ceramic powder, after adding, increase mixing speed extremely
600r/min continues to stir 8min, obtains mixture after mixing；Mixture is poured into mold, is then pressed under vacuum conditions
Type is made, vacuum degree is -0.8MPa, and plate after molding curing reaction at 100 DEG C is cooling after reaction by demoulding,
Up to fire-retardant quartzite slate.
Comparative example 1
A kind of fire-retardant quartzite slate, each component including following mass percentage: the silica flour 29% of 150 mesh, 40
Purpose glass particle 42%, the ceramic powder 10% of 150 mesh, silane coupling agent vinyl triethoxysilane (A151) 2%, solidification
Agent methyl ethyl ketone peroxide 1%, tert-butyl hydroquinone 1%, fire retardant aluminium hydroxide or magnesium hydroxide 3%, phenolic resin 12%.
Its manufacturing method is as follows:
1) glass particle, silane coupling agent and fire retardant are uniformly mixing to obtain mixing under the mixing speed of 400r/min
Object；
2) curing agent, tert-butyl hydroquinone and unsaturated polyester resin are then added into mixture, 60r/min's
It is uniformly mixed under mixing speed, is eventually adding silica flour and ceramic powder, after adding, increased mixing speed to 500r/min, continue
5min is stirred, obtains mixture after mixing；Mixture is poured into mold, then compression moulding under vacuum conditions, vacuum degree
For -0.1MPa, plate after molding curing reaction at 90 DEG C, after reaction by demoulding, cooling is to get fire-retardant quartz
Plate.
Comparative example 2
A kind of fire-retardant quartzite slate, each component including following mass percentage: the silica flour 29% of 150 mesh, 40
Purpose glass particle 43%, the ceramic powder 10% of 150 mesh, silane coupling agent vinyl triethoxysilane (A151) 2%, solidification
Agent methyl ethyl ketone peroxide 1%, fire retardant aluminium hydroxide or magnesium hydroxide 3%, phenolic resin 12%.
Its manufacturing method is as follows:
1) glass particle, silane coupling agent and fire retardant are uniformly mixing to obtain mixing under the mixing speed of 400r/min
Object；
2) curing agent and unsaturated polyester resin are then added into mixture, is mixed under the mixing speed of 60r/min
Uniformly, it is eventually adding silica flour and ceramic powder, after adding, increases mixing speed to 500r/min, continues to stir 5min, after mixing
Obtain mixture；Mixture is poured into mold, then compression moulding under vacuum conditions, vacuum degree is -0.1MPa, after molding
Plate at 90 DEG C curing reaction, it is cooling to get fire-retardant quartzite slate after reaction by demoulding.
Comparative example 3
Raw material and its ratio are same as Example 2, weigh all raw materials according to weight percent, pour into mould after mixing
In tool, then compression moulding under vacuum conditions, vacuum degree be -0.8MPa, plate after molding curing reaction at 90 DEG C, instead
It is cooling to get fire-retardant quartzite slate by demoulding after answering.
2, the performance of embodiment 1-3 and comparative example 1-3 obtained flame-retardant quartzite slate are tested, as a result such as table 1.It presses
The combustion rating of the fire-retardant quartzite slate of GB/T8626 standard detection, by the fire-retardant quartzite slate of 2406 standard detection of GB/T
Oxygen index (OI).
1 quartzite slate the performance test results of table
| Embodiment | Bending strength (MPa) | Compression strength (MPa) | Combustion rating | Oxygen index (OI) (%) |
| Embodiment 1 | 51.1 | 205.1 | A | 58 |
| Embodiment 2 | 55.5 | 204.5 | A | 60 |
| Embodiment 3 | 53.2 | 201.6 | A | 54 |
| Comparative example 1 | 46.7 | 199.5 | B2 | 28 |
| Comparative example 2 | 42.5 | 189.5 | B2 | 26 |
| Comparative example 3 | 50.8 | 101.1 | B2 | 34 |
As can be seen from the above table, the fire-retardant quartzite slate and comparative example phase obtained using raw material and method of the invention
Than, the fire-retardant quartzite slate that bending strength and a little higher than comparative example of compression strength obtain, but combustion rating and oxygen index (OI)
Its flame retardant property will be higher than comparative example from far away, illustrate its flame retardant property due to comparative example.Embodiment 2 and the phase of comparative example 1 and 2
Than, illustrate that iron ammonium sulfate and tert-butyl hydroquinone is added in the present invention, can improve inorganic fire retardants and unsaturated-resin it
Between compatibility so that between each raw material be uniformly mixed, interface adhesion is strong, and internal gap is smaller, in conjunction with even closer, institute
Obtaining fire-retardant quartzite slate has excellent mechanical property, higher bending strength, while having good flame retardant property again.It is real
Example 2 is applied compared with comparative example 3, illustrates using raw material of the invention and control the stirring speed of sequence and day part that each raw material is added
Degree, can make uniformly to mix between each raw material, the excellent physical properties of obtained fire-retardant quartzite slate, flame retardant property is preferable.
Claims (9)
1. a kind of fire-retardant quartzite slate, which is characterized in that each component including following mass percentage: silica flour 25-
30%, particulate material 40-45%, ceramic powder 10-15%, silane coupling agent 1-2%, curing agent 1-2%, iron ammonium sulfate 0.5-
1%, tert-butyl hydroquinone 0.5-1%, fire retardant 1-3%, unsaturated polyester resin 10-15%.
2. fire-retardant quartzite slate as described in claim 1, which is characterized in that each group including following mass percentage
Part: silica flour 28%, particulate material 42%, ceramic powder 10%, silane coupling agent 2%, curing agent 1%, iron ammonium sulfate 1%,
Tert-butyl hydroquinone 1%, fire retardant 3%, unsaturated polyester resin 12%.
3. fire-retardant quartzite slate as described in claim 1, which is characterized in that the particulate material is quartz particles or glass
Particle.
4. fire-retardant quartzite slate as claimed in claim 1 or 2, which is characterized in that the partial size of the ceramic powder is 150-300
Mesh.
5. fire-retardant quartzite slate as described in any one of claims 1-3, which is characterized in that the curing agent is peroxidating first
One of ethyl ketone, peroxidized t-butyl perbenzoate or dibenzoyl peroxide.
6. fire-retardant quartzite slate as described in any one of claims 1-3, which is characterized in that the unsaturated polyester resin is
One of epoxy resin, phenolic resin or acrylic resin are a variety of.
7. fire-retardant quartzite slate as described in any one of claims 1-3, which is characterized in that the fire retardant is aluminium hydroxide
Or magnesium hydroxide.
8. the manufacturing method of fire-retardant quartzite slate as described in claim 1, which comprises the following steps:
1) glass particle, silane coupling agent and fire retardant are uniformly mixing to obtain mixing under the mixing speed of 300-400r/min
Object；
2) curing agent, iron ammonium sulfate, tert-butyl hydroquinone and unsaturated polyester resin are then added into mixture,
It is uniformly mixed under the mixing speed of 50-80r/min, is eventually adding silica flour and ceramic powder, after adding, increase mixing speed extremely
500-600r/min continues to stir 5-10min, obtains mixture after mixing；Mixture is poured into mold, then in vacuum item
Compression moulding under part, plate after molding curing reaction at 80-100 DEG C are cooling to get resistance after reaction by demoulding
Fire quartzite slate.
9. the manufacturing method of fire-retardant quartzite slate as claimed in claim 8, which is characterized in that the step 2) vacuum condition
Under vacuum degree be -0.1~-0.08MPa.
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| CN201810982565.2A CN109053028A (en) | 2018-08-27 | 2018-08-27 | A kind of fire-retardant quartzite slate and its manufacturing method |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111548053A (en) * | 2020-06-24 | 2020-08-18 | 葛荣山 | Artificial stone and preparation method thereof |
| CN112456862A (en) * | 2020-12-17 | 2021-03-09 | 河源新宝丽雅装饰材料有限公司 | Quartz plate with flame retardant property and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408250A (en) * | 2013-07-29 | 2013-11-27 | 广东中旗新材料科技有限公司 | Nanocomposite quartz stone board and manufacturing method thereof |
| CN106915921A (en) * | 2017-03-22 | 2017-07-04 | 佛山市蓝瑞欧特信息服务有限公司 | A kind of fire retardant man-made quartzite slate and preparation method thereof |
| CN106977136A (en) * | 2017-05-19 | 2017-07-25 | 广东中旗新材料科技有限公司 | A kind of fire retardant man-made quartzite slate and preparation method thereof |
| CN107827393A (en) * | 2017-11-24 | 2018-03-23 | 朱冠军 | The quartzy sheet material and its preparation technology of a kind of additive flame retardant |
| CN108328977A (en) * | 2018-03-23 | 2018-07-27 | 常德市万福达环保节能建材有限公司 | A kind of concrete repairing material |
-
2018
- 2018-08-27 CN CN201810982565.2A patent/CN109053028A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103408250A (en) * | 2013-07-29 | 2013-11-27 | 广东中旗新材料科技有限公司 | Nanocomposite quartz stone board and manufacturing method thereof |
| CN106915921A (en) * | 2017-03-22 | 2017-07-04 | 佛山市蓝瑞欧特信息服务有限公司 | A kind of fire retardant man-made quartzite slate and preparation method thereof |
| CN106977136A (en) * | 2017-05-19 | 2017-07-25 | 广东中旗新材料科技有限公司 | A kind of fire retardant man-made quartzite slate and preparation method thereof |
| CN107827393A (en) * | 2017-11-24 | 2018-03-23 | 朱冠军 | The quartzy sheet material and its preparation technology of a kind of additive flame retardant |
| CN108328977A (en) * | 2018-03-23 | 2018-07-27 | 常德市万福达环保节能建材有限公司 | A kind of concrete repairing material |
Non-Patent Citations (1)
| Title |
|---|
| 李振华等: ""SiO2在聚合物阻燃中的应用研究进展"", 《中国塑料》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111548053A (en) * | 2020-06-24 | 2020-08-18 | 葛荣山 | Artificial stone and preparation method thereof |
| CN112456862A (en) * | 2020-12-17 | 2021-03-09 | 河源新宝丽雅装饰材料有限公司 | Quartz plate with flame retardant property and preparation method thereof |
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Application publication date: 20181221 |
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