CN109043187A - A kind of feed addictive and preparation method thereof rich in organic trace element - Google Patents

Abstract

A kind of feed addictive and preparation method thereof rich in organic trace element disclosed by the invention, it is related to supporting the preparation technical field of pig feed additive, feed addictive is by being by including that following raw material is prepared: organic iodine, apple powder, tea polyphenols, organic selenium, sucrose ester, glucose, calcium stearate, sodium chloride, anthocyanidin, fatty acid glyceride, chitosan, galactomannans, organic metal microelement；Its preparation process is as follows: (1), stocking up；(2), crush；(3), coating powder preparation soluble in the stomach；(4), prepared by enteric coating powder；(5), mix.Have the characteristics that micronutrient element absorptivity is high, remain less, environmental pollution is small after feeding and feeding cost is lower, is suitable for including the addition of the market pigs breeding feed such as clay fertilizer pig and bacon hogs, it can also be used to chicken and duck feed.

Description

A kind of feed addictive and preparation method thereof rich in organic trace element

Technical field

It is especially a kind of rich in organic trace element the present invention relates to the preparation technical field of feeding pig feed additive Feed addictive and preparation method thereof.

Background technique

Microelement is to maintain necessary nutriment stable in domestic animal pig body environment, lacks any microelement all It will lead to the corresponding disease of domestic animal pig to occur, the growth and development of the domestic animal pig both influenced also generate the economic benefit of domestic animal pig cultivation It influences.Currently, most domestic animal pig breeding enterprise is all confined to traditional cultural methods such as feed is single or formula is unreasonable, do not have Consider the balance of various nutrients necessary to domestic animal pig grows, the addition of a large amount of inorganic microelements utilizes in addition, causes domestic animal The residual and environmental pollution of heavy metal in swine excrement.How microelement efficient absorption benefit in domestic animal pig breeding process is solved With, it has also become the hot spot that domestic animal pig breeding enterprise is paid close attention to.

" a kind of confection of organic green feed disclosed in Chinese patent (number of patent application 200910109142.0) And application method ", it is made of saccharomycete and its culture, anhydrous betaine and aminoacid chelating microelement, uses When feed addition 1KG-5KG or drinking water per ton in add 0.5KG-2.5KG.Since component used is bion, containing more Kind nutritional ingredient and some coordinating factors, and stable chelate, and have the characteristics that nontoxic, noresidue.The invention is made The organic green feed additive obtained improves gastrointestinal tract environment and Bacterial community by adding microbial flora into animal body, Promote stomach and intestine to increase the digestion, absorption and utilization of feed nutrition substance feed intake, improve feed conversion rate, improves animal Production performance, enhancing animal immunizing power, the survival rate for improving piglet and raising sow produce number pigs weaned per year.

Another Chinese patent (number of patent application 201010122315.5) is disclosed, and " glutamic acid microelement chelate is made For the application of animal feed additive ", glutamic acid microelement described in the invention includes glutamic acid and copper, iron, manganese, zinc and cobalt The chelate of equal formation.Compared with other organic trace elements, glutamic acid microelement chelate has lower water-soluble, more Good fat-soluble and stronger acid resistance, thus can more be effectively ensured metallic element in vivo in the form of organic presence and by It absorbs, bioavilability obviously increases.Compared with inorganic microelement, the bioavilability of glutamic acid microelement chelate Height significantly reduces the discharge of ground inorganic microelement, alleviates breeding production to the adverse effect of environment；Nothing can be effectively reduced simultaneously Destruction of the machine microelement to nutrients such as vitamins.Glutamic acid microelement chelate has as animal feed additive Conducive to the cost of manufacture and environmental protection for reducing feed.

There are also " a kind of additive of compound feed for pig disclosed in Chinese patent (number of patent application 201711037489.X) And the preparation method and application thereof ", feed addictive includes following components and parts by weight content: 19-33 parts of plant extracts, yeast 5-7 parts of beta glucan, 1.52-4.06 parts of organic microelement chelate and 55.94-74.48 parts of carrier matrix；When preparation, first Stock, and carrier matrix is divided into carrier matrix A, carrier matrix B, after plant extracts is sieved later, it is added to carrier base It in matter A and the mixture of organic microelement chelate, and stirs evenly, adds yeast beta-dextran and carrier matrix B's Mixture stirs evenly；The feed addictive is added into the basal diet of pig, by weight percentage, feed adds The adding proportion for adding agent is 0.5-1.5%.Compared with prior art, which can significantly improve animal immunizing power, reduce hair Sick rate, substitute antibiotics and chemical synthesis class drug, improve safety and the meat taste of meat products, while can significantly promote dynamic Object growth and development improves efficiency of feed utilization.

There are also Chinese patent (number of patent application 201710003884.X) it is disclosed " composite additive of trace elements and its Using and pig's feed ", the invention provide a kind of composite additive of trace elements, mainly by inorganic microelement, You Jiwei Secondary element, phytase and filler material composition, inorganic and organic trace element is used cooperatively, and the absorption that can increase microelement is logical Road facilitates being absorbed and utilized for microelement；Meanwhile it being cooperateed with and being matched with inorganic microelement, organic trace element using phytase It closes, the generation for the complex compound that inorganic microelement and organic trace element are formed with phytic acid respectively can be effectively reduced, eliminate and plant The anti-oxidant action of acid discharges phosphorus and microelement in feed, so that the discharge of microelement reduces 30% or more, improves and raises Expect the digestive utilization ratio of various nutrition compositions；The invention additionally provides a kind of application of composite additive of trace elements, will be described Composite additive of trace elements is applied in pig's feed, can be effectively improved feed applications effect.

Summary of the invention

The purpose of the present invention is to provide a kind of micronutrient element absorptivity height, residuals less, environmental pollution after feeding The lower feed addictive of small and feeding cost, and preparation method is provided.

To achieve the above object, the technical solution adopted by the present invention is that inventing a kind of feed rich in organic trace element Additive is to be prepared from raw materials including the following parts by weight:

The technical solution that it optimizes is first is that be prepared from raw materials including the following parts by weight:

The technical solution that it optimizes is second is that be prepared from raw materials including the following parts by weight:

The technical solution that it optimizes is third is that be prepared from raw materials including the following parts by weight:

The organic metal microelement can be commercially available, and be also possible to be prepared by the following method: by tricyclic or Fourth Ring terpene carboxylic acid compound (such as carnosic acid) and metal trace element are (including one in iron, magnesium, aluminium, copper, barium, cobalt, strontium Kind or it is a variety of, when for two or more, the parts by weight such as the ratio of each component is) hydroxide fine powder (more than 100 mesh) massage The ratio mixing of your mass ratio 1:0.2-0.5, adds the surface for accounting for the hydroxide weight 0.2-0.8% of metal trace element Activating agent (dodecyldimethylamine base glycine betaine or dodecyldimethylammonium hydroxide inner salt) mixes again, and then, addition is equivalent to three Ring or Fourth Ring 2-4 times of weight of terpene carboxylic acid compound, the edible ethanol solution that volumetric concentration is 45-65%, stir process is to molten Liquid pH value is 6.5-7.5, and then via hole diameter 5-10 microns of filter membrane device filtering, obtains clarified solution；It is added and accounts for into clarified solution again The neutral sorbent of former tricyclic or Fourth Ring terpene carboxylic acid compound weight 0.3-0.75%, the stir process 1.5- at 45-55 DEG C 2.5h, then 0.1-0.5 microns of via hole diameter of filter membrane device filtering, obtain processing solution；Again by processing solution pressure 15-25KPa, It is 1.1-1.6mg/ml that solid object amount content is concentrated at 65-72 DEG C of temperature, obtains concentrate；Concentrate is transferred in freezer, 4-5h is handled in -4-0 DEG C of quiet put, the filter membrane device that then via hole diameter is 0.1-0.5 microns filters, and obtains processing solution；It again will be dense Contracting liquid is spray-dried to get organic metal microelement.

The organic iodine can be commercially available, and be also possible to be prepared by the following method: choose leaf width thickness, dark purple brown Kelp, with clear water rinse drying；Kelp is first processed into partial size in the slurry of 0.05-0.12cm through beater, adds and accounts for The ammonium citrate of its weight 0.15-0.35%, -5 phenyl amylalcohol of 3- methyl of 0.12-0.22%, 1.5-3.6% cellulose Enzyme is uniformly mixed, and stir process 10-16h is then sealed at 45-50 DEG C, ethyl alcohol is added later, and adjusting its alcoholic degree is 70- 78%, it is stirred for 10-20min, filtering (aperture is 300 mesh) obtains processing screenings；It again will the drying at 60-70 DEG C of processing screenings To moisture less than 10%, reprocessing is less than the powder of 0.05cm at partial size；Thereafter, clear water is added into powder, is adjusted to holding Powder can be agglomerating, adds di (isooctyl) phosphate, the 70- of the N530 extractant, 10-20% that account for former powder weight 10-18% The sodium chloride mixing of 80% sulfonated kerosene, 1.5-2.5% stirs evenly, and stir process 7-15h is sealed under room temperature, (aperture is for filtering 300 mesh), obtain processing material；Processing material is diluted to solid content 2.5-3.5mg/ml's with 28-35 DEG C of warm water again Powder liquid, and the glycosidase of the protease, 0.2-0.45% that account for former kelp weight 0.5-0.75% is added, in closed environment Processing 1-2 days, obtains enzymolysis liquid；The n-hexylamine for accounting for original powder end liquid weight 60-75%, 1-1.5 times of weight is added into enzymolysis liquid again N-butanol, stir evenly, be then heated to 50-65 DEG C, constant temperature processing 10-15h, then via hole diameter is 5-10 microns of filter membrane device mistake Filter, obtains enzymolysis processing powder；Enzymolysis processing powder is washed 2-3 times with 4-10 DEG C of cold water, is transferred in drying box, It dries to moisture less than 8% at 60-70 DEG C to get organic iodine.

The organic selenium can be commercially available, and be also possible to be prepared by the following method: the konjaku for pruning epidermis is passed through Beater is processed into the konjaku slurry that partial size is less than 0.2cm, then is added into konjaku slurry and accounts for konjaku slurry weight 1.5-2.6% Salt, the ginger slice of 10-18%, 50-65% vinegar (weight concentration 10-18%), the stir process at 40-50 DEG C 30-45min, filtering (aperture is 300-400 mesh), and ginger slice is removed, konjaku screenings must be handled；Konjaku screenings matter will be handled The ammonium sulfate solution that amount score is 4.2-5.5% dilutes its moisture content to 20-32%, adds and accounts for processing konjaku screenings weight The glycosidase of 1.5-2.5%, the amylolytic enzyme of 2.5-3.8% are measured, is sealed under room temperature stir process 1-2 days, presses 5-10 later DEG C/heating rate of min is heated to 50-60 DEG C, extrusion process, obtains slurry filter residue while hot；Again by slurry filter residue at 60-70 DEG C It is dry to be processed into the powder that partial size is less than 0.1cm less than 10%, then through homogenizer to moisture, then with 1-3 times of powder weight of boiling Water stirring and dissolving 2.5-3.5h, obtains water-soluble liquid；Water-soluble liquid is down to 35-45 DEG C again, while hot upper cellulose gel rubber column gel column, flow velocity Control is 5-10L/h, collects cellulose gel rubber column gel column upper prop liquid；Then, cellulose gel rubber column gel column upper prop liquid is down to room temperature, the Portugal Zai Shang Polysaccharide gel column, flow control 4-8L/h collect sephadex column upper prop liquid；Sephadex column upper prop liquid is being pressed again Power 10-15KPa, the upper prop concentrate that solid content is 1.2-1.6mg/ml is concentrated at 60-70 DEG C of temperature；Thereafter, upwards The sulfonation of the di (isooctyl) phosphate, 70-80% of the N530 extractant, 10-20% that account for its weight 10-18% is added in column concentrate The sodium chloride of kerosene, 1.5-2.5%, mixing stir evenly, and stir process 7-15h is sealed under room temperature, and stratification collects aqueous solution； Aqueous solution is concentrated into the processing that solid content is 2.0-2.8mg/ml again to be concentrated at pressure 5-10KPa, 70-85 DEG C of temperature Liquid, then edible ethanol is added into processing concentrate and adjusts its alcoholic degree to 70% or more, be then transferred in freezer (temperature is- 4-0 DEG C) it is quiet put to no Precipitation, precipitating is collected in filtering；Precipitating be dry, pulverize into (granularity is 80 mesh or more) to get having again Machine selenium.

The apple powder can be commercially available, and be also possible to be prepared by the following method: immature green apple is washed Net peeling, through extrusion process, collects the apple juice filtered out；The acetic acid for accounting for its weight 10-15% is put into apple juice again The zinc chloride of sodium, 0.6-1.5% seals stir process extremely at 50-65 DEG C of temperature, and filtering (aperture is 10-20 microns) is collected Cider handles filtrate；Cider processing filtrate is adjusted into its alcoholic degree to 70% or more with ethyl alcohol again, it is then quiet to put to no precipitating It is precipitated, alcohol tune filtrate is collected in filtering；Alcohol tune filtrate is 8-12KPa, is concentrated into no alcohol at 50-65 DEG C of temperature in pressure again, is obtained Cider concentrate；Again by cider concentrate through drying, crush (granularity be 80 mesh or more) to get apple powder.

At the same time, a kind of preparation method of feed addictive rich in organic trace element, preparation process are also provided It is as follows:

(1), stock up: taking organic iodine, apple powder, tea polyphenols, organic selenium, sucrose ester, glucose, hard respectively by weight ratio Resin acid calcium, sodium chloride, anthocyanidin, fatty acid glyceride, chitosan, galactomannans and organic metal microelement, it is spare；

(2), crush: by organic iodine, organic selenium, organic metal microelement, tea polyphenols, apple powder, anthocyanidin, stearic acid It is micro less than the organic iodine nano powder of 20nm, organic selenium nano, organic metal that calcium is processed into partial size through micronizer respectively Element nano powder, tea polyphenol nano powder, apple nano powder, anthocyanidin nano powder, calcium stearate nano powder, it is spare；

(3), coating powder preparation soluble in the stomach: being first the viscous of 60-75% with the mass concentration that warm water is dissolved into glucose by glucose Thick liquid glucose, then organic metal microelement nano powder, tea polyphenol nano powder, anthocyanidin nano powder, sucrose ester are sequentially added, Side edged stirs, and stirring rate control is 200-300r/min, and uniform liquid glucose microballoon is made；Then it is mixed with stomach dissolution type coating agent It stirs evenly, through drying, crushes (granularity is 80 mesh or more), coating powder soluble in the stomach is made, it is spare；

(4), prepared by enteric coating powder: it is 55- that chitosan and galactomannans, which are first brewed into mass concentration with warm water, 68% thick liquid, then by organic iodine nano powder, organic selenium nano, apple nano powder, sodium chloride, calcium stearate nanometer Powder, fatty acid glyceride are sequentially added, and stir evenly, and transfer in the oscillator that frequency is 500-800Hz and handle 10-18min, Uniform sticky microballoon is made；Then it mixes and stirs evenly with enteric solubility coating membrane, through drying, crush (granularity is 80 mesh or more), system It is spare at enteric coating powder；

(5), mix: coating powder soluble in the stomach and enteric coating powder being mixed to get the feed addition of organic trace element is rich in Agent.

Feed addictive rich in organic trace element of the invention has the following characteristics that compared with existing similar product

First is that organic trace element used carries out processing preparation using the active constituent in plant, safety absorbs height Effect, had not only been able to satisfy the growth demand of animal, but also can reduce residual, reduce environmental pollution.

Second is that taking different Cotton seeds, by targeted Cotton seeds, microelement is avoided because of environment Factor changes and rotten or oxidation risk；After feeding, energy efficient-decomposition, release absorbs, and obtains limited microelement sufficiently To utilization, feed throwing amount and aquaculture cost are reduced.

Third is that other compositions, such as tea polyphenols, apple powder, anthocyanidin liposoluble ingredient, it can adsorb and not digest and assimilate Heavy metal, the excretion for reducing heavy metal, and antibacterial can be played a dual role of to body, improve immunity；Sucrose ester with it is sweet Oil and fat acid esters plays the role of surfactant, keeps the ingredient coefficient of dispersion high；Glucose, chitosan and galactomannans rise To the effect of crosslinking agent, it polymerize material, is convenient for subsequent operation；Calcium stearate and sodium chloride improve intestines peristalsis etc.；It is organic Iodine and organic selenium exist in the form of natural amino acid polymer；Organic metal microelement exists with carboxylate form, into It is decomposed after entering stomach through slightly sour effect, antibacterial can be played in gastrointestinal tract by forming carboxylic acid compound and metal ion, carboxylic acid compound Effect, while can also be absorbed and used, it can also adsorb indigested heavy metal；It is of the invention rich in organic trace element to make Feed addictive it is more scientific and reasonable.

Following table 1 be the pannage of the addition feed addictive rich in organic trace element of the invention (hereinafter referred to as " adding pannage of the invention ") with addition normal diet additive pannage (hereinafter referred to as " common pannage ") raising Check experiment data:

Table 1: raising check experiment tables of data

(note: adding pannage of the invention, and basic pannage is identical as the common pannage of control, and two kinds of feedings The type of microelement and total content are essentially identical in material additive used, and the physiological status of piglet is essentially identical, feeding side Formula is essentially identical)

It can be seen that from the data of table 1 above using pannage raising domestic animal pig of the invention is added, due to the use of its feed Amount is reduced, the reduction of the expenses for prevention and control of swine disease in addition, thus, the profit of raising has reached 9.21 raised with common pannage Times.

Following table 2 is microelement in excrement caused by the raising of addition pannage Yu common pannage of the invention The residual quantity table of comparisons:

Table 2: the residual quantity table of comparisons (being calculated with per kilogram) of microelement in excrement

It can be seen that from the data of table 2 above in excrement caused by the pannage raising domestic animal pig of the invention using addition, The residual quantity of microelement is significantly compared with the residual quantity using microelement in excrement caused by common pannage raising domestic animal pig It reduces.

Specific embodiment

With reference to embodiments, the present invention is further illustrated.Following explanation be by the way of enumerating, but this The protection scope of invention should not be limited to thoses mentioned above.

Embodiment 1:

The feed addictive rich in organic trace element of the present embodiment, preparation process are as follows:

(i), pretreatment of raw material:

(1), organic metal microelement pre-processes: by carnosic acid and metal trace element (including equivalent weight part Iron, magnesium, aluminium, copper, barium, cobalt, strontium) hydroxide fine powder (more than 100 mesh) in mole mass ratio 1:0.35 ratio mix, then The 3 dodecyldimethylamine base glycine betaines that the hydroxide weight 0.2-0.8% for accounting for metal trace element is added mix again, so Afterwards, it is added and is equivalent to 3 times of weight of carnosic acid, the edible ethanol solution that volumetric concentration is 55%, stir process to solution ph For 7.0, (with the increase of concentration of alcohol, the meltage of carnosic acid increases, and increases with the reacting dose of hydroxide, therefore its pH value Can reduce, so that its pH value be made to be adjusted), then via hole diameter 5-10 microns of filter membrane device filtering, obtains clarified solution；Again to clear The neutral sorbent (silica decoloration sand) for accounting for former carnosic acid weight 0.3-0.75%, the stir process at 50 DEG C are added in clear liquid 2.0h, then 0.3 micron of via hole diameter of filter membrane device filtering, obtain processing solution；Again by processing solution in pressure 20KPa, temperature 68 It is 1.4mg/ml that solid object amount content is concentrated at DEG C, obtains concentrate；Concentrate is transferred in freezer, quiet puts processing at -2 DEG C 5h, the filter membrane device that then via hole diameter is 0.3 micron filter, and obtain processing solution；It is again that concentrate is spray-dried to get organic Metal trace element.

(2), organic iodine pre-processes: choosing the kelp of thick, the dark purple brown of leaf width, rinses drying with clear water；First kelp is beaten Pulp grinder is processed into partial size in the slurry of 0.05-0.12cm, adds the 3- first of the ammonium citrate, 0.16% that account for its weight 0.25% - 5 phenyl amylalcohol of base, 2.5% cellulase, be uniformly mixed, then at 48 DEG C seal stir process 13h, second is added later Alcohol, adjusting its alcoholic degree is 75%, is stirred for 15min, and filtering (aperture is 300 mesh) obtains processing screenings；Screenings will be handled again 65 It dries to moisture at DEG C less than 10%, then is processed into the powder that partial size is less than 0.05cm through homogenizer；Thereafter, it is added into powder Clear water, being adjusted to holding powder can be agglomerating, and the di(2-ethylhexyl)phosphate for adding the N530 extractant, 15% that account for former powder weight 15% is different pungent Ester, 75% sulfonated kerosene, the mixing of 2.0% sodium chloride stir evenly, and stir process 12h is sealed under room temperature, filters (aperture 300 Mesh), obtain processing material；Processing material is diluted to solid content in the powder liquid of 3.0mg/ml with 32 DEG C of warm water again, and The glycosidase of the protease, 0.35% that account for former kelp weight 0.65% is added, is handled 2 days in closed environment, obtains enzymolysis liquid； The n-butanol of the n-hexylamine, 1.2 times of weight that account for original powder end liquid weight 68% is added into enzymolysis liquid again, stirs evenly, then by 3 DEG C/ The heating rate of min is heated to 58 DEG C, constant temperature processing 12h, then the filter membrane device that via hole diameter is 8 microns filters, and obtains enzymolysis processing Powder；Enzymolysis processing powder is washed 3 times with 8 DEG C of cold water, is transferred in drying box, dries at 65 DEG C to moisture and is less than 8% to get organic iodine (organoiodine compound content is 5% or more).

(3), organic selenium pre-processes: the konjaku for pruning epidermis being processed into konjaku of the partial size less than 0.2cm through beater and is starched Material, then be added into konjaku slurry and to account for the salt, 15% ginger slice, 58% vinegar of konjaku slurry weight 2.0% (weight is dense Degree must handle konjaku slurry for 15%), the stir process 40min at 45 DEG C filters (aperture is 350 mesh), and removes ginger slice Slag；Konjaku screenings will be handled and dilute its moisture content to 25% with the ammonium sulfate solution that mass fraction is 4.8%, add and account for 2.0% glycosidase of konjaku screenings weight, 3.2% amylolytic enzyme are handled, is sealed under room temperature stir process 2 days, presses 8 later DEG C/heating rate of min is heated to 55 DEG C, extrusion process, obtains slurry filter residue while hot；Slurry filter residue is dried extremely at 65 DEG C again Moisture is processed into the powder that partial size is less than 0.1cm less than 10%, then through homogenizer, then molten with 2 times of powder weight of boiling water stirring 3.0h is solved, water-soluble liquid is obtained；Water-soluble liquid is down to 40 DEG C again, upper cellulose gel rubber column gel column, flow control 8L/h are collected while hot Cellulose gel rubber column gel column upper prop liquid；Then, cellulose gel rubber column gel column upper prop liquid is down to room temperature, then upper sephadex column, flow velocity control It is made as 6L/h, collects sephadex column upper prop liquid；Again by sephadex column upper prop liquid at pressure 12KPa, 65 DEG C of temperature It is concentrated into the upper prop concentrate that solid content is 1.4mg/ml；Thereafter, it is added into upper prop concentrate and accounts for its weight 15% N530 extractant, 15% di (isooctyl) phosphate, 75% sulfonated kerosene, 2.0% sodium chloride, mixing stirs evenly, close under room temperature Stir process 12h is sealed, stratification collects aqueous solution；Aqueous solution is concentrated into solid content at pressure 8KPa, 78 DEG C of temperature again Content is the processing concentrate of 2.5mg/ml, then edible ethanol is added into processing concentrate and adjusts its alcoholic degree to 70% or more, It is then transferred in freezer that (temperature be -4-0 DEG C) is quiet to put to no Precipitation, precipitating is collected in filtering；Drying, powder will be precipitated again Broken (granularity is 80 mesh or more) is to get organic selenium (organic selenium compounds content is 10% or more).

(4), apple powder pre-processes: by immature green apple, cleaning peeling, through extrusion process, collects the cider filtered out Liquid；The zinc chloride for putting into the sodium acetate, 1.0% that account for its weight 12% into apple juice again, seals stirring under temperature 60 C Processing is to no zinc ion residual (zinc ion can be reacted with the acid in apple juice, produce complex compound), and (aperture is for filtering 15 microns), it collects cider and handles filtrate；Again to 70% or more, then cider processing filtrate is adjusted into its alcoholic degree with ethyl alcohol Quiet to put to no Precipitation, alcohol tune filtrate is collected in filtering；Alcohol tune filtrate is concentrated into the case where pressure is 10KPa, temperature 60 C again Without alcohol, cider concentrate is obtained；Again by cider concentrate through drying, crush (granularity be 80 mesh or more) to get apple powder.

(ii), stock up:

According to parts by weight, 20 parts of organic iodine, 2 parts of apple powder, 5 parts of tea polyphenols, 30 parts of organic selenium, sucrose ester 0.5 are taken respectively Part, 7 parts of glucose, 0.5 part of calcium stearate, 0.5 part of sodium chloride, 3 parts of anthocyanidin, 1.5 parts of fatty acid glyceride, 3 parts of chitosan, 2 parts of galactomannans, 20 parts of organic metal microelement, it is spare；

(iii), crush: by organic iodine, organic selenium, organic metal microelement, tea polyphenols, apple powder, anthocyanidin, stearic acid It is micro less than the organic iodine nano powder of 20nm, organic selenium nano, organic metal that calcium is processed into partial size through micronizer respectively Element nano powder, tea polyphenol nano powder, apple nano powder, anthocyanidin nano powder, calcium stearate nano powder, it is spare；

(iv), coating powder preparation soluble in the stomach: being first the viscous of 60-75% with the mass concentration that warm water is dissolved into glucose by glucose Thick liquid glucose, then organic metal microelement nano powder, tea polyphenol nano powder, anthocyanidin nano powder, sucrose ester are sequentially added, Side edged stirs, and stirring rate control is 250r/min, and uniform liquid glucose microballoon is made；Then it mixes and stirs with stomach dissolution type coating agent It is even, through drying, (granularity is 80 mesh or more) is crushed, coating powder soluble in the stomach is made, it is spare；

(v), prepared by enteric coating powder: it is 55- that chitosan and galactomannans, which are first brewed into mass concentration with warm water, 68% thick liquid, then by organic iodine nano powder, organic selenium nano, apple nano powder, sodium chloride, calcium stearate nanometer Powder, fatty acid glyceride are sequentially added, and stir evenly, and transfer in the oscillator that frequency is 650Hz and handle 15min, are made Even sticky microballoon；Then it mixes and stirs evenly with enteric solubility coating membrane, through drying, crush (granularity is 80 mesh or more), manufactured intestines Molten coating powder, it is spare；

(vi), mix: coating powder soluble in the stomach and enteric coating powder being mixed to get the feed addition of organic trace element is rich in Agent.

It is rich in the feed addictive of organic trace element prepared by the present embodiment, uses and common feed addictive Equally.

Embodiment 2:

The feed addictive rich in organic trace element of the present embodiment, preparation process are as follows:

(ii), stock up:

According to parts by weight, 30 parts of organic iodine, 4 parts of apple powder, 3 parts of tea polyphenols, 20 parts of organic selenium, sucrose ester 1.5 are taken respectively Part, 5 parts of glucose, 1 part of calcium stearate, 1 part of sodium chloride, 1 part of anthocyanidin, 0.5 part of fatty acid glyceride, 1 part of chitosan, gala 4 parts of mannosan, 30 parts of organic metal microelement, it is spare；

Other steps are same as Example 1.

Embodiment 3:

The feed addictive rich in organic trace element of the present embodiment, preparation process are as follows:

(ii), stock up:

According to parts by weight, 25 parts of organic iodine, 3 parts of apple powder, 4 parts of tea polyphenols, 25 parts of organic selenium, sucrose ester 1.0 are taken respectively Part, 6 parts of glucose, 0.8 part of calcium stearate, 0.8 part of sodium chloride, 2 parts of anthocyanidin, 1.0 parts of fatty acid glyceride, 2 parts of chitosan, 3 parts of galactomannans, 25 parts of organic metal microelement, it is spare；

Other steps are same as Example 1.

Feed addictive rich in organic trace element of the invention is suitable for including the commodity such as clay fertilizer pig and bacon hogs Pig breeding feed addition, it can also be used to chicken and duck feed.

Claims (9)

1. a kind of feed addictive rich in organic trace element, which is characterized in that be by the raw material system including following parts by weight It is standby to form:

2. being rich in the feed addictive of organic trace element according to claim 1, which is characterized in that be by including following heavy The raw material of amount part is prepared:

3. being rich in the feed addictive of organic trace element according to claim 1, which is characterized in that be by including following heavy The raw material of amount part is prepared:

4. being rich in the feed addictive of organic trace element according to claim 1, which is characterized in that be by including following heavy The raw material of amount part is prepared:

5. being rich in the feed addictive of organic trace element according to claim 1, which is characterized in that the organic metal is micro- Secondary element is to be prepared by the following method: by tricyclic or the hydroxide of Fourth Ring terpene carboxylic acid compound and metal trace element Fine powder is mixed in the ratio of mole mass ratio 1:0.2-0.5, adds the hydroxide weight 0.2- for accounting for metal trace element 0.8% surfactant mixes again, and then, addition is equivalent to tricyclic or Fourth Ring 2-4 times of weight of terpene carboxylic acid compound, body Product concentration be 45-65% edible ethanol solution, stir process to solution ph be 6.5-7.5, then via hole diameter 5-10 microns Filter membrane device filtering, obtain clarified solution；It is added again into clarified solution and accounts for former tricyclic or Fourth Ring terpene carboxylic acid compound weight 0.3- 0.75% neutral sorbent, the stir process 1.5-2.5h at 45-55 DEG C, then 0.1-0.5 microns of via hole diameter of filter membrane device Filtering, obtains processing solution；Processing solution is concentrated into solid object amount content at pressure 15-25KPa, 65-72 DEG C of temperature again is 1.1-1.6mg/ml obtaining concentrate；Concentrate is transferred in freezer, handles 4-5h in -4-0 DEG C of quiet put, then via hole diameter is 0.1-0.5 microns of filter membrane device filtering, obtains processing solution；It is again that concentrate is spray-dried to get the micro member of organic metal Element.

6. according to claim 1 be rich in organic trace element feed addictive, which is characterized in that the organic iodine be by Following methods are prepared: kelp being processed into partial size in the slurry of 0.05-0.12cm, adds and accounts for its weight 0.15- 0.35% ammonium citrate, -5 phenyl amylalcohol of 3- methyl of 0.12-0.22%, 1.5-3.6% cellulase, be uniformly mixed, Then stir process 10-16h is sealed at 45-50 DEG C, ethyl alcohol is added later, and adjusting its alcoholic degree is 70-78%, is stirred for 10- 20min, filtering, obtains processing screenings；Processing screenings is dried to moisture at 60-70 DEG C less than 10% again, is reprocessed into partial size Powder less than 0.05cm；Thereafter, clear water is added into powder, being adjusted to holding powder can be agglomerating, adds and accounts for original powder end weight Measure the N530 extractant of 10-18%, the di (isooctyl) phosphate of 10-20%, 70-80% sulfonated kerosene, 1.5-2.5% chlorination Sodium mixing stirs evenly, and stir process 7-15h is sealed under room temperature, and filtering obtains processing material；Temperature of the material with 28-35 DEG C will be handled again Water is diluted to solid content in the powder liquid of 2.5-3.5mg/ml, and the protein for accounting for former kelp weight 0.5-0.75% is added The glycosidase of enzyme, 0.2-0.45% handles 1-2 days in closed environment, obtains enzymolysis liquid；It is added again into enzymolysis liquid and accounts for original powder end The n-butanol of the n-hexylamine of liquid weight 60-75%, 1-1.5 times of weight, stirs evenly, and is then heated to 50-65 DEG C, constant temperature processing 10- 15h, then the filter membrane device that via hole diameter is 5-10 microns filter, and obtain enzymolysis processing powder；By enzymolysis processing powder with 4-10 DEG C Cold water washs 2-3 times, transfers in drying box, dries to moisture less than 8% at 60-70 DEG C to get organic iodine.

7. according to claim 1 be rich in organic trace element feed addictive, which is characterized in that the organic selenium be by Following methods are prepared: the konjaku for pruning epidermis being processed into the konjaku slurry that partial size is less than 0.2cm, then into konjaku slurry The vinegar for accounting for the salt of konjaku slurry weight 1.5-2.6%, the ginger slice of 10-18%, 50-65% is added, is stirred at 40-50 DEG C Processing 30-45min, filtering are mixed, and removes ginger slice, konjaku screenings must be handled；It is with mass fraction by processing konjaku screenings The ammonium sulfate solution of 4.2-5.5% dilutes its moisture content to 20-32%, adds and accounts for processing konjaku screenings weight 1.5- The amylolytic enzyme of 2.5% glycosidase, 2.5-3.8% seals stir process 1-2 days under room temperature, is heated to 50-60 later DEG C, extrusion process, obtains slurry filter residue while hot；Slurry filter residue is dried to moisture at 60-70 DEG C less than 10%, then through homogeneous again Machine be processed into partial size be less than 0.1cm powder, then use 1-3 times of powder weight of boiling water stirring and dissolving 2.5-3.5h, obtain water dissolve Liquid；Water-soluble liquid is down to 35-45 DEG C again, upper cellulose gel rubber column gel column, collects cellulose gel rubber column gel column upper prop liquid while hot；Then, will Cellulose gel rubber column gel column upper prop liquid is down to room temperature, then upper sephadex column, collects sephadex column upper prop liquid；Again by glucan Gel column upper prop liquid is concentrated into the upper prop that solid content is 1.2-1.6mg/ml at pressure 10-15KPa, 60-70 DEG C of temperature Concentrate；Thereafter, into upper prop concentrate be added account for its weight 10-18% N530 extractant, the di(2-ethylhexyl)phosphate of 10-20% it is different pungent Ester, the sulfonated kerosene of 70-80%, 1.5-2.5% sodium chloride, mixing stirs evenly, and stir process 7-15h is sealed under room temperature, stands Aqueous solution is collected in layering；It is 2.0- that aqueous solution is concentrated into solid content at pressure 5-10KPa, 70-85 DEG C of temperature again The processing concentrate of 2.8mg/ml, then edible ethanol is added into processing concentrate and adjusts its alcoholic degree to 70% or more, then turn Move to quiet in freezer put to no Precipitation, filtering, collection precipitating；Precipitating dry, pulverize to get organic selenium again.

8. according to claim 1 be rich in organic trace element feed addictive, which is characterized in that the apple powder be by Following methods are prepared: by green apple, through extrusion process, collecting the apple juice filtered out；It puts into and accounts for into apple juice again The zinc chloride of the sodium acetate of its weight 10-15%, 0.6-1.5% seals stir process to no zinc ion at 50-65 DEG C of temperature Residual, filtering collect cider and handle filtrate；Cider processing filtrate is adjusted into its alcoholic degree to 70% or more, so with ethyl alcohol again Quiet afterwards to put to no Precipitation, alcohol tune filtrate is collected in filtering；It is again 8-12KPa, 50-65 DEG C of temperature in pressure by alcohol tune filtrate Under be concentrated into no alcohol, obtain cider concentrate；Again by cider concentrate through drying, crush to get apple powder.

9. a kind of preparation method of the feed addictive as described in any one of claim 1-8 rich in organic trace element, It is characterized in that, preparation process is as follows:

(1), stock up: taking organic iodine, apple powder, tea polyphenols, organic selenium, sucrose ester, glucose, stearic acid respectively by weight ratio Calcium, sodium chloride, anthocyanidin, fatty acid glyceride, chitosan, galactomannans and organic metal microelement, it is spare；

(2), crush: by organic iodine, organic selenium, organic metal microelement, tea polyphenols, apple powder, anthocyanidin, calcium stearate point Organic iodine nano powder, organic selenium nano, the organic metal microelement that partial size is less than 20nm are not processed into through micronizer Nano powder, tea polyphenol nano powder, apple nano powder, anthocyanidin nano powder, calcium stearate nano powder, it is spare；

(3), coating powder preparation soluble in the stomach: the sticky sugar for being first 60-75% with the mass concentration that warm water is dissolved into glucose by glucose Liquid, then organic metal microelement nano powder, tea polyphenol nano powder, anthocyanidin nano powder, sucrose ester are sequentially added, Bian Jia While stirring, uniform liquid glucose microballoon is made；Then it mixes and stirs evenly with stomach dissolution type coating agent, through drying, crush, coating soluble in the stomach is made Powder, it is spare；

(4), prepared by enteric coating powder: it is 55-68%'s that chitosan and galactomannans, which are first brewed into mass concentration with warm water, Thick liquid, then by organic iodine nano powder, organic selenium nano, apple nano powder, sodium chloride, calcium stearate nano powder, glycerol Aliphatic ester is sequentially added, and stirs evenly, and transfers to and handles 10-18min in oscillator, and uniform sticky microballoon is made；Then It mixes and stirs evenly with enteric solubility coating membrane, through drying, crush, enteric coating powder is made, it is spare；(5), mix: by coating powder soluble in the stomach and Enteric coating powder mixes to be rich in the feed addictive of organic trace element.