CN108998279A - A kind of handguard type dish washing liquid - Google Patents
A kind of handguard type dish washing liquid Download PDFInfo
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- CN108998279A CN108998279A CN201811013588.9A CN201811013588A CN108998279A CN 108998279 A CN108998279 A CN 108998279A CN 201811013588 A CN201811013588 A CN 201811013588A CN 108998279 A CN108998279 A CN 108998279A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
Abstract
The invention discloses a kind of handguard type dish washing liquids, belong to articles for washing technical field.The present invention is using coconut kind skin as raw material, through isopropyl alcohol extracting grease therein, adds xylose and lauric acid carries out sugar ester synthetic reaction, molecular sieve is added and keeps the activity of enzyme that can preferably dissolve grease.The present invention is using alpha-chloro tetradecylic acid and methylamine water solution as raw material; by aminolysis reaction, intermediate product is obtained, has both had long chain lipid lipophilic; it is again amphipathic with amino acid; the present invention adds extract solution from aloe with tartaric acid, sodium tartrate, forms pH buffer system; increase the protecting effect of opponent; the natural antimicrobial substances such as wormwood and cortex cinnamomi are added simultaneously, the bacteria breed after preventing cleaning forms antimicrobial protection.The present invention solves current dish washing liquid opponent and be easy to cause injury, the big problem of irritation.
Description
Technical field
The invention belongs to articles for washing technical fields, and in particular to a kind of handguard type dish washing liquid.
Background technique
Dish washing liquid is daily cleaning articles, has the characteristics that cleaning is mild, foam is soft and fine, can decompose rapidly greasy, quick
Decontamination and degerming, effectively cleaning do not remain, and wash rear pure white light as new, and general dish washing liquid distributes simple and elegant fruit flavor, is
The indispensable articles for washing of biology at home.With the development of science and technology, people's lives level is continuously improved, sanitation and hygiene meaning
Knowledge is also increasingly enhanced.In daily life, people commonly use commercially available dish washing liquid cleaning tableware, melon fruits and vegetables and birds, beasts and eggs etc., are removed with reaching
Dirt and the residual purpose of agriculture are removed, more stringent requirements are proposed to detergent especially dish washing liquid by people, not only requires dirt-removing power
By force, and it is also desirable to have effect highly-safe, that bactericidal effect is good, nonirritant.
Dish washing liquid main component is surfactant, and decontamination principle is very simple, it contains a variety of active ingredients, emulsifier,
These ingredients suspend to various greasy spots, harmful substance dissolution, emulsification, dispersion, and subsequent clear water rinsing is separated from tableware surface
It goes out, achievees the effect that clean tebleware；Also containing the ingredient of sterilization in certain dish washing liquids, can remove be harmful to the human body it is micro-
Biology, prevents that illness finds its way in by the mouth.
Currently, the mainly LAS-AES system of dish washing liquid, sodium alkyl sulfonate and fatty alcohol-ether sodium sulfate are current dish washing liquids
Main component, cost is relatively low while having ideal cleaning effect, thus using relatively broad.The system is washed
Clean essence, there is a two aspect problems in the process of cleaning: first, be it is effective to the cleaning capacity of stain, need by physics side
Method handles residual stains in advance, is then cleaned again with dish washing liquid, directly cleans, and cleaning completeness is poor, easily remains, with washing
The use of clean essence brings inconvenience.Second, existing dish washing liquid is added in component into preservative, and preservative easily remains, to human body
It damages.
Common dish washing liquid on the market at present, some do not have antibacterial functions, and some makees hand skin irritant
With wash residue is easy to do harm to huamn body.For above situation, it is clean that a kind of washing for the small handguard type of irritation need to be developed
Essence.
Summary of the invention
The technical problems to be solved by the invention: it is be easy to cause injury for current dish washing liquid opponent, irritation is big to ask
Topic, provides a kind of handguard type dish washing liquid.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of handguard type dish washing liquid, including following component, 5 ~ 8 parts of antibacterial activity agent, 2 ~ 4 parts of dodecyl benzene sulfonic acid, 1 ~ 5 part of rouge
Fat alcohol polyoxyethylene ether sulfate, 2 ~ 5 parts of olive oleates, 200 ~ 300 parts of water, further include 20 ~ 30 portions of decontamination activating agents that deoil,
5 ~ 10 parts of handguard additives that deoil, 40 ~ 50 parts of buffering aids；
The preparation method of the decontamination activating agent that deoils, includes the following steps:
S1. it takes coconut to split, collects the brown coconut kind skin being attached on coconut meat, dry, pulverize 80 meshes, collect sieving
Grain takes sieving particle 1 ~ 3:5 in mass ratio ~ 9 that isopropanol ultrasound is added, keeps the temperature, filters, take smoke filtrate rotary evaporation, must rotate
Evaporant；
S2. it takes 3A molecular sieve to activate in 200 ~ 250 DEG C, obtains activator 1 ~ 5:7 in mass ratio ~ 10 and acetone is added, stand, filtering,
Filter residue rotary evaporation is taken, it is dry, dried object is obtained, takes xylose 4 ~ 6:1 in mass ratio ~ 3 that lauric acid mixing is added, obtains mixture, press
Mass fraction meter takes 200 ~ 500 parts of mixtures, 80 ~ 120 parts of rotary evaporation objects, 15 ~ 20 parts of dried objects, 0.2 ~ 0.4 part
Novozym435 lipase, 600 ~ 700 parts of isopropanol mixing, vibrate, enzyme deactivation in 50 ~ 55 DEG C, 150r/min, and filtering takes filtrate,
Deoil decontamination activating agent to obtain the final product.
Isopropanol ultrasound, heat-retaining condition are added in the step S1 are as follows: in 20W 5 ~ 10min of ultrasound, protect then at 55 ~ 60 DEG C
3 ~ 5h of temperature.
The preparation method of the handguard additive that deoils, includes the following steps:
(1) take alpha-chloro tetradecylic acid 1 ~ 3:5 in mass ratio ~ 10 be added first ammonia spirit, add first ammonia spirit quality 20 ~
30% deionized water is stirred, then is warming up to 95 ~ 100 DEG C, and 4 ~ 8h is kept the temperature in oil bath, is cooled to room temperature, rotary evaporation,
PH to 6 ~ 7 is adjusted, rotary evaporation object a is obtained, the ethyl alcohol stirring for taking rotary evaporation object a 1 ~ 4:7 in mass ratio ~ 10 that pH3.0 is added is mixed
It closes, filtering takes filter residue rotary evaporation, and it is dry, obtain dried object a；
(2) it takes dried object a to grind, sieves with 100 mesh sieve, collect sieving particle, sieving particle 1 ~ 5:10 ~ 15 in mass ratio is taken to add
Enter dehydrated alcohol heat preservation, be cooled to room temperature, obtain cooled material, takes cooled material 80 ~ 100:13 in mass ratio ~ 18 that hydrochloric acid stirring is added mixed
Close, rotary evaporation is dry, obtains dried object b, takes dried object b 1 ~ 3:5 in mass ratio ~ 9 that ethyl acetate is added, and stands, take precipitating by
Deionized water is added in 1 ~ 3:7 of mass ratio ~ 10, extracts through anhydrous ether, takes extract liquor to get the handguard additive that deoils.
The stirring of the deionized water for the first ammonia spirit quality 20 ~ 30% that mass fraction is 33% is added in the step (1)
Mixing condition are as follows: be warming up to 65 ~ 75 DEG C and be stirred 12 ~ 15h.
The heat-retaining condition of dehydrated alcohol is added in the step (2) are as follows: be warming up to 210 ~ 220 DEG C of 3 ~ 6h of heat preservation.
The buffering aids: it takes tartaric acid 1:1 in mass ratio that sodium tartrate is added, is stirred 30 ~ 40min, must mix
Object takes mixture 1 ~ 3:20 in mass ratio ~ 30 that aloe extract mixing is added to get buffering aids.
The antibacterial activity agent: take wormwood extract 3 ~ 5:1 in mass ratio ~ 3 be added cinnamomum cassia extract mixing to get.
The present invention is compared with other methods, and advantageous effects are:
(1) present invention is using coconut kind skin as raw material, through isopropyl alcohol extracting grease therein, adds xylose and lauric acid carries out sugar
Lipase is added in ester synthesis reaction, improves esterification transformation efficiency, while the activity that molecular sieve keeps enzyme is added, and utilizes enzyme process height
Synthesis obtains the decontamination activating agent that deoils, the surfactant short as hydrophobic chain, it have faster diffusion rate and
In the ability that the surface of solids aligns, the surface that wetting can be made newborn, which quickly reaches, should minimum tension value, when shortening wetting
Between, hydrophobic group chain makes the Interaction enhanced of surface layer binding molecule, so that the solution layer under surface layer is not easy to flow away, makes its bubble
The enhancing of foam stability, can preferably dissolve grease, while selected advantages of nontoxic raw materials, environmentally friendly degradable, the unsaturation in cocounut oil
Some active materials such as fatty acid, L-arginine, opponent can form protection, not stimulate skin；
(2) present invention, by aminolysis reaction, obtains intermediate product as raw material using alpha-chloro tetradecylic acid and methylamine water solution, then passes through
High temperature decarboxylation is heated, hydrochloric acid is added to be acidified, amino fat acid hydrochloride class is formed and deoils handguard additive, both there is long chain lipid
Lipophilicity, but it is amphipathic with amino acid, and hydrophobic end directs at remaining meal grease, is dissolved, and amino acid end proposes hand skin
For skin immune function controlling, moisture, soda acid, Sage Extract are adjusted, has the antiallergic ability for improving sensitive, prevents the hair of wrinkle
It is raw, reduce the stimulation in washing process, forms protection；
(3) present invention adds extract solution from aloe with tartaric acid, sodium tartrate, forms pH buffer system, and the pH value of application on human skin is logical
It is often about 4.5 ~ 6.5, average value 5.75 is weakly acidic, weak containing organic acid such as succinic acid, succinic acid etc. in extract solution from aloe
Acid is compounded, and is on the one hand played buffer function to the alkaline decontamination surfactant that deoils, is prevented alkaline matter to skin
Damage, on the other hand allows the nutriments such as aloe to be absorbed by skin under weakly acidic condition, has the function that skin nutrition, due to
It is added into the decontamination activating agent that deoils in aloe weak acid buffer solution, keeps the surface tension of aloe weak acid buffer solution lower, aloe
Weak acid buffer solution opponent generates wetting, with the gradually evaporation of hand moisture after washing, weak acid material molecule and hand skin
Between be mutually bonded, weak acid substance be adsorbed on watch face formed weak acid coating, formed moisturizing film layer, increase opponent protection effect
Fruit, while the natural antimicrobial substances such as wormwood and cortex cinnamomi are added, the bacteria breed after preventing cleaning forms antimicrobial protection.
Specific embodiment
Deoil decontamination activating agent: S1. takes coconut to split, and collects the brown coconut kind skin being attached on coconut meat, dry, pulverize
80 meshes are crossed, sieving particle is collected, take sieving particle 1 ~ 3:5 in mass ratio ~ 9 that isopropanol is added, in 20W 5 ~ 10min of ultrasound, then
In 55 ~ 60 DEG C of 3 ~ 5h of heat preservation, filters, take smoke filtrate rotary evaporation, obtain rotary evaporation object；
S2. 3A molecular sieve is taken in 200 ~ 250 DEG C of 4 ~ 6h of activation, obtains activator 1 ~ 5:7 in mass ratio ~ 10 and acetone is added, stand 24 ~
48h, filtering, takes filter residue rotary evaporation, dry, obtains dried object, takes xylose 4 ~ 6:1 in mass ratio ~ 3 that lauric acid mixing is added, obtains
Mixture, according to the mass fraction, take 200 ~ 500 parts of mixtures, 80 ~ 120 parts of rotary evaporation objects, 15 ~ 20 parts of dried objects, 0.2 ~
0.4 part of Novozym435 lipase, the mixing of 600 ~ 700 parts of isopropanols, in 50 ~ 55 DEG C, 150r/min oscillation 18 ~ for 24 hours, enzyme deactivation,
Filtering, takes filtrate to get the decontamination activating agent that deoils.
Deoil handguard additive:
(1) it takes alpha-chloro tetradecylic acid 1 ~ 3:5 in mass ratio ~ 10 that the first ammonia spirit that mass fraction is 33% is added, adds quality
The deionized water for the first ammonia spirit quality 20 ~ 30% that score is 33%, is warming up to 65 ~ 75 DEG C and is stirred 12 ~ 15h, then heat up
To 95 ~ 100 DEG C, 4 ~ 8h is kept the temperature in oil bath, is cooled to room temperature, rotary evaporation, adjust pH to 6 ~ 7, obtain rotary evaporation object a, take
The ethyl alcohol that the mass fraction of pH3.0 is 50% is added in rotary evaporation object a 1 ~ 4:7 in mass ratio ~ 10, is stirred 20 ~ 30min, mistake
Filter, takes filter residue rotary evaporation, dry, obtains dried object a；
(2) it takes dried object a to grind, sieves with 100 mesh sieve, collect sieving particle, sieving particle 1 ~ 5:10 ~ 15 in mass ratio is taken to add
Enter dehydrated alcohol, be warming up to 210 ~ 220 DEG C of 3 ~ 6h of heat preservation, be cooled to room temperature, obtain cooled material, take cooled material in mass ratio 80 ~
The hydrochloric acid that concentration is 1mol/L is added in 100:13 ~ 18, is stirred 30 ~ 40min, and rotary evaporation is dry, obtains dried object b, takes dry
Ethyl acetate is added in dry object b 1 ~ 3:5 in mass ratio ~ 9, stands 4 ~ 6h, takes precipitating 1 ~ 3:7 in mass ratio ~ 10 that deionized water is added,
It is extracted through anhydrous ether, takes extract liquor to get the handguard additive that deoils.
Buffering aids: it takes tartaric acid 1:1 in mass ratio that sodium tartrate is added, is stirred 30 ~ 40min, obtains mixture, take
Aloe extract mixing is added to get buffering aids in mixture 1 ~ 3:20 in mass ratio ~ 30.
Antibacterial activity agent: take wormwood extract 3 ~ 5:1 in mass ratio ~ 3 be added cinnamomum cassia extract mixing to get.
A kind of handguard type dish washing liquid, according to the mass fraction, including 20 ~ 30 portions of decontamination activating agents that deoil, 5 ~ 10 parts of shields of deoiling
Hand additive, 40 ~ 50 parts of buffering aids, 5 ~ 8 parts of antibacterial activity agent, 2 ~ 4 parts of dodecyl benzene sulfonic acid, 1 ~ 5 part of fatty alcohol polyoxy
Ethylene ether sulfate, 2 ~ 5 parts of olive oleates, 200 ~ 300 parts of water.
Deoil decontamination activating agent: S1. takes coconut to split, and collects the brown coconut kind skin being attached on coconut meat, dry, pulverize
80 meshes are crossed, sieving particle is collected, take sieving particle 1:5 in mass ratio that isopropanol is added, in 20W ultrasound 5min, then at 55 DEG C
3h is kept the temperature, is filtered, is taken smoke filtrate rotary evaporation, obtain rotary evaporation object；
S2. it takes 3A molecular sieve in 200 DEG C of activation 4h, obtains activator 1:7 in mass ratio and acetone is added, stand for 24 hours, filtering takes filter
Slag rotary evaporation, it is dry, dried object is obtained, takes xylose 4:1 in mass ratio that lauric acid mixing is added, mixture is obtained, by mass fraction
Meter, takes 200 parts of mixtures, 80 parts of rotary evaporation objects, 15 parts of dried objects, 0.2 part of Novozym435 lipase, 600 parts of isopropanols
Mixing vibrates 18h, enzyme deactivation in 50 DEG C, 150r/min, and filtering takes filtrate to get the decontamination activating agent that deoils.
Deoil handguard additive:
(1) it takes alpha-chloro tetradecylic acid 1:5 in mass ratio that the first ammonia spirit that mass fraction is 33% is added, adds mass fraction
For the deionized water of 33% first ammonia spirit quality 20%, it is warming up to 65 DEG C and is stirred 12h, then be warming up to 95 DEG C, in oil bath
Middle heat preservation 4h, is cooled to room temperature, rotary evaporation, adjusts pH to 6, obtains rotary evaporation object a, take rotary evaporation object a 1:7 in mass ratio
The ethyl alcohol that the mass fraction of pH3.0 is 50% is added, is stirred 20min, filters, takes filter residue rotary evaporation, it is dry, obtain drying
Object a；
(2) it takes dried object a to grind, sieves with 100 mesh sieve, collect sieving particle, take sieving particle 1:10 in mass ratio that nothing is added
Water-ethanol is warming up to 210 DEG C of heat preservation 3h, is cooled to room temperature, obtains cooled material, takes cooled material 80:13 in mass ratio that concentration is added and is
The hydrochloric acid of 1mol/L is stirred 30min, and rotary evaporation is dry, obtains dried object b, takes dried object b 1:5 in mass ratio that second is added
Acetoacetic ester stands 4h, takes precipitating 1:7 in mass ratio that deionized water is added, extracts through anhydrous ether, take extract liquor to get deoiling
Handguard additive.
Buffering aids: it takes tartaric acid 1:1 in mass ratio that sodium tartrate is added, is stirred 30min, obtains mixture, take mixed
It closes object 1:20 in mass ratio and aloe extract mixing is added to get buffering aids.
Antibacterial activity agent: take wormwood extract 3:1 in mass ratio be added cinnamomum cassia extract mixing to get.
A kind of handguard type dish washing liquid, according to the mass fraction, including 20 portions of decontamination activating agents that deoil, 5 parts of handguard additions of deoiling
Agent, 40 parts of buffering aids, 5 parts of antibacterial activity agent, 2 parts of dodecyl benzene sulfonic acid, 1 part of fatty alcohol polyoxyethylene ether sulfate, 2 parts
Olive oleate, 200 parts of water.
Deoil decontamination activating agent: S1. takes coconut to split, and collects the brown coconut kind skin being attached on coconut meat, dry, pulverize
80 meshes are crossed, sieving particle is collected, take sieving particle 2:7 in mass ratio that isopropanol is added, in 20W ultrasound 8min, then at 58 DEG C
4h is kept the temperature, is filtered, is taken smoke filtrate rotary evaporation, obtain rotary evaporation object；
S2. it takes 3A molecular sieve in 240 DEG C of activation 5h, obtains activator 4:8 in mass ratio and acetone is added, stand 40h, filtering takes filter
Slag rotary evaporation, it is dry, dried object is obtained, takes xylose 5:2 in mass ratio that lauric acid mixing is added, mixture is obtained, by mass fraction
Meter, takes 300 parts of mixtures, 100 parts of rotary evaporation objects, 18 parts of dried objects, 0.3 part of Novozym435 lipase, 650 parts of isopropanols
Mixing vibrates 22h, enzyme deactivation in 52 DEG C, 150r/min, and filtering takes filtrate to get the decontamination activating agent that deoils.
Deoil handguard additive:
(1) it takes alpha-chloro tetradecylic acid 2:8 in mass ratio that the first ammonia spirit that mass fraction is 33% is added, adds mass fraction
For the deionized water of 33% first ammonia spirit quality 25%, it is warming up to 70 DEG C and is stirred 13h, then be warming up to 98 DEG C, in oil bath
Middle heat preservation 6h, is cooled to room temperature, rotary evaporation, adjusts pH to 6.5, obtains rotary evaporation object a, take rotary evaporation object a in mass ratio
The ethyl alcohol that the mass fraction of pH3.0 is 50% is added in 3:8, is stirred 25min, filters, takes filter residue rotary evaporation, dry, obtains dry
Dry object a；
(2) it takes dried object a to grind, sieves with 100 mesh sieve, collect sieving particle, take sieving particle 4:13 in mass ratio that nothing is added
Water-ethanol is warming up to 215 DEG C of heat preservation 5h, is cooled to room temperature, obtains cooled material, takes cooled material 90:15 in mass ratio that concentration is added and is
The hydrochloric acid of 1mol/L is stirred 35min, and rotary evaporation is dry, obtains dried object b, takes dried object b 2:6 in mass ratio that second is added
Acetoacetic ester stands 5h, takes precipitating 2:8 in mass ratio that deionized water is added, extracts through anhydrous ether, take extract liquor to get deoiling
Handguard additive.
Buffering aids: it takes tartaric acid 1:1 in mass ratio that sodium tartrate is added, is stirred 35min, obtains mixture, take mixed
It closes object 2:25 in mass ratio and aloe extract mixing is added to get buffering aids.
Antibacterial activity agent: take wormwood extract 4:2 in mass ratio be added cinnamomum cassia extract mixing to get.
A kind of handguard type dish washing liquid, according to the mass fraction, including 25 portions of decontamination activating agents that deoil, 8 parts of handguard additions of deoiling
Agent, 45 parts of buffering aids, 7 parts of antibacterial activity agent, 3 parts of dodecyl benzene sulfonic acid, 4 parts of fatty alcohol polyoxyethylene ether sulfates, 3 parts
Olive oleate, 250 parts of water.
Deoil decontamination activating agent: S1. takes coconut to split, and collects the brown coconut kind skin being attached on coconut meat, dry, pulverize
80 meshes are crossed, sieving particle is collected, take sieving particle 3:9 in mass ratio that isopropanol is added, in 20W ultrasound 10min, then at 60 DEG C
5h is kept the temperature, is filtered, is taken smoke filtrate rotary evaporation, obtain rotary evaporation object；
S2. it takes 3A molecular sieve in 250 DEG C of activation 6h, obtains activator 5:10 in mass ratio and acetone is added, stand 48h, filtering takes filter
Slag rotary evaporation, it is dry, dried object is obtained, takes xylose 6:3 in mass ratio that lauric acid mixing is added, mixture is obtained, by mass fraction
Meter, takes 500 parts of mixtures, 120 parts of rotary evaporation objects, 20 parts of dried objects, 0.4 part of Novozym435 lipase, 700 parts of isopropanols
Mixing vibrates enzyme deactivation for 24 hours in 55 DEG C, 150r/min, and filtering takes filtrate to get the decontamination activating agent that deoils.
Deoil handguard additive:
(1) it takes alpha-chloro tetradecylic acid 3:10 in mass ratio that the first ammonia spirit that mass fraction is 33% is added, adds mass fraction
For the deionized water of 33% first ammonia spirit quality 30%, it is warming up to 75 DEG C and is stirred 15h, then be warming up to 100 DEG C, in oil bath
Middle heat preservation 8h, is cooled to room temperature, rotary evaporation, adjusts pH to 7, obtains rotary evaporation object a, take rotary evaporation object a in mass ratio 4:
The ethyl alcohol that 10 mass fractions that pH3.0 is added are 50%, is stirred 30min, filters, take filter residue rotary evaporation, dry, obtains dry
Dry object a；
(2) it takes dried object a to grind, sieves with 100 mesh sieve, collect sieving particle, take sieving particle 5:15 in mass ratio that nothing is added
Water-ethanol is warming up to 220 DEG C of heat preservation 6h, is cooled to room temperature, obtains cooled material, takes cooled material 100:18 in mass ratio that concentration is added and is
The hydrochloric acid of 1mol/L is stirred 40min, and rotary evaporation is dry, obtains dried object b, takes dried object b 3:9 in mass ratio that second is added
Acetoacetic ester stands 6h, takes precipitating 3:10 in mass ratio that deionized water is added, extracts through anhydrous ether, take extract liquor to get deoiling
Handguard additive.
Buffering aids: it takes tartaric acid 1:1 in mass ratio that sodium tartrate is added, is stirred 40min, obtains mixture, take mixed
It closes object 3:30 in mass ratio and aloe extract mixing is added to get buffering aids.
Antibacterial activity agent: take wormwood extract 5:3 in mass ratio be added cinnamomum cassia extract mixing to get.
A kind of handguard type dish washing liquid, according to the mass fraction, including 30 portions of decontamination activating agents that deoil, 10 parts of handguard additions of deoiling
Agent, 50 parts of buffering aids, 8 parts of antibacterial activity agent, 4 parts of dodecyl benzene sulfonic acid, 5 parts of fatty alcohol polyoxyethylene ether sulfates, 5 parts
Olive oleate, 300 parts of water.
Comparative example 1: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking the decontamination activating agent that deoils.
Comparative example 2: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking the handguard additive that deoils.
Comparative example 3: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking buffering aids.
Comparative example 4: the dish washing liquid of Wuxi City company production.
Handguard type dish washing liquid obtained by embodiment is tested with dish washing liquid obtained by comparative example according to GB9985-2000, is surveyed
Test result is as shown in table 1.
Table 1:
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 |
| Dirt-removing power (%) | 92.1 | 90.8 | 91.6 | 84.3 | 85.9 | 89.7 | 61.4 |
| Mild pH(25 DEG C of performance, 1% solution) | 7.52 | 7.83 | 7.79 | 7.75 | 7.85 | 8.03 | 9.61 |
| Active matter content (%) | 23 | 20 | 22 | 20 | 19 | 18 | 14 |
Handguard type dish washing liquid of the invention is more preferable compared to commercial product effect, is worth promoting.
Claims (7)
1. a kind of handguard type dish washing liquid includes following component, 5 ~ 8 parts of antibacterial activity agent, 2 ~ 4 parts of dodecyls according to the mass fraction
Benzene sulfonic acid, 1 ~ 5 part of fatty alcohol polyoxyethylene ether sulfate, 2 ~ 5 parts of olive oleates, 200 ~ 300 parts of water, which is characterized in that also
Including 20 ~ 30 portions of decontamination activating agents that deoil, 5 ~ 10 parts of handguard additives that deoil, 40 ~ 50 parts of buffering aids；
The preparation method of the decontamination activating agent that deoils, includes the following steps:
S1. it takes coconut to split, collects the brown coconut kind skin being attached on coconut meat, dry, pulverize 80 meshes, collect sieving
Grain takes sieving particle 1 ~ 3:5 in mass ratio ~ 9 that isopropanol ultrasound is added, keeps the temperature, filters, take smoke filtrate rotary evaporation, must rotate
Evaporant；
S2. it takes 3A molecular sieve to activate in 200 ~ 250 DEG C, obtains activator 1 ~ 5:7 in mass ratio ~ 10 and acetone is added, stand, filtering,
Filter residue rotary evaporation is taken, it is dry, dried object is obtained, takes xylose 4 ~ 6:1 in mass ratio ~ 3 that lauric acid mixing is added, obtains mixture, press
Mass fraction meter takes 200 ~ 500 parts of mixtures, 80 ~ 120 parts of rotary evaporation objects, 15 ~ 20 parts of dried objects, 0.2 ~ 0.4 part
Novozym435 lipase, 600 ~ 700 parts of isopropanol mixing, vibrate, enzyme deactivation in 50 ~ 55 DEG C, 150r/min, and filtering takes filtrate,
Deoil decontamination activating agent to obtain the final product.
2. handguard type dish washing liquid according to claim 1, which is characterized in that in the step S1 be added isopropanol ultrasound,
Heat-retaining condition are as follows: in 20W 5 ~ 10min of ultrasound, then at 55 ~ 60 DEG C of 3 ~ 5h of heat preservation.
3. handguard type dish washing liquid according to claim 1, which is characterized in that the preparation side of the handguard additive that deoils
Method includes the following steps:
(1) take alpha-chloro tetradecylic acid 1 ~ 3:5 in mass ratio ~ 10 be added first ammonia spirit, add first ammonia spirit quality 20 ~
30% deionized water is stirred, then is warming up to 95 ~ 100 DEG C, and 4 ~ 8h is kept the temperature in oil bath, is cooled to room temperature, rotary evaporation,
PH to 6 ~ 7 is adjusted, rotary evaporation object a is obtained, the ethyl alcohol stirring for taking rotary evaporation object a 1 ~ 4:7 in mass ratio ~ 10 that pH3.0 is added is mixed
It closes, filtering takes filter residue rotary evaporation, and it is dry, obtain dried object a；
(2) it takes dried object a to grind, sieves with 100 mesh sieve, collect sieving particle, sieving particle 1 ~ 5:10 ~ 15 in mass ratio is taken to add
Enter dehydrated alcohol heat preservation, be cooled to room temperature, obtain cooled material, takes cooled material 80 ~ 100:13 in mass ratio ~ 18 that hydrochloric acid stirring is added mixed
Close, rotary evaporation is dry, obtains dried object b, takes dried object b 1 ~ 3:5 in mass ratio ~ 9 that ethyl acetate is added, and stands, take precipitating by
Deionized water is added in 1 ~ 3:7 of mass ratio ~ 10, extracts through anhydrous ether, takes extract liquor to get the handguard additive that deoils.
4. handguard type dish washing liquid according to claim 3, which is characterized in that mass fraction is added in the step (1) is
The deionized water of 33% first ammonia spirit quality 20 ~ 30% is stirred condition are as follows: be warming up to 65 ~ 75 DEG C be stirred 12 ~
15h。
5. handguard type dish washing liquid according to claim 3, which is characterized in that dehydrated alcohol is added in the step (2)
Heat-retaining condition are as follows: be warming up to 210 ~ 220 DEG C of 3 ~ 6h of heat preservation.
6. handguard type dish washing liquid according to claim 1, which is characterized in that the buffering aids: take tartaric acid by quality
Sodium tartrate is added than 1:1, is stirred 30 ~ 40min, obtains mixture, takes mixture 1 ~ 3:20 in mass ratio ~ 30 that aloe is added
Extract mixes to get buffering aids.
7. handguard type dish washing liquid according to claim 1, which is characterized in that the antibacterial activity agent: take wormwood extract
3 ~ 5:1 in mass ratio ~ 3 be added cinnamomum cassia extract mixing to get.
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| CN201811013588.9A CN108998279A (en) | 2018-08-31 | 2018-08-31 | A kind of handguard type dish washing liquid |
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| CN201811013588.9A CN108998279A (en) | 2018-08-31 | 2018-08-31 | A kind of handguard type dish washing liquid |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111961535A (en) * | 2020-08-27 | 2020-11-20 | 刘克武 | Antibacterial detergent containing wormwood extract |
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| CN106753880A (en) * | 2016-11-19 | 2017-05-31 | 华南理工大学 | A kind of Chinese cassia tree liquid detergent and preparation method thereof |
| CN107557182A (en) * | 2017-10-18 | 2018-01-09 | 桂林大创科技有限公司 | A kind of handguard Antibiotic liquid detergent and preparation method thereof |
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2018
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103540429A (en) * | 2012-07-11 | 2014-01-29 | 上海和黄白猫有限公司 | Hand-protecting and nail-protecting liquid detergent |
| CN106190594A (en) * | 2016-07-08 | 2016-12-07 | 张健 | A kind of aminoacid kitchen is clean |
| CN106753880A (en) * | 2016-11-19 | 2017-05-31 | 华南理工大学 | A kind of Chinese cassia tree liquid detergent and preparation method thereof |
| CN107557182A (en) * | 2017-10-18 | 2018-01-09 | 桂林大创科技有限公司 | A kind of handguard Antibiotic liquid detergent and preparation method thereof |
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| CN111961535A (en) * | 2020-08-27 | 2020-11-20 | 刘克武 | Antibacterial detergent containing wormwood extract |
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Application publication date: 20181214 |