CN108998257A - All-round cleaning agent and preparation method thereof - Google Patents
All-round cleaning agent and preparation method thereof Download PDFInfo
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- CN108998257A CN108998257A CN201810616704.XA CN201810616704A CN108998257A CN 108998257 A CN108998257 A CN 108998257A CN 201810616704 A CN201810616704 A CN 201810616704A CN 108998257 A CN108998257 A CN 108998257A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
Abstract
A kind of all-round cleaning agent is provided, which includes the cocamine oxide of the mixing sodium salt and 4-5 mass parts of 3-6 mass parts；It is (2-5)/(1-3)/(3-6) sodium xylene sulfonate, benzene sulfonic acid sodium salt and sodium phenylacetate that sodium salt, which is mixed, comprising mass ratio.The cleaning effect of all-round cleaning agent of the invention is strong, and product colour is beautiful, excellent to the cleaning effect of the impurity such as various spots, scale, grease stain, has in industrial and agricultural production and life and has been widely used.
Description
Technical field
The present invention relates generally to cleaning fields, and particularly, are related to all-round cleaning agent and preparation method thereof.
Background technique
With the development of the society, requirement of the people to household cleaning is higher and higher, and existing detergent on the market is clear
It during clean, is only used as simply cleaning, only has cleaning action to part of the surface, and have corrosiveness to part of the surface.
As society and consumer are higher and higher to the Functional Requirement of detergent, it is desirable to which a kind of detergent can be gone simultaneously
Except a variety of spots on a variety of surfaces, just to our product, more stringent requirements are proposed for this.Research and develop one kind can clean it is a variety of
The purpose of spot, but be suitable for unlike material hard surface and the detergent of injured surface is not a kind of trend.
Summary of the invention
The present invention provides a kind of all-round cleaning agent, which includes the mixing sodium salt and 4-5 mass parts of 3-6 mass parts
Cocamine oxide；Wherein, it is (2-5)/(1-3)/(3-6) xylene monosulfonic acid that the mixing sodium salt, which includes mass ratio,
Sodium, benzene sulfonic acid sodium salt and sodium phenylacetate.
In some embodiments, in the all-round cleaning agent, which further includes the tripolyphosphate of 3-5 mass parts
The sodium pyrophosphate of ammonium and 2-4 mass parts.
In some embodiments, in the all-round cleaning agent, which further includes the surface-active of 3-6 mass parts
Agent.
In some embodiments, in the all-round cleaning agent, the surfactant is organic silicon modified by polyether table
Face activating agent.
In some embodiments, in the all-round cleaning agent, the surfactant is fatty alcohol polyoxyethylene ether
With the mixture of one or both of alkyl glycosides.
In some embodiments, in the all-round cleaning agent, which further includes citrate, the citrate
It is (1-2)/1 with the mass ratio for mixing sodium salt.
In some embodiments, in the all-round cleaning agent, which further includes polyphosphate.
In some embodiments, in the all-round cleaning agent, which further includes the nano-titanium for adulterating vanadium ion
White, the doping of the vanadium ion is the 8-15% of Nanometer Titanium Dioxide quality.
In some embodiments, in the all-round cleaning agent, which further includes the carboxymethyl of 20-40 mass parts
The carboxymethyl chitosan alkali formula magnesium salts of chitosan and 20-40 mass parts.
Another aspect of the present invention provides a kind of preparation method of all-round cleaning agent, which includes the following steps:
Sodium tripolyphosphate is dissolved in water, cocamine oxide, sodium xylene sulfonate, benzene sulfonic acid sodium salt and benzene second is added
Sour sodium, stirring is to dissolving under 500-600r/min revolving speed, and is added with stirring surfactant under 300-500r/min revolving speed
It is dissolved to the surfactant, until bubble is emerged, obtains all-round cleaning agent.
The utility model has the advantages that
The cleaning effect of all-round cleaning agent of the invention is strong, and product colour is beautiful, and by using sodium xylene sulfonate,
The mixing sodium salt and surfactant of benzene sulfonic acid sodium salt, sodium phenylacetate, greatly improve cleaning agent to various spots, scale,
The cleaning effect of the impurity such as grease stain has in industrial and agricultural production and life and has been widely used.
Specific embodiment
The existing various exemplary embodiment that the present invention will be described in detail, the detailed description are not considered as to limit of the invention
System, and it is understood as the more detailed description to certain aspects of the invention, characteristic and embodiment.
It should be understood that it is to describe special embodiment that heretofore described term, which is only, it is not intended to limit this hair
It is bright.In addition, for the numberical range in the present invention, it is thus understood that it is also specifically disclosed that every between the upper and lower bound of the range
A median.In in the median and any other statement value in any statement value or stated ranges or in the range
Between each of between value lesser range be also included in the present invention.These small range of upper and lower bounds can independently include
Or it excludes in range.
Unless otherwise stated, all technical and scientific terms used herein has the routine in field of the present invention
The normally understood identical meanings of technical staff.Although the present invention only describes preferred method and material, of the invention
Implement or also can be used and similar or equivalent any method and material described herein in testing.The institute mentioned in this specification
There is document to be incorporated by reference into, to disclosure and description method relevant to the document and/or material.It is incorporated to any
When document conflicts, it is subject to the content of this specification.
Without departing substantially from the scope or spirit of the invention, the specific embodiment of description of the invention can be done more
Kind improvements and changes, this will be apparent to those skilled in the art.Other realities obtained by specification of the invention
Applying mode for technical personnel is apparent obtain.Present specification and embodiment are merely exemplary.
It is open term, i.e., about "comprising" used herein, " comprising ", " having ", " containing " etc.
Mean including but not limited to.
Heretofore described " mass parts " or " % " unless otherwise instructed, by mass.
A kind of all-round cleaning agent of the present invention, the cleaning agent include that same point of the toluenesulfonic acid of 0.4-1 mass parts is different
Structure body；
Wherein, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is
1/(4-9)/(2-5)。
Preferably, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid
For 1/ (4-7)/(2-4)；It is highly preferred that in the isomer, o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid
Mass ratio be 1/ (4-5)/(2-3), for example, in the isomer, o-toluene sulfonic acid, p-methyl benzenesulfonic acid and first
The mass ratio of benzene sulfonic acid is 1/4/2, alternatively, in the isomer, o-toluene sulfonic acid, p-methyl benzenesulfonic acid and toluene
The mass ratio of sulfonic acid is 1/5/3.
In some embodiments, in the all-round cleaning agent, the cleaning agent further include 82-87 mass parts glycerol,
The sodium sulfate of polyethenoxy ether of fatty alcohol of 0.3-0.5 mass parts and the orange oil of 0.2-0.4 mass parts.
In some embodiments, in the all-round cleaning agent, which further includes the suitable fourth of 3-8 mass mass parts
The Sodium Polyacrylate of enedioic acid anhydride modification.
There are many carboxylate radical anion on the strand of polyacrylate, it is strong that these anions have macromolecular chain nearby
Big electrostatic force, this electrostatic force make cation be greater than corresponding carboxylate radical with affinity of the carboxylic acid on macromolecular chain between,
Carboxylate radical is strong to the adsorption capacity of cationic dirt, and Sodium Polyacrylate Liquidity limit dirt prevents accumulation of dirt, makes schmutzband
It is loose, it is easy to be washed away by water.
In some embodiments, in the all-round cleaning agent, the polyacrylic acid of the maleic anhydride modified
Acrylic acid and maleic anhydride molar ratio are (3-4)/1 in sodium.
When acrylic acid and maleic anhydride molar ratio >=5, what the Sodium Polyacrylate of maleic anhydride modified obtained
The modifying function of mainly sodium acrylate polymer, maleic anhydride does not embody, causes molecular weight very big, and solution is very glutinous, water
Dissolubility is poor, when acrylic acid and maleic anhydride molar ratio≤2, master that the Sodium Polyacrylate of maleic anhydride modified obtains
If maleic anhydride polymer, solution colour is deep, influences cleaning effect.
In some embodiments, in the all-round cleaning agent, which further includes citrate, the citric acid
Salt prevents dirt from precipitating on object again as anti-dirt reprecipitation agent.In some embodiments, the citrate with
The mass ratio of the Sodium Polyacrylate of the maleic anhydride modified is 1-3/1, and the pH value of cleaning agent is adjusted to 7-8.At certain
In a little embodiments, the mass ratio of the Sodium Polyacrylate of the citrate and the maleic anhydride modified is 1/1,1/2
Or 1/3.
In some embodiments, in the all-round cleaning agent, which further includes the siloxanes of 3-10 mass parts
Lotion.Cleaning agent containing silicone emulsion, cleaning of objects, object is brighter and has water resistant effect.
In some embodiments, in the all-round cleaning agent, which, which further includes that 10-20 is silica modified, is received
Rice titanium dioxide.
After silica modified nano titanium dioxide, increase the strong suction-operated of nano-titanium dioxide, and in surface shape
At very strong group.On the object to take out stains, using the strong adsorption capacity between silica and object, in transparency emulsion two
Silica based titanium oxide compound can be adsorbed to body surface, and nano-titanium oxide is uniformly coated on body surface, irradiate in light
Lower Nanometer Titanium Dioxide can generate hydroxyl group anion, have strong oxidizing property, body surface debirs can be made to resolve into innocuous gas, from
And the hydroxyl group anion for making body surface self-cleaning, while generating can form one layer of hydrophilic laminate, change traditional object and dredge
The property of water, therefore, cleaning agent of the present invention can clean and the self-cleaning ability of cleaning objects, so that clearly
Object after clean can save cleaning for a long time.
During preparing silica modified nano titanium dioxide, using D- polysorbate surfactant, and D-
The dosage of D-sorbite is the 0.3%-1% of nano-titanium dioxide quality, and D- D-sorbite can be simultaneously to nano silica
It is surface-treated with nano-titanium dioxide, if D- D-sorbite dosage, less than 0.3%, very few cannot sufficiently wrap up of dosage is received
Rice corpuscles, not wrapped nano particle, which is easily assembled, makes emulsion particle diameter become larger, and dosage can not excessively obtain ideal effect, anyway
Surfactant reduces the polarity of system, the decline of system cohesive force, degradation with respect to backbone.
In some embodiments, in the all-round cleaning agent, vanadium ion is adulterated in the nano-titanium dioxide.
Containing transition metal can introduce defect in Nanometer Titanium Dioxide lattice or change cleanliness, influence answering for electrons and holes
It closes.Since vanadium metal is to appraise at the current rate, a small amount of Transition Metals V is adulterated in Nanometer Titanium Dioxide can be formed as photo-generate electron-hole pair
Shallow gesture capture trap, extend electrons and holes compound time, to achieve the purpose that improve Nanometer Titanium Dioxide photocatalytic activity.And
And due to transition metal from vanadium have light abstraction width more broader than Nanometer Titanium Dioxide, can will absorb light further extend into it is visible
Light area.When all can cleaning agent cleaned object after, the nano-titanium dioxide of the doping vanadium ion remained on object can use
Visible light carries out light-catalyzed reaction, extends the time that object keeps clean state, the automatically cleaning energy of object is improved using cleaning agent
Power.
The preparation process of vanadium ion is adulterated in nano-titanium dioxide: by TiCl4It is slowly dropped into distilled water, is formed uniform
Bright titanium compound A.Be 7-9 with ammonium hydroxide tune pH after appropriate ammonium metavanadate is dissolved in the clear solution, formed titanium hydroxide and
The colloidal attitude solution B of vanadium hydroxide, B solution is put into three-necked flask, in 100 DEG C of reaction 3-5h, after being filtered, washed, and filter
Appropriate complexing agent is added in cake, and vanadium-doped nano titanic oxide transparent photo-catalytic emulsion can be obtained through control hydrolysis.
In some embodiments, in the all-round cleaning agent, the doping of the vanadium ion is nano-titanium dioxide
The 0.9-1.5% of quality.
A small amount of doping vanadium ion enters in titanium dioxide lattice, replaces titanium ion, is conducive to the transfer of photo-generated carrier, separately
Outside, after Doped ions enter lattice, a series of doped energy-bands are formed, the transition that the increase of doped energy-band is remarkably improved electronics is several
Rate to further extend photo-generate electron-hole service life, achieve the purpose that improve photocatalytic activity；When doping is excessive, greatly
In 1.5%, part vanadium ion is attached to titania surface in the form of the inert oxide of photochemistry, so hinder it is light-catalysed into
One step carries out, and degradation rate is caused to decline；When vanadium doping amount is too small, lower than 0.9%, photocatalytic activity improves unobvious.
In some embodiments, in the all-round cleaning agent, the titanium dioxide and the nano silica
Mass ratio is 1-4/1.
It is mentioned using the network limitation nano-titanium dioxide of silica to obtain nanometer porous catalysis material
High photocatalysis efficiency.
Another aspect of the present invention also provides a kind of preparation method of all-round cleaning agent comprising following steps:
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
Isomer, glycerol, sodium sulfate of polyethenoxy ether of fatty alcohol, the orange oil, suitable fourth of toluenesulfonic acid are added in stainless steel cauldron
Material stirring is uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification afterwards
For cleaning agent.
Embodiment
Embodiment 1
A kind of all-round cleaning agent, the cleaning agent include the isomer of the toluenesulfonic acid of 0.4 mass parts, 82 mass parts
Glycerol, the sodium sulfate of polyethenoxy ether of fatty alcohol of 0.3 mass parts, the orange oil of 0.2 mass parts and 1 mass parts citrate；Its
In, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/4/2.
In above scheme, which further includes the Sodium Polyacrylate of the maleic anhydride modified of 3 mass parts；Described
Acrylic acid and maleic anhydride molar ratio are 3/1 in the Sodium Polyacrylate of maleic anhydride modified.
Preparation method:
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
Isomer, glycerol, sodium sulfate of polyethenoxy ether of fatty alcohol, the orange oil, suitable fourth of toluenesulfonic acid are added in stainless steel cauldron
Material stirring is uniformly cleaning agent by the Sodium Polyacrylate and citrate of enedioic acid anhydride modification afterwards.
Embodiment 2
A kind of all-round cleaning agent, the cleaning agent include the isomer of the toluenesulfonic acid of 1 mass parts, 87 mass parts it is sweet
Oil, the sodium sulfate of polyethenoxy ether of fatty alcohol of 0.5 mass parts, the orange oil of 0.4 mass parts and 2 mass parts citrate；Wherein,
In the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/9/5.
In above scheme, which further includes the Sodium Polyacrylate of the maleic anhydride modified of 8 mass parts；Described
Acrylic acid and maleic anhydride molar ratio are 4/1 in the Sodium Polyacrylate of maleic anhydride modified.
Preparation method:
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
Isomer, glycerol, sodium sulfate of polyethenoxy ether of fatty alcohol, the orange oil, suitable fourth of toluenesulfonic acid are added in stainless steel cauldron
Material stirring is uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification afterwards
For cleaning agent.
Embodiment 3
A kind of all-round cleaning agent, the cleaning agent include the isomer of the toluenesulfonic acid of 0.6 mass parts, 85 mass parts
Glycerol, the sodium sulfate of polyethenoxy ether of fatty alcohol of 0.4 mass parts, the orange oil of 0.3 mass parts and 1.5 mass parts citrate.；
Wherein, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/6/3.
In above scheme, which further includes the Sodium Polyacrylate of the maleic anhydride modified of 5 mass parts；Described
Acrylic acid and maleic anhydride molar ratio are 3.5/1 in the Sodium Polyacrylate of maleic anhydride modified.
Preparation method:
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
Isomer, glycerol, sodium sulfate of polyethenoxy ether of fatty alcohol, the orange oil, suitable fourth of toluenesulfonic acid are added in stainless steel cauldron
Material stirring is uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification afterwards
For cleaning agent.
Embodiment 4
A kind of all-round cleaning agent, the cleaning agent include the isomer of the toluenesulfonic acid of 0.6 mass parts, 82 mass parts
Glycerol, the sodium sulfate of polyethenoxy ether of fatty alcohol of 0.4 mass parts, the orange oil of 0.3 mass parts and 1 mass parts citrate；Its
In, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/5/3.
In above scheme, which further includes the Sodium Polyacrylate of the maleic anhydride modified of 7 mass parts；Described
Acrylic acid and maleic anhydride molar ratio are 4/1 in the Sodium Polyacrylate of maleic anhydride modified.
In above scheme, which further includes the nanoscale silica based titanium oxide compound of 5 mass parts, described
Vanadium ion is adulterated in silica based titanium oxide, the doping of the vanadium ion is the 8% of silica based titanium oxide quality；Institute
Stating titanium dioxide and the mass ratio of nano silica in silica based titanium oxide is 4/1.
Preparation method:
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
Isomer, glycerol, sodium sulfate of polyethenoxy ether of fatty alcohol, the orange oil, suitable fourth of toluenesulfonic acid are added in stainless steel cauldron
Material stirring is uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification afterwards
For cleaning agent.
Embodiment 5
A kind of all-round cleaning agent, the cleaning agent include the isomer of the toluenesulfonic acid of 0.8 mass parts, 84 mass parts
Glycerol, the sodium sulfate of polyethenoxy ether of fatty alcohol of 0.5 mass parts, the orange oil of 0.4 mass parts and 1-2 mass parts citrate；
Wherein, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/9/5.
In above scheme, which further includes the Sodium Polyacrylate of the maleic anhydride modified of 3 mass parts；Described
Acrylic acid and maleic anhydride molar ratio are 3/1 in maleic anhydride modified Sodium Polyacrylate.
In above scheme, which further includes the nanoscale silica based titanium oxide compound of 10 mass parts, institute
It states and adulterates vanadium ion in silica based titanium oxide, the doping of the vanadium ion is silica based titanium oxide quality
10%；Titanium dioxide and the mass ratio of nano silica are 2/1 in the silica based titanium oxide.
Preparation method:
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
Isomer, glycerol, sodium sulfate of polyethenoxy ether of fatty alcohol, the orange oil, suitable fourth of toluenesulfonic acid are added in stainless steel cauldron
Material stirring is uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification afterwards
For cleaning agent.
Comparative example 1
A kind of all-round cleaning agent, is made of following raw material: 2-7 parts of butyl glycol ether, 1-5 parts of propylene glycol monomethyl ether,
1-4 parts of neopelex, 1-4 parts of ethoxylated dodecyl alcohol, 4-9 parts of sodium pyrophosphate, 4-9 parts of toluenesulfonic acid sodium salt, five
2-5 parts and water 60-80 parts of water sodium metasilicate.
Performance test and evaluation
1. stability
1.1 accelerated stability test
Referring to ASTM F 1104,100mL product is stored into 15d at -8 DEG C ± 2 DEG C, then at 49 DEG C ± 10 DEG C again
15d is stored, test is finished, acutely rocked, and precipitating, lamination should not occur in product, and after test, product can be restored to original shape
State.
1.2 long-term stable experiment
By according to ASTM F 1104 normal storage, 12 months products, submits cleaning agent test center to carry out accordance and test
Confirmatory test.
5. the evaluation of cleaning effect
The cleaning effect assessment of 5.1 pairs of greasy dirts
Edible oil is smeared on calico, and after edible oil drying, embodiment and comparative example institute is smeared at the greasy dirt of calico
The cleaning agent stated evaluates the cleaning effect of greasy dirt after crumpling 10 times；
The cleaning effect assessment of 5.2 pairs of machine oil
It smears machine oil on calico, after standby oil drying, is smeared described in embodiment and comparative example at the greasy dirt of calico
Cleaning agent evaluates the cleaning effect of machine oil after crumpling 10 times；
The cleaning effect assessment of 5.3 pairs of sludge
Calico is immersed in sludge, calico is taken out, after calico is dry, embodiment and comparative example institute is smeared on calico
The cleaning agent stated evaluates the cleaning effect of dirt after crumpling 10 times；
Evaluation criterion is range estimation, wherein
Dirt is cleaned out substantially, and the calico area for exposing 95% or more is " excellent "；
Dirt is cleaned out a part, and the calico area for exposing about 70-95% is " good "；
Dirt is cleaned out a part, expose about 10-70% calico area be " in "；
Dirt is seldom cleaned out, and 90% or more calico area is still covered as " poor " by dirt；.
From the above results, the embodiment of the present invention 1 to 5 has accelerated stability and long-time stability, meanwhile, to food
Excellent cleaning effect is all had with greasy dirt, machine oil greasy dirt and dirt, is the excellent all-round cleaning agent of cleaning effect.Comparative example
Cleaning agent described in 1 has accelerated stability and long-time stability, and excellent to the cleaning effect of dirt, to edible oil greasy dirt
Cleaning effect be it is good, the cleaning effect to the cleaning of machine oil greasy dirt be it is poor, comparative example 1 cannot achieve omnipotent cleaning effect.
The present invention is carried out although having been combined and being presently considered to most practical and preferred embodiment, it should
Understand that the present invention is not limited only to above-mentioned disclosed embodiment, those skilled in the art are it is conceivable that of the invention
Technical solution of the present invention is changed and is improved in purport and spirit, without departing from determining in the appended claims
The scope of the present invention of justice.
Claims (10)
1. a kind of all-round cleaning agent, wherein the cleaning agent includes the lauryl of the mixing sodium salt and 4-5 mass parts of 3-6 mass parts
Dimethyl ammonium；
Wherein, it is (2-5)/(1-3)/(3-6) sodium xylene sulfonate, benzene sulfonic acid sodium salt and benzene that the mixing sodium salt, which includes mass ratio,
Sodium acetate.
2. all-round cleaning agent according to claim 1, wherein the cleaning agent further includes the tripolyphosphate ammonium of 3-5 mass parts
With the sodium pyrophosphate of 2-4 mass parts.
3. all-round cleaning agent according to claim 1, wherein the cleaning agent further includes the surfactant of 3-6 mass parts.
4. all-round cleaning agent according to claim 3, wherein the surfactant is living for organic silicon modified by polyether surface
Property agent.
5. all-round cleaning agent according to claim 3, wherein the surfactant is fatty alcohol polyoxyethylene ether and alkane
The mixture of one or both of base glucosides.
6. all-round cleaning agent according to claim 1, wherein the cleaning agent further includes citrate, the citrate with
The mass ratio of the mixing sodium salt is (1-2)/1.
7. all-round cleaning agent according to claim 1, wherein the cleaning agent also 5-10 mass parts include polyphosphate.
8. all-round cleaning agent according to claim 7, wherein the cleaning agent further includes the doping vanadium ion of 5-10 mass parts
Nanometer Titanium Dioxide, the doping of the vanadium ion is the 8-15% of Nanometer Titanium Dioxide quality.
9. all-round cleaning agent according to claim 1, wherein the cleaning agent further includes the carboxymethyl shell of 20-40 mass parts
The carboxymethyl chitosan alkali formula magnesium salts of glycan and 20-40 mass parts.
10. a kind of preparation method of all-round cleaning agent according to any one of claims 1 to 9, wherein the preparation method packet
Include following steps:
Sodium tripolyphosphate is dissolved in water, cocamine oxide, sodium xylene sulfonate, benzene sulfonic acid sodium salt and phenylacetic acid is added
Sodium, stirring is to dissolving under 500-600r/min revolving speed, and is added with stirring surfactant extremely under 300-500r/min revolving speed
The surfactant dissolution obtains all-round cleaning agent until bubble is emerged.
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