CN108774588A - Glass cleaner and preparation method thereof - Google Patents
Glass cleaner and preparation method thereof Download PDFInfo
- Publication number
- CN108774588A CN108774588A CN201810619914.4A CN201810619914A CN108774588A CN 108774588 A CN108774588 A CN 108774588A CN 201810619914 A CN201810619914 A CN 201810619914A CN 108774588 A CN108774588 A CN 108774588A
- Authority
- CN
- China
- Prior art keywords
- glass
- glass cleaner
- mass parts
- acid
- isomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000011521 glass Substances 0.000 title claims abstract description 119
- 238000002360 preparation method Methods 0.000 title claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000012459 cleaning agent Substances 0.000 claims abstract description 16
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims abstract description 13
- JDQDSEVNMTYMOC-UHFFFAOYSA-N 3-methylbenzenesulfonic acid Chemical compound CC1=CC=CC(S(O)(=O)=O)=C1 JDQDSEVNMTYMOC-UHFFFAOYSA-N 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 66
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 36
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 32
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 30
- 239000000377 silicon dioxide Substances 0.000 claims description 29
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 26
- -1 titanium oxide compound Chemical class 0.000 claims description 25
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 24
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 24
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 23
- 235000019502 Orange oil Nutrition 0.000 claims description 16
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 16
- 150000002191 fatty alcohols Chemical class 0.000 claims description 16
- 239000010502 orange oil Substances 0.000 claims description 16
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 16
- 235000011152 sodium sulphate Nutrition 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 15
- 235000011187 glycerol Nutrition 0.000 claims description 15
- 229910001220 stainless steel Inorganic materials 0.000 claims description 15
- 239000010935 stainless steel Substances 0.000 claims description 15
- 229910001456 vanadium ion Inorganic materials 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 12
- 239000004408 titanium dioxide Substances 0.000 claims description 11
- 230000004048 modification Effects 0.000 claims description 9
- 238000012986 modification Methods 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 20
- 239000003595 mist Substances 0.000 abstract description 10
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 9
- 150000008065 acid anhydrides Chemical class 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000001699 photocatalysis Effects 0.000 description 6
- 239000010410 layer Substances 0.000 description 5
- 239000005543 nano-size silicon particle Substances 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- 244000131522 Citrus pyriformis Species 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
- QKDGGEBMABOMMW-UHFFFAOYSA-I [OH-].[OH-].[OH-].[OH-].[OH-].[V+5] Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[V+5] QKDGGEBMABOMMW-UHFFFAOYSA-I 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 description 1
- QBNKFXYJSJOGEL-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Ti+4] QBNKFXYJSJOGEL-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- HQAITFAUVZBHNB-UHFFFAOYSA-N sodium;pentahydrate Chemical compound O.O.O.O.O.[Na] HQAITFAUVZBHNB-UHFFFAOYSA-N 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B01J35/39—
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
- C03C17/256—Coating containing TiO2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/71—Photocatalytic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/114—Deposition methods from solutions or suspensions by brushing, pouring or doctorblading
-
- C11D2111/18—
Abstract
There is provided a kind of glass cleaner, wherein the cleaning agent includes the isomer of the toluenesulfonic acid of 0.4-1 mass parts；Wherein, in isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/ (4-9)/(2-5).Glass is cleaned using glass cleaner of the present invention, the water mist noresidue of glass surface, and cleaning speed is fast, after cleaning, forms hydrophobic structure on glass, the water contact angle of glass is 110 ° -165 °, reaches persistently clean purpose.
Description
Technical field
The present invention relates generally to cleaning agent fields, and particularly, are related to glass cleaner and preparation method thereof.
Background technology
Glass is a kind of common transparent material, can be used for producing various glasswares.Glass cleaner is for cleaning glass
The greasy dirt on glass surface, main component are surfactants, and slightly alkalinity or tool is neutral, daily life of the glass cleaner in people
It has a wide range of applications in work.
But existing glass cleaner is easy to leave water mist in glass surface, influences cleaning performance.
Therefore, how to provide that a kind of residual water mist is few, and the glass cleaner with long-acting cleaning function is this field skill
Art personnel technical problem urgently to be resolved hurrily.
Invention content
The present invention provides a kind of glass cleaner, which includes the isomerism of the toluenesulfonic acid of 0.4-1 mass parts
Body；Wherein, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/ (4-
9)/(2-5)。
In some embodiments, in the glass cleaner, the cleaning agent further include 82-87 mass parts glycerine,
The orange oil of the sodium sulfate of polyethenoxy ether of fatty alcohol and 0.2-0.4 mass parts of 0.3-0.5 mass parts.
In some embodiments, in the glass cleaner, which further includes the maleic two of 3-8 mass parts
Anhydride modified Sodium Polyacrylate.
In some embodiments, in the glass cleaner, the polyacrylic acid of the maleic anhydride modified
Acrylic acid and maleic anhydride molar ratio are (3-4)/1 in sodium.
In some embodiments, in the glass cleaner, which further includes the lemon of 1-2 mass parts
Hydrochlorate.
In some embodiments, in the glass cleaner, which further includes receiving for 5-10 mass parts
The silica based titanium oxide compound of meter level.
In some embodiments, in the glass cleaner, vanadium ion is adulterated in the silica based titanium oxide.
In some embodiments, in the glass cleaner, the doping of the vanadium ion is titanium dioxide silicon substrate oxygen
Change the 8-15% of titanium quality.
In some embodiments, in the glass cleaner, in the silica based titanium oxide titanium dioxide with
The mass ratio of nano silicon dioxide is 1-4/1.
Another aspect of the present invention provides a kind of preparation method of glass cleaner, wherein the preparation method includes following step
Suddenly：
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
The isomer of addition toluenesulfonic acid, glycerine, sodium sulfate of polyethenoxy ether of fatty alcohol, orange oil, suitable fourth in stainless steel cauldron
Material stirring is afterwards uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification
For glass cleaner.
Advantageous effect：
In glass cleaner of the present invention, which nuzzles up after glass, after wiping droplet with towel, will not leave behind
Water mist.Meanwhile after the cleaning agent wipes across glass, one layer of photocatalysis layer containing Nanometer Titanium Dioxide is formed on glass, utilizes light
The light-catalyzed reaction of Catalytic Layer forms the functional layer of one layer of auxiliary glass self-cleaning in glass surface so that the glass tool after cleaning
There is the longer clean time, reduces the frequency of use of glass cleaner.
Specific implementation mode
The existing various exemplary embodiment that the present invention will be described in detail, the detailed description are not considered as the limit to the present invention
System, and it is understood as the more detailed description to certain aspects of the invention, characteristic and embodiment.
It should be understood that heretofore described term is only to describe special embodiment, being not intended to limit this hair
It is bright.In addition, for the numberical range in the present invention, it is thus understood that it is also specifically disclosed that every between the upper and lower bound of the range
A median.Median and any other statement value in any statement value or stated ranges or in the range in
Between each of between value smaller range be also included in the present invention.These small range of upper and lower bounds can include independently
Or it excludes in range.
Unless otherwise stated, all technical and scientific terms used herein has the routine in field of the present invention
The normally understood identical meanings of technical staff.Although the present invention only describes preferred method and material, the present invention's
Implement or can also be used and similar or equivalent any method and material described herein in testing.The institute mentioned in this specification
There is document to be incorporated by reference into, to disclosure and description and the relevant method of the document and/or material.It is incorporated to any
When document conflicts, it is subject to the content of this specification.
Without departing substantially from the scope or spirit of the invention, the specific implementation mode of description of the invention can be done more
Kind is improved and variation, this will be apparent to those skilled in the art.Other realities obtained by the specification of the present invention
It is apparent obtain to apply mode for technical personnel.Present specification and embodiment are merely exemplary.
It is the term of opening, i.e., about "comprising" used herein, " comprising ", " having ", " containing " etc.
Mean including but not limited to.
Heretofore described " mass parts " or " % " unless otherwise instructed, by mass.
A kind of glass cleaner of the present invention, the cleaning agent include that same point of the toluenesulfonic acid of 0.4-1 mass parts is different
Structure body；
Wherein, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is
1/(4-9)/(2-5)。
Preferably, in the isomer, o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid mass ratio
For 1/ (4-7)/(2-4)；It is highly preferred that in the isomer, o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid
Mass ratio be 1/ (4-5)/(2-3), for example, in the isomer, o-toluene sulfonic acid, p-methyl benzenesulfonic acid and first
The mass ratio of benzene sulfonic acid is 1/4/2, alternatively, in the isomer, o-toluene sulfonic acid, p-methyl benzenesulfonic acid and toluene
The mass ratio of sulfonic acid is 1/5/3.
In some embodiments, in the glass cleaner, the cleaning agent further include 82-87 mass parts glycerine,
The orange oil of the sodium sulfate of polyethenoxy ether of fatty alcohol and 0.2-0.4 mass parts of 0.3-0.5 mass parts.
In some embodiments, in the glass cleaner, which further includes the suitable fourth of 3-8 mass mass parts
The Sodium Polyacrylate of enedioic acid anhydride modification.
There are many carboxylate radical anion on the strand of polyacrylate, it is strong that these anions make macromolecular chain nearby exist
Big electrostatic force, this electrostatic force make cation be more than corresponding carboxylate radical with affinity of the carboxylic acid on macromolecular chain between,
Carboxylate radical is strong to the adsorption capacity of cationic dirt, and Sodium Polyacrylate Liquidity limit dirt prevents accumulation of dirt, makes schmutzband
It is loose, it is easy to be washed away by water.
In some embodiments, in the glass cleaner, the polyacrylic acid of the maleic anhydride modified
Acrylic acid and maleic anhydride molar ratio are (3-4)/1 in sodium.
When acrylic acid and maleic anhydride molar ratio >=5, what the Sodium Polyacrylate of maleic anhydride modified obtained
The modifying function of mainly sodium acrylate polymer, maleic anhydride does not embody, causes molecular weight very big, and solution is very glutinous, water
Dissolubility is poor, when acrylic acid and maleic anhydride molar ratio≤2, master that the Sodium Polyacrylate of maleic anhydride modified obtains
If maleic anhydride polymer, solution colour is deep, influences cleaning effect.
In some embodiments, in the glass cleaner, which further includes citrate, the lemon
Lemon hydrochlorate prevents dirt from being precipitated on glass again as anti-dirt reprecipitation agent.In some embodiments, the citric acid
The mass ratio of salt and the Sodium Polyacrylate of the maleic anhydride modified is 1-3/1, and the pH value of glass cleaner is adjusted to
7-8.In some embodiments, the mass ratio of the citrate and the Sodium Polyacrylate of the maleic anhydride modified is
1/1,1/2 or 1/3.
In some embodiments, in the glass cleaner, which further includes the silicon of 3-10 mass parts
Oxygen alkane lotion.Glass cleaner containing silicone emulsion, cleaning glass window, glass is brighter and has water resistant effect.
In some embodiments, in the glass cleaner, which further includes that 10-20 silica changes
Property nano-titanium dioxide.
After silica modified nano titanium dioxide, increase the strong suction-operated of nano-titanium dioxide, and in surface shape
At very strong group.On the glass to take out stains, using the strong adsorption capacity between silica and glass, two in transparency emulsion
Silica based titanium oxide compound can be adsorbed to glass surface, and nano-titanium oxide is uniformly coated on glass surface, be irradiated in light
Lower Nanometer Titanium Dioxide will produce hydroxyl group anion, has strong oxidizing property, glass surface debirs can be made to resolve into innocuous gas, from
And the hydroxyl group anion for making glass surface self-cleaning, while generating can form one layer of hydrophilic laminate, change traditional glass and dredge
The property of water, therefore, glass cleaner of the present invention can clean glass and increase the automatical cleaning ability of glass, make
Glass after must cleaning can preserve cleaning for a long time.
During preparing silica modified nano titanium dioxide, using D- polysorbate surfactants, and D-
The dosage of D-sorbite is the 0.3%-1% of nano-titanium dioxide quality, and D- D-sorbites can be simultaneously to nano silicon dioxide
It is surface-treated with nano-titanium dioxide, if D- D-sorbite dosages are less than 0.3%, very few cannot fully wrap up of dosage is received
Rice corpuscles, the easily aggregation of not wrapped nano particle make emulsion particle diameter become larger, and dosage can not excessively obtain ideal effect, anyway
Surfactant reduces the polarity of system with respect to backbone, and system cohesive force declines, degradation.
In some embodiments, in the glass cleaner, vanadium ion is adulterated in the nano-titanium dioxide.
Containing transition metal can introduce defect in Nanometer Titanium Dioxide lattice or change cleanliness factor, influence answering for electrons and holes
It closes.Since vanadium metal is to appraise at the current rate, a small amount of Transition Metals V is adulterated in Nanometer Titanium Dioxide can be formed as photo-generate electron-hole pair
Shallow gesture capture trap, extend electrons and holes compound time, to achieve the purpose that improve Nanometer Titanium Dioxide photocatalytic activity.And
And due to transition metal from vanadium have light abstraction width more broader than Nanometer Titanium Dioxide, can will absorb light further extend into it is visible
Light area.After glass cleaner has cleaned glass, the nano-titanium dioxide of the doping vanadium ion remained on glass can utilize
Visible light carries out light-catalyzed reaction, extends the time that glass keeps clean state, the automatically cleaning energy of glass is improved using cleaning agent
Power.
The preparation process of vanadium ion is adulterated in nano-titanium dioxide：By TiCl4It is slowly dropped into distilled water, is formed uniform
Bright titanium compound A.Be 7-9 with ammonium hydroxide tune pH after appropriate ammonium metavanadate is dissolved in the clear solution, formed titanium hydroxide and
The colloidal attitude solution B of vanadium hydroxide, B solution is put into three-necked flask, and 3-5h is reacted at 100 DEG C, after being filtered, washed, filter
Appropriate complexing agent is added in cake, can be obtained vanadium-doped nano titanic oxide transparent photo-catalytic emulsion through control hydrolysis.
In some embodiments, in the glass cleaner, the doping of the vanadium ion is nano-titanium dioxide
The 0.9-1.5% of quality.
A small amount of doping vanadium ion enters in titanium dioxide lattice, replaces titanium ion, is conducive to the transfer of photo-generated carrier, separately
Outside, a series of doped energy-bands are formed after Doped ions enter lattice, the transition that the increase of doped energy-band is remarkably improved electronics is several
Rate achievees the purpose that improve photocatalytic activity to further extend the service life of photo-generate electron-hole；When doping is excessive, greatly
In 1.5%, part vanadium ion is attached to titania surface in the form of the inert oxide of photochemistry, so hinder it is light-catalysed into
One step carries out, and degradation rate is caused to decline；When vanadium doping amount is too small, less than 0.9%, photocatalytic activity improves unobvious.
In some embodiments, in the glass cleaner, the titanium dioxide and the nano silicon dioxide
Mass ratio is 1-4/1.
It is carried using the network limitation nano-titanium dioxide of silica to obtain nanometer porous catalysis material
High photocatalysis efficiency.
Another aspect of the present invention also provides a kind of preparation method of glass cleaner comprising following steps：
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
The isomer of addition toluenesulfonic acid, glycerine, sodium sulfate of polyethenoxy ether of fatty alcohol, orange oil, suitable fourth in stainless steel cauldron
Material stirring is afterwards uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification
For glass cleaner.
Embodiment
Embodiment 1
A kind of glass cleaner, the cleaning agent include the isomer of the toluenesulfonic acid of 0.4 mass parts, 82 mass parts
The citrate of glycerine, the sodium sulfate of polyethenoxy ether of fatty alcohol of 0.3 mass parts, the orange oil of 0.2 mass parts and 1 mass parts；Its
In, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/4/2.
In said program, which further includes the Sodium Polyacrylate of the maleic anhydride modified of 3 mass parts；Described
Acrylic acid and maleic anhydride molar ratio are 3/1 in the Sodium Polyacrylate of maleic anhydride modified.
Preparation method：
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
The isomer of addition toluenesulfonic acid, glycerine, sodium sulfate of polyethenoxy ether of fatty alcohol, orange oil, suitable fourth in stainless steel cauldron
Material stirring is uniformly glass cleaner afterwards by the Sodium Polyacrylate and citrate of enedioic acid anhydride modification.
Glass is cleaned using glass cleaner described in embodiment 1, the water mist noresidue of glass surface, and cleaned
Speed is fast.After cleaning, the water contact angle of glass is 116 °.
Embodiment 2
A kind of glass cleaner, the cleaning agent include the isomer of the toluenesulfonic acid of 1 mass parts, 87 mass parts it is sweet
The citrate of oil, the sodium sulfate of polyethenoxy ether of fatty alcohol of 0.5 mass parts, the orange oil of 0.4 mass parts and 2 mass parts；Wherein,
In the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/9/5.
In said program, which further includes the Sodium Polyacrylate of the maleic anhydride modified of 8 mass parts；Described
Acrylic acid and maleic anhydride molar ratio are 4/1 in the Sodium Polyacrylate of maleic anhydride modified.
Preparation method：
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
The isomer of addition toluenesulfonic acid, glycerine, sodium sulfate of polyethenoxy ether of fatty alcohol, orange oil, suitable fourth in stainless steel cauldron
Material stirring is afterwards uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification
For glass cleaner.
Glass is cleaned using the glass cleaner described in embodiment 2, the water mist noresidue of glass surface, and cleaned
Speed is fast.After cleaning, the water contact angle of glass is 120 °.
Embodiment 3
A kind of glass cleaner, the cleaning agent include the isomer of the toluenesulfonic acid of 0.6 mass parts, 85 mass parts
The citrate of glycerine, the sodium sulfate of polyethenoxy ether of fatty alcohol of 0.4 mass parts, the orange oil of 0.3 mass parts and 1.5 mass parts.；
Wherein, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/6/3.
In said program, which further includes the Sodium Polyacrylate of the maleic anhydride modified of 5 mass parts；Described
Acrylic acid and maleic anhydride molar ratio are 3.5/1 in the Sodium Polyacrylate of maleic anhydride modified.
Preparation method：
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
The isomer of addition toluenesulfonic acid, glycerine, sodium sulfate of polyethenoxy ether of fatty alcohol, orange oil, suitable fourth in stainless steel cauldron
Material stirring is afterwards uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification
For glass cleaner.
Glass is cleaned using glass cleaner described in embodiment 3, the water mist noresidue of glass surface, and cleaned
Speed is fast.After cleaning, the water contact angle of glass is 109 °.
Embodiment 4
A kind of glass cleaner, the cleaning agent include the isomer of the toluenesulfonic acid of 0.6 mass parts, 82 mass parts
The citrate of glycerine, the sodium sulfate of polyethenoxy ether of fatty alcohol of 0.4 mass parts, the orange oil of 0.3 mass parts and 1 mass parts；Its
In, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/5/3.
In said program, which further includes the Sodium Polyacrylate of the maleic anhydride modified of 7 mass parts；Described
Acrylic acid and maleic anhydride molar ratio are 4/1 in the Sodium Polyacrylate of maleic anhydride modified.
In said program, which further includes the nano level silica based titanium oxide compound of 5 mass parts,
Vanadium ion is adulterated in the silica based titanium oxide, the doping of the vanadium ion is silica based titanium oxide quality
8%；The mass ratio of titanium dioxide and nano silicon dioxide is 4/1 in the silica based titanium oxide.
Preparation method：
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
The isomer of addition toluenesulfonic acid, glycerine, sodium sulfate of polyethenoxy ether of fatty alcohol, orange oil, suitable fourth in stainless steel cauldron
Material stirring is afterwards uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification
For glass cleaner.
Glass is cleaned using the glass cleaner described in embodiment 4, the water mist noresidue of glass surface, and cleaned
Speed is fast.After cleaning, the water contact angle of glass is 161 °.
Embodiment 5
A kind of glass cleaner, the cleaning agent include the isomer of the toluenesulfonic acid of 0.8 mass parts, 84 mass parts
The citrate of glycerine, the sodium sulfate of polyethenoxy ether of fatty alcohol of 0.5 mass parts, the orange oil of 0.4 mass parts and 1-2 mass parts.；
Wherein, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/9/5.
In said program, which further includes the Sodium Polyacrylate of the maleic anhydride modified of 3 mass parts；Described
Acrylic acid and maleic anhydride molar ratio are 3/1 in maleic anhydride modified Sodium Polyacrylate.
In said program, which further includes that the nano level silica based titanium oxide of 10 mass parts is compound
Object adulterates vanadium ion in the silica based titanium oxide, and the doping of the vanadium ion is silica based titanium oxide quality
10%；The mass ratio of titanium dioxide and nano silicon dioxide is 2/1 in the silica based titanium oxide.
Preparation method：
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described
The isomer of addition toluenesulfonic acid, glycerine, sodium sulfate of polyethenoxy ether of fatty alcohol, orange oil, suitable fourth in stainless steel cauldron
Material stirring is afterwards uniformly by Sodium Polyacrylate, citrate and the silica based titanium oxide compound of enedioic acid anhydride modification
For glass cleaner.
Glass is cleaned using the glass cleaner described in embodiment 5, the water mist noresidue of glass surface, and cleaned
Speed is fast.After cleaning, the water contact angle of glass is 163 °.
Comparative example 1
A kind of glass cleaner, a kind of glass cleaner are made of following raw material：2-7 parts of butyl glycol ether, third
1-5 parts of glycol methyl ether, 1-4 parts of neopelex, 1-4 parts of ethoxylated dodecyl alcohol, 4-9 parts of sodium pyrophosphate, toluene
60-80 parts of 4-9 parts of sodium sulfonate, 2-5 parts of metasilicate pentahydrate sodium and water.
Glass is cleaned using the glass cleaner described in comparative example 1, the water mist noresidue of glass surface, and cleaned
Speed is fast.After cleaning, the water contact angle of glass is 80 °.
Without departing substantially from the scope or spirit of the invention, the specific implementation mode of description of the invention can be done more
Kind is improved and variation, this will be apparent to those skilled in the art.Other realities obtained by the specification of the present invention
It is apparent obtain to apply mode for technical personnel.Present specification and embodiment are merely exemplary.
Claims (10)
1. a kind of glass cleaner, wherein the cleaning agent includes the isomer of the toluenesulfonic acid of 0.4-1 mass parts；
Wherein, in the isomer, the mass ratio of o-toluene sulfonic acid, p-methyl benzenesulfonic acid and m-toluene sulfonic acid is 1/
(4-9)/(2-5)。
2. glass cleaner according to claim 1, wherein the cleaning agent further includes the glycerine of 82-87 mass parts, 0.3-
The orange oil of the sodium sulfate of polyethenoxy ether of fatty alcohol and 0.2-0.4 mass parts of 0.5 mass parts.
3. glass cleaner according to claim 1, wherein the cleaning agent further includes the maleic acid of 3-8 mass parts
The Sodium Polyacrylate of anhydride modification.
4. glass cleaner according to claim 3, wherein third in the Sodium Polyacrylate of the maleic anhydride modified
Olefin(e) acid is (3-4)/1 with maleic anhydride molar ratio.
5. glass cleaner according to claim 1, wherein the glass cleaner further includes the citric acid of 1-2 mass parts
Salt.
6. glass cleaner according to claim 1, wherein the glass cleaner further includes the nanoscale of 5-10 mass parts
Silica based titanium oxide compound.
7. glass cleaner according to claim 6, wherein adulterate vanadium ion in the silica based titanium oxide.
8. glass cleaner according to claim 7, wherein the doping of the vanadium ion is silica based titanium oxide
The 8-15% of quality.
9. glass cleaner according to claim 6, wherein titanium dioxide and nanometer in the silica based titanium oxide
The mass ratio of silica is 1-4/1.
10. a kind of preparation method according to claim 1 to 9 any one of them glass cleaner, wherein the preparation method packet
Include following steps：
It is added deionized water into stainless steel cauldron, mixing speed is under the stirring of 50-70r/min, to described stainless
Isomer, glycerine, sodium sulfate of polyethenoxy ether of fatty alcohol, orange oil, the maleic two of toluenesulfonic acid are added in steel reaction kettle
Material stirring is uniformly glass afterwards by anhydride modified Sodium Polyacrylate, citrate and silica based titanium oxide compound
Glass cleaning agent.
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| CN201810619914.4A CN108774588A (en) | 2018-06-15 | 2018-06-15 | Glass cleaner and preparation method thereof |
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|---|---|---|---|
| CN201810619914.4A CN108774588A (en) | 2018-06-15 | 2018-06-15 | Glass cleaner and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050003993A1 (en) * | 2002-09-13 | 2005-01-06 | Takahiro Tsumori | Liquid detergent builder and liquid detergent containing the same |
| US20050130870A1 (en) * | 2003-12-16 | 2005-06-16 | Ochomogo Maria G. | Cleaning substrates having low soil redeposition |
| CN104450221A (en) * | 2013-09-16 | 2015-03-25 | 天津普范科技开发有限公司 | Glass cleaning agent |
| CN104877791A (en) * | 2015-05-21 | 2015-09-02 | 青岛启源振东电气有限公司 | Antifreezing type automobile glass cleaning agent |
| CN105273860A (en) * | 2015-11-12 | 2016-01-27 | 扬州大学 | Efficient photocatalytic glass water |
| US20180030387A1 (en) * | 2015-02-05 | 2018-02-01 | Dalli-Werke Gmbh & Co. Kg | Cleaning composition comprising a bleach catalyst and carboxymethylcellulose |
-
2018
- 2018-06-15 CN CN201810619914.4A patent/CN108774588A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050003993A1 (en) * | 2002-09-13 | 2005-01-06 | Takahiro Tsumori | Liquid detergent builder and liquid detergent containing the same |
| US20050130870A1 (en) * | 2003-12-16 | 2005-06-16 | Ochomogo Maria G. | Cleaning substrates having low soil redeposition |
| CN104450221A (en) * | 2013-09-16 | 2015-03-25 | 天津普范科技开发有限公司 | Glass cleaning agent |
| US20180030387A1 (en) * | 2015-02-05 | 2018-02-01 | Dalli-Werke Gmbh & Co. Kg | Cleaning composition comprising a bleach catalyst and carboxymethylcellulose |
| CN104877791A (en) * | 2015-05-21 | 2015-09-02 | 青岛启源振东电气有限公司 | Antifreezing type automobile glass cleaning agent |
| CN105273860A (en) * | 2015-11-12 | 2016-01-27 | 扬州大学 | Efficient photocatalytic glass water |
Non-Patent Citations (2)
| Title |
|---|
| 张青红等: "二氧化硅基氧化钛光催化材料的制备及其活性研究", <<材料科学与工程>> * |
| 魏文德: "<<有机化工原料大全 下卷 2版>>", 31 August 1999 * |
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