CN108987518A - A kind of flexibility condenser mirror - Google Patents

A kind of flexibility condenser mirror Download PDF

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Publication number
CN108987518A
CN108987518A CN201710413138.8A CN201710413138A CN108987518A CN 108987518 A CN108987518 A CN 108987518A CN 201710413138 A CN201710413138 A CN 201710413138A CN 108987518 A CN108987518 A CN 108987518A
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CN
China
Prior art keywords
metallic reflector
buffer layer
flexibility
condenser mirror
layer
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Pending
Application number
CN201710413138.8A
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Chinese (zh)
Inventor
吴历清
张晓岚
籍龙占
王国昌
谢丑相
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Hangzhou Lang Xuxin Mstar Technology Ltd
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Hangzhou Lang Xuxin Mstar Technology Ltd
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Priority to CN201710413138.8A priority Critical patent/CN108987518A/en
Publication of CN108987518A publication Critical patent/CN108987518A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • H01L31/0547Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means comprising light concentrating means of the reflecting type, e.g. parabolic mirrors, concentrators using total internal reflection
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Optical Elements Other Than Lenses (AREA)

Abstract

The present invention provides a kind of flexible condenser mirrors, including the protective layer, metallic reflector and substrate successively contacted;It is compounded between the protective layer and metallic reflector between buffer layer or the metallic reflector and substrate and is compounded with buffer layer;Or between the protective layer and metallic reflector, buffer layer is compounded between the metallic reflector and substrate;The buffer layer is functionally gradient material (FGM).The present invention increases the buffer layer of functionally gradient material (FGM) preparation in flexible condenser mirror; protective layer and metallic reflector can be improved; or the binding force between metallic reflector and substrate and the compatibility between material, and reduce the stress as caused by coefficient of thermal expansion differences between the two;So as to effectively improve the service life of flexible mirrors.

Description

A kind of flexibility condenser mirror
Technical field
The present invention relates to technical field more particularly to a kind of flexible condenser mirrors.
Background technique
Solar energy has good prospect, has been greatly developed as permanent, the clean energy.Solar energy benefit With mainly having photo-thermal and the big system of photovoltaic two, wherein opto-thermal system has advantage at low cost because its system is simple, at present just Commercialized development.In general, solar energy optical-thermal system form has slot type, tower, dish-style (disc type), four germline of Fresnel System, and wherein for trough system due to high-efficient, technology is the most mature and is widelyd popularize.
Reflecting mirror field is the critical component in solar energy hot systems, and initial stage mainly uses 2 or 4 songs in trough system Surface glass reflecting mirror is spliced parabolic trough condenser.Bend glass reflecting mirror is since its matter is heavy, frangible, production cost Height, existing trend are replaced using flexible mirrors.
However existing flexible mirrors mostly use shaggy substrate, it is therefore desirable to add levelling to reduce cost Layer.In order to improve the service life of metallic reflector, flexible mirrors are generally also provided with protective layer.The structure of this sandwich style The poor compatibility of material, the problems such as thermal expansion coefficient difference is big, residual stress is big between the layers are usually deposited, to largely effect on The reflecting mirror service life.
Summary of the invention
In view of this, the technical problem to be solved in the present invention is that a kind of flexible condenser mirror is provided, by flexibility Some important key sequence boundaries in condenser mirror structure add suitable buffer layer, make reflecting mirror durability with higher, Weatherability and durability.
The present invention provides a kind of flexible condenser mirrors, including the protective layer, metallic reflector and substrate successively contacted; It is compounded between the protective layer and metallic reflector between buffer layer or the metallic reflector and substrate and is compounded with buffering Layer;Or between the protective layer and metallic reflector, buffer layer is compounded between the metallic reflector and substrate;It is described Buffer layer is functionally gradient material (FGM).
Preferably, the substrate is compounded with leveling layer towards the side in reflecting layer.
Preferably, the leveling layer is UV glue or organosilicon material.
Preferably, the buffer layer is sieve and silica-sesquioxide or silicon-aluminium-nitride-oxide.
Preferably, in the buffer layer, sieve and silica-sesquioxide or silicon-aluminium-nitride-oxide, material composition change in gradient, along gold Belong to reflecting layer direction aluminium content to increase, along base material direction, silicone content increases.
Preferably, the buffer layer is using silicon target and aluminium target or silico-aluminum target magnetic control sputtering method deposition.It is closed using sial When golden more target sputtering sedimentations, aluminium or silicone content change in gradient according to target site location in each silico-aluminum target.
Preferably, in the silico-aluminum target, Al content from 90% be successively decremented to the content of 10% or Si from 10% according to It is secondary to be incremented to 90%;Or the content of Al is successively decremented to 10% from 90% from 10% content incremented by successively to 90% or Si.
Preferably, the metallic reflector is aluminium, or the composite layer of silver or aluminium and silver.
Preferably, the substrate is sheet metal or resin base material.
Compared with prior art, the present invention provides a kind of flexible condenser mirrors, including protective layer, the gold successively contacted Belong to reflecting layer and substrate;Buffer layer or the metallic reflector and base are compounded between the protective layer and metallic reflector Buffer layer is compounded between material;Or between the protective layer and metallic reflector, between the metallic reflector and substrate It is compounded with buffer layer;The buffer layer is functionally gradient material (FGM).The present invention increases functionally gradient material (FGM) preparation in flexible condenser mirror Buffer layer, the binding force between protective layer and metallic reflector, metallic reflector and substrate can be improved, and reduce the two Between the stress as caused by coefficient of thermal expansion differences, improve material compatibility;So as to effectively improve the use of flexible mirrors Service life.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of flexible condenser mirror provided by the invention;
Fig. 2 is the structural schematic diagram for the flexible condenser mirror that the embodiment of the present invention 1 provides;
Fig. 3 is the structural schematic diagram for the flexible condenser mirror that the embodiment of the present invention 2 provides;
Fig. 4 is another structural schematic diagram of flexible condenser mirror provided by the invention;
Fig. 5 is another structural schematic diagram of flexible condenser mirror provided by the invention.
Specific embodiment
The present invention provides a kind of flexible condenser mirrors, including the protective layer, metallic reflector and substrate successively contacted; It is compounded between the protective layer and metallic reflector between buffer layer or the metallic reflector and substrate and is compounded with buffering Layer, or both has concurrently;The buffer layer is functionally gradient material (FGM).
Flexibility condenser mirror structural schematic diagram provided by the invention is as shown in Figure 1 comprising the protective layer that successively contacts, Buffer layer, metallic reflector and substrate.
Another flexible condenser mirror structural schematic diagram provided by the invention is as shown in Figure 2 comprising successively contacts Protective layer, buffer layer, metallic reflector, leveling layer and substrate.
Another flexible condenser mirror structural schematic diagram provided by the invention is as shown in Figure 3 comprising successively contacts Protective layer, metallic reflector, buffer layer and substrate.
Another flexible condenser mirror structural schematic diagram provided by the invention is as shown in Figure 4 comprising successively contacts Protective layer, metallic reflector, buffer layer, leveling layer and substrate.
Another flexible condenser mirror structural schematic diagram provided by the invention is as shown in Figure 5 comprising successively contacts Protective layer, buffer layer 1, metallic reflector, buffer layer 2, leveling layer and substrate.
Currently preferred, the buffer layer is sieve and silica-sesquioxide or silicon-aluminium-nitride-oxide.Material composition can become in gradient Change, increase along metallic reflector direction aluminium content, along base material direction, silicone content increases.Its thickness is preferably 10~1000nm.
Preferably, the buffer layer is using silicon target and aluminium target or silico-aluminum target magnetic control sputtering method deposition.It is closed using sial When the more target sputtering sedimentations of gold have the buffer layer of gradient, aluminium or silicone content become in gradient according to target site location in each silico-aluminum target Change.Preferably, in target material composition Al content from 90% be successively decremented to the content of 10% or Si from 10% it is incremented by successively to 90%.Or it is preferred, the content of Al is successively passed from 10% content incremented by successively to 90% or Si from 90% in target material composition Reduce to 10%.
The metallic reflector is preferably aluminium, or the composite layer of silver or aluminium and silver.Its thickness is preferably 20~200nm.This Invention is to the combination process of the metallic reflector and is not particularly limited, and can be method well known to those skilled in the art, this The method that invention preferably uses magnetron sputtering.
The substrate is preferably sheet metal or resin base material.Wherein, sheet metal is preferably aluminium sheet, aluminium alloy plate or not Become rusty steel plate etc.;Resin base material is preferably polyethylene terephthalate (PET) or polymethyl methacrylate (PMMA) or poly- third Olefin(e) acid system resin etc..Its thickness is preferably 100~2000um.Currently preferred, the substrate is before use, cleaned. The present invention is to the method for the cleaning and is not particularly limited, and can be method well known to those skilled in the art.
Currently preferred, the substrate is compounded with leveling layer towards the side in reflecting layer.The i.e. described buffer layer is between stream Between leveling and metallic reflector, or between metallic reflector and protective layer.As shown in Fig. 3,4 and 5.
Preferably, the leveling layer is UV glue or organosilicon material.Its thickness is preferably 1~50um.
The present invention increases the buffer layer of functionally gradient material (FGM) preparation in flexible condenser mirror, and leveling layer and gold can be improved Belong to the binding force between reflecting layer, and reduce the stress as caused by coefficient of thermal expansion differences between the two, improves material compatibility; So as to effectively improve the service life of flexible mirrors.
In order to further illustrate the present invention, flexible condenser mirror provided by the invention is carried out below with reference to embodiment detailed Thin description.
Embodiment 1
1, using reflectivity is 60%~70% wire drawing aluminium as substrate, and with a thickness of 0.1~1mm, surface clean is clean;
2, prepared by UV glue leveling layer, and one layer of UV glue is sprayed on aluminium sheet mirror surface, is then exposed, leveling layer with a thickness of 2~ 50um;
3, metallic reflector and buffer layer use magnetron sputtering successive sedimentation, but complete in two process cavities: first Metallic reflector is sputtered in pure Ar atmosphere using aluminium target;Then buffer layer uses 3~5 silico-aluminum targets, in target material composition The content of Al is successively decremented to that the content of 10% or Si is incremented by successively to 90% from 10%, and sputter gas uses Ar/O from 90%2 Mixed gas or Ar/O2/N2Mixed gas.
4, one layer of organosilicon is sprayed as protective layer, with a thickness of 10~100um.
The mirror structure of preparation is as shown in Figure 2.
Embodiment 2
1, substrate is used as using polyethylene terephthalate (PET), with a thickness of 0.1~1mm, surface clean is clean;
2, novel buffer layer and metallic reflector use magnetron sputtering successive sedimentation, but complete in two process cavities: Novel buffer layer uses 3~5 silico-aluminum targets first, and the content of Al is incremented by successively to 90% from 10% in target material composition, or The content of Si is successively decremented to 10% from 90%, and sputter gas uses Ar/O2Mixed gas or Ar/O2/N2Mixed gas;Then Metallic reflector is sputtered under pure Ar atmosphere using aluminium target.
3, one layer of organosilicon is sprayed as protective layer, with a thickness of 10~100um.
The mirror structure of preparation is as shown in Figure 3.
Comparative example 1
According to the method for embodiment 1, cushioning layer material is only replaced with into SiO2, other process conditions are identical, preparation reflection Mirror.Its thickness is identical as reflecting mirror prepared by embodiment 1.
Comparative example 2
According to the method for embodiment 2, cushioning layer material is only replaced with into SiO2, other process conditions are identical, preparation reflection Mirror.Its thickness is identical as reflecting mirror prepared by embodiment 2.
For the improvement effect for testing novel gradient buffer layer prepared by the present invention, following contrast test is carried out:
Boiling water boiling test and the thereafter test of hundred lattice: test is sent out according to by GSB (the German quality association of aluminium part plated film) Capable guide executes.It is 98 that planar sample having a size of 100mmx100mm, which is placed on and dyes red temperature with special color, DEG C desalted water in 8 hours, be then shut off heating function and water temperature be gradually decreased to room temperature, during the cooling of 16 hours Sample, which retains, to be placed in water;The poly- circulation of aforesaid operations step executes 3 times, and it is 72 small that sample, which retains the total duration placed in water, When.
After completing the above boiling water boiling test, according to ISO2409-1992 standard, hundred lattice are carried out on the surface of all samples Test, test result are as shown in table 1:
1 boiling test of table and thereafter hundred lattice test results
In above-mentioned test, the edge of notch is completely smooth, and grid edge does not have any peeling.ISO grade: 0;
There is small pieces peeling in the intersection of notch, actual spoilage is no more than 5% in the area Hua Ge.ISO grade: 1;
The edge and/or intersection of notch, which have, to be peeled off, and area is greater than 5%, but less than 15%.ISO grade: 2;
Reflecting mirror prepared by the present invention has excellent adhesive force it can be seen from testing above.
Salt spray test: (NSS) is tested according to the neutral salt spray of ISO 9227-2012, to Examples 1 to 2 and comparative example 1 The reflecting mirror of~2 preparations is detected, and the results are shown in Table 2:
2 salt spray test result of table
As can be seen from the above embodiments, flexible condenser mirror prepared by the present invention has longer service life.
The above description of the embodiment is only used to help understand the method for the present invention and its core ideas.It should be pointed out that pair For those skilled in the art, without departing from the principle of the present invention, the present invention can also be carried out Some improvements and modifications, these improvements and modifications also fall within the scope of protection of the claims of the present invention.

Claims (10)

1. a kind of flexibility condenser mirror, which is characterized in that including the protective layer, metallic reflector and substrate successively contacted;Institute It states to be compounded between protective layer and metallic reflector between buffer layer or the metallic reflector and substrate and is compounded with buffering Layer;Or between the protective layer and metallic reflector, buffer layer is compounded between the metallic reflector and substrate;It is described Buffer layer is functionally gradient material (FGM).
2. it is according to claim 1 flexibility condenser mirror, which is characterized in that the substrate towards metallic reflector one Side is compounded with leveling layer.
3. flexibility condenser mirror according to claim 2, which is characterized in that the leveling layer is UV glue or organosilicon material Material.
4. flexibility condenser mirror according to claim 1, which is characterized in that the buffer layer is sieve and silica-sesquioxide or silicon Aluminum ox nitride.
5. it is according to claim 4 flexibility condenser mirror, which is characterized in that in the buffer layer, sieve and silica-sesquioxide or Silicon-aluminium-nitride-oxide, material composition change in gradient, increase along metallic reflector direction aluminium content, along base material direction, silicone content Increase.
6. flexibility condenser mirror according to claim 4, which is characterized in that the buffer layer uses silicon target and aluminium target, Or silico-aluminum target magnetic control sputtering method deposition.
7. flexibility condenser mirror according to claim 5, which is characterized in that the buffer layer uses the more targets of silico-aluminum Sputtering sedimentation, aluminium or silicone content change in gradient according to target site location in each silico-aluminum target.
8. it is according to claim 7 flexibility condenser mirror, which is characterized in that in the silico-aluminum target, Al content from 90% be successively decremented to 10% or Si content it is incremented by successively to 90% from 10%;Or the content of Al is incremented by successively from 10% Content to 90% or Si is successively decremented to 10% from 90%.
9. flexibility condenser mirror according to claim 1, which is characterized in that the metallic reflector is aluminium, or silver-colored, or The composite layer of aluminium and silver.
10. flexibility condenser mirror according to claim 1, which is characterized in that the substrate is sheet metal or resin Substrate.
CN201710413138.8A 2017-06-05 2017-06-05 A kind of flexibility condenser mirror Pending CN108987518A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112397528A (en) * 2019-08-16 2021-02-23 新唐科技股份有限公司 Optical sensing filter and forming method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070243355A1 (en) * 2004-09-21 2007-10-18 Guardian Industries Corp. First surface mirror with silicon-metal oxide nucleation layer
CN201344978Y (en) * 2009-02-10 2009-11-11 光驰科技(上海)有限公司 Silver-coated reflector
CN201654264U (en) * 2010-03-17 2010-11-24 常州龙腾太阳能热电设备有限公司 Reflector suitable for trough solar power generation
CN102277520A (en) * 2010-06-08 2011-12-14 西安康博新材料科技有限公司 Aluminium-based material reflector and preparation method thereof
CN202710766U (en) * 2012-08-12 2013-01-30 兰州大成科技股份有限公司 Solar reflector
CN104678469A (en) * 2015-03-17 2015-06-03 中国科学院上海高等研究院 Graded-index material distributed bragg reflector (DBR) and manufacturing method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070243355A1 (en) * 2004-09-21 2007-10-18 Guardian Industries Corp. First surface mirror with silicon-metal oxide nucleation layer
CN201344978Y (en) * 2009-02-10 2009-11-11 光驰科技(上海)有限公司 Silver-coated reflector
CN201654264U (en) * 2010-03-17 2010-11-24 常州龙腾太阳能热电设备有限公司 Reflector suitable for trough solar power generation
CN102277520A (en) * 2010-06-08 2011-12-14 西安康博新材料科技有限公司 Aluminium-based material reflector and preparation method thereof
CN202710766U (en) * 2012-08-12 2013-01-30 兰州大成科技股份有限公司 Solar reflector
CN104678469A (en) * 2015-03-17 2015-06-03 中国科学院上海高等研究院 Graded-index material distributed bragg reflector (DBR) and manufacturing method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112397528A (en) * 2019-08-16 2021-02-23 新唐科技股份有限公司 Optical sensing filter and forming method thereof
TWI748226B (en) * 2019-08-16 2021-12-01 新唐科技股份有限公司 Photo sensor filtron and methods for forming the same
CN112397528B (en) * 2019-08-16 2023-09-29 新唐科技股份有限公司 Optical sensing filter and forming method thereof

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Application publication date: 20181211