CN108977717A - A kind of durable filament of incandescent lamp and its manufacturing process - Google Patents

A kind of durable filament of incandescent lamp and its manufacturing process Download PDF

Info

Publication number
CN108977717A
CN108977717A CN201810717005.4A CN201810717005A CN108977717A CN 108977717 A CN108977717 A CN 108977717A CN 201810717005 A CN201810717005 A CN 201810717005A CN 108977717 A CN108977717 A CN 108977717A
Authority
CN
China
Prior art keywords
powder
parts
incandescent lamp
tungsten
filament
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810717005.4A
Other languages
Chinese (zh)
Inventor
沈建飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dingyuan Langsai Pu Lighting Appliance Co Ltd
Original Assignee
Dingyuan Langsai Pu Lighting Appliance Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dingyuan Langsai Pu Lighting Appliance Co Ltd filed Critical Dingyuan Langsai Pu Lighting Appliance Co Ltd
Priority to CN201810717005.4A priority Critical patent/CN108977717A/en
Publication of CN108977717A publication Critical patent/CN108977717A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/02Alloys containing less than 50% by weight of each constituent containing copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/04Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
    • B05D1/06Applying particulate materials
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/045Alloys based on refractory metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C27/00Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/04Alloys based on tungsten or molybdenum
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/60Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01KELECTRIC INCANDESCENT LAMPS
    • H01K1/00Details
    • H01K1/02Incandescent bodies
    • H01K1/04Incandescent bodies characterised by the material thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01KELECTRIC INCANDESCENT LAMPS
    • H01K1/00Details
    • H01K1/02Incandescent bodies
    • H01K1/04Incandescent bodies characterised by the material thereof
    • H01K1/08Metallic bodies
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01KELECTRIC INCANDESCENT LAMPS
    • H01K3/00Apparatus or processes adapted to the manufacture, installing, removal, or maintenance of incandescent lamps or parts thereof
    • H01K3/02Manufacture of incandescent bodies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Common Detailed Techniques For Electron Tubes Or Discharge Tubes (AREA)

Abstract

The invention discloses a kind of durable filament of incandescent lamp and its manufacturing process, it is characterised in that it includes following parts by weight raw material: 10-20 parts of tungsten powder, 5-10 parts of nickel powder, 5-10 parts of molybdenum powder, 3-7 parts of copper powder, cobalt powder 2-6 powder, 2-6 parts of potassium oxide powder, 2-6 parts of silica powder, 2-6 parts of alumina powder, oxidation sodium powder 2-6 parts, 1-4 parts of silicon dioxide powder, 1-4 parts of thorium anhydride powder, 1-4 parts of silica flour, 1-3 parts of hardening agent, 1-3 parts of stabilizer, 1-2 parts of antioxidant.A kind of durable filament of incandescent lamp of the present invention and its manufacturing process, raw material are made of various metals, and material evaporation rate is small, improves the service life of filament, enhances the conductivity of filament, there is certain intensity, toughness, and lighting hours is long.

Description

A kind of durable filament of incandescent lamp and its manufacturing process
Technical field
The present invention relates to bulb technologies fields, and in particular to a kind of durable filament of incandescent lamp and its production technology.
Background technique
Traditional incandescent lamp filament is that single tungsten metal passes through forging, powder metallurgy, the manufacturing process such as wire drawing, use mostly Service life is short, and conductivity is not high, and light radiation range is small, and intensity is low, does not have toughness, blacks using over time, tungsten wire is easy, is sagging Fracture.The high-end tungsten wire material having, price is relatively high, is not suitable for being used in incandescent lamp field on a large scale, is unfavorable for being widely applied It uses.
Summary of the invention
The purpose of the present invention is to solve the above-mentioned problems, a kind of durable filament of incandescent lamp is provided, in traditional tungsten wire Nickel, molybdenum, cobalt etc. is added, tungsten wire alloy is made, in electroplating surface oxidation resistant alloy layer, then plating heat-resistant stable layer, improves tungsten Intensity, toughness, the conductivity, radiation scope of silk, are allowed to use for a long time in the high temperature environment, and manufacturing process is simple, Be conducive to produce on a large scale and promote.
To achieve the goals above, the present invention is achieved by the following technical solutions: a kind of durable filament of incandescent lamp is pressed According to following parts by weight raw material composition: 10-20 parts of tungsten powder, 5-10 parts of nickel powder, 5-10 parts of molybdenum powder, 3-7 parts of copper powder, cobalt powder 2-6 powder, 2-6 parts of potassium oxide powder, 2-6 parts of silica powder, 2-6 parts of alumina powder, oxidation sodium powder 2-6 parts, 1-4 parts of silicon dioxide powder, dioxy Change 1-4 parts of thorium powder, 1-4 parts of silica flour, 1-3 parts of hardening agent, 1-3 parts of stabilizer, 1-2 parts of antioxidant.
Further, the durable filament of a kind of incandescent lamp forms: 13-17 parts of tungsten powder, nickel powder according to the raw material of following parts by weight 6-8 parts, 6-8 parts of molybdenum powder, 4-6 parts of copper powder, cobalt powder 3-5 powder, 3-5 parts of potassium oxide powder, 3-5 parts of silica powder, alumina powder 3-5 Part, oxidation sodium powder 3-5 parts, 2-3 parts of silicon dioxide powder, 2-3 parts of thorium anhydride powder, 2-3 parts of silica flour, 1.5-2.5 parts of hardening agent, 1.5-2.5 parts of stabilizer, 1.2-1.8 parts of antioxidant.
Further, the durable filament of a kind of incandescent lamp forms: 15 parts of tungsten powder, nickel powder 7 according to the raw material of following parts by weight Part, 7 parts of molybdenum powder, 5 parts of copper powder, 4 powder of cobalt powder, 4 parts of potassium oxide powder, 4 parts of silica powder, 4 parts of alumina powder, oxidation 4 parts of sodium powder, two 2.5 parts of silica powder, 2.5 parts of thorium anhydride powder, 2.5 parts of silica flour, 2 parts of hardening agent, 2 parts of stabilizer, 1.5 parts of antioxidant.
A kind of its manufacturing process of durable filament of incandescent lamp, includes the following steps:
S1, powder metallurgy: by tungsten powder, nickel powder, molybdenum powder, copper powder, cobalt powder, in the ratio mix, be put into hydrogen furnace be powered burn Knot, is made alloyed tungsten metal bar;
S2, it pulls out and draws wire: metal bar rotation hammer machine forging will be obtained in S1, by diamond pore, silk is repeatedly drawn into, crimps Spiral alloy tungsten wire;
S3, electrostatic spraying: by the ratio potassium oxide powder, silica powder, alumina powder, oxidation sodium powder, silicon dioxide powder, dioxy Change thorium powder to be sufficiently mixed, by electrostatic spraying, on the alloy tungsten wire that even application to S1 obtains, obtains spraying alloy tungsten wire;
S4, plating: the ratio silica flour, hardening agent, stabilizer, antioxidant are sufficiently mixed, the spray that plating to S3 obtains It applies on alloy tungsten wire, obtains the durable filament of incandescent lamp.
In summary the invention has the following advantages: the produced filament of the present invention, with certain intensity, tough Property, conductivity is high, radiation scope is big, is not easy to black, long service life, can be for a long time using in the high temperature environment, manufacture Simple process, being capable of large-scale promotion use.
Specific embodiment
Specific embodiment 1: a kind of durable filament of incandescent lamp forms: 10 parts of tungsten powder, nickel powder according to the raw material of following parts by weight 5 parts, 5 parts of molybdenum powder, 3 parts of copper powder, 2 powder of cobalt powder, 2 parts of potassium oxide powder, 2 parts of silica powder, 2 parts of alumina powder, oxidation 2 parts of sodium powder, 1 part of silicon dioxide powder, 1 part of thorium anhydride powder, 1 part of silica flour, 1 part of hardening agent, 1 part of stabilizer, 1 part of antioxidant.
A kind of manufacturing process of the durable filament of incandescent lamp are as follows:
S1, powder metallurgy: by tungsten powder, nickel powder, molybdenum powder, copper powder, cobalt powder, in the ratio mix, be put into hydrogen furnace be powered burn Knot, is made alloyed tungsten metal bar;
S2, it pulls out and draws wire: metal bar rotation hammer machine forging will be obtained in S1, by diamond pore, silk is repeatedly drawn into, crimps Spiral alloy tungsten wire;
S3, electrostatic spraying: by the ratio potassium oxide powder, silica powder, alumina powder, oxidation sodium powder, silicon dioxide powder, dioxy Change thorium powder to be sufficiently mixed, by electrostatic spraying, on the alloy tungsten wire that even application to S1 obtains, obtains spraying alloy tungsten wire;
S4, plating: the ratio silica flour, hardening agent, stabilizer, antioxidant are sufficiently mixed, the spray that plating to S3 obtains It applies on alloy tungsten wire, obtains the durable filament of incandescent lamp.
Specific embodiment 2: a kind of durable filament of incandescent lamp forms: 15 parts of tungsten powder, nickel powder 7 according to following raw material Part, 7 parts of molybdenum powder, 5 parts of copper powder, 4 powder of cobalt powder, 4 parts of potassium oxide powder, 4 parts of silica powder, 4 parts of alumina powder, oxidation 4 parts of sodium powder, two 2.5 parts of silica powder, 2.5 parts of thorium anhydride powder, 2.5 parts of silica flour, 2 parts of hardening agent, 2 parts of stabilizer, 1.5 parts of antioxidant.
A kind of manufacturing process of the durable filament of incandescent lamp are as follows:
S1, powder metallurgy: by tungsten powder, nickel powder, molybdenum powder, copper powder, cobalt powder, in the ratio mix, be put into hydrogen furnace be powered burn Knot, is made alloyed tungsten metal bar;
S2, it pulls out and draws wire: metal bar rotation hammer machine forging will be obtained in S1, by diamond pore, silk is repeatedly drawn into, crimps Spiral alloy tungsten wire;
S3, electrostatic spraying: by the ratio potassium oxide powder, silica powder, alumina powder, oxidation sodium powder, silicon dioxide powder, dioxy Change thorium powder to be sufficiently mixed, by electrostatic spraying, on the alloy tungsten wire that even application to S1 obtains, obtains spraying alloy tungsten wire;
S4, plating: the ratio silica flour, hardening agent, stabilizer, antioxidant are sufficiently mixed, the spray that plating to S3 obtains It applies on alloy tungsten wire, obtains the durable filament of incandescent lamp.
Specific embodiment 3: a kind of durable filament of incandescent lamp forms: 20 parts of tungsten powder, nickel powder 10 according to following raw material Part, 10 parts of molybdenum powder, 7 parts of copper powder, 6 powder of cobalt powder, 6 parts of potassium oxide powder, 6 parts of silica powder, 6 parts of alumina powder, oxidation 6 parts of sodium powder, 4 parts of silicon dioxide powder, 4 parts of thorium anhydride powder, 4 parts of silica flour, 3 parts of hardening agent, 3 parts of stabilizer, 2 parts of antioxidant.
A kind of manufacturing process of the durable filament of incandescent lamp are as follows:
S1, powder metallurgy: by tungsten powder, nickel powder, molybdenum powder, copper powder, cobalt powder, in the ratio mix, be put into hydrogen furnace be powered burn Knot, is made alloyed tungsten metal bar;
S2, it pulls out and draws wire: metal bar rotation hammer machine forging will be obtained in S1, by diamond pore, silk is repeatedly drawn into, crimps Spiral alloy tungsten wire;
S3, electrostatic spraying: by the ratio potassium oxide powder, silica powder, alumina powder, oxidation sodium powder, silicon dioxide powder, dioxy Change thorium powder to be sufficiently mixed, by electrostatic spraying, on the alloy tungsten wire that even application to S1 obtains, obtains spraying alloy tungsten wire;
S4, plating: the ratio silica flour, hardening agent, stabilizer, antioxidant are sufficiently mixed, the spray that plating to S3 obtains It applies on alloy tungsten wire, obtains the durable filament of incandescent lamp.
Embodiment provided above is better embodiment of the invention, only is used to facilitate to illustrate the present invention, not to this hair It is bright to make any form of restriction, any those of ordinary skill in the art, if not departing from the proposed skill of the present invention In the range of art feature, using the equivalent embodiment for locally changing or modifying made by disclosed technology contents, and Without departing from technical feature content of the invention, in the range of still falling within the technology of the present invention feature.

Claims (4)

1. a kind of durable filament of incandescent lamp, which is characterized in that be made of raw material from the following weight: 10-20 parts of tungsten powder, nickel powder 5- 10 parts, 5-10 parts of molybdenum powder, 3-7 parts of copper powder, cobalt powder 2-6 powder, 2-6 parts of potassium oxide powder, 2-6 parts of silica powder, alumina powder 2-6 Part, 1-4 parts of silicon dioxide powder, 1-4 parts of thorium anhydride powder, 1-4 parts of silica flour, 1-3 parts of hardening agent, is stablized at sodium powder 2-6 parts of oxidation 1-3 parts of agent, 1-2 parts of antioxidant.
2. the durable filament of a kind of incandescent lamp according to claim 1, which is characterized in that by the raw material system of following parts by weight At: 13-17 parts of tungsten powder, 6-8 parts of nickel powder, 6-8 parts of molybdenum powder, 4-6 parts of copper powder, cobalt powder 3-5 powder, 3-5 parts of potassium oxide powder, silica powder 3-5 parts, 3-5 parts of alumina powder, oxidation sodium powder 3-5 parts, 2-3 parts of silicon dioxide powder, 2-3 parts of thorium anhydride powder, silica flour 2-3 Part, 1.5-2.5 parts of hardening agent, 1.5-2.5 parts of stabilizer, 1.2-1.8 parts of antioxidant.
3. the durable filament of a kind of incandescent lamp according to claim 1, which is characterized in that by the raw material group of following parts by weight At: 15 parts of tungsten powder, 7 parts of nickel powder, 7 parts of molybdenum powder, 5 parts of copper powder, 4 powder of cobalt powder, 4 parts of potassium oxide powder, 4 parts of silica powder, alumina powder 4 Part, oxidation 4 parts of sodium powder, 2.5 parts of silicon dioxide powder, 2.5 parts of thorium anhydride powder, 2.5 parts of silica flour, 2 parts of hardening agent, stabilizer 2 Part, 1.5 parts of antioxidant.
4. a kind of manufacturing process of the durable filament of incandescent lamp according to claim 1 to 3, which is characterized in that including such as Lower step:
S1, powder metallurgy: by tungsten powder, nickel powder, molybdenum powder, copper powder, cobalt powder, in the ratio mix, be put into hydrogen furnace be powered burn Knot, is made alloyed tungsten metal bar;
S2, it pulls out and draws wire: metal bar rotation hammer machine forging will be obtained in S1, by diamond pore, silk is repeatedly drawn into, crimps Spiral alloy tungsten wire;
S3, electrostatic spraying: by the ratio potassium oxide powder, silica powder, alumina powder, oxidation sodium powder, silicon dioxide powder, dioxy Change thorium powder to be sufficiently mixed, by electrostatic spraying, on the alloy tungsten wire that even application to S1 obtains, obtains spraying alloy tungsten wire;
S4, plating: the ratio silica flour, hardening agent, stabilizer, antioxidant are sufficiently mixed, the spray that plating to S3 obtains It applies on alloy tungsten wire, obtains the durable filament of incandescent lamp.
CN201810717005.4A 2018-07-03 2018-07-03 A kind of durable filament of incandescent lamp and its manufacturing process Withdrawn CN108977717A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810717005.4A CN108977717A (en) 2018-07-03 2018-07-03 A kind of durable filament of incandescent lamp and its manufacturing process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810717005.4A CN108977717A (en) 2018-07-03 2018-07-03 A kind of durable filament of incandescent lamp and its manufacturing process

Publications (1)

Publication Number Publication Date
CN108977717A true CN108977717A (en) 2018-12-11

Family

ID=64536549

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810717005.4A Withdrawn CN108977717A (en) 2018-07-03 2018-07-03 A kind of durable filament of incandescent lamp and its manufacturing process

Country Status (1)

Country Link
CN (1) CN108977717A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1281330A (en) * 2000-07-21 2001-01-24 陈刘旸 Electrothermal tungsten powder and its preparing process and application
CN104008939A (en) * 2014-06-19 2014-08-27 苏州普京真空技术有限公司 Durable electronic gun lamp filament
CN105750342A (en) * 2007-11-21 2016-07-13 株式会社东芝 Process for producing tungsten wire

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1281330A (en) * 2000-07-21 2001-01-24 陈刘旸 Electrothermal tungsten powder and its preparing process and application
CN105750342A (en) * 2007-11-21 2016-07-13 株式会社东芝 Process for producing tungsten wire
CN104008939A (en) * 2014-06-19 2014-08-27 苏州普京真空技术有限公司 Durable electronic gun lamp filament

Similar Documents

Publication Publication Date Title
Schade 100 years of doped tungsten wire
CN101178957B (en) Method of producing the copper alloy contact wire
CN103920870B (en) A kind of porous spherical tungsten-rhenium alloy powder body and preparation method thereof
CN102601378A (en) Method for preparing ultrafine tungsten copper composite powder by low-temperature combustion method
CN114213001B (en) Glass tube for lead-free ultraviolet-transmitting lamp
CN101392347B (en) In-situ synthesized Al2O3 reinforced molybdenum based composite material and preparation method thereof
CN110106418A (en) A kind of rare earth molybdenum and tungsten alloy and preparation method thereof for cutting wire
CA2563856A1 (en) Method for manufacturing rhenium-containing alloy powder and conductor paste
CN104505287A (en) Preparation method of rod-shaped tin oxide-reinforced silver-based electric contact material
CN108977717A (en) A kind of durable filament of incandescent lamp and its manufacturing process
CN109797391A (en) A kind of preparation method of wind power bearing low dilution rate FeCrCoNiMoTi high-entropy alloy powder and its cladding layer
CN107282083A (en) A kind of graphite phase carbon nitride nano material of silicon zinc doping and its application in photo catalytic reduction
CN111500104A (en) Preparation method of nickel-coated graphene silicon carbide
JP2006160596A (en) Highly wear-resistant zirconia microsphere and method for producing the same
CN110014162A (en) A method of preparing spherical molybdenum base powder
CN102832087B (en) Steel core wire replaces the tungsten filament manufacture craft of molybdenum filament
CN105234586A (en) Cadmium-free low-silver brazing material
JPH08311630A (en) Corrosion resistant and wear resistant self-fluxing alloy for thermal spraying
CN101640159A (en) Electrode main-post material of rhenium-tungsten filaments, and applications thereof
CN104591740A (en) Impact-resistant ceramic material and preparation method thereof
CN101249567A (en) Preparation method of nano-scale molybdenum powder
CN102430610B (en) Preparation method for molybdenum alloy wires doped with nanometer rare earth oxides
Bowers Scanning our past from London: The filament lamp and new materials
CN102560311A (en) Alloy used in hot plating process of tinned wire
CN105463257B (en) A kind of nickel base superalloy powder

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20181211