CN108975710A - 用于河道浅水区护坡的釉面砖的制备方法及其应用 - Google Patents
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Abstract
本发明涉及水体治理领域，特别是指用于河道浅水区护坡的釉面砖的制备方法及其应用。包括以下步骤：石墨烯混杂Bi2WO6微晶玻璃微粉制备；石墨烯混杂Bi2WO6微晶玻璃粉通过等离子体方法处理制备石墨烯混杂Bi2WO6微晶玻璃釉面砖。本发明无需爆气增氧，节能环保，废物利用，工艺简单。
Description
技术领域
本发明涉及水体治理领域，特别是指用于河道浅水区护坡的釉面砖的制备方法及其应用。
背景技术
现代化工业的发展导致资源和能源的极大消耗，伴随而来的是自然环境的严重恶化。为了应对工业污染带来的环境危机，寻求廉价高效的环境污染治理技术成为科技工作者的关注焦点。要求环境与经济协调发展，就需要我们研究新型材料，尤其是印染、炼油和制药等工业生产，产生的污水对人们生活造成了很大影响。为了解决水污染，光催化技术已经广泛的引起了人们的注意，因为光催化技术在可见光的条件下具有高效性和环境友好性的优点。
光催化氧化技术是由日本科学家Fujishima和Honda发现的n型TiO2半导体的光解水现象发展而来的一种高级氧化技术，可以利用自然界广泛存在的太阳能降解有机污染物。随后半导体光催化迅速发展。TiO2是一种重要的光催化剂，具有好的化学稳定性和光化学稳定性。然而，TiO2只能利用波长较短的紫外光（λ<387nm）,而且太阳光中的紫外光只占大约5%，从而极大地限制了TiO2光催化技术向实际应用的转化。为了更好地利用可见光，近年来光催化领域的研究集中在高可见光响应和活性的光催化材料的研发。为了提高宽禁带光催化剂的可见光催化性能，研究者们研究了各种改性方法，主要包括：掺杂金属离子或者非金属离子（目前仍无法实现全谱强吸收），与禁带宽度相匹配的半导体复合，光敏化处理，异质结等。虽然掺杂改性可以提高 TiO2在可见光下的光催化性能，但是其本身的禁带宽度较宽（3.2e V），对可见光的利用率仍不高。另外一种方法就是开发出新型的光催化剂此外，其中钨酸盐材料表现比较好。钨酸铋作为 Aurivillius 家族中最简单的一种成为了研究的热点。
Bi2WO6是一种典型的n型半导体,其禁带宽度为 2.75e V，它是由Bi2O2 2+层和WO4 2-层沿着c轴交替组成的钙钛矿片层结构，在电极材料、太阳能转化、催化剂等中有广泛的应用。已经有文献报道：Kudo和Hiji发现Bi2WO6光催化剂对O2的发展具有光催化作用和Zou等发现在可见光下能够降解有机化合物，作为一种新型的半导体材料，Bi2WO6光催化材料的研究将为光催化去除和降解有机污染物开辟一条新的途径，在环境净化和新能源开发方面具有非常重要的实用价值。由于Bi2WO6本身具有特殊的层状结构，窄的禁带宽度，能充分的利用太阳光，所以研究Bi2WO6光催化材料，提高其对太阳光的利用，对治理环境污染和开发新能源方面具有重要的意义。
众所周知，有效的光催化过程需要具备以下几个条件：光生电子和空穴的高迁移率；直接的可见光催化效果；合适的能带宽度；对有机污染物的高吸附能力。一般认为，光催化反应发生的前提条件是受体电势比半导体导带电势低，供体电势比半导体价带电势高，这样才能获得有效的光生电荷载流子的迁移。
发明内容
本发明提出用于河道浅水区护坡的釉面砖的制备方法，解决了治理环境污染和开发新能源的技术问题。
本发明的技术方案是这样实现的：
用于河道浅水区护坡的釉面砖的制备方法，包括以下步骤：
（1）石墨烯混杂Bi2WO6微晶玻璃微粉制备；
（2）石墨烯混杂Bi2WO6微晶玻璃粉通过等离子体方法处理制备石墨烯混杂Bi2WO6微晶玻璃釉面砖。
所述步骤（1）的具体操作为：使用超细粉碎装置，将石墨烯混合Bi2WO6微晶玻璃粉碎成0.1-100μm大小的颗粒微粉。
所述步骤（2）的具体操作为：使用等离子体喷涂装置将石墨烯混杂Bi2WO6微晶玻璃微粉喷涂到砖的表面，直接制备出石墨烯混杂Bi2WO6微晶玻璃釉面砖。
所述的用于河道浅水区护坡的釉面砖的应用，所述用于河道浅水区护坡的釉面砖在河涌黑臭水体净化、整治方面的应用。
所述的用于河道浅水区护坡的釉面砖的应用，所述用于河道浅水区护坡的釉面砖在河涌黑臭水体净化、整治方面的应用。
本发明的有益效果在于：
本发明专利，根据这个实际需求，利用超细粉碎的方法，制备Bi2WO6微晶玻璃晶体材料粉，经等离子体涂覆加工，将Bi2WO6微晶玻璃晶体材料粉喷涂改性聚丙烯或聚乙烯纤维制成网上，制备出具有清洁河涌黑臭水体功能的自清洁网。与现有技术相比最大的特点在于不需要通电，无需爆气增氧，节能环保，废物利用，工艺简单。
具体实施方式
下面将结合本发明实施例，对本发明的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有付出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
本实施例的用于河道浅水区护坡的釉面砖的制备方法，包括以下步骤：
用超微粉碎机制备Bi2WO6微晶玻璃粉到1μm大小、石墨烯粉碎至50μm。利用等离子体喷涂机处理石墨烯混杂Bi2WO6微晶玻璃制备石墨烯混杂Bi2WO6微晶玻璃釉面砖。将石墨烯混杂Bi2WO6微晶玻璃釉面砖置于河涌浅水区护坡，实现石墨烯混杂Bi2WO6微晶玻璃釉面砖对河涌黑臭水体进行整治。
实施例2
本实施例的用于河道浅水区护坡的釉面砖的制备方法，包括以下步骤：
用超微粉碎机制备Bi2WO6微晶玻璃粉到0.5μm大小、石墨烯粉碎至80μm。利用等离子体处理石墨烯混杂Bi2WO6微晶玻璃制备石墨烯混杂Bi2WO6微晶玻璃釉面砖。将石墨烯混杂Bi2WO6微晶玻璃釉面砖置于河涌浅水区护坡，实现石墨烯混杂Bi2WO6微晶玻璃釉面砖对河涌黑臭水体进行整治。
实施例3
本实施例的用于河道浅水区护坡的釉面砖的制备方法，包括以下步骤：
用超微粉碎机制备Bi2WO6微晶玻璃粉到20μm大小、石墨烯粉碎至100μm。利用等离子体处理石墨烯混杂Bi2WO6微晶玻璃制备石墨烯混杂Bi2WO6微晶玻璃釉面砖。将石墨烯混杂Bi2WO6微晶玻璃釉面砖置于河涌浅水区护坡，实现石墨烯混杂Bi2WO6微晶玻璃釉面砖对河涌黑臭水体进行整治。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (4)
1.用于河道浅水区护坡的釉面砖的制备方法，其特征在于，包括以下步骤：
（1）石墨烯混杂Bi2WO6微晶玻璃微粉制备；
（2）石墨烯混杂Bi2WO6微晶玻璃粉通过等离子体方法处理制备石墨烯混杂Bi2WO6微晶玻璃釉面砖。
2.如权利要求1所述的用于河道浅水区护坡的釉面砖的制备方法，其特征在于，所述步骤（1）的具体操作为：使用超细粉碎机将石墨烯混合Bi2WO6微晶玻璃粉碎成0.1-100μm大小的颗粒微粉。
3.如权利要求1所述的用于河道浅水区护坡的釉面砖的制备方法，其特征在于，所述步骤（2）的具体操作为：使用等离子体喷涂装置将石墨烯混杂Bi2WO6微晶玻璃微粉喷涂到砖的表面，直接制备出石墨烯混杂Bi2WO6微晶玻璃釉面砖。
4.如权利要求1所述的用于河道浅水区护坡的釉面砖的应用，其特征在于：所述用于河道浅水区护坡的釉面砖在河涌黑臭水体净化、整治方面的应用。
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110304879A (zh) * | 2019-06-28 | 2019-10-08 | 济南大学 | 一种使混凝土具有水体净化功能的方法及具有水体净化功能的混凝土 |
| CN110655141A (zh) * | 2019-09-20 | 2020-01-07 | 蚌埠学院 | 一种利用CdS玻璃色釉修复水体微生态系统的方法 |
| CN115217073A (zh) * | 2022-07-12 | 2022-10-21 | 杭州乾智坤达新材料科技有限公司 | 一种微晶玻璃水工护坡组件及其施工方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102121720A (zh) * | 2011-03-31 | 2011-07-13 | 芦建锋 | 光量子油烟净化器 |
| CN103301833A (zh) * | 2013-02-04 | 2013-09-18 | 上海交通大学 | Yb3+-Tm3+-Li+三掺杂Bi2WO6/CNTs上转换光催化材料 |
| CN105772221A (zh) * | 2016-03-08 | 2016-07-20 | 上海交通大学 | 一种多功能空气净化装置 |
| CN106698585A (zh) * | 2016-12-27 | 2017-05-24 | 钟华 | 利用石墨烯改性纳米二氧化钛光触媒纤维网整治河涌黑臭水体的方法 |
| CN106999847A (zh) * | 2014-09-10 | 2017-08-01 | 日东电工株式会社 | 改进的空气净化系统和用于除去甲醛的方法 |
-
2018
- 2018-07-26 CN CN201810833095.3A patent/CN108975710A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102121720A (zh) * | 2011-03-31 | 2011-07-13 | 芦建锋 | 光量子油烟净化器 |
| CN103301833A (zh) * | 2013-02-04 | 2013-09-18 | 上海交通大学 | Yb3+-Tm3+-Li+三掺杂Bi2WO6/CNTs上转换光催化材料 |
| CN106999847A (zh) * | 2014-09-10 | 2017-08-01 | 日东电工株式会社 | 改进的空气净化系统和用于除去甲醛的方法 |
| CN105772221A (zh) * | 2016-03-08 | 2016-07-20 | 上海交通大学 | 一种多功能空气净化装置 |
| CN106698585A (zh) * | 2016-12-27 | 2017-05-24 | 钟华 | 利用石墨烯改性纳米二氧化钛光触媒纤维网整治河涌黑臭水体的方法 |
Non-Patent Citations (1)
| Title |
|---|
| 高二平等: "石墨烯/Bi2WO6可见光催化材料合成及增强的光催化性能", 《第十三届全国太阳能光化学与光催化学术会议》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110304879A (zh) * | 2019-06-28 | 2019-10-08 | 济南大学 | 一种使混凝土具有水体净化功能的方法及具有水体净化功能的混凝土 |
| CN110655141A (zh) * | 2019-09-20 | 2020-01-07 | 蚌埠学院 | 一种利用CdS玻璃色釉修复水体微生态系统的方法 |
| CN115217073A (zh) * | 2022-07-12 | 2022-10-21 | 杭州乾智坤达新材料科技有限公司 | 一种微晶玻璃水工护坡组件及其施工方法 |
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