CN108966380A - A kind of novel heating film - Google Patents

A kind of novel heating film Download PDF

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Publication number
CN108966380A
CN108966380A CN201810948849.XA CN201810948849A CN108966380A CN 108966380 A CN108966380 A CN 108966380A CN 201810948849 A CN201810948849 A CN 201810948849A CN 108966380 A CN108966380 A CN 108966380A
Authority
CN
China
Prior art keywords
heating film
electric heating
parts
graphite
mixed powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810948849.XA
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Chinese (zh)
Inventor
刘小明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHENZHEN DELONG ELECTRICAL APPLIANCE Co.,Ltd.
Original Assignee
Shenzhen Tongyi High And New Electronic Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Tongyi High And New Electronic Technology Co Ltd filed Critical Shenzhen Tongyi High And New Electronic Technology Co Ltd
Priority to CN201810948849.XA priority Critical patent/CN108966380A/en
Publication of CN108966380A publication Critical patent/CN108966380A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/20Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/02Details
    • H05B3/06Heater elements structurally combined with coupling elements or holders
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic

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  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of novel heating films, including electric heating film paddle material and solvent, there are also the glass fabrics for carrying the electric heating film paddle material, the electric heating film paddle material includes the adhesive and mixed powder mixed, the adhesive is polyimide resin, the mixed powder is by the graphite within 50nm partial size, carbon black, silver, zinc oxide and rare earth material composition, the novel heating film of one kind provided by the invention, when the mixing of the graphite of mixed powder and other components, the additive amount of graphite is controlled into the 2.5-5% in total amount, be conducive to improve the electric-thermal emission conversion efficiency of heating film;Binder is polyimide resin; it is high with conducting powder, glass fabric associativity; above-mentioned material can be made to be entirely incorporated in one through process flow described above production; for conducting powder without falling off, power stability, magnifying no cracked phenomenon by magnifying glass, exothermic material and insulation protection interlayer have good cementation when product is through being repeatedly used for a long.

Description

A kind of novel heating film
Technical field
The invention belongs to hairdressing appliance fever technical field of membrane, more specifically, more particularly to a kind of novel fever Film.
Background technique
It is about the AC marcel waver for being precisely controlled temperature with heating film if being described in more detail on the hairdressing appliances such as hair-waving The hairdressing appliance that the present invention on tool is suitable for being switched on by AC power supplies, is that insulating film and heating resistor form, insulating film A minimum of one side has been evaporated in vacuo the insulating film composition of metallic film and packet metallic film in front or back.
But traditional electric heating material (general such as metal material) electric conversion efficiency is low, generally 70% or so, but It is that planar electric conductor solves the low situation of electric conversion efficiency, the service life of planar electric conductor is that metallic threadlike silk is conductive 5-10 times of body, and same heating effect can at least 30% than wire tie.The thermoplastic polyurethane resin material of use, it is resistance to It is hot not high, thus it is heated when easily soften, intensity is low;Without effective flame-retardant composition in conducting medium, safety in utilization is low;Fever The PE and pet layer used outside material is acted on as non-binding between protection insulating layer, with heater.Electric heating film has become electric hair A developing direction in hot material.
Summary of the invention
The purpose of the present invention is to solve disadvantage existing in the prior art, and the novel heating film of one kind for proposing and Preparation method.
To achieve the above object, the invention provides the following technical scheme: a kind of novel heating film, including electric heating film paddle Material and solvent, also carry the glass fabric of the electric heating film paddle material, and the electric heating film paddle material includes pressing quality percentage Than the 20-40%:60-80% adhesive mixed and mixed powder, the adhesive is polyimide resin, the mixing Powder is made of graphite, carbon black, silver, zinc oxide and the rare earth material within 50nm partial size, and the solvent is butyl vinegar Acid esters, n-butyl acetate, Propylene glycol n-propyl ether, terpinol, mixed acid dimethyl, dimethylbenzene, polyamide rouge and polyimides are high The mixture of molecular solution is 1:2:1:4:2:3:4:2 by quality proportioning, the material composition in the glass fabric are as follows: 100 parts of aromatic polyester polyol, 50-100 parts of carbon nanotube, 40-80 parts of fire retardant, 1-5 parts of silane coupling agent, plasticizer 5- 20 parts and 0.5-2 parts of catalyst.
Preferably, the graphite, carbon black, silver, zinc oxide and rare earth material 5:2:1:2:0.5 in mass ratio are formed.
Preferably, the electric heating film paddle material and glass fabric stack gradually and pass through hot-forming, the heating film Between be fixed with conductive silver paste and copper-foil conducting electricity as electrode.
Preferably, the electric heating film paddle material viscosity reaches 2000-10000Pa.s.
Technical effect and advantage of the invention: the novel heating film of one kind provided by the invention, the graphite of mixed powder and its When the mixing of its component, by the additive amount control of graphite in the 2.5-5% of total amount, be conducive to the electric-thermal radiation for improving heating film Transfer efficiency can specifically make the electric-thermal emission conversion efficiency of heating film be up to 80%;Binder is polyimide resin, with Conducting powder, glass fabric associativity are high, above-mentioned material can be made to be entirely incorporated in through process flow described above production One, when product is through being repeatedly used for a long conducting powder without fall off, power stability, by magnifying glass magnify it is not cracked Phenomenon, exothermic material and insulation protection interlayer have good cementation, and macromolecule complex electrocaloric film meets 94V-0 grades of UL Halogen-free flameproof effect, to improve security reliability.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not For limiting the present invention.Based on the embodiments of the present invention, those of ordinary skill in the art are not before making creative work Every other embodiment obtained is put, shall fall within the protection scope of the present invention.
Embodiment 1
A kind of novel heating film, including electric heating film paddle material and solvent also carry the glass of the electric heating film paddle material Glass fiber cloth, the electric heating film paddle material include the adhesive and mixed powder that 20%:60% is mixed by mass percentage, The adhesive is polyimide resin, and the mixed powder is by graphite, carbon black, silver, zinc oxide and the rare earth within 50nm partial size Material composition, the solvent are butyl acetate, n-butyl acetate, Propylene glycol n-propyl ether, terpinol, mixed diacid two Methyl esters, dimethylbenzene, polyamide rouge and polyimides Polymer Solution mixture, be 1:2:1:4:2:3:4 by quality proportioning: 2, the material composition in the glass fabric are as follows: 100 parts of aromatic polyester polyol, 50 parts of carbon nanotube, 40 parts of fire retardant, 3 parts of silane coupling agent, 5 parts of plasticizer and 1 part of catalyst.
The graphite, carbon black, silver, zinc oxide and rare earth material 5:2:1:2:0.5 in mass ratio composition.
The electric heating film paddle material and glass fabric stack gradually and pass through hot-forming, fixation between the heating film There are the conductive silver paste and copper-foil conducting electricity as electrode.
The electric heating film paddle material viscosity reaches 2000Pa.s.
Embodiment 2
A kind of novel heating film, including electric heating film paddle material and solvent also carry the glass of the electric heating film paddle material Glass fiber cloth, the electric heating film paddle material include the adhesive and mixed powder that 40%:80% is mixed by mass percentage, The adhesive is polyimide resin, and the mixed powder is by graphite, carbon black, silver, zinc oxide and the rare earth within 50nm partial size Material composition, the solvent are butyl acetate, n-butyl acetate, Propylene glycol n-propyl ether, terpinol, mixed diacid two Methyl esters, dimethylbenzene, polyamide rouge and polyimides Polymer Solution mixture, be 1:2:1:4:2:3:4 by quality proportioning: 2, the material composition in the glass fabric are as follows: 100 parts of aromatic polyester polyol, 100 parts of carbon nanotube, fire retardant 40 Part, 5 parts of silane coupling agent, 20 parts of plasticizer and 2 parts of catalyst.
The graphite, carbon black, silver, zinc oxide and rare earth material 5:2:1:2:0.5 in mass ratio composition.
The electric heating film paddle material and glass fabric stack gradually and pass through hot-forming, fixation between the heating film There are the conductive silver paste and copper-foil conducting electricity as electrode.
The electric heating film paddle material viscosity reaches 8000Pa.s.
Embodiment 3
A kind of novel heating film, including electric heating film paddle material and solvent also carry the glass of the electric heating film paddle material Glass fiber cloth, the electric heating film paddle material include the adhesive and mixed powder that 30%:70% is mixed by mass percentage, The adhesive is polyimide resin, and the mixed powder is by graphite, carbon black, silver, zinc oxide and the rare earth within 50nm partial size Material composition, the solvent are butyl acetate, n-butyl acetate, Propylene glycol n-propyl ether, terpinol, mixed diacid two Methyl esters, dimethylbenzene, polyamide rouge and polyimides Polymer Solution mixture, be 1:2:1:4:2:3:4 by quality proportioning: 2, the material composition in the glass fabric are as follows: 100 parts of aromatic polyester polyol, 50 parts of carbon nanotube, 60 parts of fire retardant, 5 parts of silane coupling agent, 15 parts of plasticizer and 2 parts of catalyst.
The graphite, carbon black, silver, zinc oxide and rare earth material 5:2:1:2:0.5 in mass ratio composition.
The electric heating film paddle material and glass fabric stack gradually and pass through hot-forming, fixation between the heating film There are the conductive silver paste and copper-foil conducting electricity as electrode.
The electric heating film paddle material viscosity reaches 5000Pa.s.
In summary: when the mixing of the novel heating film of one kind provided by the invention, the graphite of mixed powder and other components, By the additive amount control of graphite in the 2.5-5% of total amount, is conducive to the electric-thermal emission conversion efficiency for improving heating film, specifically may be used The electric-thermal emission conversion efficiency of heating film is set to be up to 80%;Binder is polyimide resin, with conducting powder, glass fibre Cloth associativity is high, above-mentioned material can be made to be entirely incorporated in one through process flow described above production, product is through long-term Conducting powder is without falling off, power stability, magnify no cracked phenomenon by magnifying glass when Reusability, exothermic material with Insulation protection interlayer has good cementation, and macromolecule complex electrocaloric film meets UL 94V-0 grade non-halogen flame-retardant effect, from And improve security reliability.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features, All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (4)

1. a kind of novel heating film, including electric heating film paddle material and solvent, also carry the glass of the electric heating film paddle material Fiber cloth, it is characterised in that: the electric heating film paddle material include by mass percentage 20-40%:60-80% mix Adhesive and mixed powder, the adhesive be polyimide resin, the mixed powder by within 50nm partial size graphite, carbon black, Silver, zinc oxide and rare earth material composition, the solvent be butyl acetate, n-butyl acetate, Propylene glycol n-propyl ether, Terpinol, the mixture for mixing acid dimethyl, dimethylbenzene, polyamide rouge and polyimides Polymer Solution, by quality proportioning It is 1:2:1:4:2:3:4:2, the material composition in the glass fabric are as follows: 100 parts of aromatic polyester polyol, carbon nanotube 50-100 parts, 40-80 parts of fire retardant, 1-5 parts of silane coupling agent, 5-20 parts of plasticizer and 0.5-2 parts of catalyst.
2. the novel heating film of one kind according to claim 1, it is characterised in that: the graphite, carbon black, silver, zinc oxide It is formed with rare earth material 5:2:1:2:0.5 in mass ratio.
3. the novel heating film of one kind according to claim 1, it is characterised in that: the electric heating film paddle material and glass fibers Wei Bu is stacked gradually and is passed through hot-forming, and conductive silver paste and copper-foil conducting electricity as electrode are fixed between the heating film.
4. the novel heating film of one kind according to claim 1, it is characterised in that: the electric heating film paddle material viscosity reaches 2000-10000Pa.s。
CN201810948849.XA 2018-08-20 2018-08-20 A kind of novel heating film Pending CN108966380A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810948849.XA CN108966380A (en) 2018-08-20 2018-08-20 A kind of novel heating film

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Application Number Priority Date Filing Date Title
CN201810948849.XA CN108966380A (en) 2018-08-20 2018-08-20 A kind of novel heating film

Publications (1)

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CN108966380A true CN108966380A (en) 2018-12-07

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CN201810948849.XA Pending CN108966380A (en) 2018-08-20 2018-08-20 A kind of novel heating film

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110087346A (en) * 2019-04-08 2019-08-02 新疆翰阳电热科技股份有限公司 A kind of graphite-epoxy heat generating pastes

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101873729A (en) * 2010-06-07 2010-10-27 刘忠耀 Electric heating film and preparation method thereof
CN106183239A (en) * 2016-07-20 2016-12-07 刘子寒 A kind of macromolecule complex electrocaloric film and preparation method thereof
CN107493612A (en) * 2017-07-03 2017-12-19 孙克智 Flexible nano carbon composite high temperature electric heating film and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101873729A (en) * 2010-06-07 2010-10-27 刘忠耀 Electric heating film and preparation method thereof
CN106183239A (en) * 2016-07-20 2016-12-07 刘子寒 A kind of macromolecule complex electrocaloric film and preparation method thereof
CN107493612A (en) * 2017-07-03 2017-12-19 孙克智 Flexible nano carbon composite high temperature electric heating film and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110087346A (en) * 2019-04-08 2019-08-02 新疆翰阳电热科技股份有限公司 A kind of graphite-epoxy heat generating pastes

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Effective date of registration: 20200911

Address after: 518000 First to Fourth Floors of Building A6, Datianyang Industrial Zone, Dongfang Community, Songgang Street, Baoan District, Shenzhen City, Guangdong Province

Applicant after: SHENZHEN DELONG ELECTRICAL APPLIANCE Co.,Ltd.

Address before: 518000 Guangdong Shenzhen Baoan District Songgang street down hill door 1-1

Applicant before: SHENZHEN TONGYI HI-TECH ELECTRONIC TECHNOLOGY Co.,Ltd.

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20181207