CN109489104A - A kind of fever wallpaper and its manufacturing method for indoor heating - Google Patents
A kind of fever wallpaper and its manufacturing method for indoor heating Download PDFInfo
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- CN109489104A CN109489104A CN201710812080.4A CN201710812080A CN109489104A CN 109489104 A CN109489104 A CN 109489104A CN 201710812080 A CN201710812080 A CN 201710812080A CN 109489104 A CN109489104 A CN 109489104A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D13/00—Electric heating systems
- F24D13/02—Electric heating systems solely using resistance heating, e.g. underfloor heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Fluid Mechanics (AREA)
- Paper (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of fever wallpapers and its manufacturing method for indoor heating.The fever wallpaper is that a certain proportion of graphene is added in elder generation in discongesting the eucalyptus fibers being beaten and paper is manufactured paper with pulp into carbon fiber mixing, the liquid toner dispersion for being scattered in organic solvent in right amount is impregnated or is applied on the body paper of above-mentioned completion again, heating paper is made through high temperature high pressure process, one layer of insulative water-proof material is respectively then bonded on heating paper two sides by adhesive and constitutes heating layer;With using heterogeneity high molecular material constitute thermal insulation layer, reflecting layer and fire-retardant decorative layer in order it is Nian Jie composition.The fever wallpaper heating area is big, fever is uniform, can discharge far infrared, improves human circulation, promotes cell activity.Have the characteristics that simple process compared to traditional ground heating type heat supply and electric heating device, have excellent performance, environmental-friendly and safety and comfort, and decorative aesthetics and heating function coexist.
Description
Technical field
The present invention relates to wallpaper decoration technical fields, more particularly to the far infrared heating heating technical field of carbon fiber, the hair
Hot wallpaper manufacture craft is simple, has excellent performance, is environmental-friendly, and safety and comfort of warming oneself.
Background technique
Traditional heating mode has electric oven, concentrated supply of heating in the city and floor heating.And electric oven is because of the hair using metal material
Heated filament heating power, calorific value is big, and power consumption is high, and fever heating range is small, and electromagnetic radiation is big, and safety difference is extremely easy to cause fire
Accident is affected to the safe and healthy of people;Geothermal heating system need to then install ground installation when house builds up finishing, to
The house that finishing is completed then is not suitable for, and construction and installation and later maintenance are all sufficiently complex, it has not been convenient to.Therefore new heating is needed
Mode, equipment replace traditional heating mode, and fever wallpaper had not only had a decorative aesthetics but also have the new of safety heating as a
Product is paid close attention to and is developed.Heating wall paper product is few currently on the market, in the stage having just emerged.
Patent of invention CN205531118U is proposed a kind of by wallpaper bottom (including electro-insulating rubber layer or plastic layer), conduction
The fever wallpaper that material layer, IR resisting layer, insulating layer, waterproof layer decorative cover are constituted, the bad heat loss of heat insulation effect is fast, deposits
In the unclear situation of conductive material layer and IR resisting layer material therefor.A kind of fever for indoor heating proposed by the present invention
Wallpaper heating area is big, fever is uniform, and heat insulation effect is good, safety and comfort;Far infrared can be discharged, human circulation is improved, is promoted
Cell activity.
Summary of the invention
The main purpose of the invention patent is to overcome poor safety in the prior art, construction maintenance complex process, heat preservation
The problems such as ineffective, provide a kind of simple process, have excellent performance, environmental-friendly and decorative aesthetics and heating function coexist can
For the fever wallpaper and its manufacturing method of indoor heating.
Carbon fiber used in the present invention has high intensity, high-modulus, low-density, excellent tensile property and calorifics, electricity
The advantages of performance, especially its Far infrared electric-heat radiation conversion ratio, are higher than 70%, radiate the far infrared of 5um-20um, this
It is to adapt to blood circulation of human body, far infrared wave with health care function.The use in thermal insulation layer and reflecting layer can play preferable guarantor
Temp effect reduces scattering and disappearing for heat;The insulative water-proof material of heating layer two sides bonding prevents from leaking electricity, and reduces security risk and avoids thing
Therefore generation.
The purpose of the present invention is achieved through the following technical solutions:
1, a kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four
Layer: first layer is the thermal insulation layer that Kapton plate or polyvinyl chloride panel constitute of aluminizing from the bottom up;The second layer is metal film
Reflecting layer made of composite material;Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then is impregnated or coated carbon dust
Dispersion liquid obtains heating paper through high temperature high pressure process, and heating paper two sides is respectively bonded with one layer of insulative water-proof material and constitutes fever
Layer;4th layer is PVC(polyvinyl chloride) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, beating degree control is 40 °
SR-60 ° of SR, so that the hydroxyl on fiber sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 1:1~1000:1 ratio, as heating paper
Core skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added in 1:1~5:1 ratio
In water, high speed emulsification mixing again is added after dispersing agent and manufactures paper with pulp into paper;
(4) preparation of liquid toner dispersion: by the diameter of certain mass be 2nm-40nm carbon dust, conducting polymer, dispersing agent, have
Solvent and water-soluble binder are mixed and made into carbon dust mixed dispersion liquid;
(5) solution processing craft: homogeneous impregnation or coating walk after the body paper drying that step (3) is manufactured paper with pulp is lower than 10% to moisture content
Suddenly the liquid toner dispersion of (4) preparation, forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: step (5) is carried out after solvent seasoning evaporates into moisture content lower than 15% through solution treated body paper
10s-600s is handled at temperature (30 DEG C -300 DEG C) and pressure (1Mpa-100Mpa), surface compact, smooth and layer can be obtained
Secondary preferable heating paper;
(7) preparation of heating layer: one layer is respectively bonded on the heating paper two sides prepared and fever paper format is of the same size absolutely
Edge waterproof material constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
2, the thermal insulation layer is by aluminizing Kapton plate or polyvinyl chloride panel forms, and thickness 0.5cm~
1.5cm。
3, the thermal insulation layer is fixed on metope by resin bonding.
4, the reflecting layer metal film composite material is the non-woven fabric compounded reflectance coating of aluminium film or polyethylene foamed aluminizer
Or the kraft compounded reflectance coating of aluminium film, with a thickness of 0.5mm~2.0mm.
5, the carbon fiber be one of polyacrylonitrile-based carbon fibre, viscose-based carbon fiber and asphalt base carbon fiber or
A variety of mixing;Dispersing agent is PEO(polyethylene glycol oxide) either calcium dodecyl benzene sulfonate or neopelex, dosage
For the 1%-5% of eucalyptus fibers.
6, the conducting polymer in the liquid toner dispersion is by one or more of polythiophene, polypyrrole and polyaniline
It mixes;Organic solvent is ethyl alcohol or ethyl acetate or dimethyl sulfoxide;Dispersing agent is that stearmide or hexenyl are double
Stearmide or glyceryl monostearate;Water-soluble binder is epoxy resin or acrylic resin or polyurethane tree
Rouge.
7, two layers of insulative water-proof material of the composition heating layer is the resistance to soft film of 200 DEG C of PVC.
8, the fire-retardant decorative layer uses PVC(polyvinyl chloride) material is made, and 120 DEG C of heatproof, fire resistance rating B1, thickness
0.15mm~0.5mm.
9, the resin that the bonding process uses is non-toxic epoxy.
10, the intelligent temperature controller includes control system, temperature measurement system and humidity control system.
Compared with the prior art, the invention has the following advantages:
1, a kind of fever wallpaper and its manufacturing method for indoor heating of the invention, the fever wallpaper heating area is big, sends out
Hot uniform, heat insulation effect is good.
2, the heating paper compares traditional ground heating type heat supply and electric heating device and has simple process, has excellent performance, environment
The features such as friendly and safety and comfort, and decorative aesthetics and heating function coexist.
3, good using heating paper tensile strength strength character made of carbon fiber and grapheme material, far infrared can be discharged
Line improves human circulation, promotes cell activity.
Detailed description of the invention
Fig. 1 is the heating wall paper structure schematic diagram for indoor heating.
In Fig. 1: 1 power switch, 2 intelligent temperature control systems, 3, fire-retardant decorative layer 4, insulative water-proof material 5, heating paper
6, reflecting layer 7, thermal insulation layer.
Specific embodiment
Embodiment 1
A kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four layers:
From the bottom up first layer be aluminize Kapton plate composition thermal insulation layer;The second layer is the non-woven fabric compounded reflectance coating system of aluminium film
At reflecting layer;Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then is impregnated or coated liquid toner dispersion through height
Warm HIGH PRESSURE TREATMENT obtains heating paper, and heating paper two sides is respectively bonded with one layer of insulative water-proof material and constitutes heating layer;4th layer is
PVC(polyvinyl chloride) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, so that the hydroxyl on fiber
Base sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 1000:1 ratio, the core as heating paper
Skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added to the water in 3:2 ratio,
High speed emulsification mixing again is added after 1% polyethylene glycol oxide of eucalyptus fibers amount and manufactures paper with pulp into paper;
(4) carbon dust, polythiophene, stearmide, ethyl alcohol and epoxy resin that diameter is 10nm the preparation of liquid toner dispersion: are pressed 2:
The liquid toner dispersion for accounting for original paper quality 3% is made in 1:1:3:1 ratio;
(5) solution processing craft: homogeneous impregnation or application step after body paper drying to the moisture content that step (3) is manufactured paper with pulp is 8%
(4) liquid toner dispersion prepared forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: by step (5) through solution treated body paper carry out after solvent seasoning evaporates into moisture content position 12%
200s is handled under 100 DEG C of temperature and pressure 2Mpa, surface compact, the preferable heating paper of smooth and level can be obtained;
(7) preparation of heating layer: the heating paper two sides prepared be respectively bonded with one layer with fever paper format it is of the same size resistance to
The soft film of 200 DEG C of PVC constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
The fever wallpaper obtained after above-mentioned process, electric-thermal radiation conversion ratio are that 96%, radiating surface temperature is uneven
Even degree is 0.1%, and electric energy conversion speed is fast;Selected materials fire resistance rating B1 and the control of intelligent temperature control system, there is safely guarantor
Barrier.
Embodiment 2
A kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four layers:
First layer is the thermal insulation layer that polyvinyl chloride panel is constituted from the bottom up;The second layer is reflecting layer made of polyethylene foamed aluminizer;
Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then is impregnated or coated liquid toner dispersion through high temperature high pressure process
Heating paper is obtained, heating paper two sides is respectively bonded with one layer of insulative water-proof material and constitutes heating layer;4th layer is PVC(polychlorostyrene second
Alkene) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, so that the hydroxyl on fiber
Base sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 900:1 ratio, the core as heating paper
Skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added to the water in 1:1 ratio,
High speed emulsification mixing again is added after 1% polyethylene glycol oxide of eucalyptus fibers amount and manufactures paper with pulp into paper;
(4) carbon dust, polypyrrole, stearmide, ethyl alcohol and epoxy resin that diameter is 8nm the preparation of liquid toner dispersion: are pressed 1:
The liquid toner dispersion for accounting for original paper quality 3% is made in 1:1:2:1 ratio;
(5) solution processing craft: homogeneous impregnation or application step after body paper drying to the moisture content that step (3) is manufactured paper with pulp is 9%
(4) liquid toner dispersion prepared forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: by step (5) through solution treated body paper carry out solvent seasoning evaporate into after moisture content is 13%
400S is handled under 105 DEG C of temperature and pressure 2Mpa, surface compact, the preferable heating paper of smooth and level can be obtained;
(7) preparation of heating layer: the heating paper two sides prepared be respectively bonded with one layer with fever paper format it is of the same size resistance to
The soft film of 200 DEG C of PVC constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
The fever wallpaper obtained after above-mentioned process, electric-thermal radiation conversion ratio are that 96%, radiating surface temperature is uneven
Even degree is 0.05%, and electric energy conversion speed is fast;Selected materials fire resistance rating B1 and the control of intelligent temperature control system, there is safely guarantor
Barrier.
Embodiment 3
A kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four layers:
From the bottom up first layer be aluminize Kapton plate composition thermal insulation layer;The second layer is the kraft compounded reflectance coating system of aluminium film
At reflecting layer;Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then is impregnated or coated liquid toner dispersion through height
Warm HIGH PRESSURE TREATMENT obtains heating paper, and heating paper two sides is respectively bonded with one layer of resistance to soft film of 200 DEG C of PVC and constitutes heating layer;The
Four layers are PVC(polyvinyl chloride) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, so that the hydroxyl on fiber
Base sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 980:1 ratio, the core as heating paper
Skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added to the water in 4:3 ratio,
High speed emulsification mixing again is added after 1% neopelex of eucalyptus fibers amount and manufactures paper with pulp into paper;
(4) preparation of liquid toner dispersion: carbon dust, polythiophene, stearmide, ethyl acetate and the epoxy resin for being 9nm by diameter
The liquid toner dispersion for accounting for original paper quality 4% is made in 1:1:1:2:1 ratio;
(5) solution processing craft: homogeneous impregnation or application step after body paper drying to the moisture content that step (3) is manufactured paper with pulp is 7%
(4) liquid toner dispersion prepared forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: by step (5) through solution treated body paper carry out solvent seasoning evaporate into after moisture content is 12%
500S is handled under 110 DEG C of temperature and pressure 2Mpa, surface compact, the preferable heating paper of smooth and level can be obtained;
(7) preparation of heating layer: the heating paper two sides prepared be respectively bonded with one layer with fever paper format it is of the same size resistance to
The soft film of 200 DEG C of PVC constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
The fever wallpaper obtained after above-mentioned process, electric-thermal radiation conversion ratio are that 97%, radiating surface temperature is uneven
Even degree is 0.05%, and electric energy conversion speed is fast;Selected materials fire resistance rating B1 and the control of intelligent temperature control system, there is safely guarantor
Barrier.
Embodiment 4
A kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four layers:
First layer is the thermal insulation layer that polyvinyl chloride panel is constituted from the bottom up;The second layer is reflection made of the non-woven fabric compounded reflectance coating of aluminium film
Layer;Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then be impregnated or coated liquid toner dispersion through high temperature and pressure at
Reason obtains heating paper, and heating paper two sides is respectively bonded with one layer of resistance to soft film of 200 DEG C of PVC and constitutes heating layer;4th layer is PVC
(polyvinyl chloride) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, so that the hydroxyl on fiber
Base sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 950:1 ratio, the core as heating paper
Skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added to the water in 3:2 ratio,
High speed emulsification mixing again is added after 2% neopelex of eucalyptus fibers amount and manufactures paper with pulp into paper;
(4) preparation of liquid toner dispersion: carbon dust, polypyrrole, stearmide, ethyl alcohol and acrylic resin that diameter is 8nm are pressed
The liquid toner dispersion for accounting for original paper quality 4% is made in 1:1:1:3:1 ratio;
(5) solution processing craft: homogeneous impregnation or application step after body paper drying to the moisture content that step (3) is manufactured paper with pulp is 8%
(4) liquid toner dispersion prepared forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: by step (5) through solution treated body paper carry out solvent seasoning evaporate into after moisture content is 12%
150S is handled under 115 DEG C of temperature and pressure 3Mpa, surface compact, the preferable heating paper of smooth and level can be obtained;
(7) preparation of heating layer: the heating paper two sides prepared be respectively bonded with one layer with fever paper format it is of the same size resistance to
The soft film of 200 DEG C of PVC constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
The fever wallpaper obtained after above-mentioned process, electric-thermal radiation conversion ratio are that 98%, radiating surface temperature is uneven
Even degree is 0.1%, and electric energy conversion speed is fast;Selected materials fire resistance rating B1 and the control of intelligent temperature control system, there is safely guarantor
Barrier.
Embodiment 5
A kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four layers:
From the bottom up first layer be aluminize Kapton plate composition thermal insulation layer;The second layer is made of polyethylene foamed aluminizer
Reflecting layer;Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then is impregnated or coated liquid toner dispersion through high temperature height
Pressure handles to obtain heating paper, and heating paper two sides is respectively bonded with one layer of resistance to soft film of 200 DEG C of PVC and constitutes heating layer;4th layer
For PVC(polyvinyl chloride) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, so that the hydroxyl on fiber
Base sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 800:1 ratio, the core as heating paper
Skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added to the water in 1:1 ratio,
High speed emulsification mixing again is added after 2% polyethylene glycol oxide of eucalyptus fibers amount and manufactures paper with pulp into paper;
(4) preparation of liquid toner dispersion: carbon dust, polyaniline, stearmide, ethyl acetate and the acrylic acid tree for being 10nm by diameter
The liquid toner dispersion for accounting for original paper quality 3% is made in 1:1:1:2:1 ratio for rouge;
(5) solution processing craft: homogeneous impregnation or application step after body paper drying to the moisture content that step (3) is manufactured paper with pulp is 8%
(4) liquid toner dispersion prepared forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: by step (5) through solution treated body paper carry out solvent seasoning evaporate into after moisture content is 13%
600S is handled under 110 DEG C of temperature and pressure 3Mpa, surface compact, the preferable heating paper of smooth and level can be obtained;
(7) preparation of heating layer: the heating paper two sides prepared be respectively bonded with one layer with fever paper format it is of the same size resistance to
The soft film of 200 DEG C of PVC constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
The fever wallpaper obtained after above-mentioned process, electric-thermal radiation conversion ratio are that 96%, radiating surface temperature is uneven
Even degree is 0.1%, and electric energy conversion speed is fast;Selected materials fire resistance rating B1 and the control of intelligent temperature control system, there is safely guarantor
Barrier.
Embodiment 6
A kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four layers:
First layer is the thermal insulation layer that polyvinyl chloride panel is constituted from the bottom up;The second layer is reflection made of the kraft compounded reflectance coating of aluminium film
Layer;Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then be impregnated or coated liquid toner dispersion through high temperature and pressure at
Reason obtains heating paper, and heating paper two sides is respectively bonded with one layer of resistance to soft film of 200 DEG C of PVC and constitutes heating layer;4th layer is PVC
(polyvinyl chloride) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, so that the hydroxyl on fiber
Base sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 1000:1 ratio, the core as heating paper
Skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added to the water in 2:3 ratio,
High speed emulsification mixing again is added after 3% polyethylene glycol oxide of eucalyptus fibers amount and manufactures paper with pulp into paper;
(4) preparation of liquid toner dispersion: carbon dust, polyaniline, glyceryl monostearate, ethyl acetate and the ring for being 8nm by diameter
The liquid toner dispersion for accounting for original paper quality 4% is made in 1:1:1:2:1 ratio for oxygen resin;
(5) solution processing craft: homogeneous impregnation or application step after body paper drying to the moisture content that step (3) is manufactured paper with pulp is 9%
(4) liquid toner dispersion prepared forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: by step (5) through solution treated body paper carry out solvent seasoning evaporate into after moisture content is 12%
350S is handled under 115 DEG C of temperature and pressure 3Mpa, surface compact, the preferable heating paper of smooth and level can be obtained;
(7) preparation of heating layer: the heating paper two sides prepared be respectively bonded with one layer with fever paper format it is of the same size resistance to
The soft film of 200 DEG C of PVC constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
The fever wallpaper obtained after above-mentioned process, electric-thermal radiation conversion ratio are that 98%, radiating surface temperature is uneven
Even degree is 0.1%, and electric energy conversion speed is fast;Selected materials fire resistance rating B1 and the control of intelligent temperature control system, there is safely guarantor
Barrier.
Embodiment 7
A kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four layers:
From the bottom up first layer be aluminize Kapton plate composition thermal insulation layer;The second layer is the non-woven fabric compounded reflectance coating system of aluminium film
At reflecting layer;Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then is impregnated or coated liquid toner dispersion through height
Warm HIGH PRESSURE TREATMENT obtains heating paper, and heating paper two sides is respectively bonded with one layer of resistance to soft film of 200 DEG C of PVC and constitutes heating layer;The
Four layers are PVC(polyvinyl chloride) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, so that the hydroxyl on fiber
Base sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 700:1 ratio, the core as heating paper
Skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added to the water in 3:4 ratio,
High speed emulsification mixing again is added after 2% calcium dodecyl benzene sulfonate of eucalyptus fibers amount and manufactures paper with pulp into paper;
(4) preparation of liquid toner dispersion: being the carbon dust of 7nm, polypyrrole, glyceryl monostearate, ethyl acetate and poly- by diameter
The liquid toner dispersion for accounting for original paper quality 3% is made in 2:1:1:2:1 ratio for urethane resin;
(5) solution processing craft: homogeneous impregnation or application step after body paper drying to the moisture content that step (3) is manufactured paper with pulp is 8%
(4) liquid toner dispersion prepared forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: by step (5) through solution treated body paper carry out solvent seasoning evaporate into after moisture content is 13%
450S is handled under 125 DEG C of temperature and pressure 2Mpa, surface compact, the preferable heating paper of smooth and level can be obtained;
(7) preparation of heating layer: the heating paper two sides prepared be respectively bonded with one layer with fever paper format it is of the same size resistance to
The soft film of 200 DEG C of PVC constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
The fever wallpaper obtained after above-mentioned process, electric-thermal radiation conversion ratio are that 97%, radiating surface temperature is uneven
Even degree is 0.1%, and electric energy conversion speed is fast;Selected materials fire resistance rating B1 and the control of intelligent temperature control system, there is safely guarantor
Barrier.
Embodiment 8
A kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four layers:
First layer is the thermal insulation layer that polyvinyl chloride panel is constituted from the bottom up;The second layer is reflecting layer made of bubble polyethylene aluminizer;The
Three layers are manufactured paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then are impregnated or coated liquid toner dispersion and are obtained through high temperature high pressure process
To heating paper, heating paper two sides is respectively bonded with one layer of resistance to soft film of 200 DEG C of PVC and constitutes heating layer;4th layer poly- for PVC(
Vinyl chloride) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, so that the hydroxyl on fiber
Base sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 800:1 ratio, the core as heating paper
Skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added to the water in 1:1 ratio,
High speed emulsification mixing again is added after 1% neopelex of eucalyptus fibers amount and manufactures paper with pulp into paper;
(4) preparation of liquid toner dispersion: being the carbon dust of 8nm, polythiophene, glyceryl monostearate, dimethyl sulfoxide and poly- by diameter
The liquid toner dispersion for accounting for original paper quality 3% is made in 1:1:1:2:1 ratio for urethane resin;
(5) solution processing craft: homogeneous impregnation or application step after body paper drying to the moisture content that step (3) is manufactured paper with pulp is 9%
(4) liquid toner dispersion prepared forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: by step (5) through solution treated body paper carry out solvent seasoning evaporate into after moisture content is 13%
250S is handled under 120 DEG C of temperature and pressure 3Mpa, surface compact, the preferable heating paper of smooth and level can be obtained;
(7) preparation of heating layer: the heating paper two sides prepared be respectively bonded with one layer with fever paper format it is of the same size resistance to
The soft film of 200 DEG C of PVC constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
The fever wallpaper obtained after above-mentioned process, electric-thermal radiation conversion ratio are that 97%, radiating surface temperature is uneven
Even degree is 0.15%, and electric energy conversion speed is fast;Selected materials fire resistance rating B1 and the control of intelligent temperature control system, there is safely guarantor
Barrier.
Embodiment 9
A kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four layers:
From the bottom up first layer be aluminize Kapton plate composition thermal insulation layer;The second layer is the kraft compounded reflectance coating system of aluminium film
At reflecting layer;Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then is impregnated or coated liquid toner dispersion through height
Warm HIGH PRESSURE TREATMENT obtains heating paper, and heating paper two sides is respectively bonded with one layer of resistance to soft film of 200 DEG C of PVC and constitutes heating layer;The
Four layers are PVC(polyvinyl chloride) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, so that the hydroxyl on fiber
Base sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 900:1 ratio, the core as heating paper
Skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added to the water in 3:2 ratio,
High speed emulsification mixing again is added after 4% polyethylene glycol oxide of eucalyptus fibers amount and manufactures paper with pulp into paper;
(4) preparation of liquid toner dispersion: carbon dust, polypyrrole, glyceryl monostearate, the ethyl acetate and third for being 9nm by diameter
The liquid toner dispersion for accounting for original paper quality 3% is made in 2:1:1:2:1 ratio for olefin(e) acid resin;
(5) solution processing craft: homogeneous impregnation or application step after body paper drying to the moisture content that step (3) is manufactured paper with pulp is 8%
(4) liquid toner dispersion prepared forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: by step (5) through solution treated body paper carry out solvent seasoning evaporate into after moisture content is 14%
300S is handled under 105 DEG C of temperature and pressure 3Mpa, surface compact, the preferable heating paper of smooth and level can be obtained;
(7) preparation of heating layer: the heating paper two sides prepared be respectively bonded with one layer with fever paper format it is of the same size resistance to
The soft film of 200 DEG C of PVC constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
The fever wallpaper obtained after above-mentioned process, electric-thermal radiation conversion ratio are that 97%, radiating surface temperature is uneven
Even degree is 0.2%, and electric energy conversion speed is fast;Selected materials fire resistance rating B1 and the control of intelligent temperature control system, there is safely guarantor
Barrier.
Embodiment 10
A kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four layers:
First layer is the thermal insulation layer that polyvinyl chloride panel is constituted from the bottom up;The second layer is reflection made of the non-woven fabric compounded reflectance coating of aluminium film
Layer;Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then be impregnated or coated liquid toner dispersion through high temperature and pressure at
Reason obtains heating paper, and heating paper two sides is respectively bonded with one layer of resistance to soft film of 200 DEG C of PVC and constitutes heating layer;4th layer is PVC
(polyvinyl chloride) material is as fire-retardant decorative layer.Include the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, so that the hydroxyl on fiber
Base sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 980:1 ratio, the core as heating paper
Skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added to the water in 2:3 ratio,
High speed emulsification mixing again is added after 3% polyethylene glycol oxide of eucalyptus fibers amount and manufactures paper with pulp into paper;
(4) preparation of liquid toner dispersion: by diameter be the carbon dust of 7nm, polyaniline, hexenyl bis-stearamides, dimethyl sulfoxide and
The liquid toner dispersion for accounting for original paper quality 5% is made in 1:1:1:2:1 ratio for polyurethane resin;
(5) solution processing craft: homogeneous impregnation or application step after body paper drying to the moisture content that step (3) is manufactured paper with pulp is 9%
(4) liquid toner dispersion prepared forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: by step (5) through solution treated body paper carry out solvent seasoning evaporate into after moisture content is 13%
400S is handled under 110 DEG C of temperature and pressure 2Mpa, surface compact, the preferable heating paper of smooth and level can be obtained;
(7) preparation of heating layer: the heating paper two sides prepared be respectively bonded with one layer with fever paper format it is of the same size resistance to
The soft film of 200 DEG C of PVC constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
The fever wallpaper obtained after above-mentioned process, electric-thermal radiation conversion ratio are that 98%, radiating surface temperature is uneven
Even degree is 0.15%, and electric energy conversion speed is fast;Selected materials fire resistance rating B1 and the control of intelligent temperature control system, there is safely guarantor
Barrier.
Claims (10)
1. a kind of fever wallpaper and its manufacturing method for indoor heating, it is characterised in that the heating wall paper includes four
Layer: first layer is the thermal insulation layer that Kapton plate or polyvinyl chloride panel constitute of aluminizing from the bottom up;The second layer is metal film
Reflecting layer made of composite material;Third layer manufactures paper with pulp into paper by eucalyptus fibers, graphene and carbon fiber, then is impregnated or coated carbon dust
Dispersion liquid obtains heating paper through high temperature high pressure process, and heating paper two sides is respectively bonded with one layer of insulative water-proof material and constitutes fever
Layer;4th layer is PVC(polyvinyl chloride) material as fire-retardant decorative layer, includes the following steps and process conditions:
(1) mashing of eucalyptus fibers: eucalyptus fibers are carried out using PFI fiberizer to discongest mashing processing, beating degree control is 40 °
SR-60 ° of SR, so that the hydroxyl on fiber sufficiently exposes;
(2) mixing of carbon fiber and graphene: carbon fiber and graphene are mixed in 1:1~1000:1 ratio, as heating paper
Core skeleton;
(3) body paper is manufactured paper with pulp: the eucalyptus fibers wood pulp of the composite fibre of step (2) and step (1) is added in 1:1~5:1 ratio
In water, high speed emulsification mixing again is added after dispersing agent and manufactures paper with pulp into paper;
(4) preparation of liquid toner dispersion: by the diameter of certain mass be 2nm-40nm carbon dust, conducting polymer, dispersing agent, have
Solvent and water-soluble binder are mixed and made into carbon dust mixed dispersion liquid;
(5) solution processing craft: homogeneous impregnation or coating walk after the body paper drying that step (3) is manufactured paper with pulp is lower than 10% to moisture content
Suddenly the liquid toner dispersion of (4) preparation, forms carbon dust mixed layer, constitutes multifunctional heating matrix;
(6) concora crush technique: step (5) is carried out after solvent seasoning evaporates into moisture content lower than 15% through solution treated body paper
10s-600s is handled at temperature (30 DEG C -300 DEG C) and pressure (1Mpa-100Mpa), surface compact, smooth and layer can be obtained
Secondary preferable heating paper;
(7) preparation of heating layer: one layer is respectively bonded on the heating paper two sides prepared and fever paper format is of the same size absolutely
Edge waterproof material constitutes heating layer, and heating paper one end connects electrified wire;
(8) bonding of fever wallpaper: by the thermal insulation layer of breadth different materials structure composition of the same size, reflecting layer, heating layer
And fire-retardant decorative layer is good with resin bonding in order, connects intelligent temperature controller and power backup by the electrified wire of heating layer.
2. a kind of fever wallpaper and its manufacturing method for indoor heating according to claim 1, it is characterised in that institute
The thermal insulation layer stated is by aluminizing Kapton plate or polyvinyl chloride panel forms, thickness 0.5cm~1.5cm.
3. a kind of fever wallpaper and its manufacturing method for indoor heating according to claim 1, it is characterised in that institute
The thermal insulation layer stated is adhesively fixed on metope by cold coating.
4. a kind of fever wallpaper and its manufacturing method for indoor heating according to claim 1, it is characterised in that institute
The reflecting layer metal film composite material stated is the non-woven fabric compounded reflectance coating of aluminium film or polyethylene foamed aluminizer or aluminium film brown paper
Composite reflective film, with a thickness of 0.5mm~2.0mm.
5. a kind of fever wallpaper and its manufacturing method for indoor heating according to claim 1, it is characterised in that institute
The carbon fiber stated is one of polyacrylonitrile-based carbon fibre, viscose-based carbon fiber and asphalt base carbon fiber or a variety of mixing;Point
Powder is PEO(polyethylene glycol oxide) either calcium dodecyl benzene sulfonate or neopelex, dosage are eucalyptus fibers
1%-5%.
6. a kind of fever wallpaper and its manufacturing method for indoor heating according to claim 1, it is characterised in that institute
The conducting polymer in liquid toner dispersion stated is mixed by one or more of polythiophene, polypyrrole and polyaniline;Have
Solvent is ethyl alcohol or ethyl acetate or dimethyl sulfoxide;Dispersing agent be stearmide or hexenyl bis-stearamides or
Glyceryl monostearate;Water-soluble binder is epoxy resin or acrylic resin or polyurethane resin.
7. a kind of fever wallpaper and its manufacturing method for indoor heating according to claim 1, it is characterised in that institute
Two layers of insulative water-proof material of the composition heating layer stated is the resistance to soft film of 200 DEG C of PVC.
8. a kind of fever wallpaper and its manufacturing method for indoor heating according to claim 1, it is characterised in that institute
The fire-retardant decorative layer stated uses PVC(polyvinyl chloride) material is made, and 120 DEG C of heatproof, fire resistance rating B1, thickness 0.15mm~
0.5mm。
9. a kind of fever wallpaper and its manufacturing method for indoor heating according to claim 1, it is characterised in that institute
The resin that the bonding process stated uses is non-toxic epoxy.
10. a kind of fever wallpaper and its manufacturing method for indoor heating according to claim 1, it is characterised in that institute
The intelligent temperature controller stated includes control system, temperature measurement system and humidity control system.
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Cited By (4)
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CN110670411A (en) * | 2019-09-10 | 2020-01-10 | 衢州五洲特种纸业股份有限公司 | Food paperboard with heat preservation and heating functions and preparation method thereof |
CN110685186A (en) * | 2019-09-10 | 2020-01-14 | 衢州五洲特种纸业股份有限公司 | Modified graphene/nano-cellulose conductive functional coating and preparation method and application thereof |
CN113681886A (en) * | 2021-07-30 | 2021-11-23 | 广东金瓷三维技术有限公司 | Droplet jetting 3D printing process using flexible heating pad |
CN114351506A (en) * | 2022-01-06 | 2022-04-15 | 阳光王子(寿光)特种纸有限公司 | Novel electrogenerated heating decorative paper and preparation method thereof |
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CN114351506A (en) * | 2022-01-06 | 2022-04-15 | 阳光王子(寿光)特种纸有限公司 | Novel electrogenerated heating decorative paper and preparation method thereof |
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