CN108949391A - A kind of adhesive sticker detergent - Google Patents
A kind of adhesive sticker detergent Download PDFInfo
- Publication number
- CN108949391A CN108949391A CN201810941649.1A CN201810941649A CN108949391A CN 108949391 A CN108949391 A CN 108949391A CN 201810941649 A CN201810941649 A CN 201810941649A CN 108949391 A CN108949391 A CN 108949391A
- Authority
- CN
- China
- Prior art keywords
- locust
- adhesive sticker
- mixing
- parts
- mass ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 63
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 63
- 239000003599 detergent Substances 0.000 title claims abstract description 36
- 239000004615 ingredient Substances 0.000 claims abstract description 58
- 239000000843 powder Substances 0.000 claims abstract description 36
- 239000002131 composite material Substances 0.000 claims abstract description 29
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 29
- 238000004140 cleaning Methods 0.000 claims abstract description 28
- 239000004909 Moisturizer Substances 0.000 claims abstract description 27
- 229920001971 elastomer Polymers 0.000 claims abstract description 27
- 230000001333 moisturizer Effects 0.000 claims abstract description 27
- 239000006185 dispersion Substances 0.000 claims abstract description 25
- 238000002360 preparation method Methods 0.000 claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 15
- 229920002472 Starch Polymers 0.000 claims abstract description 14
- 235000019698 starch Nutrition 0.000 claims abstract description 14
- 239000008107 starch Substances 0.000 claims abstract description 14
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 44
- 239000003153 chemical reaction reagent Substances 0.000 claims description 35
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 35
- 239000000243 solution Substances 0.000 claims description 34
- 239000007788 liquid Substances 0.000 claims description 33
- 235000007164 Oryza sativa Nutrition 0.000 claims description 25
- 235000009566 rice Nutrition 0.000 claims description 25
- 239000002671 adjuvant Substances 0.000 claims description 23
- 238000005260 corrosion Methods 0.000 claims description 23
- 230000007797 corrosion Effects 0.000 claims description 23
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- 210000001015 abdomen Anatomy 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 238000002347 injection Methods 0.000 claims description 18
- 239000007924 injection Substances 0.000 claims description 18
- -1 octenyl succinate anhydrides Chemical class 0.000 claims description 16
- NTYJJOPFIAHURM-UHFFFAOYSA-N Histamine Chemical compound NCCC1=CN=CN1 NTYJJOPFIAHURM-UHFFFAOYSA-N 0.000 claims description 14
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 12
- 235000021388 linseed oil Nutrition 0.000 claims description 12
- 239000000944 linseed oil Substances 0.000 claims description 12
- 239000000341 volatile oil Substances 0.000 claims description 11
- 150000005686 dimethyl carbonates Chemical class 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 10
- 238000007873 sieving Methods 0.000 claims description 9
- 241000238814 Orthoptera Species 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 7
- OIPILFWXSMYKGL-UHFFFAOYSA-N acetylcholine Chemical compound CC(=O)OCC[N+](C)(C)C OIPILFWXSMYKGL-UHFFFAOYSA-N 0.000 claims description 7
- 229960004373 acetylcholine Drugs 0.000 claims description 7
- 229960001340 histamine Drugs 0.000 claims description 7
- 239000000787 lecithin Substances 0.000 claims description 7
- 229940067606 lecithin Drugs 0.000 claims description 7
- 235000010445 lecithin Nutrition 0.000 claims description 7
- 229920002401 polyacrylamide Polymers 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920001732 Lignosulfonate Polymers 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- 210000000683 abdominal cavity Anatomy 0.000 claims description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical class N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 6
- 239000007853 buffer solution Substances 0.000 claims description 6
- 238000005119 centrifugation Methods 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 6
- 108010064470 polyaspartate Proteins 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- 239000001509 sodium citrate Substances 0.000 claims description 6
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 6
- 230000008961 swelling Effects 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 4
- 238000003825 pressing Methods 0.000 claims 3
- 240000005385 Jasminum sambac Species 0.000 claims 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 abstract description 6
- 239000000084 colloidal system Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 230000003204 osmotic effect Effects 0.000 abstract description 5
- 125000003342 alkenyl group Chemical group 0.000 abstract description 3
- 210000001711 oxyntic cell Anatomy 0.000 abstract description 3
- 230000028327 secretion Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 102000004190 Enzymes Human genes 0.000 abstract description 2
- 108090000790 Enzymes Proteins 0.000 abstract description 2
- 238000005054 agglomeration Methods 0.000 abstract description 2
- 230000002776 aggregation Effects 0.000 abstract description 2
- 238000009395 breeding Methods 0.000 abstract description 2
- 230000001488 breeding effect Effects 0.000 abstract description 2
- 230000001079 digestive effect Effects 0.000 abstract description 2
- 238000005189 flocculation Methods 0.000 abstract description 2
- 230000016615 flocculation Effects 0.000 abstract description 2
- 210000004211 gastric acid Anatomy 0.000 abstract description 2
- 238000001879 gelation Methods 0.000 abstract description 2
- 230000002209 hydrophobic effect Effects 0.000 abstract description 2
- 230000006698 induction Effects 0.000 abstract description 2
- 244000005700 microbiome Species 0.000 abstract description 2
- 230000000750 progressive effect Effects 0.000 abstract description 2
- 241000209094 Oryza Species 0.000 description 21
- 241000207840 Jasminum Species 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 7
- 239000003292 glue Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000013019 agitation Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000012258 culturing Methods 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 4
- 238000004108 freeze drying Methods 0.000 description 4
- 238000005360 mashing Methods 0.000 description 4
- 210000001519 tissue Anatomy 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 238000005057 refrigeration Methods 0.000 description 3
- 241000690711 Locusta migratoria migratoria Species 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 229940112822 chewing gum Drugs 0.000 description 2
- 235000015218 chewing gum Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 230000002496 gastric effect Effects 0.000 description 1
- 210000004051 gastric juice Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 210000002460 smooth muscle Anatomy 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/362—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C11D2111/10—
Abstract
The present invention relates to a kind of adhesive sticker detergents, belong to daily chemical product field.The present invention carries out progressive induction to locust larva and raises, parietal cell is stimulated to secrete gastric acid, strengthen locust to the amount of the secretion of rubber powder digestive function enzyme and the corresponding enteric microorganism of breeding, it is greatly improved the decomposing force to adhesive sticker, biology cleaning ingredient compound can first decompose adhesive sticker outer component, gap is formed, cooperation moisturizer is greatly improved other component osmosises, plays cleaning action；There is hydrophobic alkenyl long chain and hydrophilic carboxylic group in starch octenyl succinate anhydride structure in composite emulsifying ingredient, so that adhesive sticker detergent system is not easy to form gel or flocculation, improve pressure sensitive colloid system good free mobility during the preparation process and hydrophobicity, it prevents other ingredients such as compounded mix from particle agglomeration occurs, improves the dispersion effect and osmotic effect of pressure sensitive adhesive.The present invention solves the problems, such as to commonly use that adhesive sticker detergent osmotic effect is poor, cleaning efficiency is not high at present.
Description
Technical field
The invention belongs to daily chemical product technical fields, and in particular to a kind of adhesive sticker detergent.
Background technique
In modern society, pressure sensitive adhesive has been deep into our daily life, due to very easy to use, so it
Using extremely wide, penetrated into all trades and professions and family, but its negative effect is also evident from, telephone booth, station board, advertisement
The small advertisement of various stickup, extremely unbecoming on the wall of the public places such as board, becomes " city ox-hide moss " this malignant tumor
Main source.The chemical stability of the viscose glues such as adhesive sticker is fabulous, when some adhesive sticker advertisements are damaged or replace, is difficult that it is clear
Except clean, even paper above adhesive sticker small advertisement is disposed, but the colloid under paper can be still attached on object, these
Viscose glue through solarization and absorption dust after, be hardened nigrescence and it is dirty, commonly settle accounts agent and be difficult to thoroughly remove them.In addition, by
The label paper of one layer of different-thickness is generally adhered in adhesive sticker surface layer, is also covered with colloid overlay film on the label paper sometimes,
Want to reach removing adhesive sticker, it is necessary to allow solvent penetration that can realize the dissolution of adhesive sticker, removing to inside tags, to increase
Thoroughly remove the difficulty of adhesive sticker.Adhesive sticker detergent time of penetration currently on the market is long, and removal rate is not high.
Summary of the invention
The technical problems to be solved by the invention: the poor, cleaning efficiency for common adhesive sticker detergent osmotic effect at present
Not high problem provides a kind of adhesive sticker detergent.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of adhesive sticker detergent, according to the mass fraction, including following component: 15 ~ 25 parts of dimethyl carbonates, 1 ~ 4 part of Jasmine
Essential oil, 2 ~ 5 parts of promotors, 3 ~ 7 parts of moisturizer, 3 ~ 7 parts of corrosion inhibiter, 30 ~ 50 parts of water, further includes: 25 ~ 40 parts biology cleaning at
Divide, 15 ~ 30 parts of composite emulsifying ingredients.
The preparation method of the biology cleaning ingredient compound, includes the following steps:
(1) water intaking spike of rice washing, dries, pulverizes and sieves, and takes sieving particle, reagent A mixing in mass ratio for 1:6 ~ 10, is homogenized,
Filtering, obtain rice mix juice, take discarded adhesive sticker to pulverize and sieve, take sieving particle 1:0.001:6 in mass ratio ~ 10 be added adjuvant,
Rice mixes juice mixing, obtains culture solution, spare, takes discarded adhesive sticker powder 1:12 in mass ratio ~ 20 that citric acid solution mixing is added and stirs
It mixes, obtains rubber powder dispersion liquid；
(2) in 25 ~ 30 DEG C, juice feeding 3 age locust larva is mixed with rice, grows to 5 age locusts, in locust growth period,
Every 12 ~ spare to every 5 ~ 10uL of locust abdomen injection for 24 hours culture solution, take 5 age locusts with rubber powder dispersion liquid feeding locust
Worm, and take rubber powder to disperse after culture 12 ~ 16 days every 12 ~ culture solution spare to every 5 ~ 10uL of locust abdomen injection for 24 hours
Liquid feeding locust, and every 12 ~ for 24 hours to the rubber powder dispersion liquid of every 5 ~ 10uL of locust abdomen injection, it cultivates 5 ~ 8 days, obtains locust
Adult；
(3) it takes locust adult abdominal cavity to mix juicing with reagent B for 1:12 ~ 25 in mass ratio, filters, obtain locust juice；Take locust
The mixing of saturated ammonium sulfate solution is added in 1:1 ~ 3 to juice by volume, obtains mixed liquid, is stored at room temperature, be centrifuged, it is cold to collect centrifugation object
Be lyophilized it is dry, discharging to get biology clean ingredient.
Reagent A in the step (1): in mass ratio 1:1 ~ 3:12 ~ 20 take sodium chloride, sodium citrate, water mixing to get
Reagent A.
Adjuvant in the step (1): 1:3 ~ 5 take acetylcholine, histamine mixing to get adjuvant in mass ratio.
Reagent B in the step (3): 10 ~ 15:2 takes by volume PBS buffer solution, dehydrated alcohol mix to get examination
Agent B.
The composite emulsifying ingredient: according to the mass fraction, successively take 8 ~ 15 parts of starch octenyl succinate anhydrides, 1 ~ 3 part it is auxiliary
Agent, 50 ~ 70 parts of water, 10 ~ 15 portions of linseed oil first take starch octenyl succinate anhydride, additive, water stirring mixed in 30 ~ 45 DEG C
It closes, stands swelling, linseed oil mixing is added in heating, and high-speed stirred is to get composite emulsifying ingredient.
The additive: 4:1 ~ 2 take lecithin, polyacrylamide mixing to get regulator in mass ratio.
The promotor: 6:0.1 ~ 0.3 takes triethanolamine, ferric trichloride mixing to get promotor in mass ratio.
The moisturizer: 10:1 ~ 3 take glycerol, fatty alcohol polyoxyethylene ether mixing to get moisturizer in mass ratio.
The corrosion inhibiter: 1:8 ~ 15 take poly-aspartate, lignosulfonate mixing to get corrosion inhibiter in mass ratio.
Compared with other methods, advantageous effects are the present invention:
(1) present invention carries out progressive induction raising to locust larva, mixes juice raising by rice before this, and inject micro culture
Liquid, the gastrointestinal smooth muscle of the acetylcholine excitement locust in culture solution make that its shrinkage amplitude, tension, wriggling increases, Jin Erke
Promote the secretion of locust gastric juice, and histamine may act on the H of the other parietal cell of neighbour of locust abdomen2Receptor, and stimulate parietal cell point
Gastric acid is secreted, the two mutually cooperates with, and is greatly improved the digestion power of locust larva, and can be improved to digest adhesive sticker powder and adapt to
Property, then using rubber powder dispersion liquid as main feed, supplemented by culture solution, its eupepsy to rubber powder is improved, sufficiently strengthens locust to glue
The secretion of powder digestive function enzyme and the amount of the corresponding enteric microorganism of breeding, are greatly improved the decomposing force to adhesive sticker, are using
In the process, biology cleaning ingredient compound can first decompose adhesive sticker outer component, form gap, and cooperation moisturizer can mention significantly
High other component osmosises, preferably play cleaning action；
(2) with hydrophobic alkenyl long chain and hydrophilic in the starch octenyl succinate anhydride structure in composite emulsifying ingredient of the present invention
Carboxylic group so that this adhesive sticker detergent system is not easy to form gel or flocculation, the polysaccharide long-chain having was being emulsified
Cheng Zhong, hydrophilic carboxylic acid group go deep into water, and the alkenyl long chain of oleophylic gos deep into oil, so that polysaccharide long-chain is on oil/water interface
One layer of very thick interfacial film is formed, better than the small-molecular emulsifier that can be only formed unimolecule interfacial film, and particle can be prevented solidifying
Gather and make emulsion stability, cooperates lecithin, the polyacrylamide in regulator, improve pressure sensitive colloid and tie up to preparation process
In good free mobility and hydrophobicity, prevent the other ingredients such as compounded mix from particle agglomeration occur, improve pressure sensitive adhesive
Dispersion effect and osmotic effect.
Specific embodiment
Reagent A: 1:1 ~ 3:12 ~ 20 take sodium chloride, sodium citrate, deionized water mixing to get reagent A in mass ratio.
Reagent B: 10 ~ 15:2 takes PBS buffer solution, dehydrated alcohol that pH is 7.2 ~ 7.8 to mix to get reagent B by volume.
Adjuvant: 1:3 ~ 5 take acetylcholine, histamine mixing to get adjuvant in mass ratio.
Corrosion inhibiter: 1:8 ~ 15 take poly-aspartate, lignosulfonate mixing to get corrosion inhibiter in mass ratio.
Moisturizer: 10:1 ~ 3 take glycerol, fatty alcohol polyoxyethylene ether mixing to get moisturizer in mass ratio.
Promotor: 6:0.1 ~ 0.3 takes triethanolamine, ferric trichloride mixing to get promotor in mass ratio.
Additive: 4:1 ~ 2 take lecithin, polyacrylamide mixing to get regulator in mass ratio.
Locust larva: any one in Asiatic migrotory locust, Asiatic migratory locust.
The preparation method of biology cleaning ingredient compound, includes the following steps:
(1) water intaking spike of rice washes with water 3 ~ 5 times, and naturally dry, moving to pulverizer crushed 80 meshes, be in mass ratio 1:6 ~ 10
It takes sieving particle, reagent A to mix in tissue mashing machine, is homogenized, filtering obtains rice and mixes juice, takes discarded adhesive sticker in pulverizer powder
Broken 200 mesh of mistake takes sieving particle 1:0.001:6 in mass ratio ~ 10 that the mixed juice mixing of adjuvant, rice is added, obtains culture solution, standby
With, took the discarded adhesive sticker powder 1:12 in mass ratio ~ 20 of 400 meshes that the citric acid solution mixing of concentration 0.5mol/L is added,
20 ~ 45min is stirred with 400 ~ 600r/min, obtains rubber powder dispersion liquid；
(2) in 25 ~ 30 DEG C, under the conditions of relative humidity is 45 ~ 55%, juice feeding 3 age locust larva is mixed with rice, until growth
To 5 age locusts, in locust growth period, every 12 ~ spare to every 5 ~ 10uL of locust abdomen injection for 24 hours culture solution, take 5
Age locust is cultivated in 28 ~ 32 DEG C, the culturing room that relative humidity is 35 ~ 45%, takes rubber powder dispersion liquid feeding locust, and every 12 ~
Culture solution spare to every 5 ~ 10uL of locust abdomen injection for 24 hours takes rubber powder dispersion liquid feeding locust after culture 12 ~ 16 days, and
Every 12 ~ and for 24 hours to the rubber powder dispersion liquid of every 5 ~ 10uL of locust abdomen injection, it cultivates 5 ~ 8 days, obtains locust adult；
(3) it takes locust adult abdominal cavity to mix with reagent B for 1:12 ~ 25 in mass ratio and pours into juice extractor juicing, filtering obtains locust juice
Liquid；Take locust juice by volume 1:1 ~ 3 be added saturated ammonium sulfate solution mixing, with 400 ~ 600r/min magnetic agitation 30 ~
50min obtains mixed liquid, after being stored at room temperature 6 ~ 10min, is transferred to centrifuge, with 3000 ~ 4000r/min revolving speed centrifuge separation 10 ~
15min collects centrifugation object and is transferred to vacuum freezing drying oven, and in -40 DEG C of 4 ~ 6h of freeze-drying, discharging cleans ingredient to get biology.
The preparation of composite emulsifying ingredient: according to the mass fraction, 8 ~ 15 parts of starch octenyl succinate anhydrides, 1 ~ 3 part are successively taken
Adjuvant, 50 ~ 70 parts of water, 10 ~ 15 portions of linseed oil first take starch octenyl succinate anhydride, additive, water to stir in 30 ~ 45 DEG C of water-bath
It mixes mixing, stands swelling, be warming up to 55 ~ 70 DEG C, linseed oil mixing is added, with 3000 ~ 4000r/min, 5 ~ 10min of high-speed stirred,
Up to composite emulsifying ingredient.
A kind of adhesive sticker detergent, according to the mass fraction, including following component: 15 ~ 25 parts of dimethyl carbonates, 1 ~ 4 part of jasmine
Jasmine flower essential oil, 2 ~ 5 parts of promotors, 3 ~ 7 parts of moisturizer, 3 ~ 7 parts of corrosion inhibiter, 30 ~ 50 parts of water, 25 ~ 40 parts of biologies cleaning ingredients, 15
~ 30 parts of composite emulsifying ingredients.
A kind of preparation method of adhesive sticker detergent, includes the following steps:
(1) according to the mass fraction, 15 ~ 25 parts of dimethyl carbonates, 1 ~ 4 part of jasmine essential oil, 2 ~ 5 parts of promotors, 3 ~ 7 parts of moisturizings are taken
Agent, 3 ~ 7 parts of corrosion inhibiter, 30 ~ 50 parts of water, 25 ~ 40 parts of biologies cleaning ingredients, 15 ~ 30 parts of composite emulsifying ingredients；
(2) prior to 35 ~ 50 DEG C, dimethyl carbonate, jasmine essential oil, promotor, water is taken to mix in reaction kettle, with 400 ~ 600r/
After 30 ~ 50min of min magnetic agitation, be cooled to 20 ~ 30 DEG C, be added moisturizer, corrosion inhibiter, biology cleaning ingredient, composite emulsifying at
Divide mixing, 10 ~ 20min is handled to get adhesive sticker detergent with 45 ~ 55kHz frequency ultrasonic wave.
Reagent A: 1:1:12 in mass ratio takes sodium chloride, sodium citrate, deionized water mixing to get reagent A.
Reagent B: 10:2 takes PBS buffer solution, dehydrated alcohol that pH is 7.2 to mix to get reagent B by volume.
Adjuvant: 1:3 in mass ratio takes acetylcholine, histamine mixing to get adjuvant.
Corrosion inhibiter: 1:8 in mass ratio takes poly-aspartate, lignosulfonate mixing to get corrosion inhibiter.
Moisturizer: 10:1 in mass ratio takes glycerol, fatty alcohol polyoxyethylene ether mixing to get moisturizer.
Promotor: 6:0.1 in mass ratio takes triethanolamine, ferric trichloride mixing to get promotor.
Additive: 4:1 in mass ratio takes lecithin, polyacrylamide mixing to get regulator.
Locust larva: Asiatic migrotory locust.
The preparation method of biology cleaning ingredient compound, includes the following steps:
(1) water intaking spike of rice washes with water 3 times, and naturally dry, moving to pulverizer crushed 80 meshes, take in mass ratio for 1:6
Particle, reagent A are sieved in tissue mashing machine's mixing, is homogenized, filtering, is obtained rice and mix juice, discarded adhesive sticker is taken to crushed in pulverizer
200 meshes take sieving particle 1:0.001:6 in mass ratio that the mixed juice mixing of adjuvant, rice is added, obtain culture solution, spare, take
The citric acid solution mixing of concentration 0.5mol/L is added in the discarded adhesive sticker powder 1:12 in mass ratio of 400 meshes, with 400r/min
20min is stirred, rubber powder dispersion liquid is obtained；
(2) in 25 DEG C, under the conditions of relative humidity is 45%, juice feeding 3 age locust larva is mixed with rice, until growing to for 5 ages
Locust takes 5 age locusts in 28 in locust growth period every the 12h culture solution spare to every locust abdomen injection 5uL
DEG C, the culturing room that relative humidity is 35% cultivate, take rubber powder dispersion liquid feeding locust, and every 12h to every locust abdomen injection
5uL spare culture solution takes rubber powder dispersion liquid feeding locust after culture 12 days, and every 12h to every locust abdomen injection
The rubber powder dispersion liquid of 5uL is cultivated 5 days, obtains locust adult；
(3) it takes locust adult abdominal cavity to mix with reagent B for 1:12 in mass ratio and pours into juice extractor juicing, filtering obtains locust juice；
Taking locust juice, the mixing of saturated ammonium sulfate solution is added in 1:1 by volume, with 400r/min magnetic agitation 30min, obtains mixed liquid, room
After temperature stands 6min, it is transferred to centrifuge, 10min is centrifugated with 3000r/min revolving speed, it is dry that collection centrifugation object is transferred to vacuum refrigeration
Dry case, in -40 DEG C of freeze-drying 4h, discharging cleans ingredient to get biology.
The preparation of composite emulsifying ingredient: according to the mass fraction, successively take 8 parts of starch octenyl succinate anhydrides, 1 part of adjuvant,
50 parts of water, 10 portions of linseed oil first take starch octenyl succinate anhydride, additive, water to be stirred in 30 DEG C of water-bath, stand molten
It is swollen, 55 DEG C are warming up to, linseed oil mixing is added, with 3000r/min high-speed stirred 5min to get composite emulsifying ingredient.
A kind of adhesive sticker detergent, according to the mass fraction, including following component: 15 parts of dimethyl carbonates, 1 part of jasmine anthosin
Oil, 2 parts of promotors, 3 parts of moisturizer, 3 parts of corrosion inhibiter, 30 parts of water, 25 parts of biologies cleaning ingredients, 15 parts of composite emulsifying ingredients.
A kind of preparation method of adhesive sticker detergent, includes the following steps:
(1) according to the mass fraction, take 15 parts of dimethyl carbonates, 1 part of jasmine essential oil, 2 parts of promotors, 3 parts of moisturizer, 3 parts it is slow
Lose agent, 30 parts of water, 25 parts of biologies cleaning ingredients, 15 parts of composite emulsifying ingredients；
(2) prior to 35 DEG C, dimethyl carbonate, jasmine essential oil, promotor, water is taken to mix in reaction kettle, with 400r/min magnetic force
After stirring 30min, 20 DEG C are cooled to, moisturizer, corrosion inhibiter, biology cleaning ingredient, the mixing of composite emulsifying ingredient is added, with
45kHz frequency ultrasonic wave handles 10min to get adhesive sticker detergent.
Reagent A: 1:3:20 in mass ratio takes sodium chloride, sodium citrate, deionized water mixing to get reagent A.
Reagent B: 15:2 takes PBS buffer solution, dehydrated alcohol that pH is 7.8 to mix to get reagent B by volume.
Adjuvant: 1:5 in mass ratio takes acetylcholine, histamine mixing to get adjuvant.
Corrosion inhibiter: 1:15 in mass ratio takes poly-aspartate, lignosulfonate mixing to get corrosion inhibiter.
Moisturizer: 10:3 in mass ratio takes glycerol, fatty alcohol polyoxyethylene ether mixing to get moisturizer.
Promotor: 6:0.3 in mass ratio takes triethanolamine, ferric trichloride mixing to get promotor.
Additive: 4:2 in mass ratio takes lecithin, polyacrylamide mixing to get regulator.
Locust larva: Asiatic migratory locust.
The preparation method of biology cleaning ingredient compound, includes the following steps:
(1) water intaking spike of rice washes with water 5 times, and naturally dry, moving to pulverizer crushed 80 meshes, take in mass ratio for 1:10
Particle, reagent A are sieved in tissue mashing machine's mixing, is homogenized, filtering, is obtained rice and mix juice, discarded adhesive sticker is taken to crushed in pulverizer
200 meshes take sieving particle 1:0.001:10 in mass ratio that the mixed juice mixing of adjuvant, rice is added, obtain culture solution, spare, take
The citric acid solution mixing of concentration 0.5mol/L is added in the discarded adhesive sticker powder 1:20 in mass ratio of 400 meshes, with 600r/min
45min is stirred, rubber powder dispersion liquid is obtained；
(2) in 30 DEG C, under the conditions of relative humidity is 55%, juice feeding 3 age locust larva is mixed with rice, until growing to for 5 ages
Locust takes 5 age locusts in 32 in locust growth period every culture solution spare to every locust abdomen injection 10uL for 24 hours
DEG C, relative humidity be 45% culturing room cultivate, take rubber powder dispersion liquid feeding locust, and every for 24 hours to every locust abdomen injection
10uL spare culture solution takes rubber powder dispersion liquid feeding locust, and every for 24 hours to every locust abdomen injection after culture 16 days
The rubber powder dispersion liquid of 10uL is cultivated 8 days, obtains locust adult；
(3) it takes locust adult abdominal cavity to mix with reagent B for 1:25 in mass ratio and pours into juice extractor juicing, filtering obtains locust juice；
Taking locust juice, the mixing of saturated ammonium sulfate solution is added in 1:3 by volume, with 600r/min magnetic agitation 50min, obtains mixed liquid, room
After temperature stands 10min, it is transferred to centrifuge, 15min is centrifugated with 4000r/min revolving speed, centrifugation object is collected and is transferred to vacuum refrigeration
Drying box, in -40 DEG C of freeze-drying 6h, discharging cleans ingredient to get biology.
The preparation of composite emulsifying ingredient: according to the mass fraction, successively take 15 parts of starch octenyl succinate anhydrides, 3 parts of adjuvants,
70 parts of water, 15 portions of linseed oil first take starch octenyl succinate anhydride, additive, water to be stirred in 45 DEG C of water-bath, stand molten
It is swollen, 70 DEG C are warming up to, linseed oil mixing is added, with 4000r/min high-speed stirred 10min to get composite emulsifying ingredient.
A kind of adhesive sticker detergent, according to the mass fraction, including following component: 25 parts of dimethyl carbonates, 4 parts of jasmine anthosin
Oil, 5 parts of promotors, 7 parts of moisturizer, 7 parts of corrosion inhibiter, 50 parts of water, 40 parts of biologies cleaning ingredients, 30 parts of composite emulsifying ingredients.
A kind of preparation method of adhesive sticker detergent, includes the following steps:
(1) according to the mass fraction, take 25 parts of dimethyl carbonates, 4 parts of jasmine essential oils, 5 parts of promotors, 7 parts of moisturizer, 7 parts it is slow
Lose agent, 50 parts of water, 40 parts of biologies cleaning ingredients, 30 parts of composite emulsifying ingredients；
(2) prior to 50 DEG C, dimethyl carbonate, jasmine essential oil, promotor, water is taken to mix in reaction kettle, with 600r/min magnetic force
After stirring 50min, 30 DEG C are cooled to, moisturizer, corrosion inhibiter, biology cleaning ingredient, the mixing of composite emulsifying ingredient is added, with
55kHz frequency ultrasonic wave handles 20min to get adhesive sticker detergent.
Reagent A: 1:2:15 in mass ratio takes sodium chloride, sodium citrate, deionized water mixing to get reagent A.
Reagent B: 13:2 takes PBS buffer solution, dehydrated alcohol that pH is 7.5 to mix to get reagent B by volume.
Adjuvant: 1:4 in mass ratio takes acetylcholine, histamine mixing to get adjuvant.
Corrosion inhibiter: 1:11 in mass ratio takes poly-aspartate, lignosulfonate mixing to get corrosion inhibiter.
Moisturizer: 10:2 in mass ratio takes glycerol, fatty alcohol polyoxyethylene ether mixing to get moisturizer.
Promotor: 6:0.2 in mass ratio takes triethanolamine, ferric trichloride mixing to get promotor.
Additive: 4:1.5 in mass ratio takes lecithin, polyacrylamide mixing to get regulator.
Locust larva: Asiatic migrotory locust.
The preparation method of biology cleaning ingredient compound, includes the following steps:
(1) water intaking spike of rice washes with water 4 times, and naturally dry, moving to pulverizer crushed 80 meshes, take in mass ratio for 1:8
Particle, reagent A are sieved in tissue mashing machine's mixing, is homogenized, filtering, is obtained rice and mix juice, discarded adhesive sticker is taken to crushed in pulverizer
200 meshes take sieving particle 1:0.001:8 in mass ratio that the mixed juice mixing of adjuvant, rice is added, obtain culture solution, spare, take
The citric acid solution mixing of concentration 0.5mol/L is added in the discarded adhesive sticker powder 1:17 in mass ratio of 400 meshes, with 500r/min
35min is stirred, rubber powder dispersion liquid is obtained；
(2) in 27 DEG C, under the conditions of relative humidity is 50%, juice feeding 3 age locust larva is mixed with rice, until growing to for 5 ages
Locust takes 5 age locusts in 30 in locust growth period every the 20h culture solution spare to every locust abdomen injection 7uL
DEG C, the culturing room that relative humidity is 40% cultivate, take rubber powder dispersion liquid feeding locust, and every 20h to every locust abdomen injection
7uL spare culture solution takes rubber powder dispersion liquid feeding locust after culture 14 days, and every 20h to every locust abdomen injection
The rubber powder dispersion liquid of 7uL is cultivated 7 days, obtains locust adult；
(3) it takes locust adult abdominal cavity to mix with reagent B for 1:15 in mass ratio and pours into juice extractor juicing, filtering obtains locust juice；
Taking locust juice, the mixing of saturated ammonium sulfate solution is added in 1:2 by volume, with 500r/min magnetic agitation 40min, obtains mixed liquid, room
After temperature stands 8min, it is transferred to centrifuge, 12min is centrifugated with 3500r/min revolving speed, it is dry that collection centrifugation object is transferred to vacuum refrigeration
Dry case, in -40 DEG C of freeze-drying 5h, discharging cleans ingredient to get biology.
The preparation of composite emulsifying ingredient: according to the mass fraction, successively take 11 parts of starch octenyl succinate anhydrides, 2 parts of adjuvants,
60 parts of water, 12 portions of linseed oil first take starch octenyl succinate anhydride, additive, water to be stirred in 35 DEG C of water-bath, stand molten
It is swollen, 60 DEG C are warming up to, linseed oil mixing is added, with 3500r/min high-speed stirred 7min to get composite emulsifying ingredient.
A kind of adhesive sticker detergent, according to the mass fraction, including following component: 20 parts of dimethyl carbonates, 2 parts of jasmine anthosin
Oil, 3 parts of promotors, 5 parts of moisturizer, 4 parts of corrosion inhibiter, 40 parts of water, 35 parts of biologies cleaning ingredients, 25 parts of composite emulsifying ingredients.
A kind of preparation method of adhesive sticker detergent, includes the following steps:
(1) according to the mass fraction, take 20 parts of dimethyl carbonates, 3 parts of jasmine essential oils, 3 parts of promotors, 4 parts of moisturizer, 5 parts it is slow
Lose agent, 40 parts of water, 35 parts of biologies cleaning ingredients, 25 parts of composite emulsifying ingredients；
(2) prior to 45 DEG C, dimethyl carbonate, jasmine essential oil, promotor, water is taken to mix in reaction kettle, with 500r/min magnetic force
After stirring 40min, 25 DEG C are cooled to, moisturizer, corrosion inhibiter, biology cleaning ingredient, the mixing of composite emulsifying ingredient is added, with
50kHz frequency ultrasonic wave handles 15min to get adhesive sticker detergent.
Comparative example 1: it is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking biology cleaning ingredient.
Comparative example 2: it is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking composite emulsifying ingredient.
Comparative example 3: the adhesive sticker detergent of Yancheng City company production.
It is with the plastics spray bottle with handle nozzle that adhesive sticker detergent made from the embodiment and comparative example is filling, then to
The pressure sensitive adhesive of adhesive sticker colloid vestiges, chewing gum residue glue and common label paper from anywhere in public place and room
Surface is spraying respectively, sufficiently soaks, and is then wiped with dry cotton, or rejected with small scoop；For being stained with overlay film label paper
Pressure sensitive adhesive provokes a corner in advance, sprays this product solution to glue attachment surface then along direction is torn, and when hydrojet is suitably used
Power tearing is completely exfoliated until pressure sensitive adhesive, reaches the time used in 95% elimination effect.Obtain that the results are shown in Table 1.
Table 1:
| Implementation project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Clean adhesive sticker colloid residual (s) | 50 | 40 | 60 | 60 | 55 | 120 |
| Clean the adhesive sticker residue glue (s) of common label paper | 105 | 100 | 103 | 95 | 98 | 112 |
| It cleans chewing gum residue glue (s) | 17 | 15 | 19 | 20 | 25 | 85 |
In summary, adhesive sticker detergent osmotic effect of the invention is good, cleaning efficiency is high, is worth of widely use.
Claims (10)
1. a kind of adhesive sticker detergent, according to the mass fraction, including following component: 15 ~ 25 parts of dimethyl carbonates, 1 ~ 4 portion of jasmine
Flower essential oil, 2 ~ 5 parts of promotors, 3 ~ 7 parts of moisturizer, 3 ~ 7 parts of corrosion inhibiter, 30 ~ 50 parts of water, which is characterized in that further include: 25 ~ 40
Part biology cleaning ingredient, 15 ~ 30 parts of composite emulsifying ingredients.
2. a kind of adhesive sticker detergent according to claim 1, which is characterized in that the system of the biology cleaning ingredient compound
Preparation Method includes the following steps:
(1) water intaking spike of rice washing, dries, pulverizes and sieves, and takes sieving particle, reagent A mixing in mass ratio for 1:6 ~ 10, is homogenized,
Filtering, obtain rice mix juice, take discarded adhesive sticker to pulverize and sieve, take sieving particle 1:0.001:6 in mass ratio ~ 10 be added adjuvant,
Rice mixes juice mixing, obtains culture solution, spare, takes discarded adhesive sticker powder 1:12 in mass ratio ~ 20 that citric acid solution mixing is added and stirs
It mixes, obtains rubber powder dispersion liquid；
(2) in 25 ~ 30 DEG C, juice feeding 3 age locust larva is mixed with rice, grows to 5 age locusts, in locust growth period,
Every 12 ~ spare to every 5 ~ 10uL of locust abdomen injection for 24 hours culture solution, take 5 age locusts with rubber powder dispersion liquid feeding locust
Worm, and take rubber powder to disperse after culture 12 ~ 16 days every 12 ~ culture solution spare to every 5 ~ 10uL of locust abdomen injection for 24 hours
Liquid feeding locust, and every 12 ~ for 24 hours to the rubber powder dispersion liquid of every 5 ~ 10uL of locust abdomen injection, it cultivates 5 ~ 8 days, obtains locust
Adult；
(3) it takes locust adult abdominal cavity to mix juicing with reagent B for 1:12 ~ 25 in mass ratio, filters, obtain locust juice；Take locust
The mixing of saturated ammonium sulfate solution is added in 1:1 ~ 3 to juice by volume, obtains mixed liquid, is stored at room temperature, be centrifuged, it is cold to collect centrifugation object
Be lyophilized it is dry, discharging to get biology clean ingredient.
3. a kind of adhesive sticker detergent according to claim 2, which is characterized in that the reagent A in the step (1): pressing matter
Amount takes sodium chloride, sodium citrate, water mixing to get reagent A than 1:1 ~ 3:12 ~ 20.
4. a kind of adhesive sticker detergent according to claim 2, which is characterized in that the adjuvant in the step (1): pressing quality
Take acetylcholine, histamine mixing to get adjuvant than 1:3 ~ 5.
5. a kind of adhesive sticker detergent according to claim 2, which is characterized in that the reagent B in the step (3): press body
Product is mixed than the PBS buffer solution that 10 ~ 15:2 takes, dehydrated alcohol to get reagent B.
6. a kind of adhesive sticker detergent according to claim 1, which is characterized in that the composite emulsifying ingredient: pressing mass parts
Number meter, successively takes 8 ~ 15 parts of starch octenyl succinate anhydrides, 1 ~ 3 part of adjuvant, 50 ~ 70 parts of water, 10 ~ 15 portions of linseed oil, in 30 ~ 45
DEG C, it first takes starch octenyl succinate anhydride, additive, water to be stirred, stands swelling, linseed oil mixing, high speed is added in heating
Stirring is to get composite emulsifying ingredient.
7. a kind of adhesive sticker detergent according to claim 6, which is characterized in that the additive: 4:1 ~ 2 take in mass ratio
Lecithin, polyacrylamide mixing are to get regulator.
8. a kind of adhesive sticker detergent according to claim 1, which is characterized in that the promotor: 6:0.1 in mass ratio ~
0.3 takes triethanolamine, ferric trichloride mixing to get promotor.
9. a kind of adhesive sticker detergent according to claim 1, which is characterized in that the moisturizer: 10:1 ~ 3 in mass ratio
Take glycerol, fatty alcohol polyoxyethylene ether mixing to get moisturizer.
10. a kind of adhesive sticker detergent according to claim 1, which is characterized in that the corrosion inhibiter: 1:8 ~ 15 in mass ratio
Take poly-aspartate, lignosulfonate mixing to get corrosion inhibiter.
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| CN111454789A (en) * | 2020-04-07 | 2020-07-28 | 苏州健雄职业技术学院 | High-performance stamp gum cleaning agent |
| CN114679976A (en) * | 2022-03-08 | 2022-07-01 | 陕西省西安植物园 | Restoration and protection method for magnolia ancient trees |
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| CN107853336A (en) * | 2017-11-03 | 2018-03-30 | 常州市鑫嘉生物科技有限公司 | A kind of preparation method of functional biological herbicide |
| CN107868729A (en) * | 2017-10-30 | 2018-04-03 | 广东石油化工学院 | A kind of degumming composition and its preparation method and application |
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| CN103834491A (en) * | 2014-03-19 | 2014-06-04 | 广州麦饭石化工技术有限公司 | Adhesive sticker blot cleaning agent based on biological enzyme technology and production technology thereof |
| CN106497706A (en) * | 2015-09-06 | 2017-03-15 | 南京嵘天绿色化学有限公司 | A kind of adhesive sticker abluent of environmental protection |
| CN107868729A (en) * | 2017-10-30 | 2018-04-03 | 广东石油化工学院 | A kind of degumming composition and its preparation method and application |
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| CN111454789A (en) * | 2020-04-07 | 2020-07-28 | 苏州健雄职业技术学院 | High-performance stamp gum cleaning agent |
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| CN114679976A (en) * | 2022-03-08 | 2022-07-01 | 陕西省西安植物园 | Restoration and protection method for magnolia ancient trees |
| CN114679976B (en) * | 2022-03-08 | 2023-03-07 | 陕西省西安植物园 | Restoration and protection method for magnolia ancient trees |
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