CN108949282A - The manufacturing method of the derivative fuel of high heating value solid-state - Google Patents
The manufacturing method of the derivative fuel of high heating value solid-state Download PDFInfo
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- CN108949282A CN108949282A CN201710355889.9A CN201710355889A CN108949282A CN 108949282 A CN108949282 A CN 108949282A CN 201710355889 A CN201710355889 A CN 201710355889A CN 108949282 A CN108949282 A CN 108949282A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/46—Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/445—Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/48—Solid fuels essentially based on materials of non-mineral origin on industrial residues and waste materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/08—Drying or removing water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/24—Mixing, stirring of fuel components
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/32—Molding or moulds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/36—Applying radiation such as microwave, IR, UV
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Abstract
A kind of manufacturing method of the derivative fuel of high heating value solid-state, it include: that an organic sludge and a useless natural food materials are puddled into one and puddle object by A., B. this is puddled into object and mixes the silicon reclaimed materials that addition is recycled by the useless silicon mud of Silicon Wafer cutting, C. this is puddled into object and is shaped as a molding, D. the molding is subjected to a microwave radiation with a microwave and removes water process, the moisture content of the molding is set to be down to 40% or less, E. deoxidation treatment is carried out to the molding, so as to obtaining the derivative fuel of a solid-state, whereby, the Silicon Wafer generated in recycling and reusing such as solar battery manufacturing process cuts useless silicon mud, all raw materials and be all life, waste caused by industry, and it can further improve the calorific value of the derivative fuel of solid-state, obtain the green energy resource of high burning efficiency.
Description
Technical field
The present invention relates to a kind of manufacturing method of derivative fuel of high heating value solid-state, especially a kind of mixing organic sludge
In conjunction with useless natural food materials, and adds and the silicon reclaimed materials and penetrate microwave radiation water removal that useless silicon mud is recycled are cut by Silicon Wafer
Processing reduces the manufacturing method of moisture content and the manufactured derivative fuel of high heating value solid-state.
Background technique
Organic sludge, just like sludge or paper pulp mud caused by domestic sludge, sewage sludge, clean and reuse PET bottle
Deng, wherein being mostly produced by paper mill production paper device product processing procedure such as paper pulp mud, moisture content is high (being greater than 75%),
And have and be not easy to be dehydrated because of material property, and because main component includes carbon, nitrogen, sulphur, and it is easy to disadvantage smelly in the short time.
Again in recent years, the problems such as domestic also Chang Youru food peace, waste edible oil can not be dealt carefully with and recycle.
The applicant was once proposed in the past such as TaiWan, China patent of invention bulletin I 527770 " organic sludge and useless food
With oily conformability processing method, derivative fuel, feed additive " preceding case, which is to solve known wastewater treatment to be produced
Raw organic sludge derives many disadvantages during recovery processing, and in the preceding case, organic sludge and waste edible oil are handled
Program step includes: an organic sludge and a starch are given up cohered after food materials mix in appropriate proportions puddle step, at
Type step improves reforming step and separating step through waste edible oil, to obtain a final product.Whereby, aforementioned organic sludge is promoted
Calorific value and moisture content is greatly reduced with sharp long-term preservation, enable the final product apply be used as derivative fuel (RDF-5 (d-
RDF)) with the purposes of feed additive.
However, the waste edible oil that the preceding case carries out improves reforming step, it need to be with higher oil temperature to organic sludge and starch
Useless food materials puddle molding molding and carry out conditioning modification, need to be to waste edible oil heat treatment, processing procedure consuming energy, and need longer
Time.Also, the calorific value of the preceding case still has the space that can improve again.
Domestic You Sheng section scholar professor Jiang Zhenyu studies for many years, has tested just in European Chinese silvergrass and has been mixed combustion with coal extensively
Power generation is burnt, the heats of combustion (32MJ/kg=7,600kcal/kg) by silicon in Chinese silvergrass plant is biomass energy material of new generation.
In addition, solar energy accounts for extremely important in following alternative energy source with the development of science and technology the demand for the energy also increases
Status.And therefore the Silicon Wafer demand to manufacture solar battery also increases, wherein in production and cutting silicon crystal circle
In the process, largely useless silicon mud can be generated, containing a large amount of carborundum particles, silicon bits, metal and cutting oil in these useless silicon mud, no
The loss in cost is only caused, more needs additional cost to carry out waste commission removing processing, otherwise will cause dirt environmentally
Dye.If can effectively be recycled, the cost of offal treatment is not only reduced, can also be provided by recycling and reusing silicon carbide and silicon etc.
Source and promote economic benefit.Accordingly, with respect to the renewable sources of energy application of Chinese silvergrass (natural fuel), the present invention is also intended to addition solar energy
Artificial fuels such as silicon mud (> 50% silicone contents) are cut, to increase the calorific value of the derivative fuel of solid-state (RDF).
Summary of the invention
For this purpose, the present inventor is dedicated to studying for the known deficiency of improvement and missing place, high heating value of the invention is proposed
The manufacturing method of the derivative fuel of solid-state a, comprising: organic sludge and a useless natural food materials are puddled into one and puddle object by A., this has
The parts by weight of machine sludge and the useless natural food materials are 98:2 to 80:20;B. this object mixing addition is puddled to be given up by Silicon Wafer cutting
The silicon reclaimed materials that silicon mud is recycled, the adding proportion of the silicon reclaimed materials is to account for 3% to 10%;C. this is puddled into object and is shaped as one
Molding;D. the molding is subjected to a microwave radiation with a microwave and removes water process, the moisture content of the molding is made to be down to 18%
Below;E. deoxidation treatment is carried out to the molding, so as to obtaining the derivative fuel of a solid-state: the molding is utilized discarded one
Waste edible oil carries out frying, and frying temperature is 130 DEG C to 220 DEG C, and deep-fat frying time is 5 minutes to 30 minutes, makes the molding
Be formed as the derivative fuel of the solid-state, the moisture content of the derivative fuel of the solid-state is made to reach 7% hereinafter, whereby, obtaining has height
The derivative fuel of the solid-state of calorific value.
Further, the step B silicon reclaimed materials is to cut useless silicon mud comprising the Silicon Wafer to contain polyethylene glycol without washing
(PEG) and the useless silicon mud of the cutting oil of the tool cooling effect such as diethylene glycol (DEG).
Further, the step B silicon reclaimed materials is comprising the useless silicon mud of the Silicon Wafer chip is utilized centrifugal action, flotation or acid
Alkali impregnates separated silicon and silicon carbide out.
Further, step B impregnates separated silicon and silicon carbide out through centrifugal action, flotation or sour alkali, and is by water
Wash, and by drying temperature 250 degree to 300 degree Celsius, drying time at least 4 hours drying processes and contained by removing
Polyethylene glycol or diethylene glycol.
Further, step B is to isolate the useless silicon mud of the Silicon Wafer chip using centrifugal action, flotation or sour alkali dipping
Silicon and silicon carbide, then purity is made again from silicon and silicon carbide and is 80% to 98% silicon, and obtain the silicon reclaimed materials.
Further, it is to be handled using an industrial micro-wave oven the molding that the step D microwave radiation, which removes water process,
The consumption power of the industrial micro-wave oven is 2kW, and operating current system is 2 to 6 amperes, and the microwave water removal time is 4 to 10 minutes.
Further, the moisture content of the step A organic sludge is between 75% to 89%, and it includes processing TFT-LCD liquid crystal surfaces
Sludge caused by the waste sludge of plate, clean and reuse PET bottle, the paper pulp mud for handling paper-making process, domestic sewage factory it is useless
The waste sludge generated after water process it is any or combinations thereof;The step A natural food materials that should give up are the food materials that give up for a starch, and are made
It is puddled for an adhesive and the organic sludge, it includes following any or combinations thereof: being filtered out from the useless food materials after processing
Sweet potato flour, Cornstarch, corn flour, or rice, congee, paste from useless prepared food material through preliminary screening;The step E waste edible oil includes
The discarded vegetalitas edible oil of expired food, animality edible oil or combinations thereof, the vegetalitas edible oil include an olive oil, one
Soybean oil, a salad oil or a sunflower oil, the animality edible oil include a lard, a butter or a sheep oil.
Further, step C is that this is puddled object moulding using an extrusion shaping machine, a pelletizer or a Jet forming machine
For bulk, strip, rodlike, hollow rod-shape, column, hollow columnar, sheet, the spherical or granular molding.
The manufacturing method of the derivative fuel of high heating value solid-state of the invention, be also possible to include: A. by an organic sludge with
One useless natural food materials puddle into one and puddle object, and the parts by weight of the organic sludge and the useless natural food materials are 98:2 to 80:20;B. will
This is puddled object and carries out a microwave radiation except water process with a microwave, and the moisture content for puddling object is made to be down to 40% or less;C. should
It puddles object mixing addition and the silicon reclaimed materials that useless silicon mud is recycled is cut by Silicon Wafer, the adding proportion of the silicon reclaimed materials is to account for
3% to 10%;D. this is puddled into object and is shaped as a molding;E. deoxidation treatment is carried out to the molding, so as to obtaining a solid-state
Derivative fuel: the molding is subjected to frying using a discarded waste edible oil, frying temperature is 130 DEG C to 220 DEG C, oil
The fried time is 5 minutes to 30 minutes, so that the molding is formed as the derivative fuel of the solid-state, makes containing for the derivative fuel of the solid-state
Water rate reaches 7% hereinafter, whereby, obtaining the derivative fuel of the solid-state with high heating value.
The manufacturing method of the derivative fuel of high heating value solid-state of the invention, be also possible to include: A. by an organic sludge with
One useless natural food materials puddle into one and puddle object, and the parts by weight of the organic sludge and the useless natural food materials are 98:2 to 80:20;B. will
This is puddled object mixing addition and cuts the silicon reclaimed materials that useless silicon mud is recycled by Silicon Wafer, and the adding proportion of the silicon reclaimed materials is to account for
3% to 10%;C. this is puddled into object and one microwave radiation is carried out except water process with a microwave, be down to the moisture content for puddling object
40% or less;D. this is puddled into object and is shaped as a molding;E. deoxidation treatment is carried out to the molding, spread out so as to obtaining a solid-state
Natural disposition fuel: the molding is subjected to frying using a discarded waste edible oil, frying temperature is 130 DEG C to 220 DEG C, fried
Time is 5 minutes to 30 minutes, so that the molding is formed as the derivative fuel of the solid-state, makes the aqueous of the derivative fuel of the solid-state
Rate reaches 7% hereinafter, whereby, obtaining the derivative fuel of the solid-state with high heating value.
It may achieve following effect according to above-mentioned technical characteristic:
1. addition is recovered from the silicon reclaimed materials that Silicon Wafer cuts useless silicon mud, the calorific value about 6 of the derivative fuel of solid-state can be improved,
270 to 7,820kcal/kg, and all it is higher than the mean calorie 6,000kcal/kg of coal.
2. the silicon reclaimed materials that Silicon Wafer cuts different phase in useless silicon mud removal process can be added, calorific value can be promoted, and
The Silicon Wafer generated in solar battery manufacturing process such as is recycled to cut useless silicon mud.
3. the silicon reclaimed materials has been removed using the useless silicon mud without washing and containing polyethylene glycol and diethylene glycol, relatively addition
The silicon and silicon carbide of contained polyethylene glycol and diethylene glycol, calorific value are more higher by about 1,010 to 1,510kcal/kg, and can subtract
Gently because Silicon Wafer is cut in useless silicon mud removal process, the processing load for the waste water having by washing.
4. all raw materials are all from life, the waste that generates in industry, such as using organic sludge, useless natural food materials and
The silicon reclaimed materials that useless silicon mud is recycled is cut by Silicon Wafer, solves the problems, such as the processing of a variety of wastes, and recycling and reusing.
It is that can mitigate landfill site, incinerator and wastewater treatment to set 5. the processing of a variety of wastes can be solved the problems, such as simultaneously
The burden applied etc., and the green energy resource of high heating value, high value is created, the green energy resource simultaneously can be used for generating electricity.
6. borrowing microwave radiation except water process enables molding or puddle object to be down in moisture content in the short time by 75% or more
18% hereinafter, substantially shorten the processing time, and can save the cost of baking needed.
The derivative fuel energy long-term preservation of solid-state made of 7. and tool high burning efficiency, and it is total through general boiler or vapour electricity
It gives birth to the residual substance after burning (referred to as raw matter charcoal) and can be used as soil conditioner to neutralize the pH acid alkali value and its benefit of soil
It can be used as activated carbon adsorbent with the carbon residue (referred to as raw matter charcoal) after thermal cracking burning (anoxycausis) and be applied to a processing huge sum of money
Belong to waste water to be used with exhaust gas, reach the treatment of wastes with processes of wastes against one another, being can resource for a green.
Detailed description of the invention
Fig. 1 is the flow chart of the manufacturing method of the derivative fuel of high heating value solid-state of the embodiment of the present invention.
Specific embodiment
In summary technical characteristic, the main function of the manufacturing method of the derivative fuel of high heating value solid-state of the embodiment of the present invention
Effect can clearly appear from following embodiments.
Refering to shown in the first figure, the manufacturing method of the derivative fuel of high heating value solid-state of the present embodiment be include following step
It is rapid:
A. an organic sludge and a useless natural food materials are puddled into one and puddles object, the organic sludge and the natural food materials of giving up
Parts by weight are 98:2 to 80:20.The moisture content of the organic sludge may include processing TFT-LCD liquid crystal between 75% to 89%
Sludge caused by the waste sludge of panel, clean and reuse PET bottle, the paper pulp mud that handles paper-making process, domestic sewage factory
The waste sludge generated after wastewater treatment it is any or combinations thereof.The useless natural food materials are the useless food materials of a starch, and as one
Adhesive is puddled with the organic sludge, and it includes following any or combinations thereof: the sweet potato filtered out from the useless food materials after processing
Powder, Cornstarch, corn flour, or rice, congee, paste from useless prepared food material through preliminary screening.
B. this is puddled into object and mixes the silicon reclaimed materials that addition is recycled by the useless silicon mud of Silicon Wafer cutting, the silicon reclaimed materials
Adding proportion is to account for 3% to 10%.The silicon reclaimed materials, which can be, cuts useless silicon mud without washing and containing poly- comprising the Silicon Wafer
The useless silicon mud of ethylene glycol (PEG) and diethylene glycol (DEG).Also or, it includes by the Silicon Wafer chip which, which can be,
The useless silicon mud of the Silicon Wafer chip (is such as placed in a centrifuge using centrifugal action, isolates silicon using centrifugal action by useless silicon mud
With silicon carbide), flotation (such as by the Silicon Wafer chip give up silicon mud be placed in a wet type whirlpool cone sorting machine in, take out silicon from floating mine, from
Take out silicon carbide in heavy mine) or sour alkali impregnate it is separated go out silicon and silicon carbide, also, through centrifugal action, flotation or sour alkali leaching
Stain it is separated go out silicon and silicon carbide, and can be through washing and by 250 degree Celsius to 300 degree Celsius of drying temperature,
At least 4 hours drying time and the present embodiment are preferably 4~7 hours drying processes and remove contained polyethylene glycol
(PEG) and diethylene glycol (DEG).Also or, the silicon reclaimed materials can be by the Silicon Wafer chip give up silicon mud using centrifugal action,
Flotation or sour alkali impregnate and isolate silicon and silicon carbide, and it is 80% to 98% that purity is made again from silicon and silicon carbide again
Silicon is as the silicon reclaimed materials.
C. this is puddled into object and is shaped as a molding.Be available with an extrusion shaping machine, a pelletizer or one project at
This is puddled object and is shaped as bulk, strip, rodlike, hollow rod-shape, column, hollow columnar, sheet, spherical or graininess by type machine
The molding.
D. the molding is subjected to a microwave radiation with a microwave and removes water process, the moisture content of the molding is made to be down to 40%
Below.The microwave radiation is to be handled using an industrial micro-wave oven the molding except water process, the industrial micro-wave oven
Use consumption power for 2kW, operating current system is 2 to 6 amperes, and the microwave radiation water removal time is 4 to 10 minutes, makes its moisture content
It is rapidly decreased to 18% or less.
E. deoxidation treatment is carried out to the molding, so as to obtaining the derivative fuel of a solid-state.The molding is utilized discarded
A waste edible oil carry out fried, frying temperature is 130 DEG C to 220 DEG C, and deep-fat frying time is 5 minutes to 30 minutes, make this at
Type object is formed as the derivative fuel of the solid-state, and the moisture content of the derivative fuel of the solid-state is made to reach 7% hereinafter, whereby, can be improved
The calorific value of the derivative fuel of the solid-state, as explained below, the calorific value of the derivative fuel of the solid-state can improve again to 6,270 to
7820kcal/kg.The waste edible oil can be vegetalitas edible oil, animality edible oil or its group discarded comprising expired food
It closes, which includes an olive oil, a soybean oil, a salad oil or a sunflower oil, which includes
One lard, a butter or a sheep oil.
Refering to following table one, the combustion heat value for the derivative fuel of solid-state being made through abovementioned steps is analyzed, and not add
A control group of aforementioned silicon reclaimed materials is added to compare, in which:
The calorific value of the derivative fuel of the solid-state of the present embodiment can reach 6270kcal/kg or more.
Table one
It is it is found that the present embodiment adds aforementioned various forms of silicon reclaimed materials, it is derivative that solid-state can be improved through practical measurement
The calorific value of fuel is all higher than the calorific value 6,000kcal/kg of known coal about to 6,270 to 7,820kcal/kg, and compared to
The known calorific value for being not added with the derivative fuel of solid-state for reclaimed materials simultaneously can preferably improve about 2,560kcal/kg again.Its
In, in the present embodiment, add useless silicon mud without washing and containing polyethylene glycol and diethylene glycol, compare addition removed it is contained
Polyethylene glycol and diethylene glycol silicon and silicon carbide, calorific value preferably more can be more higher by there are about 1080kcal/kg, and be used
Without washing removal polyethylene glycol and the useless silicon mud of diethylene glycol, it more can reduce in solar battery processing procedure, have because of washing
The burden of wastewater treatment, and add recycling and the silicon powder that the purity obtained is 80~98% is made again, whole calorific value can then mention again
It is high by about 310 to 1550kcal/kg or more.
The microwave radiation of this creation removes water process and is not limited to carry out after being shaped as molding again, is also possible in moulding
Be before molding or addition be reclaimed materials before carry out, enable the molding or this puddle object in moisture content in the short time by
75% or more is down to 18% hereinafter, substantially shortening the processing time.
The present embodiment cuts the silicon recycling that useless silicon mud is recycled using organic sludge, useless natural food materials and by Silicon Wafer
Material not only solves the problems, such as the processing of a variety of wastes simultaneously, mitigates the negative of landfill site, incinerator and waste water disposal facility etc.
Load, and the green energy resource of high heating value, high value is created, the green energy resource simultaneously can be used for generating electricity.And manufactured solid-state is derivative
Fuel energy long-term preservation and tool high burning efficiency, and its residual substance after general boiler or steam-electric accreting burning is (referred to as raw
Matter charcoal) and can be used as soil conditioner with neutralize soil pH acid alkali value and its using thermal cracking burning (anoxycausis) after
Carbon residue (referred to as raw matter charcoal) can be used as activated carbon adsorbent and be applied to processing heavy metal wastewater thereby and be used with exhaust gas, reach to give up
Control useless, being can resource for a green.
Explanation based on the above embodiments, when can fully understand the present invention operation, use and the present invention generate the effect of, it is above
The embodiment is only for presently preferred embodiments of the present invention, when that cannot be limited the scope of implementation of the present invention with this, i.e., according to the present invention
Claim and invention description content make simple equivalent changes and modifications, all belong in the range that the present invention covers.
Claims (10)
1. a kind of manufacturing method of the derivative fuel of high heating value solid-state, it is characterised in that: include:
A. an organic sludge and a useless natural food materials are puddled into one and puddles object, the weight of the organic sludge and the useless natural food materials
Part is 98:2 to 80:20;
B. this is puddled into object and mixes the silicon reclaimed materials that addition is recycled by the useless silicon mud of Silicon Wafer cutting, the addition of the silicon reclaimed materials
Ratio system accounts for 3% to 10%;
C. this is puddled into object and is shaped as a molding;
D. by the molding with a microwave carry out a microwave radiation remove water process, make the moisture content of the molding be down to 18% with
Under;
E. deoxidation treatment is carried out to the molding, so as to obtaining the derivative fuel of a solid-state: the molding is utilized discarded one
Waste edible oil carries out frying, and frying temperature is 130 DEG C to 220 DEG C, and deep-fat frying time is 5 minutes to 30 minutes, makes the molding
Be formed as the derivative fuel of the solid-state, the moisture content of the derivative fuel of the solid-state is made to reach 7% hereinafter, whereby, obtaining has height
The derivative fuel of the solid-state of calorific value.
2. the manufacturing method of the derivative fuel of high heating value solid-state according to claim 1, it is characterised in that: the step B silicon
Reclaimed materials is that useless useless silicon mud of the silicon mud without washing and containing polyethylene glycol and diethylene glycol is cut comprising the Silicon Wafer.
3. the manufacturing method of the derivative fuel of high heating value solid-state according to claim 1, it is characterised in that: the step B silicon
Reclaimed materials is comprising the useless silicon mud of the Silicon Wafer chip is impregnated separated silicon and carbonization out using centrifugal action, flotation or sour alkali
Silicon.
4. the manufacturing method of the derivative fuel of high heating value solid-state according to claim 3, it is characterised in that: step B pass through from
Heart effect, flotation or sour alkali impregnate separated silicon and silicon carbide out, and are Celsius by washing, and by drying temperature
250 degree to 300 degree, drying time at least 4 hours drying processes and remove contained polyethylene glycol and diethylene glycol.
5. the manufacturing method of the derivative fuel of high heating value solid-state according to claim 3, it is characterised in that: step B simultaneously will
The Silicon Wafer chip is given up the silicon and silicon carbide that silicon mud is isolated using centrifugal action, flotation or sour alkali dipping, then from silicon and carbon
Purity is made in SiClx again and is 80% to 98% silicon, and obtains the silicon reclaimed materials.
6. the manufacturing method of the derivative fuel of high heating value solid-state according to claim 1, it is characterised in that: this is micro- by step D
Wave radiation water removal processing system is handled the molding using an industrial micro-wave oven, the consumption power of the industrial micro-wave oven
For 2kW, operating current system is 2 to 6 amperes, and the microwave water removal time is 4 to 10 minutes.
7. the manufacturing method of the derivative fuel of high heating value solid-state according to claim 1, it is characterised in that: step A should have
The moisture content of machine sludge is between 75% to 89%, and it includes the waste sludges of processing TFT-LCD liquid crystal display panel, processing paper-making process
Paper pulp mud, domestic sewage factory wastewater treatment after generate waste sludge it is any or combinations thereof;Step A should give up Natural Food
Material is that a starch is given up food materials, and is puddled as an adhesive and the organic sludge, and it includes following any or combinations thereof: from adding
Sweet potato flour, Cornstarch, the corn flour that useless food materials after work are filtered out, or rice, congee, slurry from useless prepared food material through preliminary screening
Paste;The step E waste edible oil includes the discarded vegetalitas edible oil of expired food, animality edible oil or combinations thereof, the plant
Property edible oil include an olive oil, a soybean oil, a salad oil or a sunflower oil, the animality edible oil include a lard, one
Butter or a sheep oil.
8. the manufacturing method of the derivative fuel of high heating value solid-state according to claim 1, it is characterised in that: step C is utilized
One extrusion shaping machine, a pelletizer or a Jet forming machine, by this puddle object be shaped as bulk, strip, rodlike, hollow rod-shape,
Column, hollow columnar, sheet, the spherical or granular molding.
9. a kind of manufacturing method of the derivative fuel of high heating value solid-state, comprising:
A. an organic sludge and a useless natural food materials are puddled into one and puddles object, the weight of the organic sludge and the useless natural food materials
Part is 98:2 to 80:20;
B. this is puddled into object and one microwave radiation is carried out except water process with a microwave, make this puddle the moisture content of object be down to 18% with
Under;
C. this is puddled into object and mixes the silicon reclaimed materials that addition is recycled by the useless silicon mud of Silicon Wafer cutting, the addition of the silicon reclaimed materials
Ratio is to account for 3% to 10%;
D. this is puddled into object and is shaped as a molding;
E. deoxidation treatment is carried out to the molding, so as to obtaining the derivative fuel of a solid-state: the molding is utilized discarded one
Waste edible oil carries out frying, and frying temperature is 130 DEG C to 220 DEG C, and deep-fat frying time is 5 minutes to 30 minutes, makes the molding
Be formed as the derivative fuel of the solid-state, the moisture content of the derivative fuel of the solid-state is made to reach 7% hereinafter, whereby, obtaining has height
The derivative fuel of the solid-state of calorific value.
10. a kind of manufacturing method of the derivative fuel of high heating value solid-state, comprising:
A. an organic sludge and a useless natural food materials are puddled into one and puddles object, the weight of the organic sludge and the useless natural food materials
Part is 98:2 to 80:20;
B. this is puddled into object and mixes the silicon reclaimed materials that addition is recycled by the useless silicon mud of Silicon Wafer cutting, the addition of the silicon reclaimed materials
Ratio is to account for 3% to 10%;
C. this is puddled into object and one microwave radiation is carried out except water process with a microwave, make this puddle the moisture content of object be down to 18% with
Under;
D. this is puddled into object and is shaped as a molding;
E. deoxidation treatment is carried out to the molding, so as to obtaining the derivative fuel of a solid-state: the molding is utilized discarded one
Waste edible oil carries out frying, and frying temperature is 130 DEG C to 220 DEG C, and deep-fat frying time is 5 minutes to 30 minutes, makes the molding
Be formed as the derivative fuel of the solid-state, the moisture content of the derivative fuel of the solid-state is made to reach 7% hereinafter, whereby, obtaining has height
The derivative fuel of the solid-state of calorific value.
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