CN108948876A - A kind of preparation method of multi-functional actual granite imitation coating - Google Patents

A kind of preparation method of multi-functional actual granite imitation coating Download PDF

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Publication number
CN108948876A
CN108948876A CN201810753598.XA CN201810753598A CN108948876A CN 108948876 A CN108948876 A CN 108948876A CN 201810753598 A CN201810753598 A CN 201810753598A CN 108948876 A CN108948876 A CN 108948876A
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China
Prior art keywords
preparation
parts
imitation coating
granite imitation
functional actual
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CN201810753598.XA
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Chinese (zh)
Inventor
李文彪
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Taicang Meihang Coatings Co Ltd
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Taicang Meihang Coatings Co Ltd
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Priority to CN201810753598.XA priority Critical patent/CN108948876A/en
Publication of CN108948876A publication Critical patent/CN108948876A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C09D101/08Cellulose derivatives
    • C09D101/26Cellulose ethers
    • C09D101/28Alkyl ethers
    • C09D101/284Alkyl ethers with hydroxylated hydrocarbon radicals
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of preparation method of multi-functional actual granite imitation coating, include the following steps: that (1) prepares colored gravel;(2) preparation bonding lotion;(3) raw material mixes;(4) stone paint is prepared.A kind of preparation method of multi-functional actual granite imitation coating of the present invention, on the basis of reasonable raw material selects and is formulated design, pass through the adjustment of preparation process, prepare shock resistance, stone paint not scaling-off, hydrophobicity is good, easy to clean, and cost of material is effectively reduced, there is the biggish market competitiveness.

Description

A kind of preparation method of multi-functional actual granite imitation coating
Technical field
The present invention relates to paint fields, more particularly to a kind of preparation method of multi-functional actual granite imitation coating.
Background technique
With the continuous improvement of living standards, people are also higher and higher to the finishing requirements of facade.Building at present In to achieve the effect that natural stone material, commonly use lithotome, but lithotome is limited by natural crystal, after decoration color and Figure line is inhomogenous, can not also renovate, tool exploitation processing difficulties, it is expensive the defects of, using being very restricted.
Stone paint is the coating for being currently used primarily in decorating outer wall of building, having containing two or more in ingredient Colored particle, colored particle are mainly suspended in coating system, generate the single group of multicolour on exterior walls of buildings by being sprayed on Part coating.Current stone paint exist in use not impact resistance, easily scaling-off, heat insulation is poor and not easy to clean etc. lacks It falls into.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of preparation method of multi-functional actual granite imitation coating, energy Enough solve existing stone paint above shortcomings place.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: a kind of multifunction imitated granite is provided The preparation method of stone paint, includes the following steps:
(1) it prepares colored gravel: the waste material of stone, discarded sand and quartz sand is sieved, after magnetic separation by formulation ratio, it is broken to grind It is milled to required partial size, it is dry after being then mixed with the mill base of particular color, obtain the colored gravel;
(2) preparation bonding lotion: a certain amount of distilled water being added into sodium carboxymethylcellulose and waterglass, after mixing evenly, It adds hydroxyethyl cellulose solution and is prepared into bonding lotion;
(3) raw material mix: by weight, weigh 2~4 parts of coalescing agents, 1~3 part of defoaming agent, 1~2 part of hydrophobing agent, 0.5~ 0.8 part of anticorrosion and bactericidal agent, 10~20 parts of fiberfill fibers and 50~60 parts of deionized water, after being thoroughly mixed, add 3~5 Part rubber powder and 3~5 parts of polyurethane particles material are sufficiently mixed uniformly, obtain mixed material;
(4) it prepares stone paint: the bonding lotion prepared in step (2) being added into mixed material obtained in step (3), stirs After mixing mixing, the colored gravel prepared in 3-8 parts of steps (1) is added, after agitated mixing, obtains the stone paint.
In a preferred embodiment of the present invention, the mass ratio of the waste material of stone, discarded sand and quartz sand is 2~3:1 ~2:3~5.
In a preferred embodiment of the present invention, the partial size is 60~80 mesh.
In a preferred embodiment of the present invention, in the step (2), it is described bonding lotion the preparation method comprises the following steps: to pressing Parts by weight meter weighs 3~5 parts of sodium carboxymethylcellulose and is put into 2L beaker, and the distilled water of 50~100 times of volumes is added inwards, It is placed on magnetic stirrer, after stirring 5~15min with the revolving speed of 200~300r/min, then 2~3 weight is added into beaker The waterglass of part improves revolving speed to 300~500r/min, continues 20~30min of stirring, be eventually adding the hydroxyl of 6~10 parts by weight Ethyl cellulose solution continues 20~30min of stirring under the revolving speed of 500~800 r/min, and bonding lotion is made.
In a preferred embodiment of the present invention, in the step (4), the condition being stirred are as follows: stirring rate 550 revs/min, 10~20min of time.
In a preferred embodiment of the present invention, the fiberfill fibers include glass fibre, rock wool fibers and nylon fiber.
In a preferred embodiment of the present invention, the mass ratio of the glass fibre, rock wool fibers and nylon fiber be 1~ 2:2~3:3~5.
In a preferred embodiment of the present invention, the length of the glass fibre is greater than the length of the rock wool fibers, institute The length for stating rock wool fibers is greater than the length of the nylon fiber.
The beneficial effects of the present invention are: a kind of preparation method of multi-functional actual granite imitation coating of the present invention, reasonable Raw material selection and formula design on the basis of, by the adjustment of preparation process, prepare shock resistance, not scaling-off, hydrophobicity is good, Stone paint easy to clean, and cost of material is effectively reduced, there is the biggish market competitiveness.
Specific embodiment
The preferred embodiments of the present invention will be described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that so as to make a clearer definition of the protection scope of the present invention.
The embodiment of the present invention includes:
Embodiment 1
Present invention discloses a kind of multi-functional actual granite imitation coatings, including following parts by weight of component: 3 parts of colored gravel is filled out It is molten to fill 10 parts of fiber, 3 parts of rubber powder, 3 parts of polyurethane particles material, 2 parts of waterglass, 3 parts of hydroxyl potassium base sodium cellulosate, hydroxyethyl cellulose 6 parts of liquid, 2 parts of coalescing agent, 1 part of defoaming agent, 1 part of hydrophobing agent, 0.5 part of crosslinking agent, 0.5 part of anticorrosion and bactericidal agent, deionized water 50 Part.
Wherein, it includes waste material of stone, discarded sand and quartz sand that the partial size of the colored gravel, which is 60~80 mesh, and stone material is useless The mass ratio of material, discarded sand and quartz sand is 2:1:3.By the way that waste material of stone, such as granite, basalt rock were being exploited The discarded sand material generated in the discarded powder that generates in journey, casting process mixes together with quartz sand with pigment, is prepared into colour On the one hand gravel can turn waste into wealth, solve the problems, such as that waste material post-processes, on the other hand can reduce the dosage of quartz sand, have Imitate save the cost.
The fiberfill fibers include glass fibre, rock wool fibers and nylon fiber, and glass fibre, rock wool fibers and nylon The mass ratio of fiber is 1:2:3, wherein the length of the glass fibre is greater than the length of the rock wool fibers, and the rock wool is fine The length of dimension is greater than the length of the nylon fiber.It, can be effective by the use of glass fibre, rock wool fibers and nylon fiber The overall performance for improving stone paint prevents stone paint from occurring hitting situations such as scaling-off or vibration is scaling-off.Wherein, pass through glass The Design of length of fiber, rock wool fibers and nylon fiber, realization are sequentially connected fixed whole similar to trunk, long branch, short branch The effect of a stone paint.
The crosslinking agent includes the iron chloride and magnesium chloride that mass ratio is 1:2.
The rubber powder refers to powdered rubber material obtained from waste rubber goods are handled through crushing and processing.Pass through rubber powder With the addition of polyurethane particles, waste utilization on the one hand may be implemented, reduce cost of material, another aspect rubber powder and polyurethane Grain exists in the form of elastic granule in stone paint, impact energy can be absorbed to a certain extent, thus after assigning molding The certain shock resistance of stone paint.
The preparation method of above-mentioned multi-functional actual granite imitation coating, includes the following steps:
(1) it prepares colored gravel: the waste material of stone, discarded sand and quartz sand is sieved, after magnetic separation by formulation ratio, it is broken to grind Being milled to partial size is 60~80 mesh, dry after being then mixed with the mill base of particular color, obtains the colored gravel;Pigment Color be 2 in more than;
(2) preparation bonding lotion: be put into 2L beaker to by weight, weighing 3~5 parts of sodium carboxymethylcellulose, inwards plus The distilled water for entering 50~100 times of volumes, is placed on magnetic stirrer, stirs 5~15min with the revolving speed of 200~300r/min Afterwards, the waterglass of 2~3 parts by weight is added then into beaker, improves revolving speed to 300~500r/min, continue stirring 20~ 30min is eventually adding the hydroxyethyl cellulose solution of 6~10 parts by weight, under the revolving speed of 500~800 r/min, continues to stir Bonding lotion is made in 20~30min;
(3) raw material mixes: by weight, weighing 2 parts of coalescing agents, 1 part of defoaming agent, 1 part of hydrophobing agent, 0.5 part of antisepsis and sterilization Agent, 10 parts of fiberfill fibers and 60 parts of deionized water after being thoroughly mixed, add 5 parts of rubber powders and 5 parts of polyurethane particles material, 30min is sufficiently mixed with the rate of 200~300r/min to obtain mixed material up to uniform;
(4) it prepares stone paint: the bonding lotion prepared in step (2) being added into mixed material obtained in step (3), with After 550 revs/min of rate is stirred 10min, the colored gravel prepared in 3-8 parts of steps (1) is added, through 550 revs/min After rate is stirred 20min, the stone paint is obtained.
Embodiment 2
The difference from embodiment 1 is that the multi-functional actual granite imitation coating, including following parts by weight of component: colored sand 8 parts of gravel, 20 parts of fiberfill fibers, 5 parts of rubber powder, 5 parts of polyurethane particles material, 3 parts of waterglass, 5 parts of hydroxyl potassium base sodium cellulosate, ethoxy 10 parts of cellulose solution, 4 parts of coalescing agent, 3 parts of defoaming agent, 2 parts of hydrophobing agent, 1 part of crosslinking agent, 0.8 part of anticorrosion and bactericidal agent, go from 60 parts of sub- water.
Wherein, it includes waste material of stone, discarded sand and quartz sand that the partial size of the colored gravel, which is 60~80 mesh, and stone material is useless The mass ratio of material, discarded sand and quartz sand is 3:2:5.
The fiberfill fibers include glass fibre, rock wool fibers and nylon fiber, and glass fibre, rock wool fibers and nylon The mass ratio of fiber is 2:3:5, wherein the length of the glass fibre is greater than the length of the rock wool fibers, and the rock wool is fine The length of dimension is greater than the length of the nylon fiber.
The crosslinking agent includes the iron chloride and magnesium chloride that mass ratio is 1:3.
A kind of preparation method of multi-functional actual granite imitation coating of the present invention selects and is formulated design in reasonable raw material On the basis of, by the adjustment of preparation process, shock resistance, stone paint not scaling-off, hydrophobicity is good, easy to clean are prepared, and Cost of material is effectively reduced, there is the biggish market competitiveness.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (8)

1. a kind of preparation method of multi-functional actual granite imitation coating, which comprises the steps of:
(1) it prepares colored gravel: the waste material of stone, discarded sand and quartz sand is sieved, after magnetic separation by formulation ratio, it is broken to grind It is milled to required partial size, it is dry after being then mixed with the mill base of particular color, obtain the colored gravel;
(2) preparation bonding lotion: a certain amount of distilled water being added into sodium carboxymethylcellulose and waterglass, after mixing evenly, It adds hydroxyethyl cellulose solution and is prepared into bonding lotion;
(3) raw material mix: by weight, weigh 2~4 parts of coalescing agents, 1~3 part of defoaming agent, 1~2 part of hydrophobing agent, 0.5~ 0.8 part of anticorrosion and bactericidal agent, 10~20 parts of fiberfill fibers and 50~60 parts of deionized water, after being thoroughly mixed, add 3~5 Part rubber powder and 3~5 parts of polyurethane particles material are sufficiently mixed uniformly, obtain mixed material;
(4) it prepares stone paint: the bonding lotion prepared in step (2) being added into mixed material obtained in step (3), stirs After mixing mixing, the colored gravel prepared in 3-8 parts of steps (1) is added, after agitated mixing, obtains the stone paint.
2. the preparation method of multi-functional actual granite imitation coating according to claim 1, which is characterized in that the stone material The mass ratio of waste material, discarded sand and quartz sand is 2~3:1~2:3~5.
3. the preparation method of multi-functional actual granite imitation coating according to claim 1, which is characterized in that the partial size For 60~80 mesh.
4. the preparation method of multi-functional actual granite imitation coating according to claim 1, which is characterized in that the step (2) in, the bonding lotion the preparation method comprises the following steps: to by weight, weigh 3~5 parts of sodium carboxymethylcellulose and be put into 2L burning In cup, the distilled water of 50~100 times of volumes is added inwards, is placed on magnetic stirrer, is stirred with the revolving speed of 200~300r/min After mixing 5~15min, then into beaker be added 2~3 parts by weight waterglass, improve revolving speed to 300~500r/min, continue to stir 20~30min is mixed, the hydroxyethyl cellulose solution of 6~10 parts by weight is eventually adding, under the revolving speed of 500~800 r/min, after Bonding lotion is made in 20~30min of continuous stirring.
5. the preparation method of multi-functional actual granite imitation coating according to claim 1, which is characterized in that the step (4) in, the condition being stirred are as follows: 550 revs/min of stirring rate, 10~20min of time.
6. the preparation method of multi-functional actual granite imitation coating according to claim 1, which is characterized in that the filling Fiber includes glass fibre, rock wool fibers and nylon fiber.
7. the preparation method of multi-functional actual granite imitation coating according to claim 6, which is characterized in that the glass The mass ratio of fiber, rock wool fibers and nylon fiber is 1~2:2~3:3~5.
8. the preparation method of multi-functional actual granite imitation coating according to claim 7, which is characterized in that the glass The length of fiber is greater than the length of the rock wool fibers, and the length of the rock wool fibers is greater than the length of the nylon fiber.
CN201810753598.XA 2018-07-10 2018-07-10 A kind of preparation method of multi-functional actual granite imitation coating Pending CN108948876A (en)

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CN108948876A true CN108948876A (en) 2018-12-07

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106366928A (en) * 2016-08-29 2017-02-01 成都龙之泉科技股份有限公司 Graphene coating for corrosion prevention of thermal power plant desulfurization chimney, and preparation method of graphene coating
CN107162484A (en) * 2017-04-01 2017-09-15 三明学院 The discarded sand regeneration stone paint of one kind casting and its manufacture method
CN107879677A (en) * 2017-11-16 2018-04-06 山西亮龙涂料有限公司 A kind of true mineral varnish of self demixing anti-soil and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106366928A (en) * 2016-08-29 2017-02-01 成都龙之泉科技股份有限公司 Graphene coating for corrosion prevention of thermal power plant desulfurization chimney, and preparation method of graphene coating
CN107162484A (en) * 2017-04-01 2017-09-15 三明学院 The discarded sand regeneration stone paint of one kind casting and its manufacture method
CN107879677A (en) * 2017-11-16 2018-04-06 山西亮龙涂料有限公司 A kind of true mineral varnish of self demixing anti-soil and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
彭亮: "大悟县地区花岗岩加工废料生产仿石涂料", 《中国优秀硕士学位论文全文数据库(工程科技Ⅰ辑)》 *

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Application publication date: 20181207