CN108948656A - 一种空调继电器的环保型环氧密封组合物 - Google Patents

一种空调继电器的环保型环氧密封组合物 Download PDF

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CN108948656A
CN108948656A CN201710368036.9A CN201710368036A CN108948656A CN 108948656 A CN108948656 A CN 108948656A CN 201710368036 A CN201710368036 A CN 201710368036A CN 108948656 A CN108948656 A CN 108948656A
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curing agent
air conditioner
environment
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sealing compositions
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徐月香
李孝伟
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Hui Yue Electronic Materials (shanghai) Co Ltd
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Hui Yue Electronic Materials (shanghai) Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/504Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5046Amines heterocyclic
    • C08G59/5053Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/5073Amines heterocyclic containing only nitrogen as a heteroatom having two nitrogen atoms in the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
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Abstract

本发明涉及环氧树脂,尤其涉及一种采用粉末固化剂的空调继电器的环氧密封组合物。一种空调继电器的环保型环氧密封组合物,该组合物包括:环氧树脂EL‑128E 54‑60%、双氰胺固化剂4‑5%、填料氧化铝AM210 25‑30%、咪唑固化剂5‑6%、陶氏732 2‑3%、有机脲促进剂UR‑300 1‑2%、色膏2‑3%、气相硅TS‑720 0.4‑0.5%;有机硅消泡剂0.03‑0.04%、所述百分比为重量百分比;将环氧树脂和双氰胺固化剂及咪唑固化剂混合后,加入填料氧化铝AM210,陶氏732和剩余组分,混合均匀,真空脱泡即成所述组合物。本发明的组合物固化温度低,使用方便,成本低。

Description

一种空调继电器的环保型环氧密封组合物
技术领域
本发明涉及环氧树脂,尤其涉及一种采用粉末固化剂的空调继电器的环氧密封组合物。
背景技术
作为空调继电器的密封组合物,环氧树脂以其良好的电气性能和机械性能得到了广泛的运用。当前,所有的环氧都是采用树脂组分和固化剂组分的形式。作为固化剂组分,有液态固化剂,也有粉末固化剂。
液态固化剂对存储要求很高,需要冷藏,而使用时候需要回温到环境温度,十分麻烦。
粉末固化剂能解决液态固化剂的上述问题,可直接使用,但是现有的固化剂要求近200℃的温度,加工成本高。
发明内容
本发明旨在克服现有技术的上述缺陷,提供一种空调继电器的环保型环氧密封组合物。本发明的組合物固化溫度低,使用方便,成本低。
本发明一种空调继电器的环保型环氧密封组合物,该组合物包括:
环氧树脂EL-128E 54-60%、
双氰胺 4-5%、
填料氧化铝AM210 25-30%、
咪唑固化剂 5-6%、
陶氏732 2-3%、
有机脲促进剂 UR-300 1-2%、
色膏 2-3%、
气相硅TS-720 0.4-0.5%;
有机硅消泡剂 0.03-0.04%、
所述百分比为重量百分比;
将环氧树脂和双氰胺固化剂及咪唑固化剂混合后,加入填料氧化铝AM210,陶氏732和剩余组分,混合均匀,真空脱泡即成所述组合物。。
所述的一种空调继电器的环保型环氧密封组合物,所述组合物的粘度40℃35000--40000cps。
所述的一种空调继电器的环保型环氧密封组合物,所述的组合物的固化温度是100℃-105℃。
本发明的組合物中,粉末状固化剂双氰胺的引入能让咪唑固化剂的固化温度降低到100℃左右,较业内的的170℃-180℃降低许多,同时反应中不会产生需要分离的胶油,更容易达到,降低了成本。本发明的组合物具有粉末类固化剂本身所具有的易于运输、操作方便的特性。
具体实施方式:
本发明本发明一种空调继电器的环保型环氧密封组合物,该组合物包括:
环氧树脂EL-128E 54-60%、
双氰胺 4-5%、
填料氧化铝AM210 25-30%、
咪唑固化剂 5-6%、
陶氏732 2-3%、
有机脲促进剂 UR-300 1-2%、
色膏 2-3%、
气相硅TS-720 0.4-0.5%;
有机硅消泡剂 0.03-0.04%、
所述百分比为重量百分比;
将环氧树脂和双氰胺固化剂及咪唑固化剂混合后,加入填料氧化铝AM210,陶氏732和剩余组分,混合均匀,真空脱泡即成所述组合物。
所述的一种空调继电器的环保型环氧密封组合物,所述组合物的粘度40℃35000--40000cps。
所述的一种空调继电器的环保型环氧密封组合物,所述的组合物的固化温度是100℃-105℃。
本发明的实施例见下表
实施例1 实施例2 实施例3
环氧树脂EL-128E ,% 54 60 54
双氰胺,% 5 4 4
填料氧化铝AM210,% 28 25 30
咪唑固化剂,% 5 6 5
陶氏732,% 2.5 2.48 3
有机脲促进剂 UR-300,% 2 1 1
色膏,% 3 1 2.57
气相硅TS-720,%,% 0.5 0.5 0.4
有机硅消泡剂 0.03 0.02 0.03
粘度40℃,cps 35000 40000 32500
固化温度℃ 100-102 102-105 101-104
本领域的技术人员应当清楚,本实施方式描述的技术方案仅供理解本发明,而不应认为是对保护范围的限定。本发明的保护范围应当以权利要求书限定的范围为准,任何在权利要求书提供的技术方案的基础上做的变形替换都将落入本发明权利要求所保护的范围。

Claims (3)

1.一种空调继电器的环保型环氧密封组合物,其特征在于,该组合物包括:
环氧树脂EL-128E 54-60%、
双氰胺固化剂 4-5%、
填料氧化铝AM210 25-30%、
咪唑固化剂 5-6%、
陶氏732 2-3%、
有机脲促进剂 UR-300 1-2%、
色膏 2-3%、
气相硅TS-720 0.4-0.5%;
有机硅消泡剂 0.03-0.04%、
所述百分比为重量百分比;
将环氧树脂和双氰胺固化剂及咪唑固化剂混合后,加入填料氧化铝AM210,陶氏732和剩余组分,混合均匀,真空脱泡即成所述组合物。
2.根据权利要求1所述的一种空调继电器的环保型环氧密封组合物,其特征在于,所述组合物的粘度40℃ 35000--40000cps。
3.根据权利要求1所述的一种空调继电器的环保型环氧密封组合物,其特征在于,所述的组合物的固化温度是100℃-105℃。
CN201710368036.9A 2017-05-23 2017-05-23 一种空调继电器的环保型环氧密封组合物 Pending CN108948656A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5390344A (en) * 1977-01-21 1978-08-09 Hitachi Ltd Adhesive composition
JPH02145676A (ja) * 1988-11-28 1990-06-05 Hitachi Chem Co Ltd 銅張積層板用銅箔接着剤
CN103087664A (zh) * 2013-01-29 2013-05-08 深圳市宝力科技有限公司 继电器液态环氧树脂灌封胶及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5390344A (en) * 1977-01-21 1978-08-09 Hitachi Ltd Adhesive composition
JPH02145676A (ja) * 1988-11-28 1990-06-05 Hitachi Chem Co Ltd 銅張積層板用銅箔接着剤
CN103087664A (zh) * 2013-01-29 2013-05-08 深圳市宝力科技有限公司 继电器液态环氧树脂灌封胶及其制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张志冬 等: "《胶接原理与实用胶接配方600种 上册》", 31 October 1985 *
王德中: "《环氧树脂生产与应用》", 30 June 2001, 化学工业出版社 *

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Application publication date: 20181207