CN108948518A - A kind of multifunction negative ion polypropylene agglomerate and preparation method - Google Patents

A kind of multifunction negative ion polypropylene agglomerate and preparation method Download PDF

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Publication number
CN108948518A
CN108948518A CN201810569787.1A CN201810569787A CN108948518A CN 108948518 A CN108948518 A CN 108948518A CN 201810569787 A CN201810569787 A CN 201810569787A CN 108948518 A CN108948518 A CN 108948518A
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parts
negative ion
weight percent
corresponding components
polypropylene agglomerate
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CN201810569787.1A
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Inventor
吴瑛
吴春金
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Taizhou Tengzhi Home Appliances Co Ltd
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Taizhou Tengzhi Home Appliances Co Ltd
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Priority to CN201810569787.1A priority Critical patent/CN108948518A/en
Publication of CN108948518A publication Critical patent/CN108948518A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10—Homopolymers or copolymers of propene
    • C08J2423/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/222—Magnesia, i.e. magnesium oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/045—Fullerenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of multifunction negative ion polypropylene agglomerate, the component including following weight ratio: any one 5-10 parts of 30-50 parts of igneous rock, 50-70 parts of six ring stone, 0.01-0.1 parts of football alkene, 0.001-0.01 parts of graphene, 20-30 parts of vector resin, 0.1-0.3 parts of functional aid, titanate esters and Aluminate, 5-15 parts of dispersing agent.Selected in functional material have spontaneous polarization can under natural conditions can releasing negative oxygen ion and far infrared igneous rock and ore and six ring stone ore stones and by crushing/wet grinding at nano-powder, can produce macro quanta tunnel effect, small-size effect, skin effect etc.；And by the hydrophobicity for improving its surface after titanate esters and igneous rock powder, six ring mountain flour body hybrid reactions, its dispersion stabilization and release anion and far infrared function in vector resin is improved.

Description

A kind of multifunction negative ion polypropylene agglomerate and preparation method
Technical field
The present invention relates to quantum field of material technology, a kind of multifunction negative ion polypropylene agglomerate and preparation side are referred specifically to Method.
Background technique
Polypropylene is an important species in five big general synthetic resins, and whole world polyethylene in 2014, gathers polyamide The big synthetic resin total yield of propylene, polyester, polyvinyl chloride etc. five reaches 100,000,000 9 thousand ten thousand tons.Wherein 48,780,000 tons of polypropylene product, account for The a quarter of five big synthetic resin aggregated capacities.
But there is tertiary carbon atom on polypropylene chemical structural formula main chain, its pole under the external cause actions such as hot Dian oxygen, ultraviolet light Chemical change easily occurs.And causing its product there are major defect, folding such as easy to aging, easy to crack, not weather-proof, electrostatic degree is high asks Topic.
And it proposes to solve technical solution, then rare report using multinomial integration technology level in quantum Material Field.Especially It is merged using inorganic mineral nano material with acrylic resin and a variety of auxiliary agents with quantum-mechanical theory and reaches reinforcing release height Concentration anion and transmitting infrared function, create quantum state anion multifunctional polypropylene (monofilament) new material, at home Still in space state in outer industry.
Summary of the invention
The present invention is insufficient according to prior art, proposes a kind of multifunction negative ion polypropylene agglomerate and preparation method, choosing Select titanic oxide material as uvioresistant, prevent acrylic resin aging and antibacterial agent；Selective oxidation zinc and oxidation again simultaneously Magnesium material makes polypropylene monofilament preferably play more function as weather resisting agent, fire retardant, anti-cracking agent and antibacterial electromagnetic radiation resistant agent Effect and it can prolong the service life.
In order to solve the above-mentioned technical problem, the technical solution of the present invention is as follows:
A kind of multifunction negative ion polypropylene agglomerate, the component including following weight ratio: 30-50 parts of igneous rock, six ring stones 50-70 parts, 0.01-0.1 parts of football alkene, 0.001-0.01 parts of graphene, 20-30 parts of vector resin, functional aid 0.1-0.3 Part, titanate esters and any one 5-10 parts of Aluminate, 5-15 parts of dispersing agent.
Preferably, including 2 parts of nuisanceless toner.
Preferably, the functional aid include the identical titanium dioxide of weight ratio, zinc oxide, it is any one in magnesia Kind is a variety of.
Preferably, the dispersing agent is poly amic acid.
Preferably, the vector resin is the powder acrylic resin and random polypropylene resin of liquid phase noumenal method synthesis In any one.
Preferably, the igneous rock and six ring stones are micro-, nano-powder.
The invention also discloses a kind of preparation method of multifunction negative ion polypropylene agglomerate, step includes:
Step S1, the preparation of natural and multi-functional anion compound additive,
It takes the micro-nano seperated and six ring stone micro-nano powders of the igneous rock of corresponding components by weight percent to carry out mixing to stir
Mix, be then added corresponding components by weight percent titanate esters and Aluminate any one, corresponding weight group is added
The football alkene divided；
Step S2, it takes the vector resin of corresponding components by weight percent to put into professional equipment and reaches molten condition；
Step S3, natural and multi-functional anion compound additive obtained in step S1 is put under molten condition
Vector resin in；
Step S4, it takes the dispersing agent of corresponding components by weight percent to put into step S3 in mixture obtained and stirs
It mixes uniformly；
Step S5, the functional aid of corresponding components by weight percent is put into；
Step S6, it puts into the nuisanceless toner of corresponding components by weight percent and disperses homogeneous；
Step S7, product made from step S6 is pelletized.
The present invention have the characteristics that it is following and the utility model has the advantages that
By adopting the above technical scheme, select that there is spontaneous polarization can discharge under natural conditions is negative in functional material The igneous rock and ore and six ring stone ore stones of oxonium ion and far infrared simultaneously pass through crushing/wet grinding into nano-powder, can produce Macro quanta tunnel effect, small-size effect, skin effect etc.；And pass through titanate esters and igneous rock powder, six ring mountain flour bodies The hydrophobicity that its surface is improved after hybrid reaction improves its dispersion stabilization in vector resin and release anion and remote Infrared function；It selects titanic oxide material as uvioresistant, prevent acrylic resin aging and antibacterial agent；It selects again simultaneously Zinc oxide and magnesium oxide material make polypropylene monofilament more as weather resisting agent, fire retardant, anti-cracking agent and antibacterial electromagnetic radiation resistant agent Play multifunctional effect and expanded service life well；Select football alkene C60 as igneous rock, six ring stone quantum activator, this A component can reach again promotion functions material release anion efficiency with save the cost.
Specific embodiment
Specific embodiments of the present invention will be further explained below.It should be noted that for these implementations The explanation of mode is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, invention described below Technical characteristic involved in each embodiment can be combined with each other as long as they do not conflict with each other.
Embodiment 1
The present invention provides a kind of multifunction negative ion polypropylene agglomerate, the component including following weight ratio: igneous rock 30 Part, 50 parts of six ring stone, 0.01 part of football alkene, 0.001 part of graphene, 20 parts of vector resin, 0.1 part of functional aid, titanate esters With 5 parts of any one 5, dispersing agent of Aluminate.
In above-mentioned technical proposal, selecting in functional material, there is spontaneous polarization can discharge negative oxygen under natural conditions The igneous rock and ore and six ring stone ore stones of ion and far infrared simultaneously pass through crushing/wet grinding into nano-powder, can produce macro See quantum tunneling effect, small-size effect, skin effect etc.；And it is mixed by titanate esters and igneous rock powder, six ring mountain flour bodies The hydrophobicity on its surface is improved after closing reaction, improves its dispersion stabilization and release anion in vector resin and remote red Outside line function；
It should be understood that selecting football alkene C60 as igneous rock, six ring stone quantum activator, this component can be saved Cost reaches promotion functions material release anion efficiency again.
It should be understood that titanate esters and Aluminate are as coupling agent.
Further, including 2 parts of nuisanceless toner.
Further, functional aid include the identical titanium dioxide of weight ratio, zinc oxide, any one in magnesia or It is a variety of.It selects titanic oxide material as uvioresistant, prevent acrylic resin aging and antibacterial agent；While and selective oxidation zinc And magnesium oxide material sends out polypropylene monofilament preferably as weather resisting agent, fire retardant, anti-cracking agent and antibacterial electromagnetic radiation resistant agent Wave multifunctional effect and expanded service life.
Further, dispersing agent is poly amic acid.
Further, vector resin is to appoint in the powder acrylic resin and random polypropylene resin of liquid phase noumenal method synthesis It anticipates one kind.
Wherein, vector resin selection fusing point low (be no more than 100 degrees Celsius), price are honest and clean and to be extremely easy to inorganic filler mixing equal Even, itself is again powder, and the powdered polypropylene resin for the liquid phase noumenal method synthesis that will not be layered in loading hopper is as this hair The vector resin of the filler of bright multifunction negative ion polypropylene monofilament master batch.
Further, igneous rock and six ring stones are micro-, nano-powder.
The invention also discloses a kind of preparation method of multifunction negative ion polypropylene agglomerate, step includes:
Step S1, the preparation of natural and multi-functional anion compound additive,
It takes the micro-nano seperated and six ring stone micro-nano powders of the igneous rock of corresponding components by weight percent to carry out mixing to stir
It mixes, any one progress surface modification treatment of the titanate esters and Aluminate of corresponding components by weight percent is then added,
The football alkene of corresponding components by weight percent is added；
Step S2, it takes the vector resin of corresponding components by weight percent to put into professional equipment and reaches molten condition；
Step S3, natural and multi-functional anion compound additive obtained in step S1 is put under molten condition
Vector resin in；
Step S4, it takes the dispersing agent of corresponding components by weight percent to put into step S3 in mixture obtained and stirs
It mixes uniformly；
Step S5, the functional aid for putting into corresponding components by weight percent, the first high speed 1000 in high speed mixing smelting machine equipment
Rpm revolving speed after be stirred until homogeneous that (incorporation time 20 is divided to 30 after 800 rpms of revolving speeds
Point)；
Step S6, it puts into the nuisanceless toner of corresponding components by weight percent and disperses homogeneous；
Step S7, product made from step S6 is pelletized.
Embodiment 2
The present embodiment the difference from embodiment 1 is that, the component including following weight ratio: 40 parts of igneous rock, six ring stones 60 Part, 0.05 part of football alkene, 0.005 part of graphene, 25 parts of vector resin, 0.2 part of functional aid, titanate esters and Aluminate are any It is 7 parts, 10 parts of dispersing agent a kind of.
Embodiment 3
The present embodiment the difference from embodiment 1 is that, the component including following weight ratio: 50 parts of igneous rock, six ring stones 70 Part, 0.1 part of football alkene, 0.01 part of graphene, 30 parts of vector resin, 0.3 part of functional aid, titanate esters and Aluminate are any one 10 parts, 15 parts of dispersing agent of kind.
Embodiment 4
The present embodiment the difference from embodiment 1 is that, including following weight ratio ingredient: natural and multi-functional anion is compound to be added Add 80 parts of agent, 20 parts of vector resin, 5 parts of coupling agent, 0.001 part of football alkene C60 powder, 3.5 parts of ethoxylated alkylamine (or 5 parts of calcium stearate)；
Wherein coupling agent is metatitanic acid rouge or calcium stearate, and football alkene C60 powder is as quantum activator, ethoxylated alkyl Amine is as dispersing agent；
Further, further include Tan ?2 parts, with football alkene mixing material.
The anion multifunctional polypropylene agglomerate that above-mentioned technical proposal is prepared, predominantly using polypropylene material as raw material Plastic product manufacturing industry releasable high-concentration anion polypropylene agglomerate is provided.
Embodiment 5
The present embodiment the difference from embodiment 1 is that, including following weight ratio ingredient: natural negative ion compound additive 75 Part, 25 parts of vector resin, 5 parts of the calcium stearate as coupling agent, the football alkene C60 powder as quantum activator O.01 part, 3.5 parts of ethoxylated alkylamine as dispersing agent.
The quantum state anion multifunctional polypropylene agglomerate that above-mentioned technical proposal is prepared, predominantly polypropylene brush class Corresponding master batch is provided with Tong Lei producer, and then produces anion brush class product and cylinder class product.
Embodiment 6
The present embodiment the difference from embodiment 1 is that, including following weight ratio ingredient: natural negative ion compound additive 70 Part, 25 parts of vector resin, 5 parts of the Aluminate as coupling agent, 0.001 part of football alkene C60 powder, carbon as quantum activator 0.001 part of nanotube powder, 3.5 parts of the ethoxylated alkylamine as dispersing agent, the heteropolymerization object as colouring aid are (poly- Rouge) 5 parts；
It further, further include 2 parts of nuisanceless toner, nuisanceless toner includes: the nothing for meeting national safety standard range Machine toner and organic toner powder；It also include plant-derived toner.
Above the embodiments of the present invention are described in detail, but the present invention is not limited to described embodiments.It is right It include portion to these embodiments in the case where not departing from the principle of the invention and spirit for those skilled in the art Part carries out a variety of change, modification, replacement and modification, still falls in protection scope of the present invention.

Claims (7)

1. a kind of multifunction negative ion polypropylene agglomerate, which is characterized in that the component including following weight ratio: igneous rock 30-50 Part, 50-70 parts of six ring stone, 0.01-0.1 parts of football alkene, 0.001-0.01 parts of graphene, 20-30 parts of vector resin, functionality help Any one 5-10 parts of 0.1-0.3 parts of agent, titanate esters and Aluminate, 5-15 parts of dispersing agent.
2. multifunction negative ion polypropylene agglomerate according to claim 1, which is characterized in that including 2 parts of nuisanceless toner.
3. multifunction negative ion polypropylene agglomerate according to claim 1, which is characterized in that the functional aid includes The identical titanium dioxide of weight ratio, zinc oxide, any one or more in magnesia.
4. multifunction negative ion polypropylene agglomerate according to claim 1, which is characterized in that the dispersing agent is polypropylene Acid amide.
5. multifunction negative ion polypropylene agglomerate according to claim 1, which is characterized in that the vector resin is liquid phase Any one in the powder acrylic resin and random polypropylene resin of substance law synthesis.
6. multifunction negative ion polypropylene agglomerate according to claim 1, which is characterized in that the igneous rock and six ring stones It is micro-, nano-powder.
7. it is a kind of according to claim 1 to the preparation method of multifunction negative ion polypropylene agglomerate described in 6 any one, it is special Sign is that step includes:
Step S1, the preparation of natural and multi-functional anion compound additive,
It takes the micro-nano seperated and six ring stone micro-nano powders of the igneous rock of corresponding components by weight percent to be mixed, is then added The coupling titanate esters and Aluminate of corresponding components by weight percent any one, the football alkene of corresponding components by weight percent is added；
Step S2, it takes the vector resin of corresponding components by weight percent to put into professional equipment and reaches molten condition；
Step S3, natural and multi-functional anion compound additive obtained in step S1 is put into the vector resin under molten condition In；
Step S4, it takes the dispersing agent of corresponding components by weight percent to put into step S3 in mixture obtained and stirs evenly；
Step S5, the functional aid of corresponding components by weight percent is put into；
Step S6, it puts into the nuisanceless toner of corresponding components by weight percent and disperses homogeneous；
Step S7, product made from step S6 is pelletized.
CN201810569787.1A 2018-06-05 2018-06-05 A kind of multifunction negative ion polypropylene agglomerate and preparation method Pending CN108948518A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109627711A (en) * 2018-12-28 2019-04-16 合复新材料科技(无锡)有限公司 A kind of preparation method and negative ion generating function high molecular material of negative ion generating function high molecular material
CN113737394A (en) * 2021-09-11 2021-12-03 东营俊富净化科技有限公司 Superfine high-efficiency negative ion non-woven fabric for mask and preparation method thereof
CN116462913A (en) * 2023-05-22 2023-07-21 广州海天塑胶有限公司 PP composite material with microcosmic pore canal and capable of releasing negative oxygen ions and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109627711A (en) * 2018-12-28 2019-04-16 合复新材料科技(无锡)有限公司 A kind of preparation method and negative ion generating function high molecular material of negative ion generating function high molecular material
CN113737394A (en) * 2021-09-11 2021-12-03 东营俊富净化科技有限公司 Superfine high-efficiency negative ion non-woven fabric for mask and preparation method thereof
CN113737394B (en) * 2021-09-11 2022-09-30 东营俊富净化科技有限公司 Superfine high-efficiency negative ion non-woven fabric for mask and preparation method thereof
CN116462913A (en) * 2023-05-22 2023-07-21 广州海天塑胶有限公司 PP composite material with microcosmic pore canal and capable of releasing negative oxygen ions and preparation method thereof

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