CN110015865A - A kind of stonite and preparation method thereof - Google Patents
A kind of stonite and preparation method thereof Download PDFInfo
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- CN110015865A CN110015865A CN201910362728.1A CN201910362728A CN110015865A CN 110015865 A CN110015865 A CN 110015865A CN 201910362728 A CN201910362728 A CN 201910362728A CN 110015865 A CN110015865 A CN 110015865A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
The present invention relates to artificial stone field, especially a kind of stonite and preparation method thereof, the stonite includes the component of following weight percent: unsaturated polyester resin: 5-40wt%；Curing agent: 1-4wt%；Curing accelerator: 0.01-2wt%；Modifier: 0.01-3wt%；Filler: 55-93wt%；The filler includes microlite, feldspar or perlite, and silica weight percentage is 90% or more in microlite, feldspar or perlite.The filler that the stonite uses mainly replaces quartz or glass stone material using being easier to obtain microlite, feldspar or perlite, guarantee artificial granitic application range and characteristic simultaneously, microlite, feldspar or perlite are more as raw material acquiring way, it is convenient and more environmentally friendly, cheaper, while the production cost of artificial stone can be substantially reduced, it is also beneficial to environmental protection.
Description
Technical field
The present invention relates to artificial stone field, especially a kind of stonite and preparation method thereof.
Background technique
The production and selling of artificial stone is increasingly mature perfect in recent years, and artificial stone typically refers to artificial solid material, people
Make quartz, artificial hilllock stone and man-made glass stone etc., the wide variety of artificial stone, different types of artificial stone, ingredient is not yet
It is identical to the greatest extent.It but is all the quartz or glass by 70-95% at present in the production of manifold artificial quartz stone or man-made glass stone
The auxiliary agents such as glass and resin, colorant and other adjustings, bonding or curing agent, are fabricated under vacuum, high temperature and high pressure.It is artificial
Quartz sand and silica flour are to belong to non-renewable resources, in man-made glass stone for mineral products are broken by mining in quartz
Glass stone is all industrially prepared to be obtained, if a large amount of glass masonrys is used to manufacture man-made glass stone for raw material, raw material can only be from
It purchases in the market；The content of silica needs broken screening application generally 90% or more in quartz and glass stone, if
The main building stones of artificial stone can be very high using quartz sand or silica flour or glass stone, manufacturing cost, a large amount of to exploit quartz or work
Industry prepares glass stone, both uneconomical or not environmentally, can seriously affect a large amount of production and selling requirement of artificial stone, therefore researches and develops
One kind can substitute artificial quartz stone, artificial hilllock stone or man-made glass stone in the prior art as urgent problem to be solved out.
Summary of the invention
In view of the foregoing drawbacks, it is an object of the invention to propose a kind of stonite and preparation method thereof.
To achieve this purpose, the present invention adopts the following technical scheme:
A kind of stonite comprising the component of following weight percent:
Unsaturated polyester resin: 5-40wt%；Curing agent: 1-4wt%；Curing accelerator: 0.01-2wt%；
Modifier: 0.01-3wt%；Filler: 55-93wt%；Main filler be microlite, feldspar or perlite, microlite,
Silica weight percentage is 90% or more in feldspar or perlite；The unsaturated polyester resin, curing agent, solidification promote
The sum of component of agent, modifier and filler is 100%.
More preferably, when the main filler is microlite, the microlite includes at least crystallite stone sand, the 26- of 16-26 mesh
The crystallite stone flour and 800 purposes of the crystallite stone sand of 40 mesh, the crystallite stone sand of 40-70 mesh, the crystallite stone sand of 70-120 mesh, 325 mesh
Two kinds in crystallite stone flour.When the main filler is feldspar；The feldspar includes at least the length of the feldspathic sand of 16-26 mesh, 26-40 mesh
Stone sand, the feldspathic sand of 40-70 mesh, the feldspathic sand of 70-120 mesh, the feldspar powder of 325 mesh and 800 mesh feldspar powder in two kinds.It is described
When main filler is perlite, the perlite includes at least pearl rock sand, the 40-70 of the pearl rock sand of 16-26 mesh, 26-40 mesh
Purpose pearl rock sand, the pearl rock sand of 70-120 mesh, the crushed crude pearlite of 325 mesh and 800 mesh crushed crude pearlite in two kinds；The master
When microlite, feldspar or perlite are only with unified mesh number specification in filler, stonite's texture obtained is single, Er Qiecai
Although material performance can achieve the quality requirement of stonite, but performance needs to be further increased；Not using at least two
Crystallite stone sand or feldspathic sand or pearl rock sand with mesh number are mixed with the stonite, and the people on the one hand may be implemented
The diversification of granite texture is made, on the other hand it is also ensured that the microlite of different waste material preparations can be more sharp
With, while the crystallite stone sand or feldspathic sand of different meshes or pearl rock sand are used in mixed way can allow the quality of the stonite
More uniform, density is higher, is less prone to hole and bubble, to substantially increase the quality of the stonite.It is more excellent
, the filler further includes hard filler and soft filler, and the microlite, feldspar or perlite account for the weight hundred of the filler
Score is 60% or more；The weight ratio of the hard filler and soft filler is 10:(0.5-8).Institute is mixed in main filler
Hard filler and soft filler are stated, so that the filler prepares raw material more diversity, while between the filler of differing texture
With certain modifying function, the mobility and Forming Quality of the filler can be further improved, but to control the people
The content of silica in granite is made, and needs to limit the content of microlite or feldspar in the filler and accounts for mainly, therefore
It needs to carry out weight percent restriction, Cai Nengbao to the content and microlite of silica or the content of feldspar when raw material screening
The component and quality of stonite made of demonstrate,proving.
Specifically, the hard filler is aluminium oxide, titanium oxide, glass powder, silica flour, perlite, white carbon black, iron oxide
And/or inorganic cement；The soft filler are as follows: wollastonite, mica powder, calcium carbonate, calcium sulfate, kaolin, talcum powder, hydroxide
Aluminium, barite and/or pyrophillite.
Specifically, feldspar and perlite are lithotomes, and microlite is not lithotome, and the microlite is in existing production
Have in many in product, the component of the microlite in the application includes: silica, calcium carbonate and calcium oxide, and oxidation
At least one of zinc, barium carbonate, boron oxide, potassium oxide, sodium oxide molybdena, and the quality required to guarantee product, it is desirable that titanium dioxide
The weight percent of silicon at least over microlite weight half, although being defined to microlite constituent content,
This microlite amount that meets the requirements is very big in shraff, is also conducive to screening application.
Specifically, the curing agent includes hydroperoxides, dialkyl peroxide, diacyl peroxide, peroxidating
The combination of one or more of ester, ketone peroxide.
Specifically, the curing accelerator includes the combination of one or both of metallic salt, amine.
Specifically, the modifier include toughener, plasticizer, diluent, reinforcing agent, coupling agent, fire retardant, color paste,
At least one of wetting dispersing agent, defoaming agent, emulsifier, rheological agent.
It is used to prepare a kind of preparation method of stonite as described above comprising following steps:
1) filler is packed into feed bin to reach homo-effect；Because there are many type for including in filler, colored particle exists
Certain difference, therefore homogenization theory is utilized in this step, can allow filler blanking of the cloth in feed bin when color and quality
It is more uniform, guarantee stonite's quality and color also more uniform unification that molding obtains.
2) filler after completing homogenizing is poured into blender and is stirred evenly, then by unsaturated polyester resin, curing agent, solid
It pours into blender and stirs evenly after change promotor and modifier mixing, obtain mixture；
3) distribution cabins and press storehouse are sealed, and by distribution cabins and press storehouse and is evacuated down to -0.97 to -0.99 megapascal range
It is interior, continue to be stirred material under vacuum conditions；The constituent species of composition mixture are very special in the application, make nature solid
Material continues stirring under specific vacuum environment can guarantee that bubble is completely exhausted out in mixture, mix more uniform.
It 4) will be in the splicing vehicle in the smooth cloth to distribution cabins of mixture；
5) mixture after smooth cloth is sent into the press storehouse of press by splicing vehicle, and press shakes under vacuum conditions to be made to mix
Material is closed to flatten；
6) vacuum environment is released, obtains stonite's quarry stone after spontaneous curing 7-15 days at normal temperature；People in the step
Granite rough block is made using spontaneous curing under room temperature, does not need to carry out Special controlling to temperature, convenient for more large batch of solid
Chemical conversion type saves energy consumption.
7) stonite's quarry stone is cut, rubbing down processing obtains finished synthetic's granite.The stonite
The filler for being is mainly microlite or feldspar, and since said components ratio is mixed, due to the microlite and existing
Quartz or glass stone material property are different, thus to the mixture futher stir, cloth and when compacting, it is necessary to
Using vacuumizing, and vacuum is pressed in the range of -0.97 to -0.99 megapascal, just can guarantee the process of the mixture, sufficiently
Exhaust, cloth effect and Forming Quality are higher, and the preparation method uses pressure quarry stone moulding process and prepares stonite, at
It is homogeneous that high-strength entity fabric is obtained after type, no hole, intensity is higher.
More preferably, further include main filler preparation step before the step 1): the waste material that micro-crystalline ceramic production generates is carried out
Screening and attrition process, obtain the crystallite stone sand or crystallite stone flour of a variety of specific mesh number specifications；Or feldspar is screened and ground
Mill processing, obtains the feldspathic sand or feldspar powder of a variety of specific mesh number specifications；Or perlite is subjected to screening and attrition process, it obtains
The pearl rock sand or crushed crude pearlite of a variety of specific mesh number specifications.It is described after adding the step when the main filler is microlite
Microlite in preparation method can directly be sieved from the waste material of existing Production of Ceramics enterprise takes processing to obtain, specific to screen
Microlite of the available silica weight content 90% or more can use the side of sampling Detection component in screening process
Method can more recycle the production waste material of Ceramics Enterprises, and the recycling for being more advantageous to Production of Ceramics scrap materials of enterprises is controlled
Reason, the production cost for both having saved the stonite are also beneficial to environmental protection.When the main filler is feldspar or perlite,
After adding the step, feldspar or perlite in the preparation method can more easily be sieved from earth's crust mine takes processing to obtain,
Feldspar or perlite of the available silica weight content 90% or more are specifically screened, can be used in screening process
The method of sampling Detection component, feldspar content in the earth's crust is high and widely distributed, takes convenient and pollutes low more environmentally friendly, both saved
The production cost of the stonite is also beneficial to environmental protection.
The present invention proposes a kind of stonite and preparation method thereof, compared with the prior art in stonite's diamond stone or
Man-made glass stone, the filler that the stonite uses mainly use the lower microlite of dioxide-containing silica, feldspar or treasure
Zhu Yan replaces quartz or glass stone material, on the one hand can reduce the content of silica in the stonite,
Sales applications range is wider, and another aspect microlite can be processed to obtain from most of Production of Ceramics waste material, feldspar or perlite
Lithotome very rich in the earth's crust, raw material acquiring way is more, and facilitates environmental protection, allow the main filler price more just
Preferably, while the production cost of stonite can be substantially reduced, it is also beneficial to environmental protection.
Specific embodiment
To further illustrate the technical scheme of the present invention With reference to embodiment.
A kind of stonite comprising the component of following weight percent: unsaturated polyester resin: 5-40wt%；Gu
Agent: 1-4wt%；Curing accelerator: 0.01-2wt%；Modifier: 0.01-3wt%；Filler: 55-93wt%；The filler
Including microlite, silica weight percentage is 50% or more in microlite；The unsaturated polyester resin, is consolidated curing agent
Changing the sum of component of promotor, modifier and filler is 100%.
Specifically, crystallite stone sand, the 26-40 of 16-26 mesh can be included at least according to production needs, the microlite
Purpose crystallite stone sand, the crystallite stone sand of 40-70 mesh, the crystallite stone sand of 70-120 mesh, the crystallite stone flour of 325 mesh and 800 purposes are micro-
Two kinds in spar powder；When the main filler is feldspar；The feldspar includes at least the feldspar of the feldspathic sand of 16-26 mesh, 26-40 mesh
Sand, the feldspathic sand of 40-70 mesh, the feldspathic sand of 70-120 mesh, the feldspar powder of 325 mesh and 800 mesh feldspar powder in two kinds.The treasure
Zhu Yan includes at least the pearl rock sand of 16-26 mesh, the pearl rock sand of 26-40 mesh, the pearl rock sand of 40-70 mesh, 70-120 purpose
Two kinds in the crushed crude pearlite of pearl rock sand, the crushed crude pearlite of 325 mesh and 800 mesh.It is described in order to further increase the quality of product
Filler further includes hard filler and soft filler, and the weight percent that the microlite, feldspar or perlite account for the filler exists
60% or more；The weight ratio of the hard filler and soft filler is 10:(0.5-8).
There are many type of the hard filler, can be aluminium oxide, titanium oxide, glass powder, feldspathic sand, silica flour, pearl
One or more combination in rock, white carbon black, iron oxide and inorganic cement.Similarly, the type of the soft filler is also very much, can
Think one of wollastonite, mica powder, calcium carbonate, calcium sulfate, kaolin, talcum powder, aluminium hydroxide, barite and pyrophillite
Or a variety of combination.Because microlite is not natural material, the type of the product of microlite in the prior art is especially more,
The component of microlite described herein includes: silica, calcium carbonate and calcium oxide and zinc oxide, barium carbonate, oxidation
At least one of boron, potassium oxide, sodium oxide molybdena, and as described above microlite, in feldspar or perlite silica weight percent
Number must need the component of raw material to carry out screening control 90% or more, just effectively control dioxy in stonite
The content of SiClx.Specifically, the curing agent includes hydroperoxides, dialkyl peroxide, diacyl peroxide, peroxide
Change the combination of one or more of ester, ketone peroxide；The curing accelerator includes one of metallic salt, amine or two
The combination of kind；The modifier includes toughener, plasticizer, diluent, reinforcing agent, coupling agent, fire retardant, color paste, wetting point
At least one of powder, defoaming agent, emulsifier, rheological agent.
It is used to prepare the preparation method of above-mentioned stonite a kind of comprising following steps:
1) filler is packed into feed bin to reach homo-effect.
2) filler after completing homogenizing is poured into blender and is stirred evenly, then by unsaturated polyester resin, curing agent, solid
It pours into blender and stirs evenly after change promotor and modifier mixing, obtain mixture.
3) distribution cabins and press storehouse are sealed, and by distribution cabins and press storehouse and is evacuated down to -0.97 to -0.99 megapascal range
It is interior, continue to be stirred material 3-8 minutes under vacuum conditions, to eliminate the bubble in mixing.
It 4) will be in the splicing vehicle in the smooth cloth to distribution cabins of mixture.
5) mixture after smooth cloth is sent into the press storehouse of press by splicing vehicle, and press shakes under vacuum conditions to be made to mix
It closes material to flatten, and keeps 5-15 minutes better effects of completed state.
6) vacuum environment is released, obtains stonite's quarry stone after spontaneous curing 7-15 days at normal temperature；7) by artificial flower
Hilllock Waste stone material is cut, and rubbing down processing obtains finished synthetic's granite.
Since microlite, feldspar or perlite are alternative main filler each other in this application, respectively with two
When person is as main filler, testing result is almost the same, below just using main filler as microlite when contrasting detection data it is further
Verify the quality of the stonite；
Specifically, the crystallite sand or powder are that the waste material for generating micro-crystalline ceramic production carries out screening and attrition process and obtains
It arrives.
Testing inspection process substantially, according to said components and preparation method, adjusts the proportion between each component, obtains not
The same stonite, and product is tested for the property, testing result is hard with water absorption rate, density, bending strength, Pasteur
Degree, compression strength and impact strength compare for index, table specific as follows:
It can be seen that from above-described embodiment 1-12 when each component while within the scope of the weight percentages of components of above-mentioned restriction
When, i.e. unsaturated polyester resin is within the scope of 5-40wt%, and curing agent is within the scope of 1-4wt%, and curing accelerator is in 0.01-
Within the scope of 2wt%, modifier is within the scope of 0.01-3wt%, filler: when within the scope of 55-94wt%, than the component of above-mentioned restriction
When weight percent is not in the range of restriction, the stonite being prepared is by detection discovery, in addition to water absorption rate
Outside variation is smiled, density, bending strength, hardness Barcol, compression strength and impact strength five indices parameter have significantly
It improves, it may be said that the weight percent of component is within the scope of above-mentioned restriction, i.e., unsaturated poly- in stonite described in bright side
Ester resin is within the scope of 5-40wt%, and within the scope of 1-4wt%, curing accelerator changes curing agent within the scope of 0.01-2wt%
Into agent within the scope of 0.01-3wt%, filler: when within the scope of 55-94wt%, stonite's mass meeting for being prepared
It is higher, more meet production demand.
It can be seen that after being mixed into the hard filler and soft filler in the filler from above-described embodiment 3-9, product
Water absorption rate, density and bending strength have a slight change, but three hardness Barcol, compression strength and impact strength index parameters
It is significantly improved, it may be said that bright when being also mixed into the hard other than the microlite in the filler of the stonite
Filler and soft filler can be further improved the product quality of the stonite.
It can be seen that from above-described embodiment 8-12 when the microlite is mixed using the crystallite stone sand of a variety of mesh numbers
, significant change occurs for bending strength in the stonite being prepared, i.e., micro- when what is used in the microlite
The mesh number of spar sand is related to that four mesh number segment numbers are more, and stonite's bending strength is higher, according to described in the rule
Microlite is micro- comprising the crystallite stone sand of 16-26 mesh, the crystallite stone sand of 26-40 mesh, the crystallite stone sand of 40-70 mesh, 70-120 purpose
Mesh number specification kind number is more in the crystallite stone flour of spar sand, the crystallite stone flour of 325 mesh and 800 mesh, stonite's bending
Intensity is higher.
According to the conclusion that above-mentioned testing inspection result embodies, the present invention is by the weight of each component of the stonite
Amount percentage is limited in corresponding numberical range, can be further ensured that main filling kind is being substituted in the stonite
Afterwards, it reduces production cost and still has better product quality.
The present invention proposes a kind of stonite and preparation method thereof, compared with the prior art in stonite's diamond stone or
On the one hand man-made glass stone can reduce the content of silica in the stonite, sales applications range is wider, separately
One side microlite can be processed to obtain from most of Production of Ceramics waste material, and feldspar or perlite are days very rich in the earth's crust
Right stone material, raw material acquiring way is more, and facilitates environmental protection, allows the cheaper of the main filler, can substantially reduce artificial flower hilllock
While the production cost of stone, it is also beneficial to environmental protection.
The technical principle of the invention is described above in combination with a specific embodiment.These descriptions are intended merely to explain of the invention
Principle, and shall not be construed in any way as a limitation of the scope of protection of the invention.Based on the explanation herein, the technology of this field
Personnel can associate with other specific embodiments of the invention without creative labor, these modes are fallen within
Within protection scope of the present invention.
Claims (10)
1. a kind of stonite, which is characterized in that the component including following weight percent: unsaturated polyester resin: 5-
40wt%；Curing agent: 1-4wt%；Curing accelerator: 0.01-2wt%；Modifier: 0.01-3wt%；Filler: 55-94wt%；
The filler includes main filler, and main filler is microlite, feldspar or perlite；Dioxy in microlite, feldspar or perlite
SiClx weight percent is 90% or more；
The sum of the unsaturated polyester resin, curing agent, curing accelerator, modifier and component of filler are 100%.
2. a kind of stonite according to claim 1, which is characterized in that the microlite includes at least 16-26 mesh
Crystallite stone sand, the crystallite stone sand of 26-40 mesh, the crystallite stone sand of 40-70 mesh, the crystallite stone sand of 70-120 mesh, 325 mesh crystallite
Two kinds in the crystallite stone flour of mountain flour and 800 mesh；The feldspar include at least the feldspathic sand of 16-26 mesh, 26-40 mesh feldspathic sand,
The feldspathic sand of 40-70 mesh, the feldspathic sand of 70-120 mesh, the feldspar powder of 325 mesh and 800 mesh feldspar powder in two kinds；The pearl
Rock includes at least the treasure of the pearl rock sand of 16-26 mesh, the pearl rock sand of 26-40 mesh, the pearl rock sand of 40-70 mesh, 70-120 mesh
Two kinds in the crushed crude pearlite of pearl rock sand, the crushed crude pearlite of 325 mesh and 800 mesh.
3. a kind of stonite according to claim 1, which is characterized in that the filler further includes hard filler and soft
Matter filler, the main filler account for the weight percent of the filler 60% or more；The weight of the hard filler and soft filler
The ratio between amount is 10:(0.5-8).
4. a kind of stonite according to claim 3, which is characterized in that the hard filler is aluminium oxide, oxidation
Titanium, glass powder, feldspathic sand, silica flour, perlite, white carbon black, iron oxide and/or inorganic cement；
The soft filler are as follows: wollastonite, mica powder, calcium carbonate, calcium sulfate, kaolin, talcum powder, aluminium hydroxide, barite
And/or pyrophillite.
5. a kind of stonite according to claim 3 or 4, which is characterized in that the component of the microlite includes: two
At least one of silica, calcium carbonate and calcium oxide and zinc oxide, barium carbonate, boron oxide, potassium oxide, sodium oxide molybdena.
6. a kind of stonite according to claim 1, which is characterized in that the curing agent include hydroperoxides,
The combination of one or more of dialkyl peroxide, diacyl peroxide, peroxyester, ketone peroxide.
7. a kind of stonite according to claim 1, which is characterized in that the curing accelerator includes metal salt
The combination of one or both of class, amine.
8. a kind of stonite according to claim 1, which is characterized in that the modifier includes toughener, plasticising
Agent, diluent, reinforcing agent, coupling agent, fire retardant, color paste, wetting dispersing agent, defoaming agent, emulsifier, at least one in rheological agent
Kind.
9. being used to prepare the preparation method of stonite as described in any one of claim 1-8 a kind of, feature exists
In including the following steps:
1) filler is packed into feed bin to reach homo-effect；
2) filler after completing homogenizing is poured into blender and is stirred evenly, then unsaturated polyester resin, curing agent, solidification are promoted
It pours into blender and stirs evenly after into agent and modifier mixing, obtain mixture；
3) distribution cabins and press storehouse are sealed, and by distribution cabins and press storehouse and is evacuated down within the scope of -0.97 to -0.99 megapascal,
Continue to be stirred material under vacuum conditions；
It 4) will be in the splicing vehicle in the smooth cloth to distribution cabins of mixture；
5) mixture after smooth cloth is sent into the press storehouse of press by splicing vehicle, and press shakes under vacuum conditions makes mixture
It flattens；
6) vacuum environment is released, obtains stonite's quarry stone after spontaneous curing 7-15 days at normal temperature；
7) stonite's quarry stone is cut, rubbing down processing obtains finished synthetic's granite.
10. preparation method according to claim 9, which is characterized in that
Further include main filler preparation step before the step 1): by micro-crystalline ceramic production generate waste material screened and ground plus
Work obtains the crystallite stone sand or crystallite stone flour of a variety of specific mesh number specifications；Or feldspar is subjected to screening and attrition process, it obtains more
The feldspathic sand or feldspar powder of the specific mesh number specification of kind；Or perlite is subjected to screening and attrition process, obtain a variety of specific mesh numbers
The pearl rock sand or crushed crude pearlite of specification.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110436824A (en) * | 2019-09-05 | 2019-11-12 | 厦门高时实业有限公司 | A kind of artificial stone and preparation method thereof made of marble wastes |
| CN111348862A (en) * | 2020-03-17 | 2020-06-30 | 山东天马泰山机械集团有限公司 | Artificial stone and preparation method thereof |
| AT525892B1 (en) * | 2022-06-10 | 2023-09-15 | STRASSER Steine GmbH | countertop |
| CN117510131A (en) * | 2023-11-16 | 2024-02-06 | 广东中旗新材料股份有限公司 | Quartz stone plate with low silicon formula and production process thereof |
| CN117510131B (en) * | 2023-11-16 | 2024-04-30 | 广东中旗新材料股份有限公司 | Quartz stone plate with low silicon formula and production process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5588599A (en) * | 1994-09-12 | 1996-12-31 | Novak; James P. | Method of manufacture of polyester-chip products for casting artificial-stone articles |
| CN1167477A (en) * | 1994-10-31 | 1997-12-10 | 株式会社多佩尔 | Artificial stone composition and method of mfg. artificial stone |
| CN103396040A (en) * | 2013-07-15 | 2013-11-20 | 肇庆富盛复合材料有限公司 | Artificial solid plane materiel and manufacturing method thereof |
| CN103467002A (en) * | 2013-08-19 | 2013-12-25 | 佛山市亮剑陶瓷有限公司 | Method for producing resin type artificial stones by using tile polishing residues |
| CN109265068A (en) * | 2018-10-10 | 2019-01-25 | 广东中旗新材料股份有限公司 | It is a kind of using non-natural mineral as artificial stone of major ingredient and preparation method thereof |
-
2019
- 2019-04-30 CN CN201910362728.1A patent/CN110015865A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5588599A (en) * | 1994-09-12 | 1996-12-31 | Novak; James P. | Method of manufacture of polyester-chip products for casting artificial-stone articles |
| CN1167477A (en) * | 1994-10-31 | 1997-12-10 | 株式会社多佩尔 | Artificial stone composition and method of mfg. artificial stone |
| CN103396040A (en) * | 2013-07-15 | 2013-11-20 | 肇庆富盛复合材料有限公司 | Artificial solid plane materiel and manufacturing method thereof |
| CN103467002A (en) * | 2013-08-19 | 2013-12-25 | 佛山市亮剑陶瓷有限公司 | Method for producing resin type artificial stones by using tile polishing residues |
| CN109265068A (en) * | 2018-10-10 | 2019-01-25 | 广东中旗新材料股份有限公司 | It is a kind of using non-natural mineral as artificial stone of major ingredient and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘新红等: "《建筑装饰材料与绿色装修》", 31 October 2014, 河南科学技术出版社 * |
| 曾昭远编著: "《装修完全手册 家居篇》", 31 January 2014, 海天出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110436824A (en) * | 2019-09-05 | 2019-11-12 | 厦门高时实业有限公司 | A kind of artificial stone and preparation method thereof made of marble wastes |
| CN111348862A (en) * | 2020-03-17 | 2020-06-30 | 山东天马泰山机械集团有限公司 | Artificial stone and preparation method thereof |
| AT525892B1 (en) * | 2022-06-10 | 2023-09-15 | STRASSER Steine GmbH | countertop |
| AT525892A4 (en) * | 2022-06-10 | 2023-09-15 | STRASSER Steine GmbH | countertop |
| CN117510131A (en) * | 2023-11-16 | 2024-02-06 | 广东中旗新材料股份有限公司 | Quartz stone plate with low silicon formula and production process thereof |
| CN117510131B (en) * | 2023-11-16 | 2024-04-30 | 广东中旗新材料股份有限公司 | Quartz stone plate with low silicon formula and production process thereof |
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Application publication date: 20190716 |