CN108947648B - Foliar fertilizer taking edible fungus residues and tangerine peel and citrus pulp residues as raw materials and preparation method thereof - Google Patents
Foliar fertilizer taking edible fungus residues and tangerine peel and citrus pulp residues as raw materials and preparation method thereof Download PDFInfo
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- CN108947648B CN108947648B CN201810723461.XA CN201810723461A CN108947648B CN 108947648 B CN108947648 B CN 108947648B CN 201810723461 A CN201810723461 A CN 201810723461A CN 108947648 B CN108947648 B CN 108947648B
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
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- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F5/00—Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
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- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
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Abstract
The invention provides a fermented fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials, which is prepared by fermenting the following components in percentage by weight: 0.1-1% of a leavening agent, 0.1-1% of a fermentation starter, 10-89% of tangerine peel and citrus pulp residues and 10-89% of edible fungus residues. The invention also provides a foliar fertilizer taking edible fungus residues and tangerine peel and meat residues as raw materials and a preparation method thereof. The invention produces the biological organic fertilizer which can be used for plants and has the function of foliar fertilizer by using the tangerine peel and citrus pulp residues and the edible fungus residues as main raw materials, and has a certain biological pesticide effect, and the byproduct after fertilizer production can be directly used for feed addition, thereby realizing the maximum waste utilization.
Description
Technical Field
The invention relates to the field of agricultural fertilizers, in particular to a foliar fertilizer, and particularly relates to a foliar fertilizer taking edible fungus residues and tangerine peel and citrus pulp residues as raw materials and a preparation method thereof.
Background
The edible fungus slag is a waste solid culture medium after the production of edible fungi, the scale for producing the edible fungi in China is huge, the quantity of the edible fungus slag is increased sharply along with the development of the edible fungus industry, but the utilization rate is low and is about 35 percent. The edible fungus dregs are generally rich in protein, crude fat, crude fiber and trace elements, and also contain bioactive substances such as polysaccharide, organic acid, enzyme and the like, and a large amount of fungus dregs are not treated in an environment-friendly way and are discarded at will, so that not only is the resource waste caused, but also the fungus dregs are easy to go moldy and deteriorate, pollute land and water sources and harm the health of human bodies.
At present, the main utilization approach of the edible fungus residues is to prepare organic fertilizer by stacking, use the organic fertilizer as an edible fungus cultivation material and a feed after treatment, but the comprehensive utilization is low and the effect is poor. The method for preparing the organic fertilizer by adopting the edible fungus residues mainly comprises two modes, wherein one mode is that the edible fungus residues are all used as raw materials, the organic fertilizer is prepared by stacking fermentation, the fermentation time is more than 30 days, and the nutrition in the organic fertilizer is single; one method is to add a small amount of the edible fungi residue into other raw materials to prepare an organic fertilizer, and the problem of low utilization rate of the edible fungi residue cannot be solved due to the small amount of the edible fungi residue. The edible fungus slag can not be fully utilized, so that the waste is turned into treasure and is discarded at will, which not only causes serious environmental pollution to the producing area of the edible fungus, but also wastes resources. Therefore, the comprehensive and efficient utilization of edible fungus resources is a common requirement for protecting the environment and saving resources.
In recent years, tea products prepared by using tangerine peel and tangerine peel are more and more popular, such as citrus-common tea in Xinhui city of Guangdong province. The tangerine peel and tangerine peel tea is divided into two types, one is a product prepared by mixing tangerine peel prepared from small green tangerine oranges and Yunnan Pu' er ripe tea, and the other is prepared from ripe large tangerine peel oranges. In any case, a large amount of byproduct citrus pulp residues are generated in the manufacturing process, and because the acidity of the citrus pulp is high, the citrus pulp residues are wasted in large quantity at present, and an effective solution is not provided at present. According to statistics, ten thousand tons of tangerine peel meat residues are required to be subjected to environment-friendly treatment every year in Xinhui county of Guangdong province, and if the tangerine peel meat residues can be comprehensively utilized, the method is beneficial to environment and resource reutilization.
Disclosure of Invention
In view of the above, the invention provides a foliar fertilizer taking edible fungus residues and tangerine peel meat residues as raw materials and a preparation method thereof.
The invention provides a fermented fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials, which is mainly prepared by fermenting the following components in percentage by weight: 0.1-1% of a leavening agent, 0.1-1% of a fermentation starter, 10-89% of tangerine peel and citrus pulp residue and 10-89% of edible fungus residue;
in one embodiment of the invention, the fermented fertilizer taking the edible fungus residues and the tangerine peel and tangerine pulp residues as raw materials is prepared by fermenting the following components in percentage by weight: 0.1-0.5% of a leavening agent, 0.4-0.1% of a fermentation starter, 30-70% of tangerine peel and citrus pulp residues and 30-70% of edible fungus residues.
In a preferred embodiment of the invention, the fermented fertilizer taking the edible fungus residues and the tangerine peel and tangerine pulp residues as raw materials is prepared by fermenting the following components in percentage by weight: 0.1% of leaven, 0.5% of fermentation starter, 50% of tangerine peel and citrus pulp residue and 50% of edible fungus residue.
In one embodiment of the present invention, the leavening agent is pichia pastoris.
In a preferred embodiment of the invention, the effective viable count of the pichia pastoris is 500 hundred million viable bacteria/g.
In one embodiment of the present invention, the fermentation starter is glucose.
The invention provides a foliar fertilizer taking edible fungus residues and tangerine peel meat residues as raw materials, which is mainly prepared by mixing the fermented fertilizer provided by the first aspect of the invention and a foliar fertilizer extracting solution and then extracting the liquid, wherein the foliar fertilizer extracting solution comprises tangerine peel and tangerine peel juice.
In one embodiment of the invention, the ratio of the fermented fertilizer foliar fertilizer to the extracting solution is 1: 2 to 8.
In a preferred embodiment of the invention, the ratio of the fermented fertilizer foliar fertilizer to the extracting solution is 1: 5.
in one embodiment of the invention, the tangerine peel juice is prepared by the following method: and (3) carrying out residue-liquid separation on the tangerine peel and tangerine pulp, and obtaining liquid obtained by separation, namely tangerine peel and tangerine juice.
The third aspect of the invention provides a preparation method of a foliar fertilizer taking edible fungus residues and tangerine peel and meat residues as raw materials, which comprises the following steps:
(1) pretreatment of fermentation raw materials: separating residue and liquid of tangerine peel and tangerine pulp, mixing the obtained meat residue with edible fungus residue, and grinding to obtain a first mixture;
(2) fermentation: adding a fermenting agent and a fermentation starter into the mixture obtained in the step (1) to obtain a second mixture, adjusting the pH, stirring, and fermenting to obtain a fermented fertilizer, wherein the fermenting agent is 0.1-1%, the fermentation starter is 0.1-1%, the tangerine peel meat residue is 10-89%, and the edible fungus residue is 10-89%;
(3) and (3) adding a leaf fertilizer extracting solution into the fermentation material obtained in the step (2), adjusting the pH value, preserving the temperature, adjusting the pH value to be neutral, and separating out liquid, namely leaf fertilizer.
In an embodiment of the invention, in the step (1), the ratio of the tangerine peel and citrus reticulata pulp residue to the edible fungus residue is 1: 1 to 5.
In a preferred embodiment of the present invention, in the step (1), the ratio of the tangerine peel and citrus reticulata pulp residue to the edible fungus residue is 1: 1.
in an embodiment of the present invention, in the step (2), the leavening agent is pichia pastoris.
In a preferred embodiment of the present invention, in the step (2), the number of effective viable bacteria of pichia pastoris is 500 hundred million viable bacteria/g, and the addition amount is 0.1%.
In an embodiment of the present invention, in the step (2), the fermentation starter is glucose.
In a preferred embodiment of the present invention, in the step (2), the fermentation starter glucose is added in an amount of 0.5%.
In one embodiment of the present invention, in the step (2), the PH of the second mixture is adjusted to 4.0-6.5 during fermentation.
In a preferred embodiment of the present invention, in the step (2), the PH of the second mixture is adjusted to 6.0 during the fermentation.
In one embodiment of the present invention, in the step (2), the second mixture is stirred for 5 minutes every half hour during fermentation.
In an embodiment of the invention, in the step (2), the fermentation time of the second mixture is 5 to 15 days.
In a preferred embodiment of the present invention, in the step (2), the fermentation time of the second mixture is 10 days.
In an embodiment of the invention, in the step (3), the ratio of the fermented fertilizer foliar fertilizer to the extracting solution is 1: 2 to 8.
In a preferred embodiment of the invention, in the step (3), the ratio of the fermented fertilizer foliar fertilizer to the extracting solution is 1: 5.
in an embodiment of the invention, in the step (3), the foliar fertilizer extracting solution is tangerine peel and tangerine juice.
In one embodiment of the invention, in the step (3), after the foliar fertilizer extracting solution is added to the fermentation material, the PH value is adjusted to 4.0-6.0.
In a preferred embodiment of the invention, in the step (3), after the foliar fertilizer extracting solution is added to the fermentation material, the PH value is adjusted to 5.5.
In an embodiment of the present invention, in the step (3), the holding temperature is 40 ℃.
In an embodiment of the invention, in the step (3), the heat preservation time is 4-10 hours.
In a preferred embodiment of the present invention, in the step (3), the incubation time is 8 hours.
In a fourth aspect, the invention provides an application of the fermented fertilizer using the edible mushroom dregs and the tangerine peel and.
The invention has the advantages that:
firstly, the dried orange peel and citrus reticulata pulp which is difficult to recover and the mushroom residue are skillfully utilized to be mixed and fermented to prepare the foliar fertilizer, so that the waste utilization is realized;
secondly, fermenting the orange peel and citrus reticulata pulp and mushroom residue mixture by using pichia pastoris, only adding a small amount of glucose as a starter, and fermenting for 5 days to increase the microbial concentration to 1.2 multiplied by 109The method is favorable for processing tens of thousands of tons of tangerine peel residues in more than one month in the harvesting season, and the pichia pastoris has low nutrient requirement, fast growth and cheap culture medium, can be fermented at high density and is convenient for industrial production.
And thirdly, extracting the foliar fertilizer from the fermented fertilizer by using the tangerine peel and tangerine peel juice, so that the fiber of the mixture is degraded, the effective ingredients are increased, the harm of the tangerine peel and tangerine peel juice to the environment is reduced, and the use value of the waste is improved.
Drawings
Fig. 1 is a preparation flow chart of a foliar fertilizer using edible fungus residues and tangerine peel residue as raw materials, which is provided by the embodiment of the invention.
Detailed Description
While the following is a description of the preferred embodiments of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.
The preferred embodiment of the present invention will be described in detail with reference to fig. 1. The experimental methods in the examples, in which specific conditions are not specified, are generally carried out under conventional conditions. In the examples of the present invention, unless otherwise specified, reagents and consumables used therein are commercially available.
Example 1
1. Preparation of fermented fertilizer
A fermented fertilizer taking edible fungus residues and tangerine peel meat residues as raw materials is prepared by fermenting the following components in percentage by weight: 0.1% of fermentation starter pichia pastoris, 0.1% of fermentation starter glucose, 29.8% of tangerine peel and citrus pulp residues and 70% of edible fungus residues.
2. Preparation of foliar fertilizer
A foliar fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials is prepared from the fermented fertilizer obtained in the step 1 and a foliar fertilizer extracting solution tangerine peel and tangerine juice according to the proportion of 1: 5 mixing, and extracting the liquid to obtain the final product.
3. Specific preparation method of foliar fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials
(1) Pretreatment of fermentation raw materials: carrying out residue-liquid separation on tangerine peel and tangerine pulp to obtain meat residue with the water content of 80%, and mixing the obtained meat residue with edible mushroom residue (the mushroom residue in the embodiment) according to the ratio of 3: 7, mixing and grinding to obtain a first mixture;
(2) fermentation: adding 0.1% of fermentation agent pichia pastoris with 500 hundred million viable bacteria/g of effective viable bacteria and 0.1% of fermentation starter glucose into the first mixture obtained in the step (1) to obtain a second mixture, adjusting the pH to 6.0, stirring for 5 minutes every half hour, and fermenting for 10 days to obtain a fermented fertilizer;
(3) adding a leaf fertilizer extracting solution, namely tangerine peel and tangerine peel juice into the fermented fertilizer obtained in the step (2), wherein the weight ratio of the fermented fertilizer to the tangerine peel and tangerine peel juice is 1: 2, regulating the pH value to 5.5 by using potassium hydroxide, keeping the temperature at 40 ℃ for 8 hours, regulating the pH value to be neutral, and separating out liquid, namely the foliar fertilizer.
Example 2
1. Preparation of fermented fertilizer
A fermented fertilizer taking edible fungus residues and tangerine peel meat residues as raw materials is prepared by fermenting the following components in percentage by weight: 0.1% of fermentation starter pichia pastoris, 0.5% of fermentation starter glucose, 50% of tangerine peel and citrus pulp residues and 49.4% of edible fungus residues.
2. Preparation of foliar fertilizer
A foliar fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials is prepared from the fermented fertilizer obtained in the step 1 and a foliar fertilizer extracting solution tangerine peel and tangerine juice according to the proportion of 1: 5 mixing, and extracting the liquid to obtain the final product.
3. Specific preparation method of foliar fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials
(1) Pretreatment of fermentation raw materials: separating residue and liquid of tangerine peel and tangerine pulp to obtain meat residue with the water content of 80%, and mixing the obtained meat residue with edible mushroom residue (mushroom residue in the embodiment) according to the ratio of 1: 1, mixing and grinding to obtain a first mixture;
(2) fermentation: adding 0.1% of pichia pastoris serving as a leavening agent with the effective viable count of 500 hundred million viable bacteria/g and 0.5% of glucose serving as a fermentation starter into the first mixture obtained in the step (1) to obtain a second mixture, adjusting the pH to 6.0, stirring for 5 minutes every half hour, and fermenting for 10 days to obtain a fermented fertilizer;
(3) adding a leaf fertilizer extracting solution, namely tangerine peel and tangerine peel juice into the fermented fertilizer obtained in the step (2), wherein the weight ratio of the fermented fertilizer to the tangerine peel and tangerine peel juice is 1: and 5, regulating the pH value to 5.5 by using potassium hydroxide, keeping the temperature at 40 ℃ for 8 hours, regulating the pH value to be neutral, and separating out liquid to obtain the foliar fertilizer.
Example 3
1. Preparation of fermented fertilizer
A fermented fertilizer taking edible fungus residues and tangerine peel meat residues as raw materials is prepared by fermenting the following components in percentage by weight: 0.5% of fermentation starter pichia pastoris, 0.8% of fermentation starter glucose, 60% of tangerine peel and citrus pulp residue and 38.7% of edible fungus residue.
2. Preparation of foliar fertilizer
A foliar fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials is prepared from the fermented fertilizer obtained in the step 1 and a foliar fertilizer extracting solution tangerine peel and tangerine juice according to the proportion of 1: 6 mixing, and extracting the liquid to obtain the final product.
3. Specific preparation method of foliar fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials
(1) Pretreatment of fermentation raw materials: carrying out residue-liquid separation on tangerine peel and tangerine pulp to obtain meat residue with the water content of 80%, and mixing the obtained meat residue with edible mushroom residue (the mushroom residue in the embodiment) according to the ratio of 3: 2, mixing and grinding to obtain a first mixture;
(2) fermentation: adding 0.5% of pichia pastoris serving as a leavening agent with the effective viable count of 500 hundred million viable bacteria/g and 0.8% of glucose serving as a fermentation starter into the first mixture obtained in the step (1) to obtain a second mixture, adjusting the pH to 6.0, stirring for 5 minutes every half hour, and fermenting for 10 days to obtain a fermented fertilizer;
(3) adding a leaf fertilizer extracting solution, namely tangerine peel and tangerine peel juice into the fermented fertilizer obtained in the step (2), wherein the weight ratio of the fermented fertilizer to the tangerine peel and tangerine peel juice is 1: and 10, regulating the pH value to 5.5 by using potassium hydroxide, keeping the temperature at 40 ℃ for 8 hours, regulating the pH value to be neutral, and separating out liquid to obtain the foliar fertilizer.
Example 4
1. Preparation of fermented fertilizer
A fermented fertilizer taking edible fungus residues and tangerine peel meat residues as raw materials is prepared by fermenting the following components in percentage by weight: 1% of fermentation starter pichia pastoris, 1% of fermentation starter glucose, 80% of tangerine peel and citrus pulp residue and 18% of edible fungus residue.
2. Preparation of foliar fertilizer
A foliar fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials is prepared from the fermented fertilizer obtained in the step 1 and a foliar fertilizer extracting solution tangerine peel and tangerine juice according to the proportion of 1: 8 mixing, and extracting the liquid to obtain the final product.
3. Specific preparation method of foliar fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials
(1) Pretreatment of fermentation raw materials: separating residue and liquid of tangerine peel and tangerine pulp to obtain meat residue with the water content of 80%, and mixing the obtained meat residue with edible mushroom residue (mushroom residue in the embodiment) according to the ratio of 4: 1, mixing and grinding to obtain a first mixture;
(2) fermentation: adding 1% of a fermentation starter pichia pastoris with an effective viable count of 500 hundred million viable bacteria/g and 1% of fermentation starter glucose into the first mixture obtained in the step (1) to obtain a second mixture, adjusting the pH to 6.0, stirring for 5 minutes every half hour, and fermenting for 10 days to obtain a fermented fertilizer;
(3) adding a leaf fertilizer extracting solution, namely tangerine peel and tangerine peel juice into the fermented fertilizer obtained in the step (2), wherein the weight ratio of the fermented fertilizer to the tangerine peel and tangerine peel juice is 1: and 8, regulating the pH value to 5.5 by using potassium hydroxide, keeping the temperature at 40 ℃ for 8 hours, regulating the pH value to be neutral, and separating out liquid to obtain the foliar fertilizer.
Example 5
The leaf fertilizers prepared in the detection examples 1 to 4 are detected according to the requirements of national standard GB/T17419-1998 amino acid-containing leaf fertilizers, the amino acid content and the water insoluble substance content are detected, and the detection results are shown in the following table.
Comparison 1: the procedure of example 2 was followed, but the starter culture was EM bacteria.
Comparison 2: the procedure of example 2 was followed except that the foliar feed extract was water.
Comparison 3: the procedure of example 2 was followed except that the foliar feed extract was water and the starter was EM.
As can be seen from the above table, the foliar fertilizer prepared by the technical scheme of the invention reuses tangerine peel juice discarded originally as waste liquid as foliar fertilizer extract, and the amino acid content of the obtained foliar fertilizer is 1.8-4.8% higher than that of the foliar fertilizer obtained by comparison 2, which indicates that the effect of using tangerine peel juice as foliar fertilizer extract is better than that of using water as foliar fertilizer extract; in addition, pichia is used as a leavening agent, compared with comparison 1 (EM bacteria are used as leavening agents), the content of the obtained amino acid is higher than that of comparison 1 by 2.0-5.0%, which shows that the fermentation effect of pichia is better than that of EM bacteria; compared with the comparison 3 in which EM bacteria is used as a leavening agent and water is used as a foliar fertilizer extracting solution, the amino acid content of the foliar fertilizer prepared by the technical scheme of the invention is 3.1-6.1% higher. In addition, the pichia pastoris has low nutritional requirement, fast growth, cheap culture medium, high-density fermentation and convenient industrial production.
Application examples
1. The foliar fertilizer is applied to the rice:
rainwater in Henan province of Hunan province in 6 months in 2017 lasts for more than 30 days, the growth of rice is hindered, foliar fertilizers of the company are recommended to be used in the communication with Liu Youyuan of farmers in 28 days in the same month, and the foliar fertilizers are sprayed once respectively on ten mu of rice with the most serious flood in 7 months and 8 months under the condition of simultaneously supplementing base fertilizers with other paddy fields, so that 740 kg of per mu yield is finally realized, and the yield is increased by 23 percent on year-by-year basis.
2. The foliar fertilizer is applied to cotton:
in 2017, 22 days in 7 months to 15 days in 8 months, 200 mu of single Asian peng cotton land in elm ditch husbandry in the district of Changji city, 500 mu of cotton land in Machufeng in old Longhe agricultural park and 100 mu of cotton land in Ashi (northern Shawo) waiting jade badge in Xinjiang city are sprayed, and the foliar fertilizer is sprayed twice in advance without changing the original field management, so that the effect of increasing the yield by 21 to 26 percent is achieved.
Although the present invention has been described in detail with reference to the preferred embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the true spirit and scope of the present invention.
Claims (5)
1. The foliar fertilizer is characterized by being prepared by mixing a fermented fertilizer and a foliar fertilizer extracting solution and then extracting the liquid, wherein the fermented fertilizer is mainly prepared by fermenting the following components in percentage by weight: 0.1-1% of a leavening agent, 0.1-1% of a fermentation starter, 10-89% of tangerine peel and citrus pulp residue and 10-89% of edible fungus residue, wherein the leavening agent is pichia pastoris, the fermentation starter is glucose, and the ratio of the fermented fertilizer to the leaf fertilizer extracting solution is 1: 2-8, wherein the foliar fertilizer extracting solution is tangerine peel and tangerine peel juice, and is prepared by carrying out residue-liquid separation on tangerine peel and tangerine pulp liquid.
2. A preparation method of a foliar fertilizer taking edible fungus residues and tangerine peel and tangerine pulp residues as raw materials is characterized by comprising the following steps:
(1) pretreatment of fermentation raw materials: separating residue and liquid of tangerine peel and tangerine pulp, mixing the obtained meat residue with edible fungus residue, and grinding to obtain a first mixture;
(2) fermentation: adding a fermenting agent and a fermentation starter into the mixture obtained in the step (1) to obtain a second mixture, adjusting the pH, stirring, and fermenting to obtain a fermented fertilizer, wherein the fermenting agent is 0.1-1%, the fermentation starter is 0.1-1%, the tangerine peel meat residue is 10-89%, and the edible fungus residue is 10-89%;
(3) and (3) adding a leaf fertilizer extracting solution into the fermentation material obtained in the step (2), adjusting the pH value, preserving the temperature, adjusting the pH value to be neutral, and separating out liquid, namely leaf fertilizer.
3. The preparation method of the foliar fertilizer as claimed in claim 2, wherein in the step (2), the pH is adjusted to 4.0-6.5, and the mixture is stirred and fermented for 5-15 days.
4. The preparation method of the foliar fertilizer as claimed in claim 2, wherein in the step (3), the pH is adjusted to 4.0-6.0, and the temperature is maintained for 2-10 hours.
5. The application of the foliar fertilizer taking the edible mushroom dregs and the tangerine peel and.
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