CN108947384A - A kind of ecological permeable bricks and preparation method thereof - Google Patents

A kind of ecological permeable bricks and preparation method thereof Download PDF

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Publication number
CN108947384A
CN108947384A CN201810673696.2A CN201810673696A CN108947384A CN 108947384 A CN108947384 A CN 108947384A CN 201810673696 A CN201810673696 A CN 201810673696A CN 108947384 A CN108947384 A CN 108947384A
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CN
China
Prior art keywords
surface layer
permeable bricks
ecological permeable
handstone
initial bed
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Pending
Application number
CN201810673696.2A
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Chinese (zh)
Inventor
杨博
刘丹
孙茂刚
张传胜
徐卫东
褚卫东
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Hubei Yusheng Environmental Protection Technology Co Ltd
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Hubei Yusheng Environmental Protection Technology Co Ltd
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Priority to CN201810673696.2A priority Critical patent/CN108947384A/en
Publication of CN108947384A publication Critical patent/CN108947384A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/08Slag cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Road Paving Structures (AREA)

Abstract

The present invention provides a kind of ecological permeable bricks, including surface layer and initial bed, surface layer includes following component by mass percentage: quartz sand 70~80%, and white cement 15~20%, the first additive 0.5~2%, surplus is water;The initial bed includes following component by mass percentage: cement 10~15%, and handstone 20~25%, big stone 30~35%, yellow ground 20~25%, the second additive 0.5~2%, surplus is water.The invention mixes merga pass to the controllable porosity to ecological permeable bricks of the proportion adjustment of its content using two kinds of stones of size of different-grain diameter, so that rainwater suddenly will not influence ground very much through the water flow of brick, buffer function is played to the infiltration of rainwater, and its good water permeability, and there is stable porosity, excellent compression strength and fracture resistance, compression strength reaches 20~40MPa, and still has biggish porosity in higher compression strength.

Description

A kind of ecological permeable bricks and preparation method thereof
Technical field
The invention belongs to building material technical fields, and in particular to a kind of ecological permeable bricks and preparation method thereof.
Background technique
With the rapid development of China's economy and greatly developing for urbanization, greenery patches originally is by large-scale ground pavement Replace, " the city desert " of formation considerably increase Permeable stratum area, prevent urban rainwater is from back to nature, as a result, city City's underground water largely reduces, the danger for having urban architecture to sink;And heavy rain is met when city is prominent, rainwater on road surface can not quickly seep Leakage causes to municipal drainage facility and greatly bears and easily send out into urban waterlogging.At the same time, the road of mating formation of large area Face weakens the respiratory function in city, will cause " tropical island effect ", reduces city comfort level and causes urban ecological system unbalance, Therefore water-permeable brick as a kind of good water permeable paving material start by more and more attention has been paid to.
Although currently, asking for above-mentioned municipal drainage difficulty can be solved to a certain extent by having researched and developed some water-permeable bricks Topic, but a large amount of rainwater directly passes through water-permeable brick and infiltrates into ground, and ground is be easy to cause to loosen, thus water-permeable brick is needed to have Stable porosity, good compression strength and fracture resistance.
Summary of the invention
The purpose of the present invention is overcoming the porosity of existing water-permeable brick unstable, compression strength and fracture resistance is bad asks Topic.
For this purpose, the embodiment of the invention provides a kind of ecological permeable bricks, including surface layer and initial bed, the raw material of the surface layer Including following component by mass percentage: quartz sand 70~80%, white cement 15~20%, the first additive 0.5~2% are remaining Amount is water;The raw material of the initial bed includes following component by mass percentage: cement 10~15%, and handstone 20~ 25%, big stone 30~35%, yellow ground 20~25%, the second additive 0.5~2%, surplus is water.
Further, the partial size of the handstone is 1~5mm, and the partial size of big stone is 5~10mm, the handstone and The mass ratio of big stone is 1.5:1~1.7:1.
Further, first additive is one or more of curing agent, antioxidant and ultraviolet absorbing agent Mixture, the second additive are water-reducing agent.
Further, the raw material of the surface layer further includes the pigment that mass fraction is 0.5~1%.
Further, the raw material of the initial bed further includes fiber and cementitious material, and the cementitious material is by house refuse Flying ash, slag, alkali-activator are constituted.
Further, the surface layer with a thickness of 5~8mm, the initial bed with a thickness of 50~55mm.
In addition, including the following steps: the present invention also provides the preparation method of above-mentioned ecological permeable bricks
1) surface layer mixed slurry is prepared
Each raw material of surface layer is mixed evenly in mass ratio, obtains surface layer mixed slurry;
2) initial bed mixed slurry is prepared
Big stone and handstone are ground after first cleaning handstone and big stone respectively and its partial size is screened, then Other raw materials of the handstone filtered out and big stone and initial bed are mixed evenly in mass ratio, obtain initial bed Mixed slurry;
3) initial bed mixed slurry prepared by step 2) is put into molding die, is tamped through vibration, after its preliminary solidification, Surface layer mixed slurry prepared by step 1) is added in molding die again, vibration is tamped, and is demoulded after standing curing molding, natural 5~10 days are conserved under state to get ecological permeable bricks.
Compared with prior art, beneficial effects of the present invention:
(1) it mixes and leads to using two kinds of stones of size of different-grain diameter in the initial bed of this ecological permeable bricks provided by the invention Cross can be achieved to control the porosity of ecological permeable bricks to the ratio control of the two content, so that rainwater penetrates brick Water flow will not be too anxious and influence ground, buffer function is played to the infiltration of rainwater, while stone can also play filtering to rainwater Effect.
(2) fiber and cementitious material are also used in the initial bed of this ecological permeable bricks provided by the invention, utilize fiber The gelling property of the reticular structure, toughness and the cementitious material that itself have glues yellow ground, the stone etc. in initial bed It closes, enhances the compression strength and fracture resistance of the ecological permeable bricks;Cementitious material uses slag and consumer waste incineration simultaneously Flying dust utilizes Na of the slag in alkali-activator and domestic garbage incineration flyash+、K+The lower change by itself of equal excitation effect It learns composition and hydration reaction occurs and generates gum material, gelling adhesive is carried out to raw material each in initial bed, and hydration reaction produces The mineral systems such as raw hydrated calcium silicate, calcium chloroaluminate, entringite, stratlingite can pass through physically encapsulation, chemisorption Precipitating forms cenotype and ion exchange forms the modes such as solid solution and solidifies to the heavy metal in domestic garbage incineration flyash, no The secondary use of solid waste, save the cost and energy resources are only able to achieve, and is avoided that and pollutes the environment.
(3) good water permeability of this ecological permeable bricks provided by the invention, and there is stable porosity, excellent resistance to compression Intensity and fracture resistance, compression strength reaches 20~40MPa, and still has biggish hole in higher compression strength Rate.
(4) preparation method of this ecological permeable bricks provided by the invention is easy to operate, certainly by ecological permeable bricks raw material The gelling property of body carries out adhering and solidifying molding to raw material, is pressed without impressed pressure to it, reduces and be produced into This.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel all other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1:
A kind of ecological permeable bricks, including surface layer and initial bed are present embodiments provided, the raw material of the surface layer includes pressing quality hundred Divide the following component than counting: quartz sand 80%, white cement 15%, the first additive 0.5%, water 4.5%;The raw material packet of the initial bed Include following component by mass percentage: cement 15%, handstone 25%, big stone 30%, yellow ground 20%, the second additive 0.5%, water 9.5%.Wherein, the first additive is curing agent (vinyl triamine), and the second additive is water-reducing agent (lignin sulfonic acid Sodium).
The preparation method of the ecological permeable bricks of the present embodiment, process are as follows:
Firstly, each raw material of above-mentioned surface layer is mixed evenly in mass ratio, surface layer mixed slurry is obtained;Then, by gravelstone Sub and big stone grinds big stone and handstone and is screened to its partial size after cleaning respectively, choose partial size be 1~ The handstone of 5mm, partial size are the big stone of 5~10mm, then by other originals of the handstone filtered out and big stone and initial bed Material is mixed evenly by above-mentioned mass ratio, obtains initial bed mixed slurry;Finally, by initial bed mixed slurry obtained It is put into molding die, is tamped through vibration, be added to shaping mould after its preliminary solidification, then by the surface layer mixed slurry of preparation It in tool, is covered on above the initial bed of solidification, vibration is tamped, and is demoulded after standing curing molding, under natural conditions maintenance 10 days, i.e., Obtain ecological permeable bricks.The surface thickness of the ecological permeable bricks be 8mm, the initial bed with a thickness of 50mm.
Through detecting, the coefficient of permeability of ecological permeable bricks made from the present embodiment is 15mm/s, compression strength 20MPa, is resisted Rolling over intensity is about 3.7MPa.
Embodiment 2:
A kind of ecological permeable bricks, including surface layer and initial bed are present embodiments provided, the raw material of the surface layer includes pressing quality hundred Divide the following component than counting: quartz sand 75%, white cement 18%, the first additive 1%, pigment 0.5%, water 5.5%;The initial bed Raw material include following component by mass percentage: cement 10%, handstone 20%, big stone 30%, yellow ground 22%, outside second Add agent 2%, fiber 5%, cementitious material 8%, water 3%.Wherein, the first additive is antioxidant, and the second additive is water-reducing agent (wood Quality sodium sulfonate), cementitious material is domestic garbage incineration flyash, slag, alkali-activator 1:1:1 in mass ratio are mixed.
The preparation method of the ecological permeable bricks of the present embodiment, process are as follows:
Firstly, each raw material of above-mentioned surface layer is mixed evenly in mass ratio, surface layer mixed slurry is obtained;Then, by gravelstone Sub and big stone grinds big stone and handstone and is screened to its partial size after cleaning respectively, choose partial size be 1~ The handstone of 5mm, partial size are the big stone of 5~10mm, then by other originals of the handstone filtered out and big stone and initial bed Material is mixed evenly by above-mentioned mass ratio, obtains initial bed mixed slurry;Finally, by initial bed mixed slurry obtained It is put into molding die, is tamped through vibration, be added to shaping mould after its preliminary solidification, then by the surface layer mixed slurry of preparation It in tool, is covered on above the initial bed of solidification, vibration is tamped, and is demoulded after standing curing molding, under natural conditions maintenance 7 days, i.e., Obtain ecological permeable bricks.The surface thickness of the ecological permeable bricks is 6mm, and initial bed is with a thickness of 52mm.
Through detecting, the coefficients of permeability of ecological permeable bricks made from the present embodiment is 10mm/s, compression strength 38.4MPa, Flexural strength is about 5.8MPa.
Embodiment 3:
A kind of ecological permeable bricks, including surface layer and initial bed are present embodiments provided, the raw material of the surface layer includes pressing quality hundred Divide the following component than counting: quartz sand 70%, white cement 20%, the first additive 1%, pigment 1%, water 7%;The original of the initial bed Material includes following component by mass percentage: cement 10%, handstone 20%, big stone 35%, yellow ground 25%, the second additive 1%, fiber 6%, cementitious material 2%, water 1%.Wherein, the first additive is ultraviolet absorbing agent, and the second additive is water-reducing agent (wood Quality sodium sulfonate), cementitious material is domestic garbage incineration flyash, slag, alkali-activator 1:1:1 in mass ratio are mixed.
The preparation method of the ecological permeable bricks of the present embodiment, process are as follows:
Firstly, each raw material of above-mentioned surface layer is mixed evenly in mass ratio, surface layer mixed slurry is obtained;Then, by gravelstone Sub and big stone grinds big stone and handstone and is screened to its partial size after cleaning respectively, choose partial size be 1~ The handstone of 5mm, partial size are the big stone of 5~10mm, then by other originals of the handstone filtered out and big stone and initial bed Material is mixed evenly by above-mentioned mass ratio, obtains initial bed mixed slurry;Finally, by initial bed mixed slurry obtained It is put into molding die, is tamped through vibration, be added to shaping mould after its preliminary solidification, then by the surface layer mixed slurry of preparation It in tool, is covered on above the initial bed of solidification, vibration is tamped, and is demoulded after standing curing molding, under natural conditions maintenance 5 days, i.e., Obtain ecological permeable bricks.The surface thickness of the ecological permeable bricks be 5mm, the initial bed with a thickness of 55mm.
Through detecting, the coefficients of permeability of ecological permeable bricks made from the present embodiment is 12mm/s, compression strength 31.5MPa, Flexural strength is about 4.3MPa.
In conclusion this ecological permeable bricks provided by the invention are mixed and are led to using two kinds of stones of size of different-grain diameter Cross can be achieved to control the porosity of ecological permeable bricks to the ratio control of the two content, so that rainwater penetrates brick Water flow will not be too anxious and influence ground, buffer function, and its good water permeability are played to the infiltration of rainwater, and have stable Porosity, excellent compression strength and fracture resistance, compression strength reach 20~40MPa, and in higher compression strength Still there is biggish porosity.
The foregoing examples are only illustrative of the present invention, does not constitute the limitation to protection scope of the present invention, all It is within being all belonged to the scope of protection of the present invention with the same or similar design of the present invention.

Claims (7)

1. a kind of ecological permeable bricks, it is characterised in that: including surface layer and initial bed, the raw material of the surface layer includes pressing quality percentage Than the following component of meter: quartz sand 70~80%, white cement 15~20%, the first additive 0.5~2%, surplus is water;The bottom The raw material of the bed of material includes following component by mass percentage: cement 10~15%, handstone 20~25%, and big stone 30~ 35%, yellow ground 20~25%, the second additive 0.5~2%, surplus is water.
2. ecological permeable bricks as described in claim 1, it is characterised in that: the partial size of the handstone is 1~5mm, big stone Partial size be 5~10mm, the mass ratio of the handstone and big stone is 1.5:1~1.7:1.
3. ecological permeable bricks as described in claim 1, it is characterised in that: first additive is curing agent, antioxidant With one or more of ultraviolet absorbing agent mixture, the second additive is water-reducing agent.
4. ecological permeable bricks as described in claim 1, it is characterised in that: the raw material of the surface layer further includes that mass fraction is 0.5~1% pigment.
5. ecological permeable bricks as described in claim 1, it is characterised in that: the raw material of the initial bed further includes fiber and gelling Material, the cementitious material are made of domestic garbage incineration flyash, slag, alkali-activator.
6. ecological permeable bricks as described in claim 1, it is characterised in that: the surface layer with a thickness of 5~8mm, the bottom material Layer with a thickness of 50~55mm.
7. the preparation method of ecological permeable bricks as described in any one of claims 1 to 6, characterized by the following steps:
1) surface layer mixed slurry is prepared
Each raw material of surface layer is mixed evenly in mass ratio, obtains surface layer mixed slurry;
2) initial bed mixed slurry is prepared
Big stone and handstone are ground after first cleaning handstone and big stone respectively and its partial size is screened, then The handstone filtered out and big stone in mass ratio mix being mixed evenly with other raw materials of initial bed, obtained on earth Bed of material mixed slurry;
3) initial bed mixed slurry prepared by step 2) is put into molding die, is tamped through vibration, after its preliminary solidification, Surface layer mixed slurry prepared by step 1) is added in molding die again, vibration is tamped, and is demoulded after standing curing molding, natural 5~10 days are conserved under state to get ecological permeable bricks.
CN201810673696.2A 2018-06-27 2018-06-27 A kind of ecological permeable bricks and preparation method thereof Pending CN108947384A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109400040A (en) * 2018-12-19 2019-03-01 阜阳市鑫源建材有限公司 A kind of anti-blocking water-permeable brick and preparation method thereof
CN113277802A (en) * 2021-05-24 2021-08-20 杭州三中新型建材科技有限公司 High-permeability concrete using recycled aggregate and preparation method thereof
CN114393672A (en) * 2022-01-21 2022-04-26 广元城建高新建材有限公司 Production process of ecological water permeable brick
CN115490478A (en) * 2022-09-26 2022-12-20 广东四通建材股份有限公司 High-strength stone-like water permeable brick and preparation method thereof

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN109400040A (en) * 2018-12-19 2019-03-01 阜阳市鑫源建材有限公司 A kind of anti-blocking water-permeable brick and preparation method thereof
CN113277802A (en) * 2021-05-24 2021-08-20 杭州三中新型建材科技有限公司 High-permeability concrete using recycled aggregate and preparation method thereof
CN114393672A (en) * 2022-01-21 2022-04-26 广元城建高新建材有限公司 Production process of ecological water permeable brick
CN115490478A (en) * 2022-09-26 2022-12-20 广东四通建材股份有限公司 High-strength stone-like water permeable brick and preparation method thereof

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