Background technique
Granite is the significant rock in continent, is the basis for constituting continent upper crust, it can be seen that the storage of granite
Amount is abundant, and most of granite is due to lacking effective development and utilization, at present still in state to be developed, even if having small part
Also it is only cut, polishing for selectivity through developing and using, is used as the foundation stone, square brick or the rank built of road
Stone.These products not only bad environments in the production process but also product matter produced is honest and clean at a low price, added value is not high,
Result in waste of resources it is serious, hidden danger is also constituted to ecological environment.
Granite is main still by quartz and orthoclase and microcline and other impurity components although complicated component:
Hornblend, tourmaline, mica etc. are constituted.And the utilization and exploitation of single quartz, spectra, domestic technique more at
It is ripe, and granite is rarely had as a kind of research that mineral are comprehensively utilized and report and is heard of.Analyze its reason, it may be possible to
Using granite only as a kind of Mineral pairs as being compared with quartz, SiO2Content is inadequate to be compared with feldspar ore, K2O、Na2O and Al2O3
Content is again relatively low, and the requirement of downstream product is not achieved in impurity content exceeding index, whiteness.According in its mineralogical composition based on feldspar
The characteristics of, it, not only can be because of mica in granite if removing mica using flotation using the method for previous feldspar ore conventional purification
Content is higher, causes reagent cost high, environmental protection pressure is big.In addition similarly there is difficulty in the separation of feldspar and quartz.Thus, to the greatest extent
Pipe rich reserves, but the domestic research to granite comprehensive utilization is still in blank.
Quartz, feldspar, mica occupy very important position in entire nonmetallic ore, their application is related to building
It builds, ceramics, electronics, the various fields such as space flight allow if can be effectively separated quartz, feldspar and the mica in granite
They have respectively entered respective field and make the most of the advantage, and will be major issues that part is benefited the nation and the people.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of method of comprehensive utilization of granite, can be by flower by this method
Quartz, feldspar, mica in the rock of hilllock are effectively separated, and are purified during separation, to reach comprehensive utilization
Purpose.
This method specifically includes that steps are as follows:
(1) granite is subjected to two sections of broken-screening closed circuit flows, obtains the granite granules of 1~4mm and the sieve of -1mm
Lower object;
(2) granite granules of 1~4mm are subjected to dry type magnetic separation, obtain biotite and magnetic tailing;
(3) magnetic tailing is subjected to color sorting, obtains that black stone English is rough, and the rough and white feldspar of red feldspar is rough;
(4) the black stone English obtained step (3) color sorting is rough, using rod mill ore grinding-screening closed circuit flow, hydraulic classiciation
Machine classification, material size is controlled in 40~180 mesh, is passed sequentially through magnetomechanical in vertical ring and is removed machinery iron and strongly magnetic mineral, then
By founding the strong magnetomechanical of ring, weak magnetic mineral is removed, obtains black quartz concentrate, weak magnetic mineral and strongly magnetic mineral, which merge, becomes magnetic
Property mineral one;
(5) that step (3) color sorting is obtained red feldspar is rough, by ball mill ore grinding, then by hydraulic classifier and is obstructed
Settler controls material size between 60-120 mesh, after the overflow concentration of hydraulic classifier, is sieved by high frequency shale shaker,
On-the-sieve material is fine fraction mica one, and lower sieve is fine fraction feldspar one;Fine fraction mica one and fine fraction feldspar one pass sequentially through
Vertical ring magnetomechanical grade magnetic separation, remove respectively mixed machinery iron and strongly magnetic mineral in mineral process, biotite, tourmaline and
Weak magnetic mineral, the product after magnetic separation obtain high potassium feldspar concentrate, magnetic separation obtains by concentration, band filter filtering, drying
All magnetic minerals merge, become magnetic mineral two;
(6) screenings for the rough -1mm obtained with step (1) of white feldspar that step (3) color sorting obtains is mixed, is passed through
Ball mill ore grinding recycles hydraulic classifier and hindered settling device that material size is controlled the hydraulic classiciation between 60-120 mesh
After the overflow concentration of machine, to be sieved by high frequency shale shaker, on-the-sieve material is fine fraction mica two, and lower sieve is fine fraction feldspar two,
Fine fraction mica two and fine fraction feldspar two pass sequentially through vertical ring magnetomechanical grade magnetic separation, remove respectively mixed in mineral process
Machinery iron and strongly magnetic mineral, biotite, tourmaline and weak magnetic mineral, the product after magnetic separation pass through concentration, belt type filter
Machine filtering, drying, obtain potassium sodium anemonsite concentrate, and all magnetic minerals that magnetic separation obtains merge, and become magnetic mineral three;
(7) fine fraction cloud obtained in fine fraction mica one, fine fraction feldspar one obtained in step (5) and step (6)
Dust caused by during mother two, fine fraction feldspar two and crushing and screening, dry type magnetic separation, color sorting, which merges, becomes fine fraction object
Material, after fine particle stage material is mixed, adds water with slurry, successively strong using magnetomechanical, vertical ring in vertical ring by agitator stirring, homogenizing
Magnetic separator, slurry formula magnetic separator magnetic separation purification are obtained thin using plate and frame filter press filters pressing, drying after the product concentration after magnetic separation
The feldspar concentrate of grade, all magnetic minerals that magnetic separation obtains merge, and become magnetic mineral four;
(8) magnetic for obtaining magnetic separation mineral two that magnetic separation mineral one that step (4) obtains, step (5) obtain, step (6)
It after the magnetic separation mineral four that ore dressing object three and step (7) obtain merge, is concentrated using thickening cone, after vibrating screen dehydration, concentrates and stack,
As cement plant, the ingredient of brick field.
Wherein, dry type magnetic separation uses dry type roll-type magnetic separator in step (2), and dry type roll-type magnetic separator surface field strength is
11000Gs。
Step (4) the neutrality strong magnetomechanical background lectromagnetism field of ring is 1.5T.
Ball mill is all made of quartz ball and quartzy liner plate in step (5) and step (6), founds the ambient field of ring magnetomechanical grade magnetic separation
It is followed successively by 0.4T, 1.0T and 1.5T by force.
Magnetomechanical magnetic field strength is 0.4T in step (7) neutrality ring, and Verticle ring high intensity magnetic separator magnetic field strength is 1.3T, slurry formula magnetic
Selecting machine magnetic field strength is 1.3T.
The overflow of all concentration links and the dewatered filtrate of vibrating screen and other waste water enter dense in above-mentioned steps
Machine concentration, concentrator overflow water is as recycling water utilization, after thickener underflow passes through plate and frame type filter-press filters pressing, as cement, brick
The ingredient product of factory.
The advantageous effects of the above technical solutions of the present invention are as follows:
The present invention is crushed-sieves closed circuit, impacting vertical crusher sand using two sections, dry type magnetic separation sorts biotite,
The method that color sorting separation black stone English and high potassium feldspar, multi-stage magnetic separation purify respectively makes granite mineral reach comprehensive utilization
Purpose, the present invention have a characteristic that
1, after two sections of the present invention is broken, using impacting vertical crusher sand, not only make granite granularity required
In the range of wanting, and granularity is relatively uniform, particle shape is preferable, the mechanical contamination of introducing is less.
2,90% or more biotite is pre-separated out using dry type magnetic separation before color sorting, is cleared away for subsequent color sorting operation
Obstacle.
3, using secondary color sorting, the biggish black stone English of color difference, the red feldspar of high potassium have been isolated, it is little to color difference
Mineral grain as potassium sodium composite ore processing.
4, to the processing mode of biotite in the present invention are as follows: dry type magnetic separation, hydraulic classiciation, the vertical triple guarantees of ring high intensity magnetic separation,
Ensure that mica can remove thoroughly in feldspar.
5, andesine ore grinding of the present invention is all made of quartz ball and quartzy liner plate, avoids mechanical contamination, reduces previous height
The fine slag of aluminium ball or middle aluminium ball is on influencing caused by subsequent Ceramic manufacturing.
6, the fine particle stage material in feldspar is separately separated out, merging treatment utilizes magnetic in vertical-ring magnetic separator by the present invention
Cooperate with strong-magnetism gradient, is finally checked on for the thin feature of material using slurry magnetic separator, the particulate for finally making high quality is long
Stone concentrate.
7, ore dressing employed in the present invention, method of purification are physical method, are generated without exhaust gas, to the powder of each operation
Dirt, waste water have all carried out rationalization processing, and production environment is friendly, are truly realized " green production ".
The present invention is not limited by production scale, after valuable mineral ingredient quartz, mica, the feldspar in granite are separated,
Carry out purification respectively to achieve the purpose that comprehensive utilization.
Specific embodiment
To keep the technical problem to be solved in the present invention, technical solution and advantage clearer, below in conjunction with specific implementation
Example is described in detail.
The present invention provides a kind of method of comprehensive utilization of granite.
In the specific implementation process, steps are as follows for this method:
1, broken-processed sand: granite is passed through into jaw crusher coarse crushing, linear vibrating screen screening, oversize returns thick
Broken, it is fine crushing to enter gyratory crusher for (- 3cm) product under sieve, is sieved again using linear vibrating screen, and oversize is back to carefully
It is broken, the fine ore of the left and right (- 1.3cm) under sieve, into impacting vertical crusher, and by linear vibrating screen screening, obtain 1~
The granite granules of 4mm and the screenings of -1mm.The particle of 1~4mm enters dry type magnetic separation;The screenings of -1mm is as particulate
Grade material processing.
2, the granite granules of 1~4mm uniformly dry type magnetic separation: are given to dry type roll-type magnetic separator (table by distributing device
Face field strength is 11000Gs), sub-elect the biotite of sheet.
3, color sorting: carrying out a color sorting for dry type magnetic separation tailing, obtains black stone English composite ore and feldspar composite ore, and two kinds mixed
It closes mine and carries out secondary color sorting respectively, the concentrate that secondary color sorting obtains is respectively that the rough and red feldspar of black stone English is rough (hereinafter referred to as
For High potassium mineral), tailing merge become white feldspar it is rough (hereinafter referred to as potassium sodium composite ore).
4, black stone English purifies: the black stone English that color sorting is obtained is rough, using on rod mill ore grinding-screening closed circuit flow, sieve
Material return is regrinded, and undersize material enters hydraulic classifier classification, and material size is controlled in 40~180 mesh, is passed sequentially through vertical
Magnetomechanical removes machinery iron and strongly magnetic mineral in ring, then by standing the strong magnetomechanical (background lectromagnetism field 1.5T) of ring, removes in mineral
Weak magnetic mineral obtains black quartz concentrate, and middle magnetic and strongly magnetic mineral, which merge, becomes magnetic mineral 1.
5, high potassium feldspar purification: color sorting is obtained into High potassium mineral, (is served as a contrast using quartz ball and quartz by ball mill ore grinding
Plate), material size is controlled between 60-120 mesh by hydraulic classifier and hindered settling device, the overflow of hydraulic classifier is dense
It after contracting, is sieved by high frequency shale shaker, on-the-sieve material is fine fraction mica 1, and lower sieve is fine fraction feldspar (hereinafter referred to as particulate
Grade feldspar 1).The material of 60-120 mesh passes sequentially through vertical-ring magnetic separator magnetic separation, background lectromagnetism field is followed successively by 0.4T, 1.0T and 1.5T,
It is removed in mineral process respectively in mixed machinery iron and strongly magnetic mineral, a small amount of biotite, tourmaline and mineral
Fe2O3Equal weak magnetic minerals, the product after magnetic separation obtain high potassium feldspar concentrate by concentration, band filter filtering, drying.
All magnetic minerals merge, become magnetic mineral 2.
6, potassium sodium composite ore purifies: the minus mesh of -1mm of potassium sodium mixed mineral and aggregate reclaiming section that color sorting is obtained
Mixing, by ball mill ore grinding (using quartz ball and quartzy liner plate), by hydraulic classifier and hindered settling device by material grain
Degree control after the overflow concentration of hydraulic classifier, is sieved, on-the-sieve material is particulate between 60-120 mesh by high frequency shale shaker
Grade mica 2, lower sieve is fine fraction feldspar (hereinafter referred to as fine fraction feldspar 2).The material of 60-120 mesh passes sequentially through vertical ring magnetic
The magnetic separation of machine grade, background lectromagnetism field are followed successively by 0.4T, 1.0T and 1.5T, remove in mineral process mixed machinery iron and strong respectively
Fe in magnetic mineral, a small amount of biotite, tourmaline and mineral2O3Equal weak magnetic minerals, product after magnetic separation by concentration,
Band filter filtering, drying, obtain potassium sodium anemonsite concentrate.All magnetic minerals merge, become magnetic mineral 3.
7, fine particle stage material purifies: the group of fine particle stage material becomes generated fine fraction object in high potassium material purification process
In material 1 and potassium sodium composite ore purification process during generated fine particle stage material 2 and crushing and screening, dry type magnetic separation, color sorting
Generated dust.After this partial material is mixed, add water with slurry, by agitator stirring, homogenizing, using successively using vertical ring
Middle magnetomechanical (0.4T), Verticle ring high intensity magnetic separator (1.3T), slurry formula magnetic separator (1.3T) magnetic separation purification, after the product concentration after magnetic separation
Using plate and frame filter press filters pressing, drying, fine-graded feldspar concentrate is just obtained.All magnetic minerals merge, become magnetic mineral
4。
8, the processing of magnetic mineral: the obtained magnetic of magnetic separation section in the predominantly above four kinds of material purification process of magnetic mineral
Property mineral, main strongly magnetic mineral and tourmaline, mica comprising in machinery iron and mineral introduced in process
Equal weak magnetic minerals, after this kind of mineral collect, are concentrated using thickening cone, after vibrating screen dehydration, are concentrated and are stacked, product can be used as water
Mud factory, brick field ingredient.
9, in this technique the overflows of all concentration links and the dewatered filtrate of vibrating screen and other waste water enter it is dense
Machine concentration, concentrator overflow water is as recycling water utilization, after thickener underflow passes through plate and frame type filter-press filters pressing, as cement, brick
The ingredient product of factory.
Certain granite is studied with method of the invention, products obtained therefrom Contents of Main Components and purposes are as follows:
The above is a preferred embodiment of the present invention, it is noted that for those skilled in the art
For, without departing from the principles of the present invention, several improvements and modifications can also be made, these improvements and modifications
It should be regarded as protection scope of the present invention.