CN108929656A - A kind of ground anti-skid preparation - Google Patents
A kind of ground anti-skid preparation Download PDFInfo
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- C09K3/149—Antislip compositions
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Abstract
The invention discloses a kind of ground anti-skid preparations, including below according to the raw material of parts by weight: 3-7 parts of Glycolic acid, 12-22 parts of acetic acid, 10-18 parts of grape acid, 10-18 parts of 2 hydroxy propanoic acid, 6-12 parts of surfactant, 3-7 parts of sodium chloride, 0.2-0.6 parts of propylene glycol, 3-7 parts of dihydromethyl propionic acid, 0.01-0.05 parts of sodium tripolyphosphate, 2.4-3.4 parts of modified meerschaum, 1.5-3 parts of pandermite, 0.04-0.16 parts of lauryl sodium sulfate, 0.1-0.3 parts of methylhydroxy silicone oil and 20-40 parts of deionized water.The dry and wet state coefficient of friction of ground anti-skid preparation of the present invention, floor tile is significantly improved, and does not influence floor tile color and brightness, and antiskid effect can be kept for a long time.
Description
Technical field
The present invention relates to building material technical fields, more particularly, to a kind of ground anti-skid preparation.
Background technique
With the continuous improvement of people's living standards, the safety to itself also starts increasingly to pay attention to, especially this several years
About between household sanitation, school, hotel, food and drink, hospital, station, many public places such as business unit dining room because ground is wet
Tumble injury event caused by cunning repeated, or even death by accident occurs, especially old man and children.It unites according to health ministry
Meter, China's tumble injury accident that slips every year has been more than tens million of, causes economic loss and moral injury to countless families.
Currently, all kinds of public places and at home in finishing, for all habitually practical ceramics of landscaping effect
Floor tile, polished bricks, glazed tile, Antique Imitation Tiles and marble etc. are used as floor decorative material, although seeming magnificent beauty,
Under cover huge security risk, especially in the case where encountering the liquid such as rainwater, humidity, grease stain, dish washing liquid, shower cream,
Tumble injury accident occurs again and again, or even relevant unit is needed to compensate huge indemnity.According to there is shutting mechanism in recent years to Chinese Ceramics Enterprises
Non-skid property is sampled investigation discovery, has the ceramic tile non-skid property of 95% Ceramics Enterprises production unqualified, or even have big
Type enterprise and well-known famous brand are also in this way, maximum coefficient of friction just reaches 0.4 in sample, and the smallest is 0.2, is below country
The 0.5 of safety standard requirement.
The patent of publication number CN108247433A discloses a kind of surface treatment method of Dali stone ceramic tile, including following step
Rapid: (1) by polished and edging, treated that Dali stone ceramic tile is filled waxing processing；(2) to filling waxing in step (1)
Marble ceramic tile surface afterwards carries out anti-skidding processing；(3) the Dali stone ceramic tile of anti-skidding processing in step (2) soft throwing is carried out to beat
Wax.The existing anti-skidding processing of waxing is only capable of directly promoting the friction system of floor tile drying regime in floor tile Surface mulch coating of wax film
Number, but coefficient of friction can sharply decline when floor tile chance water or chance oil；As time increases, it walks or cleans or damage
Cere layer, antiskid effect are difficult to persistently.
Summary of the invention
In view of this, in view of the deficiencies of the prior art, it is an object of the present invention to provide a kind of ground anti-skid preparation, floor tile
Dry and wet state coefficient of friction is significantly improved, and does not influence floor tile color and brightness, and antiskid effect can be kept for a long time.
In order to achieve the above objectives, the invention adopts the following technical scheme: a kind of ground anti-skid preparation, including below according to weight
The raw material of amount part: 3-7 parts of Glycolic acid, 12-22 parts of acetic acid, 10-18 parts of grape acid, 10-18 parts of 2 hydroxy propanoic acid, surfactant
6-12 parts, 3-7 parts of sodium chloride, 0.2-0.6 parts of propylene glycol, 3-7 parts of dihydromethyl propionic acid, 0.01-0.05 parts of sodium tripolyphosphate, change
2.4-3.4 parts of sepiolite of property, 1.5-3 parts of pandermite, 0.04-0.16 parts of lauryl sodium sulfate, methylhydroxy silicone oil 0.1-
0.3 part and 20-40 parts of deionized water；
The surfactant is the ratio that neopelex and fatty alcohol polyoxyethylene ether are 2:1 according to weight ratio
Example mixes；
The manufacture craft of the modified meerschaum is according to parts by weight to weigh sepiolite powder and be broken to 20 mesh to be placed on 18 times of bodies
In long-pending modification liquid, carried out with being sent into ultrasonic cell disruptor after the revolving speed progress high speed shear processing 40min of 7000rpm
Ultrasonic treatment, is then centrifuged with the rate of 8000r/min, is dried in vacuo at 50 DEG C after removing supernatant liquor
36h, be ground to 600 mesh to get；
It according to weight ratio is 1:2:6000's that the modification liquid, which is sodium sulfate of polyethenoxy ether of fatty alcohol, sodium citrate and water,
Ratio mixes；
The power of the ultrasonic treatment is 1000W；The time of the ultrasonic treatment is 80min.
Further, including below according to the raw material of parts by weight: 4-6 parts of Glycolic acid, 15-20 parts of acetic acid, grape acid 12-16
Part, 12-16 parts of 2 hydroxy propanoic acid, 8-10 parts of surfactant, 4-6 parts of sodium chloride, 0.3-0.5 parts of propylene glycol, dihydroxymethyl third
It is 4-6 parts sour, 0.02-0.04 parts of sodium tripolyphosphate, 2.8-3.2 parts of modified meerschaum, 2-2.5 parts of pandermite, dodecyl sulphur
Sour sodium 0.08-0.12 parts, 0.15-0.25 parts of methylhydroxy silicone oil and 25-33 parts of deionized water.
Further, including below according to the raw material of parts by weight: 5 parts of Glycolic acid, 16 parts of acetic acid, 14 parts of grape acid, 2- hydroxyl
15 parts of base propionic acid, 9 parts of surfactant, 5 parts of sodium chloride, 0.4 part of propylene glycol, 5 parts of dihydromethyl propionic acid, sodium tripolyphosphate 0.03
Part, 3 parts of modified meerschaum, 2.2 parts of pandermite, 0.1 part of lauryl sodium sulfate, 0.2 part of methylhydroxy silicone oil, and go from
28 parts of sub- water.
The beneficial effects of the present invention are:
Ground anti-skid preparation of the present invention has good antiskid effect, and the anti-skid factor on treated ground is high, by sweet
The cooperation of a variety of acid such as alkyd, acetic acid, grape acid and 2 hydroxy propanoic acid, reduces the destruction to ground；Meanwhile passing through modified sea
Afrodite and pandermite play corrosion inhibition, effectively slow down the chemical reaction with ground, are conducive to the infiltration of ground anti-skid preparation
It carries out dissolving a small amount of silicon in the pore of floor tile and stone material, forms nanoscale dent on surface, and then improve friction system
Number；Ground anti-skid preparation of the present invention also passes through modified meerschaum and pandermite cooperates, and assisting ultrasonic decentralized processing, rises
Synergistic effect has been arrived, stability is good, the durability of ground anti-skid preparation can be effectively improved, with the extension of time,
Antiskid effect remains to effectively keep, and has a vast market foreground.Anti-skid preparation safety non-pollution in ground of the present invention, after processing not
Influence the normal use of unit and house.
Detailed description of the invention
Attached drawing 1 is the marble surface schematic enlarged-scale view without anti-skidding processing；
Attached drawing 2 is the marble surface structure amplification that anti-skidding processing is carried out by ground anti-skid preparation prepared by embodiment 7
Figure.
Specific embodiment
The following is specific embodiments of the present invention, and technical scheme of the present invention will be further described, but the present invention is simultaneously
It is not limited to these embodiments.
Embodiment 1
A kind of ground anti-skid preparation, including below according to the raw material of parts by weight: 3 parts of Glycolic acid, 12 parts of acetic acid, grape acid 10
Part, 10 parts of 2 hydroxy propanoic acid, 6 parts of surfactant, 3 parts of sodium chloride, 0.2 part of propylene glycol, 3 parts of dihydromethyl propionic acid, trimerization phosphorus
0.01 part of sour sodium, 2.4 parts of modified meerschaum, 1.5 parts of pandermite, 0.04 part of lauryl sodium sulfate, methylhydroxy silicone oil 0.1
Part and 20 parts of deionized water.
Wherein, it according to weight ratio is 2 that the surfactant, which is neopelex and fatty alcohol polyoxyethylene ether:
1 ratio mixes；The manufacture craft of the modified meerschaum is to weigh sepiolite powder according to parts by weight to be broken to 20 mesh postpositions
In the modification liquid of 18 times of volumes, supersonic cell crushing is sent into after carrying out high speed shear processing 40min with the revolving speed of 7000rpm
It is ultrasonically treated in machine, is then centrifuged with the rate of 8000r/min, carried out at 50 DEG C after removing supernatant liquor
Be dried in vacuo 36h, be ground to 600 mesh to get；The modification liquid is sodium sulfate of polyethenoxy ether of fatty alcohol, sodium citrate and water
It is mixed according to the ratio that weight ratio is 1:2:6000；The power of the ultrasonic treatment is 1000W；The ultrasonic treatment when
Between be 80min；By being modified processing to sepiolite, sepiolite is subjected to removing and forms nanoscale layer structure, is effectively subtracted
Delay the chemical reaction on ground anti-skid preparation and ground, and then advantageously formed nanoscale dent, effectively increases coefficient of friction；
In the present embodiment, the manufacture craft of the ground anti-skid preparation, specifically includes the following steps:
1) sodium chloride and deionized water are weighed according to parts by weight, is stirred after mixing with the stirring rate of 300r/min
8min is mixed, mixture A is obtained；
2) pandermite being weighed according to parts by weight and being crushed to 200 mesh, modified meerschaum is then added and is uniformly mixed, must mix
Expect B；
3) it weighs surfactant according to parts by weight to be added into mixture A obtained in step 1), with 400r/min's
Stirring rate is stirred 5min, and Glycolic acid, acetic acid, grape acid, 2 hydroxy propanoic acid, propylene glycol, dihydroxymethyl third is then added
Acid and sodium tripolyphosphate, are stirred 8min with the stirring rate of 350r/min, obtain mixture C；
4) mixture B obtained in step 2) is added into mixture C obtained in step 3), with stirring for 250r/min
It mixes rate and is stirred 4min, then carry out ultrasonic disperse processing, obtain mixture D；
Wherein, the supersonic frequency of the ultrasonic disperse processing is 15kHz；The time of the ultrasonic disperse processing is 10min；
It is handled by ultrasonic disperse, effectively increases material dispersion effect, and then be conducive to improve the antiskid effect of ground anti-skid preparation；
5) methylhydroxy silicone oil and dodecyl sulphate will be sequentially added while stirring in mixture D obtained in step 4)
Sodium, then with the stirring rate of 300r/min be stirred 12min to get.
Embodiment 2
A kind of ground anti-skid preparation, including below according to the raw material of parts by weight: 7 parts of Glycolic acid, 22 parts of acetic acid, grape acid 18
Part, 18 parts of 2 hydroxy propanoic acid, 12 parts of surfactant, 7 parts of sodium chloride, 0.6 part of propylene glycol, 7 parts of dihydromethyl propionic acid, trimerization phosphorus
0.05 part of sour sodium, 3.4 parts of modified meerschaum, 3 parts of pandermite, 0.16 part of lauryl sodium sulfate, methylhydroxy silicone oil 0.3
Part and 40 parts of deionized water.
Wherein, it according to weight ratio is 2 that the surfactant, which is neopelex and fatty alcohol polyoxyethylene ether:
1 ratio mixes；The manufacture craft of the modified meerschaum is to weigh sepiolite powder according to parts by weight to be broken to 20 mesh postpositions
In the modification liquid of 18 times of volumes, supersonic cell crushing is sent into after carrying out high speed shear processing 40min with the revolving speed of 7000rpm
It is ultrasonically treated in machine, is then centrifuged with the rate of 8000r/min, carried out at 50 DEG C after removing supernatant liquor
Be dried in vacuo 36h, be ground to 600 mesh to get；The modification liquid is sodium sulfate of polyethenoxy ether of fatty alcohol, sodium citrate and water
It is mixed according to the ratio that weight ratio is 1:2:6000；The power of the ultrasonic treatment is 1000W；The ultrasonic treatment when
Between be 80min；By being modified processing to sepiolite, sepiolite is subjected to removing and forms nanoscale layer structure, is effectively subtracted
Delay the chemical reaction on ground anti-skid preparation and ground, and then advantageously formed nanoscale dent, effectively increases coefficient of friction；
In the present embodiment, the manufacture craft of the ground anti-skid preparation, specifically includes the following steps:
1) sodium chloride and deionized water are weighed according to parts by weight, is stirred after mixing with the stirring rate of 300r/min
8min is mixed, mixture A is obtained；
2) pandermite being weighed according to parts by weight and being crushed to 200 mesh, modified meerschaum is then added and is uniformly mixed, must mix
Expect B；
3) it weighs surfactant according to parts by weight to be added into mixture A obtained in step 1), with 400r/min's
Stirring rate is stirred 5min, and Glycolic acid, acetic acid, grape acid, 2 hydroxy propanoic acid, propylene glycol, dihydroxymethyl third is then added
Acid and sodium tripolyphosphate, are stirred 8min with the stirring rate of 350r/min, obtain mixture C；
4) mixture B obtained in step 2) is added into mixture C obtained in step 3), with stirring for 250r/min
It mixes rate and is stirred 4min, then carry out ultrasonic disperse processing, obtain mixture D；
Wherein, the supersonic frequency of the ultrasonic disperse processing is 15kHz；The time of the ultrasonic disperse processing is 10min；
It is handled by ultrasonic disperse, effectively increases material dispersion effect, and then be conducive to improve the antiskid effect of ground anti-skid preparation；
5) methylhydroxy silicone oil and dodecyl sulphate will be sequentially added while stirring in mixture D obtained in step 4)
Sodium, then with the stirring rate of 300r/min be stirred 12min to get.
Embodiment 3
A kind of ground anti-skid preparation, including below according to the raw material of parts by weight: 5 parts of Glycolic acid, 17 parts of acetic acid, grape acid 14
Part, 14 parts of 2 hydroxy propanoic acid, 9 parts of surfactant, 5 parts of sodium chloride, 0.4 part of propylene glycol, 5 parts of dihydromethyl propionic acid, trimerization phosphorus
0.03 part of sour sodium, 2.9 parts of modified meerschaum, 2.25 parts of pandermite, 0.1 part of lauryl sodium sulfate, methylhydroxy silicone oil 0.2
Part and 30 parts of deionized water.
Wherein, it according to weight ratio is 2 that the surfactant, which is neopelex and fatty alcohol polyoxyethylene ether:
1 ratio mixes；The manufacture craft of the modified meerschaum is to weigh sepiolite powder according to parts by weight to be broken to 20 mesh postpositions
In the modification liquid of 18 times of volumes, supersonic cell crushing is sent into after carrying out high speed shear processing 40min with the revolving speed of 7000rpm
It is ultrasonically treated in machine, is then centrifuged with the rate of 8000r/min, carried out at 50 DEG C after removing supernatant liquor
Be dried in vacuo 36h, be ground to 600 mesh to get；The modification liquid is sodium sulfate of polyethenoxy ether of fatty alcohol, sodium citrate and water
It is mixed according to the ratio that weight ratio is 1:2:6000；The power of the ultrasonic treatment is 1000W；The ultrasonic treatment when
Between be 80min；By being modified processing to sepiolite, sepiolite is subjected to removing and forms nanoscale layer structure, is effectively subtracted
Delay the chemical reaction on ground anti-skid preparation and ground, and then advantageously formed nanoscale dent, effectively increases coefficient of friction；
In the present embodiment, the manufacture craft of the ground anti-skid preparation, specifically includes the following steps:
1) sodium chloride and deionized water are weighed according to parts by weight, is stirred after mixing with the stirring rate of 300r/min
8min is mixed, mixture A is obtained；
2) pandermite being weighed according to parts by weight and being crushed to 200 mesh, modified meerschaum is then added and is uniformly mixed, must mix
Expect B；
3) it weighs surfactant according to parts by weight to be added into mixture A obtained in step 1), with 400r/min's
Stirring rate is stirred 5min, and Glycolic acid, acetic acid, grape acid, 2 hydroxy propanoic acid, propylene glycol, dihydroxymethyl third is then added
Acid and sodium tripolyphosphate, are stirred 8min with the stirring rate of 350r/min, obtain mixture C；
4) mixture B obtained in step 2) is added into mixture C obtained in step 3), with stirring for 250r/min
It mixes rate and is stirred 4min, then carry out ultrasonic disperse processing, obtain mixture D；
Wherein, the supersonic frequency of the ultrasonic disperse processing is 15kHz；The time of the ultrasonic disperse processing is 10min；
It is handled by ultrasonic disperse, effectively increases material dispersion effect, and then be conducive to improve the antiskid effect of ground anti-skid preparation；
5) methylhydroxy silicone oil and dodecyl sulphate will be sequentially added while stirring in mixture D obtained in step 4)
Sodium, then with the stirring rate of 300r/min be stirred 12min to get.
Embodiment 4
A kind of ground anti-skid preparation, including below according to the raw material of parts by weight: 4 parts of Glycolic acid, 15 parts of acetic acid, grape acid 12
Part, 12 parts of 2 hydroxy propanoic acid, 8 parts of surfactant, 4 parts of sodium chloride, 0.3 part of propylene glycol, 4 parts of dihydromethyl propionic acid, trimerization phosphorus
0.02 part of sour sodium, 2.8 parts of modified meerschaum, 2 parts of pandermite, 0.08 part of lauryl sodium sulfate, methylhydroxy silicone oil 0.15
Part and 25 parts of deionized water.
Wherein, it according to weight ratio is 2 that the surfactant, which is neopelex and fatty alcohol polyoxyethylene ether:
1 ratio mixes；The manufacture craft of the modified meerschaum is to weigh sepiolite powder according to parts by weight to be broken to 20 mesh postpositions
In the modification liquid of 18 times of volumes, supersonic cell crushing is sent into after carrying out high speed shear processing 40min with the revolving speed of 7000rpm
It is ultrasonically treated in machine, is then centrifuged with the rate of 8000r/min, carried out at 50 DEG C after removing supernatant liquor
Be dried in vacuo 36h, be ground to 600 mesh to get；The modification liquid is sodium sulfate of polyethenoxy ether of fatty alcohol, sodium citrate and water
It is mixed according to the ratio that weight ratio is 1:2:6000；The power of the ultrasonic treatment is 1000W；The ultrasonic treatment when
Between be 80min；By being modified processing to sepiolite, sepiolite is subjected to removing and forms nanoscale layer structure, is effectively subtracted
Delay the chemical reaction on ground anti-skid preparation and ground, and then advantageously formed nanoscale dent, effectively increases coefficient of friction；
In the present embodiment, the manufacture craft of the ground anti-skid preparation, specifically includes the following steps:
1) sodium chloride and deionized water are weighed according to parts by weight, is stirred after mixing with the stirring rate of 300r/min
8min is mixed, mixture A is obtained；
2) pandermite being weighed according to parts by weight and being crushed to 200 mesh, modified meerschaum is then added and is uniformly mixed, must mix
Expect B；
3) it weighs surfactant according to parts by weight to be added into mixture A obtained in step 1), with 400r/min's
Stirring rate is stirred 5min, and Glycolic acid, acetic acid, grape acid, 2 hydroxy propanoic acid, propylene glycol, dihydroxymethyl third is then added
Acid and sodium tripolyphosphate, are stirred 8min with the stirring rate of 350r/min, obtain mixture C；
4) mixture B obtained in step 2) is added into mixture C obtained in step 3), with stirring for 250r/min
It mixes rate and is stirred 4min, then carry out ultrasonic disperse processing, obtain mixture D；
Wherein, the supersonic frequency of the ultrasonic disperse processing is 15kHz；The time of the ultrasonic disperse processing is 10min；
It is handled by ultrasonic disperse, effectively increases material dispersion effect, and then be conducive to improve the antiskid effect of ground anti-skid preparation；
5) methylhydroxy silicone oil and dodecyl sulphate will be sequentially added while stirring in mixture D obtained in step 4)
Sodium, then with the stirring rate of 300r/min be stirred 12min to get.
Embodiment 5
A kind of ground anti-skid preparation, including below according to the raw material of parts by weight: 6 parts of Glycolic acid, 20 parts of acetic acid, grape acid 16
Part, 16 parts of 2 hydroxy propanoic acid, 10 parts of surfactant, 6 parts of sodium chloride, 0.5 part of propylene glycol, 6 parts of dihydromethyl propionic acid, trimerization phosphorus
0.04 part of sour sodium, 3.2 parts of modified meerschaum, 2.5 parts of pandermite, 0.12 part of lauryl sodium sulfate, methylhydroxy silicone oil
0.25 part and 33 parts of deionized water.
Wherein, it according to weight ratio is 2 that the surfactant, which is neopelex and fatty alcohol polyoxyethylene ether:
1 ratio mixes；The manufacture craft of the modified meerschaum is to weigh sepiolite powder according to parts by weight to be broken to 20 mesh postpositions
In the modification liquid of 18 times of volumes, supersonic cell crushing is sent into after carrying out high speed shear processing 40min with the revolving speed of 7000rpm
It is ultrasonically treated in machine, is then centrifuged with the rate of 8000r/min, carried out at 50 DEG C after removing supernatant liquor
Be dried in vacuo 36h, be ground to 600 mesh to get；The modification liquid is sodium sulfate of polyethenoxy ether of fatty alcohol, sodium citrate and water
It is mixed according to the ratio that weight ratio is 1:2:6000；The power of the ultrasonic treatment is 1000W；The ultrasonic treatment when
Between be 80min；By being modified processing to sepiolite, sepiolite is subjected to removing and forms nanoscale layer structure, is effectively subtracted
Delay the chemical reaction on ground anti-skid preparation and ground, and then advantageously formed nanoscale dent, effectively increases coefficient of friction；
In the present embodiment, the manufacture craft of the ground anti-skid preparation, specifically includes the following steps:
1) sodium chloride and deionized water are weighed according to parts by weight, is stirred after mixing with the stirring rate of 300r/min
8min is mixed, mixture A is obtained；
2) pandermite being weighed according to parts by weight and being crushed to 200 mesh, modified meerschaum is then added and is uniformly mixed, must mix
Expect B；
3) it weighs surfactant according to parts by weight to be added into mixture A obtained in step 1), with 400r/min's
Stirring rate is stirred 5min, and Glycolic acid, acetic acid, grape acid, 2 hydroxy propanoic acid, propylene glycol, dihydroxymethyl third is then added
Acid and sodium tripolyphosphate, are stirred 8min with the stirring rate of 350r/min, obtain mixture C；
4) mixture B obtained in step 2) is added into mixture C obtained in step 3), with stirring for 250r/min
It mixes rate and is stirred 4min, then carry out ultrasonic disperse processing, obtain mixture D；
Wherein, the supersonic frequency of the ultrasonic disperse processing is 15kHz；The time of the ultrasonic disperse processing is 10min；
It is handled by ultrasonic disperse, effectively increases material dispersion effect, and then be conducive to improve the antiskid effect of ground anti-skid preparation；
5) methylhydroxy silicone oil and dodecyl sulphate will be sequentially added while stirring in mixture D obtained in step 4)
Sodium, then with the stirring rate of 300r/min be stirred 12min to get.
Embodiment 6
A kind of ground anti-skid preparation, including below according to the raw material of parts by weight: 5 parts of Glycolic acid, 17.5 parts of acetic acid, grape acid
14 parts, 14 parts of 2 hydroxy propanoic acid, 9 parts of surfactant, 5 parts of sodium chloride, 0.4 part of propylene glycol, 5 parts of dihydromethyl propionic acid, trimerization
0.03 part of sodium phosphate, 3 parts of modified meerschaum, 2.25 parts of pandermite, 0.1 part of lauryl sodium sulfate, methylhydroxy silicone oil 0.2
Part and 29 parts of deionized water.
Wherein, it according to weight ratio is 2 that the surfactant, which is neopelex and fatty alcohol polyoxyethylene ether:
1 ratio mixes；The manufacture craft of the modified meerschaum is to weigh sepiolite powder according to parts by weight to be broken to 20 mesh postpositions
In the modification liquid of 18 times of volumes, supersonic cell crushing is sent into after carrying out high speed shear processing 40min with the revolving speed of 7000rpm
It is ultrasonically treated in machine, is then centrifuged with the rate of 8000r/min, carried out at 50 DEG C after removing supernatant liquor
Be dried in vacuo 36h, be ground to 600 mesh to get；The modification liquid is sodium sulfate of polyethenoxy ether of fatty alcohol, sodium citrate and water
It is mixed according to the ratio that weight ratio is 1:2:6000；The power of the ultrasonic treatment is 1000W；The ultrasonic treatment when
Between be 80min；By being modified processing to sepiolite, sepiolite is subjected to removing and forms nanoscale layer structure, is effectively subtracted
Delay the chemical reaction on ground anti-skid preparation and ground, and then advantageously formed nanoscale dent, effectively increases coefficient of friction；
In the present embodiment, the manufacture craft of the ground anti-skid preparation, specifically includes the following steps:
1) sodium chloride and deionized water are weighed according to parts by weight, is stirred after mixing with the stirring rate of 300r/min
8min is mixed, mixture A is obtained；
2) pandermite being weighed according to parts by weight and being crushed to 200 mesh, modified meerschaum is then added and is uniformly mixed, must mix
Expect B；
3) it weighs surfactant according to parts by weight to be added into mixture A obtained in step 1), with 400r/min's
Stirring rate is stirred 5min, and Glycolic acid, acetic acid, grape acid, 2 hydroxy propanoic acid, propylene glycol, dihydroxymethyl third is then added
Acid and sodium tripolyphosphate, are stirred 8min with the stirring rate of 350r/min, obtain mixture C；
4) mixture B obtained in step 2) is added into mixture C obtained in step 3), with stirring for 250r/min
It mixes rate and is stirred 4min, then carry out ultrasonic disperse processing, obtain mixture D；
Wherein, the supersonic frequency of the ultrasonic disperse processing is 15kHz；The time of the ultrasonic disperse processing is 10min；
It is handled by ultrasonic disperse, effectively increases material dispersion effect, and then be conducive to improve the antiskid effect of ground anti-skid preparation；
5) methylhydroxy silicone oil and dodecyl sulphate will be sequentially added while stirring in mixture D obtained in step 4)
Sodium, then with the stirring rate of 300r/min be stirred 12min to get.
Embodiment 7
A kind of ground anti-skid preparation, including below according to the raw material of parts by weight: 5 parts of Glycolic acid, 16 parts of acetic acid, grape acid 14
Part, 15 parts of 2 hydroxy propanoic acid, 9 parts of surfactant, 5 parts of sodium chloride, 0.4 part of propylene glycol, 5 parts of dihydromethyl propionic acid, trimerization phosphorus
0.03 part of sour sodium, 3 parts of modified meerschaum, 2.2 parts of pandermite, 0.1 part of lauryl sodium sulfate, 0.2 part of methylhydroxy silicone oil,
And 28 parts of deionized water.
Wherein, it according to weight ratio is 2 that the surfactant, which is neopelex and fatty alcohol polyoxyethylene ether:
1 ratio mixes；The manufacture craft of the modified meerschaum is to weigh sepiolite powder according to parts by weight to be broken to 20 mesh postpositions
In the modification liquid of 18 times of volumes, supersonic cell crushing is sent into after carrying out high speed shear processing 40min with the revolving speed of 7000rpm
It is ultrasonically treated in machine, is then centrifuged with the rate of 8000r/min, carried out at 50 DEG C after removing supernatant liquor
Be dried in vacuo 36h, be ground to 600 mesh to get；The modification liquid is sodium sulfate of polyethenoxy ether of fatty alcohol, sodium citrate and water
It is mixed according to the ratio that weight ratio is 1:2:6000；The power of the ultrasonic treatment is 1000W；The ultrasonic treatment when
Between be 80min；By being modified processing to sepiolite, sepiolite is subjected to removing and forms nanoscale layer structure, is effectively subtracted
Delay the chemical reaction on ground anti-skid preparation and ground, and then advantageously formed nanoscale dent, effectively increases coefficient of friction；
In the present embodiment, the manufacture craft of the ground anti-skid preparation, specifically includes the following steps:
1) sodium chloride and deionized water are weighed according to parts by weight, is stirred after mixing with the stirring rate of 300r/min
8min is mixed, mixture A is obtained；
2) pandermite being weighed according to parts by weight and being crushed to 200 mesh, modified meerschaum is then added and is uniformly mixed, must mix
Expect B；
3) it weighs surfactant according to parts by weight to be added into mixture A obtained in step 1), with 400r/min's
Stirring rate is stirred 5min, and Glycolic acid, acetic acid, grape acid, 2 hydroxy propanoic acid, propylene glycol, dihydroxymethyl third is then added
Acid and sodium tripolyphosphate, are stirred 8min with the stirring rate of 350r/min, obtain mixture C；
4) mixture B obtained in step 2) is added into mixture C obtained in step 3), with stirring for 250r/min
It mixes rate and is stirred 4min, then carry out ultrasonic disperse processing, obtain mixture D；
Wherein, the supersonic frequency of the ultrasonic disperse processing is 15kHz；The time of the ultrasonic disperse processing is 10min；
It is handled by ultrasonic disperse, effectively increases material dispersion effect, and then be conducive to improve the antiskid effect of ground anti-skid preparation；
5) methylhydroxy silicone oil and dodecyl sulphate will be sequentially added while stirring in mixture D obtained in step 4)
Sodium, then with the stirring rate of 300r/min be stirred 12min to get.
In the present embodiment, substance and instrument used are commercially available.
Comparative example 1
Compared with Example 7, modified meerschaum is free of, other are same as Example 7.
Comparative example 2
Compared with Example 7, pandermite is free of, other are same as Example 7.
Comparative example 3
Compared with Example 7, modified meerschaum and pandermite are free of, other are same as Example 7.
Comparative example 4
Compared with Example 7, in addition to the ultrasonic disperse processing in step 4) is changed to conventional mechanical stirring 10min, other
It is same as Example 7.
Performance test
Test one: performance detection is carried out on different type ground to ground anti-skid preparation prepared by embodiment 7
Specific method be it is horizontal positioned examine under project name as listed in Table 1 corresponding detection material (a variety of materials
Detection method is all the same, for ease of description, being described by taking the anti-skidding treatment process on vitrified tile surface as an example), to fixed placement
Processing carried out to vitrified tile surface according to situation listed in table 1 in the vitrified tile on level ground or without processing, then root
The test of friction coefficient μ is carried out according to the planar slide method of 9263 defined of national standard GB/T, specific testing result is as shown in table 1.Its
In, the processing is coated on vitrified tile surface for the ground anti-skid preparation for preparing embodiment 7, and coating thickness 0.lmm is stood
After 10-15 minutes, the ground anti-skid preparation on vitrified tile surface is rinsed with clear water, rinses 3-5 minutes, obtains anti-skidding processing
Surface；The drying regime refers to that will test material is placed in the environment of 40 DEG C of temperature, air humidity 30% 30 minutes.
1 different materials of table are through anti-skidding friction coefficient μ table before and after the processing
It can be seen that ground anti-skid preparation prepared by the present invention in conjunction with the data of table 1, each material surface can be significantly improved
The coefficient of friction of material surface, can reach 0.9 or more when water-holding quantity >=0.lmm, far more than international standard 0.5；Simultaneously also substantially
The coefficient of friction improved under material surface drying condition effectively increases antiskid effect, and then effectively increase ground close to 0.9
The anti-skid factor on face anti-skid preparation treated ground, simultaneously complexion pool is basically unchanged, and will not influence overall aesthetic degree.
Ground anti-skid preparation prepared by the present invention can effectively penetrate into the pore of floor tile and stone material, dissolve a small amount of
Silicon keeps pore thicker, forms many tiny invisible nano-scale grooves on surface, but will not change ceramic tile original in appearance
Looks；When ground meets water or meets oil, pore can be filled by water or oil, and when sole or sole pass through the ground, water is pressurized meeting
It is squeezed out out of pore, and in metapore is in vacuum state, so that the effect of physics sucker can be formed with plantar contact.Ground friction
Coefficient greatly reinforces, and reduces the danger fallen down after the wet water of floor tile with tumble injury, has the effect of that a kind of chance water is i.e. puckery, keep ground wet
Water is more anti-skidding than drying.Even earth's surface in future part wears, internal existing structure have become highly stable, can keep long
Long antiskid effect guarantees once the anti-skidding lifelong antiskid effect of processing and has very strong chemical resistance, weatherability, uvioresistant
Property etc..Floor tile and stone surface after processing also has positive effect when dry, meets its antiskid effect under water or greasy state
Enhance at several times.
Test two: durability performance detection is carried out to the ground anti-skid preparation of the preparation of embodiment 7 and comparative example 1-4
Specific detection method is that the ground anti-skid preparation for preparing embodiment 7 and comparative example 1-4 is coated on vitrified tile surface
After standing 10-15 minutes, the ground anti-skid preparation on vitrified tile surface is rinsed 3-5 minutes with clear water, in room temperature normal pressure item
Friction system is carried out at water-holding quantity >=0.1mm according to the planar slide method of 9263 defined of national standard GB/T after placement half a year under part
The test of number μ, the durability performance testing result of specific ground anti-skid preparation are shown in Table 2.
The durability performance testing result table of 2 ground anti-skid preparation of table
As can be seen from Table 2, ground anti-skid preparation prepared by the present invention can effectively improve the antiskid effect of wet and slippery bottom surface, in conjunction with reality
The data for applying example 7 and comparative example 1 compare it can be found that the present invention can effectively improve ground by addition modified meerschaum
The durability of face anti-skid preparation, with the extension of time, antiskid effect remains to effectively keep；7 with comparative example 2 in conjunction with the embodiments
Data compare it can be found that the present invention by addition pandermite, the durability of ground anti-skid preparation can be effectively improved,
With the extension of time, antiskid effect remains to effectively keep；It 7 compares and can send out with the data of comparative example 3 in conjunction with the embodiments
Existing, the present invention can effectively improve the durability of ground anti-skid preparation by addition modified meerschaum and pandermite, with when
Between extension, antiskid effect remains to effectively keep；It 7 compares in conjunction with the embodiments with the data of comparative example 4 it can be found that this hair
It is bright to be handled by ultrasonic disperse, material dispersion effect is effectively increased, and then be conducive to improve the anti-skidding effect of ground anti-skid preparation
Fruit can effectively improve the durability of ground anti-skid preparation, with the extension of time, antiskid effect remains to effectively keep.
It 7 is compared with the data of comparative example 1-4 it can be found that the present invention passes through modified meerschaum and white in conjunction with the embodiments
Bechilite cooperates, and assisting ultrasonic decentralized processing, plays synergistic effect, can effectively improve the anti-skidding system in ground
The durability of agent.With the extension of time, the time of even half a year, antiskid effect remains to effectively keep, and the color of floor tile
It is basically unchanged with brightness, the aesthetics for slowing down ceramic tile is degenerated.
Test three: stability test is carried out to the ground anti-skid preparation of embodiment 1-7 preparation
Low temperature resistant in advance adjust high-low temperature test chamber arrives -10 DEG C, and the sample of Packing Intact is placed in chamber.24h
After take out, restore to visual observations after room temperature, ground anti-skid preparation is without layering, rotten, metachromatism.
High temperature resistant is in advance adjusted high-low temperature test chamber to 40 DEG C, and the sample of Packing Intact is placed in chamber.After for 24 hours
It takes out, restores to visual observations after room temperature, ground anti-skid preparation is without layering, rotten, metachromatism.
Test four: harmful substance detection is carried out to the ground anti-skid preparation of embodiment 1-7 preparation
It is measured by ICP-OES measurement, UV-Vis 540nm measurement, GC-MS measurement and UV-Vis412nm, is not examined respectively
Lead, cadmium, mercury, Cr VI, polybrominated biphenyls/polybrominated diphenyl ethers or formaldehyde nuisance out.Volatile organic compounds and volatility first
Aldehyde also detects qualification.
As can be seen that prepared by the present invention have a good antiskid effect from result above, treated ground it is anti-
Sliding coefficient is high, by the cooperation of a variety of acid such as Glycolic acid, acetic acid, grape acid and 2 hydroxy propanoic acid, reduces the destruction to ground；
By being modified processing to sepiolite, sepiolite is subjected to removing and forms nanoscale layer structure, it is anti-effectively to slow down ground
The chemical reaction of sliding preparation and ground, and then nanoscale dent is advantageously formed, effectively increase coefficient of friction；The present invention provides
Ground anti-skid preparation can form the structure of similar sucker in natural stone floor surface, effectively increase non-skid property；Meanwhile it is logical
It crosses modified meerschaum and pandermite plays corrosion inhibition, effectively slow down the chemical reaction with ground, it is anti-skidding to be conducive to ground
Preparation, which penetrates into, to carry out dissolving a small amount of silicon in the pore of floor tile and stone material, keeps raw wool pore thicker, forms nanometer on surface
Grade dent, and then improve coefficient of friction；The present invention is cooperated by modified meerschaum and pandermite, and assisting ultrasonic point
Processing is dissipated, synergistic effect is played, the durability of ground anti-skid preparation can be effectively improved, with the extension of time,
Antiskid effect remains to effectively keep, and has a vast market foreground.
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, this field is common
Other modifications or equivalent replacement that technical staff makes technical solution of the present invention, without departing from technical solution of the present invention
Spirit and scope, be intended to be within the scope of the claims of the invention.
Claims (3)
1. a kind of ground anti-skid preparation, it is characterised in that: including below according to the raw material of parts by weight: 3-7 parts of Glycolic acid, acetic acid
12-22 parts, 10-18 parts of grape acid, 10-18 parts of 2 hydroxy propanoic acid, 6-12 parts of surfactant, 3-7 parts of sodium chloride, propylene glycol
0.2-0.6 parts, 3-7 parts of dihydromethyl propionic acid, 0.01-0.05 parts of sodium tripolyphosphate, 2.4-3.4 parts of modified meerschaum, white boron calcium
1.5-3 parts of stone, 0.04-0.16 parts of lauryl sodium sulfate, 0.1-0.3 parts of methylhydroxy silicone oil and deionized water 20-40
Part；
The surfactant is that neopelex and fatty alcohol polyoxyethylene ether are mixed according to the ratio that weight ratio is 2:1
It closes；
The manufacture craft of the modified meerschaum is according to parts by weight to weigh sepiolite powder and be broken to 20 mesh to be placed on 18 times of volumes
In modification liquid, progress ultrasound in ultrasonic cell disruptor is sent into after carrying out high speed shear processing 40min with the revolving speed of 7000rpm
Processing, is then centrifuged with the rate of 8000r/min, and vacuum drying 36h is carried out at 50 DEG C after removing supernatant liquor,
Be ground to 600 mesh to get；
The modification liquid is the ratio that sodium sulfate of polyethenoxy ether of fatty alcohol, sodium citrate and water are 1:2:6000 according to weight ratio
It mixes；
The power of the ultrasonic treatment is 1000W；The time of the ultrasonic treatment is 80min.
2. ground anti-skid preparation according to claim 1, it is characterised in that: including below according to the raw material of parts by weight: sweet
4-6 parts of alkyd, 15-20 parts of acetic acid, 12-16 parts of grape acid, 12-16 parts of 2 hydroxy propanoic acid, 8-10 parts of surfactant, sodium chloride
4-6 parts, 0.3-0.5 parts of propylene glycol, 4-6 parts of dihydromethyl propionic acid, 0.02-0.04 parts of sodium tripolyphosphate, modified meerschaum 2.8-
3.2 parts, 2-2.5 parts of pandermite, 0.08-0.12 parts of lauryl sodium sulfate, 0.15-0.25 parts of methylhydroxy silicone oil, and
25-33 parts of deionized water.
3. ground anti-skid preparation according to claim 2, it is characterised in that: including below according to the raw material of parts by weight: sweet
5 parts of alkyd, 16 parts of acetic acid, 14 parts of grape acid, 15 parts of 2 hydroxy propanoic acid, 9 parts of surfactant, 5 parts of sodium chloride, propylene glycol 0.4
Part, 5 parts of dihydromethyl propionic acid, 0.03 part of sodium tripolyphosphate, 3 parts of modified meerschaum, 2.2 parts of pandermite, dodecyl sulphate
0.1 part of sodium, 0.2 part of methylhydroxy silicone oil and 28 parts of deionized water.
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Application publication date: 20181204 |