CN108929608A - A kind of environment-friendly type lacquer and preparation method thereof - Google Patents
A kind of environment-friendly type lacquer and preparation method thereof Download PDFInfo
- Publication number
- CN108929608A CN108929608A CN201810760955.5A CN201810760955A CN108929608A CN 108929608 A CN108929608 A CN 108929608A CN 201810760955 A CN201810760955 A CN 201810760955A CN 108929608 A CN108929608 A CN 108929608A
- Authority
- CN
- China
- Prior art keywords
- parts
- agent
- environment
- added
- friendly type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
Abstract
The invention discloses a kind of environment-friendly type lacquers, including raw material below: water, prefabricated material, silicone acrylic emulsion, coalescing agent, antifreezing agent, fungicide, defoaming agent, alkali-swelling type thickener, pH adjusting agent, natural colour sand, modified gangue, pandermite.The invention also discloses the preparation methods of the environment-friendly type lacquer.Environment-friendly type lacquer prepared by the present invention has good water resistance, the present invention uses the cellulose of soybean stalk preparation by addition to reduce the use of alkali-swelling type thickener, and by being used in lacquer after being modified to gangue, energy conservation and environmental protection while improving lacquer water resistance, reduce the usage amount of color sand, also cooperated by modified gangue and pandermite, plays synergistic effect, the water resistance that material can be effectively improved, has a vast market foreground.
Description
Technical field
The present invention relates to building material technical field, specifically a kind of environment-friendly type lacquer and preparation method thereof.
Background technique
Lacquer is the coating that a kind of decorative effect exactly likes marble, granite, simple production process, the cost of lacquer
It is low, have excellent performance, it is main to be formulated using the natural stone-powder of various colors, applied to the imitation stone effect of external wall, because
This is also known as liquid stone, and the building after lacquer finishing has natural true natural colour, gives graceful, harmonious, serious
Aesthetic feeling, be suitable for the indoor and outdoor decoration of all kinds of buildings, especially decorated on curved-surface building object, it is vivid, have one kind
The effect of back to nature.
But in order to improve the viscosity of lacquer, it usually needs useization thickener, this can generate not environment
The influence of benefit, meanwhile, the solid component in lacquer is mostly the color sand exploited, also unfriendly for environment.
Therefore, the problem of designing a kind of environment-friendly type lacquer, becoming urgent need to resolve.
Summary of the invention
The purpose of the present invention is to provide a kind of environment-friendly type lacquers and preparation method thereof, to solve in above-mentioned background technique
The problem of proposition.
To achieve the above object, the invention provides the following technical scheme:
A kind of environment-friendly type lacquer, including below according to the raw material of parts by weight: 70-95 parts of water, material 50-70 parts prefabricated, silicon
210-290 parts of acrylic emulsion, 4-9 parts of coalescing agent, 0.5-2 parts of antifreezing agent, 0.5-2 parts of fungicide, 0.5-2 parts of defoaming agent, alkali soluble
0.5-2 parts of swollen type thickener, 0.5-2.5 parts of pH adjusting agent, 600-750 parts of natural colour sand, 14-25 parts of modified gangue, white boron
12-22 parts of calcium stone；Wherein, the preparation method of the prefabricated material is to weigh 110 parts of water according to parts by weight to be added into container, while stirring
It mixes side and is slowly added to 3 parts of celluloses, be stirred 10-24 minutes with 1000-1400 revs/min of speed, add ammonium hydroxide tune
PH to 8-9 is saved to get the prefabricated material.
As a further solution of the present invention: including below according to the raw material of parts by weight: 80-90 parts of water, prefabricated material 55-65
Part, 230-270 parts of silicone acrylic emulsion, 5-7 parts of coalescing agent, 1-1.5 parts of antifreezing agent, 0.8-1.2 parts of fungicide, defoaming agent 0.8-
1.2 parts, 1-1.5 parts of alkali-swelling type thickener, 1-2 parts of pH adjusting agent, 650-720 parts of natural colour sand, modified gangue 18-22
Part, 16-20 parts of pandermite.
As the present invention further scheme: including below according to the raw material of parts by weight: 84 parts of water, 62 parts of prefabricated material,
254 parts of silicone acrylic emulsion, 6 parts of coalescing agent, 1.2 parts of antifreezing agent, 1 part of fungicide, 1 part of defoaming agent, alkali-swelling type thickener 1.1
Part, 1.4 parts of pH adjusting agent, 700 parts of natural colour sand, 20 parts of modified gangue, 18 parts of pandermite.
As further scheme of the invention: the preparation method of the cellulose is that place is dried in soybean stalk
Reason is crushed to and the chitosan of 0.4% times of weight is added after 100-200 mesh is mixed, then introduces mould and carry out at 28 DEG C
Spontaneous fermentation is handled 15 days, carries out negative pressure filtration after fermentation, is then fed into disc mill and is carried out defibrination process, after the completion of defibrination
Low-temperature vacuum drying is carried out, is then etherified with ethylene oxide as etherifying agent in the presence of isopropanol, is ground after vacuum drying
40 mesh are milled to get the cellulose；Cellulose is prepared by using soybean stalk, effectively increases the exploitation value of soybean stalk
Value, while by being fermented and being etherified to soybean stalk, it is possible to reduce the use of alkali-swelling type thickener, energy conservation and environmental protection.
As further scheme of the invention: the coalescing agent is alcohol ester 12；The antifreezing agent propylene glycol or second
One of glycol；The defoaming agent is one of silicon ether copolymerization or organosiloxane；The natural color is 20- by granularity
The serial color sands of red of 40 mesh, the Yellow series color sand that granularity is 60-100 mesh and white series that granularity is 120-200 mesh
Color sand is mixed according to the ratio that weight ratio is 4:3:2.
As further scheme of the invention: the preparation method of the modified gangue is to be added after pulverizing coal gangue
The concentration of 10-14 times of volume is the sulfuric acid solution of 3mol/L, and the mechanical stirring 20-40min at 50-60 DEG C is filtered, and vacuum is dry
It is dry, then the powder obtained after vacuum drying is warming up to 260 DEG C according to the heating rate of 2 DEG C/min and keeps the temperature 2h, then cool down
To room temperature, it is ground into 40-100 mesh powder, states the kayexalate that 0.02 ‰ times of weight is added in powder, machine further along
Tool is uniformly mixed, and carries out ultraviolet light irradiation 10-20min then to get the modified gangue；By being carried out to gangue
It is modified to be used in lacquer, energy conservation and environmental protection, while effectively increasing the water resistance of lacquer.
The preparation method of the environment-friendly type lacquer, steps are as follows:
1) water is weighed according to parts by weight to put into dispersion machine, sequentially add coalescing agent, antifreezing agent while stirring and kill
Microbial inoculum carries out ultrasonic disperse 10-20min after mixing, obtains mixture A；
2) silicone acrylic emulsion is weighed according to parts by weight, mixture A obtained in step 1) is added while stirring, after mixing
Prefabricated material, pH adjusting agent, defoaming agent and alkali-swelling type thickener are sequentially added, mechanical stirring 20-30min obtains mixture B；
3) it weighs modified gangue and pandermite to be added after mixing into mixture B obtained in step 2), machine
Tool stirs 10-20min, obtains mixture C；
4) mixture C obtained in step 3) is put into blender, natural colour sand is added while stirring, mixing is equal
It is even to get.
As further scheme of the invention: in step 1), the supersonic frequency of the ultrasonic disperse is 10-20kHz.
Purposes of the environment-friendly type lacquer in preparation lacquer.
Compared with prior art, the beneficial effects of the present invention are:
Environment-friendly type lacquer prepared by the present invention has good water resistance, and the present invention uses soybean stalk system by addition
Standby cellulose is to reduce the use of alkali-swelling type thickener, and by being used in lacquer after being modified to gangue,
Energy conservation and environmental protection while improving lacquer water resistance, reduces the usage amount of color sand, also passes through modified gangue and pandermite
It cooperates, plays synergistic effect, the water resistance of material can be effectively improved, had a vast market foreground.
Specific embodiment
Technical solution of the present invention is described in more detail With reference to embodiment.
Embodiment 1
A kind of environment-friendly type lacquer, including below according to the raw material of parts by weight: 70 parts of water, 50 parts of prefabricated material, silicone acrylic emulsion
210 parts, 4 parts of coalescing agent, 0.5 part of antifreezing agent, 0.5 part of fungicide, 0.5 part of defoaming agent, 0.5 part of alkali-swelling type thickener, pH
0.5 part of regulator, 600 parts of natural colour sand, 14 parts of modified gangue, 12 parts of pandermite；Wherein, the coalescing agent is alcohol ester
12；The antifreeze glycol；The defoaming agent is silicon ether copolymerization；The natural color is by the red series that granularity is 30 mesh
Color sand, granularity are the Yellow series color sand of 80 mesh and granularity be the white series color sands of 180 mesh according to weight ratio is 4:3:2's
Ratio mixes；
The preparation method of the prefabricated material is to weigh 110 parts of water according to parts by weight to be added into container, while stirring slowly
3 parts of celluloses are added, are stirred 16 minutes with 1200 revs/min of speed, adds ammonium hydroxide and adjusts pH to 8 to get described
Prefabricated material；The preparation method of the cellulose is that soybean stalk is dried, and is added 0.4% times after being crushed to 150 mesh
The chitosan of weight is mixed, and is then introduced mould and is carried out spontaneous fermentation processing 15 days at 28 DEG C, carries out after fermentation
Negative pressure filtration is then fed into disc mill and carries out defibrination process, low-temperature vacuum drying carried out after the completion of defibrination, then in isopropanol
In the presence of be etherified with ethylene oxide as etherifying agent, 40 mesh are ground to after vacuum drying to get the cellulose；By using
Soybean stalk prepares cellulose, effectively increases the utility value of soybean stalk, at the same by soybean stalk carry out fermentation and
Etherificate, it is possible to reduce the use of alkali-swelling type thickener, energy conservation and environmental protection；
The preparation method of the modified gangue is that the concentration of 12 times of volumes of addition after pulverizing coal gangue is 3mol/L's
Sulfuric acid solution, the mechanical stirring 30min at 55 DEG C, filter, vacuum drying, then by the powder obtained after vacuum drying according to 2 DEG C/
The heating rate of min is warming up to 260 DEG C and keeps the temperature 2h, then cools to room temperature, and is ground into 70 mesh powders, states powder further along
The middle kayexalate that 0.02 ‰ times of weight is added, mechanical stirring are uniformly mixed, and then carry out ultraviolet light irradiation 15min,
Up to the modified gangue；By being used in lacquer after being modified to gangue, energy conservation and environmental protection effectively increases simultaneously
The water resistance of lacquer.
In the present embodiment, the preparation method of the environment-friendly type lacquer, steps are as follows:
1) water is weighed according to parts by weight to put into dispersion machine, sequentially add coalescing agent, antifreezing agent while stirring and kill
Microbial inoculum carries out ultrasonic disperse 15min after mixing with the supersonic frequency of 15kHz, obtains mixture A；
2) silicone acrylic emulsion is weighed according to parts by weight, mixture A obtained in step 1) is added while stirring, after mixing
Prefabricated material, pH adjusting agent, defoaming agent and alkali-swelling type thickener are sequentially added, mechanical stirring 25min obtains mixture B；
3) it weighs modified gangue and pandermite to be added after mixing into mixture B obtained in step 2), machine
Tool stirs 15min, obtains mixture C；
4) mixture C obtained in step 3) is put into blender, natural colour sand is added while stirring, mixing is equal
It is even to get.
Embodiment 2
A kind of environment-friendly type lacquer, including below according to the raw material of parts by weight: 95 parts of water, 70 parts of prefabricated material, silicone acrylic emulsion
290 parts, 9 parts of coalescing agent, 2 parts of antifreezing agent, 2 parts of fungicide, 2 parts of defoaming agent, 2 parts of alkali-swelling type thickener, pH adjusting agent 2.5
Part, 750 parts of natural colour sand, 25 parts of modified gangue, 22 parts of pandermite；Wherein, the coalescing agent is alcohol ester 12；It is described
Antifreeze glycol；The defoaming agent is silicon ether copolymerization；The natural color is by the red serial color sand, granularity that granularity is 30 mesh
Yellow series color sand and granularity for 80 mesh are that the white series color sand of 180 mesh is mixed according to the ratio that weight ratio is 4:3:2
It forms；
The preparation method of the prefabricated material is to weigh 110 parts of water according to parts by weight to be added into container, while stirring slowly
3 parts of celluloses are added, are stirred 16 minutes with 1200 revs/min of speed, adds ammonium hydroxide and adjusts pH to 8 to get described
Prefabricated material；The preparation method of the cellulose is that soybean stalk is dried, and is added 0.4% times after being crushed to 150 mesh
The chitosan of weight is mixed, and is then introduced mould and is carried out spontaneous fermentation processing 15 days at 28 DEG C, carries out after fermentation
Negative pressure filtration is then fed into disc mill and carries out defibrination process, low-temperature vacuum drying carried out after the completion of defibrination, then in isopropanol
In the presence of be etherified with ethylene oxide as etherifying agent, 40 mesh are ground to after vacuum drying to get the cellulose；By using
Soybean stalk prepares cellulose, effectively increases the utility value of soybean stalk, at the same by soybean stalk carry out fermentation and
Etherificate, it is possible to reduce the use of alkali-swelling type thickener, energy conservation and environmental protection；
The preparation method of the modified gangue is that the concentration of 12 times of volumes of addition after pulverizing coal gangue is 3mol/L's
Sulfuric acid solution, the mechanical stirring 30min at 55 DEG C, filter, vacuum drying, then by the powder obtained after vacuum drying according to 2 DEG C/
The heating rate of min is warming up to 260 DEG C and keeps the temperature 2h, then cools to room temperature, and is ground into 70 mesh powders, states powder further along
The middle kayexalate that 0.02 ‰ times of weight is added, mechanical stirring are uniformly mixed, and then carry out ultraviolet light irradiation 15min,
Up to the modified gangue；By being used in lacquer after being modified to gangue, energy conservation and environmental protection effectively increases simultaneously
The water resistance of lacquer.
In the present embodiment, the preparation method of the environment-friendly type lacquer, steps are as follows:
1) water is weighed according to parts by weight to put into dispersion machine, sequentially add coalescing agent, antifreezing agent while stirring and kill
Microbial inoculum carries out ultrasonic disperse 15min after mixing with the supersonic frequency of 15kHz, obtains mixture A；
2) silicone acrylic emulsion is weighed according to parts by weight, mixture A obtained in step 1) is added while stirring, after mixing
Prefabricated material, pH adjusting agent, defoaming agent and alkali-swelling type thickener are sequentially added, mechanical stirring 25min obtains mixture B；
3) it weighs modified gangue and pandermite to be added after mixing into mixture B obtained in step 2), machine
Tool stirs 15min, obtains mixture C；
4) mixture C obtained in step 3) is put into blender, natural colour sand is added while stirring, mixing is equal
It is even to get.
Embodiment 3
A kind of environment-friendly type lacquer, including below according to the raw material of parts by weight: 82.5 parts of water, 60 parts of prefabricated material, the third cream of silicon
250 parts of liquid, 6.5 parts of coalescing agent, 1.25 parts of antifreezing agent, 1.25 parts of fungicide, 1.25 parts of defoaming agent, alkali-swelling type thickener
1.25 parts, 1.5 parts of pH adjusting agent, 675 parts of natural colour sand, 19.5 parts of modified gangue, 17 parts of pandermite；Wherein, it is described at
Film auxiliary agent is alcohol ester 12；The antifreeze glycol；The defoaming agent is silicon ether copolymerization；The natural color is 30 by granularity
The red serial color sand of purpose, the Yellow series color sand that granularity is 80 mesh and granularity are the white series color sand of 180 mesh according to weight
Amount is than being that the ratio of 4:3:2 mixes；
The preparation method of the prefabricated material is to weigh 110 parts of water according to parts by weight to be added into container, while stirring slowly
3 parts of celluloses are added, are stirred 16 minutes with 1200 revs/min of speed, adds ammonium hydroxide and adjusts pH to 8 to get described
Prefabricated material；The preparation method of the cellulose is that soybean stalk is dried, and is added 0.4% times after being crushed to 150 mesh
The chitosan of weight is mixed, and is then introduced mould and is carried out spontaneous fermentation processing 15 days at 28 DEG C, carries out after fermentation
Negative pressure filtration is then fed into disc mill and carries out defibrination process, low-temperature vacuum drying carried out after the completion of defibrination, then in isopropanol
In the presence of be etherified with ethylene oxide as etherifying agent, 40 mesh are ground to after vacuum drying to get the cellulose；By using
Soybean stalk prepares cellulose, effectively increases the utility value of soybean stalk, at the same by soybean stalk carry out fermentation and
Etherificate, it is possible to reduce the use of alkali-swelling type thickener, energy conservation and environmental protection；
The preparation method of the modified gangue is that the concentration of 12 times of volumes of addition after pulverizing coal gangue is 3mol/L's
Sulfuric acid solution, the mechanical stirring 30min at 55 DEG C, filter, vacuum drying, then by the powder obtained after vacuum drying according to 2 DEG C/
The heating rate of min is warming up to 260 DEG C and keeps the temperature 2h, then cools to room temperature, and is ground into 70 mesh powders, states powder further along
The middle kayexalate that 0.02 ‰ times of weight is added, mechanical stirring are uniformly mixed, and then carry out ultraviolet light irradiation 15min,
Up to the modified gangue；By being used in lacquer after being modified to gangue, energy conservation and environmental protection effectively increases simultaneously
The water resistance of lacquer.
In the present embodiment, the preparation method of the environment-friendly type lacquer, steps are as follows:
1) water is weighed according to parts by weight to put into dispersion machine, sequentially add coalescing agent, antifreezing agent while stirring and kill
Microbial inoculum carries out ultrasonic disperse 15min after mixing with the supersonic frequency of 15kHz, obtains mixture A；
2) silicone acrylic emulsion is weighed according to parts by weight, mixture A obtained in step 1) is added while stirring, after mixing
Prefabricated material, pH adjusting agent, defoaming agent and alkali-swelling type thickener are sequentially added, mechanical stirring 25min obtains mixture B；
3) it weighs modified gangue and pandermite to be added after mixing into mixture B obtained in step 2), machine
Tool stirs 15min, obtains mixture C；
4) mixture C obtained in step 3) is put into blender, natural colour sand is added while stirring, mixing is equal
It is even to get.
Embodiment 4
A kind of environment-friendly type lacquer, including below according to the raw material of parts by weight: 80 parts of water, 55 parts of prefabricated material, silicone acrylic emulsion
230 parts, 5 parts of coalescing agent, 1 part of antifreezing agent, 0.8 part of fungicide, 0.8 part of defoaming agent, 1 part of alkali-swelling type thickener, pH are adjusted
1 part of agent, 650 parts of natural colour sand, 18 parts of modified gangue, 16 parts of pandermite；Wherein, the coalescing agent is alcohol ester 12；
The antifreeze glycol；The defoaming agent is silicon ether copolymerization；The natural color by the serial color sand of red that granularity is 30 mesh,
Granularity be 80 mesh Yellow series color sand and granularity be 180 mesh white series color sand be 4:3:2 according to weight ratio ratio
It mixes；
The preparation method of the prefabricated material is to weigh 110 parts of water according to parts by weight to be added into container, while stirring slowly
3 parts of celluloses are added, are stirred 16 minutes with 1200 revs/min of speed, adds ammonium hydroxide and adjusts pH to 8 to get described
Prefabricated material；The preparation method of the cellulose is that soybean stalk is dried, and is added 0.4% times after being crushed to 150 mesh
The chitosan of weight is mixed, and is then introduced mould and is carried out spontaneous fermentation processing 15 days at 28 DEG C, carries out after fermentation
Negative pressure filtration is then fed into disc mill and carries out defibrination process, low-temperature vacuum drying carried out after the completion of defibrination, then in isopropanol
In the presence of be etherified with ethylene oxide as etherifying agent, 40 mesh are ground to after vacuum drying to get the cellulose；By using
Soybean stalk prepares cellulose, effectively increases the utility value of soybean stalk, at the same by soybean stalk carry out fermentation and
Etherificate, it is possible to reduce the use of alkali-swelling type thickener, energy conservation and environmental protection；
The preparation method of the modified gangue is that the concentration of 12 times of volumes of addition after pulverizing coal gangue is 3mol/L's
Sulfuric acid solution, the mechanical stirring 30min at 55 DEG C, filter, vacuum drying, then by the powder obtained after vacuum drying according to 2 DEG C/
The heating rate of min is warming up to 260 DEG C and keeps the temperature 2h, then cools to room temperature, and is ground into 70 mesh powders, states powder further along
The middle kayexalate that 0.02 ‰ times of weight is added, mechanical stirring are uniformly mixed, and then carry out ultraviolet light irradiation 15min,
Up to the modified gangue；By being used in lacquer after being modified to gangue, energy conservation and environmental protection effectively increases simultaneously
The water resistance of lacquer.
In the present embodiment, the preparation method of the environment-friendly type lacquer, steps are as follows:
1) water is weighed according to parts by weight to put into dispersion machine, sequentially add coalescing agent, antifreezing agent while stirring and kill
Microbial inoculum carries out ultrasonic disperse 15min after mixing with the supersonic frequency of 15kHz, obtains mixture A；
2) silicone acrylic emulsion is weighed according to parts by weight, mixture A obtained in step 1) is added while stirring, after mixing
Prefabricated material, pH adjusting agent, defoaming agent and alkali-swelling type thickener are sequentially added, mechanical stirring 25min obtains mixture B；
3) it weighs modified gangue and pandermite to be added after mixing into mixture B obtained in step 2), machine
Tool stirs 15min, obtains mixture C；
4) mixture C obtained in step 3) is put into blender, natural colour sand is added while stirring, mixing is equal
It is even to get.
Embodiment 5
A kind of environment-friendly type lacquer, including below according to the raw material of parts by weight: 90 parts of water, 65 parts of prefabricated material, silicone acrylic emulsion
270 parts, 7 parts of coalescing agent, 1.5 parts of antifreezing agent, 1.2 parts of fungicide, 1.2 parts of defoaming agent, 1.5 parts of alkali-swelling type thickener, pH
2 parts of regulator, 720 parts of natural colour sand, 22 parts of modified gangue, 20 parts of pandermite；Wherein, the coalescing agent is alcohol ester ten
Two；The antifreeze glycol；The defoaming agent is silicon ether copolymerization；The natural color is color by the red series that granularity is 30 mesh
Sand, granularity be 80 mesh Yellow series color sand and granularity be 180 mesh white series color sand be 4:3:2 according to weight ratio ratio
Example mixes；
The preparation method of the prefabricated material is to weigh 110 parts of water according to parts by weight to be added into container, while stirring slowly
3 parts of celluloses are added, are stirred 16 minutes with 1200 revs/min of speed, adds ammonium hydroxide and adjusts pH to 8 to get described
Prefabricated material；The preparation method of the cellulose is that soybean stalk is dried, and is added 0.4% times after being crushed to 150 mesh
The chitosan of weight is mixed, and is then introduced mould and is carried out spontaneous fermentation processing 15 days at 28 DEG C, carries out after fermentation
Negative pressure filtration is then fed into disc mill and carries out defibrination process, low-temperature vacuum drying carried out after the completion of defibrination, then in isopropanol
In the presence of be etherified with ethylene oxide as etherifying agent, 40 mesh are ground to after vacuum drying to get the cellulose；By using
Soybean stalk prepares cellulose, effectively increases the utility value of soybean stalk, at the same by soybean stalk carry out fermentation and
Etherificate, it is possible to reduce the use of alkali-swelling type thickener, energy conservation and environmental protection；
The preparation method of the modified gangue is that the concentration of 12 times of volumes of addition after pulverizing coal gangue is 3mol/L's
Sulfuric acid solution, the mechanical stirring 30min at 55 DEG C, filter, vacuum drying, then by the powder obtained after vacuum drying according to 2 DEG C/
The heating rate of min is warming up to 260 DEG C and keeps the temperature 2h, then cools to room temperature, and is ground into 70 mesh powders, states powder further along
The middle kayexalate that 0.02 ‰ times of weight is added, mechanical stirring are uniformly mixed, and then carry out ultraviolet light irradiation 15min,
Up to the modified gangue；By being used in lacquer after being modified to gangue, energy conservation and environmental protection effectively increases simultaneously
The water resistance of lacquer.
In the present embodiment, the preparation method of the environment-friendly type lacquer, steps are as follows:
1) water is weighed according to parts by weight to put into dispersion machine, sequentially add coalescing agent, antifreezing agent while stirring and kill
Microbial inoculum carries out ultrasonic disperse 15min after mixing with the supersonic frequency of 15kHz, obtains mixture A；
2) silicone acrylic emulsion is weighed according to parts by weight, mixture A obtained in step 1) is added while stirring, after mixing
Prefabricated material, pH adjusting agent, defoaming agent and alkali-swelling type thickener are sequentially added, mechanical stirring 25min obtains mixture B；
3) it weighs modified gangue and pandermite to be added after mixing into mixture B obtained in step 2), machine
Tool stirs 15min, obtains mixture C；
4) mixture C obtained in step 3) is put into blender, natural colour sand is added while stirring, mixing is equal
It is even to get.
Embodiment 6
A kind of environment-friendly type lacquer, including below according to the raw material of parts by weight: 85 parts of water, 60 parts of prefabricated material, silicone acrylic emulsion
250 parts, 6 parts of coalescing agent, 1.25 parts of antifreezing agent, 1 part of fungicide, 1 part of defoaming agent, 1.25 parts of alkali-swelling type thickener, pH tune
Save 1.5 parts of agent, 685 parts of natural colour sand, 20 parts of modified gangue, 18 parts of pandermite；Wherein, the coalescing agent is alcohol ester ten
Two；The antifreeze glycol；The defoaming agent is silicon ether copolymerization；The natural color is color by the red series that granularity is 30 mesh
Sand, granularity be 80 mesh Yellow series color sand and granularity be 180 mesh white series color sand be 4:3:2 according to weight ratio ratio
Example mixes；
The preparation method of the prefabricated material is to weigh 110 parts of water according to parts by weight to be added into container, while stirring slowly
3 parts of celluloses are added, are stirred 16 minutes with 1200 revs/min of speed, adds ammonium hydroxide and adjusts pH to 8 to get described
Prefabricated material；The preparation method of the cellulose is that soybean stalk is dried, and is added 0.4% times after being crushed to 150 mesh
The chitosan of weight is mixed, and is then introduced mould and is carried out spontaneous fermentation processing 15 days at 28 DEG C, carries out after fermentation
Negative pressure filtration is then fed into disc mill and carries out defibrination process, low-temperature vacuum drying carried out after the completion of defibrination, then in isopropanol
In the presence of be etherified with ethylene oxide as etherifying agent, 40 mesh are ground to after vacuum drying to get the cellulose；By using
Soybean stalk prepares cellulose, effectively increases the utility value of soybean stalk, at the same by soybean stalk carry out fermentation and
Etherificate, it is possible to reduce the use of alkali-swelling type thickener, energy conservation and environmental protection；
The preparation method of the modified gangue is that the concentration of 12 times of volumes of addition after pulverizing coal gangue is 3mol/L's
Sulfuric acid solution, the mechanical stirring 30min at 55 DEG C, filter, vacuum drying, then by the powder obtained after vacuum drying according to 2 DEG C/
The heating rate of min is warming up to 260 DEG C and keeps the temperature 2h, then cools to room temperature, and is ground into 70 mesh powders, states powder further along
The middle kayexalate that 0.02 ‰ times of weight is added, mechanical stirring are uniformly mixed, and then carry out ultraviolet light irradiation 15min,
Up to the modified gangue；By being used in lacquer after being modified to gangue, energy conservation and environmental protection effectively increases simultaneously
The water resistance of lacquer.
In the present embodiment, the preparation method of the environment-friendly type lacquer, steps are as follows:
1) water is weighed according to parts by weight to put into dispersion machine, sequentially add coalescing agent, antifreezing agent while stirring and kill
Microbial inoculum carries out ultrasonic disperse 15min after mixing with the supersonic frequency of 15kHz, obtains mixture A；
2) silicone acrylic emulsion is weighed according to parts by weight, mixture A obtained in step 1) is added while stirring, after mixing
Prefabricated material, pH adjusting agent, defoaming agent and alkali-swelling type thickener are sequentially added, mechanical stirring 25min obtains mixture B；
3) it weighs modified gangue and pandermite to be added after mixing into mixture B obtained in step 2), machine
Tool stirs 15min, obtains mixture C；
4) mixture C obtained in step 3) is put into blender, natural colour sand is added while stirring, mixing is equal
It is even to get.
Embodiment 7
A kind of environment-friendly type lacquer, including below according to the raw material of parts by weight: 84 parts of water, 62 parts of prefabricated material, silicone acrylic emulsion
254 parts, 6 parts of coalescing agent, 1.2 parts of antifreezing agent, 1 part of fungicide, 1 part of defoaming agent, 1.1 parts of alkali-swelling type thickener, pH are adjusted
1.4 parts of agent, 700 parts of natural colour sand, 20 parts of modified gangue, 18 parts of pandermite；Wherein, the coalescing agent is alcohol ester ten
Two；The antifreeze glycol；The defoaming agent is silicon ether copolymerization；The natural color is color by the red series that granularity is 30 mesh
Sand, granularity be 80 mesh Yellow series color sand and granularity be 180 mesh white series color sand be 4:3:2 according to weight ratio ratio
Example mixes；
The preparation method of the prefabricated material is to weigh 110 parts of water according to parts by weight to be added into container, while stirring slowly
3 parts of celluloses are added, are stirred 16 minutes with 1200 revs/min of speed, adds ammonium hydroxide and adjusts pH to 8 to get described
Prefabricated material；The preparation method of the cellulose is that soybean stalk is dried, and is added 0.4% times after being crushed to 150 mesh
The chitosan of weight is mixed, and is then introduced mould and is carried out spontaneous fermentation processing 15 days at 28 DEG C, carries out after fermentation
Negative pressure filtration is then fed into disc mill and carries out defibrination process, low-temperature vacuum drying carried out after the completion of defibrination, then in isopropanol
In the presence of be etherified with ethylene oxide as etherifying agent, 40 mesh are ground to after vacuum drying to get the cellulose；By using
Soybean stalk prepares cellulose, effectively increases the utility value of soybean stalk, at the same by soybean stalk carry out fermentation and
Etherificate, it is possible to reduce the use of alkali-swelling type thickener, energy conservation and environmental protection；
The preparation method of the modified gangue is that the concentration of 12 times of volumes of addition after pulverizing coal gangue is 3mol/L's
Sulfuric acid solution, the mechanical stirring 30min at 55 DEG C, filter, vacuum drying, then by the powder obtained after vacuum drying according to 2 DEG C/
The heating rate of min is warming up to 260 DEG C and keeps the temperature 2h, then cools to room temperature, and is ground into 70 mesh powders, states powder further along
The middle kayexalate that 0.02 ‰ times of weight is added, mechanical stirring are uniformly mixed, and then carry out ultraviolet light irradiation 15min,
Up to the modified gangue；By being used in lacquer after being modified to gangue, energy conservation and environmental protection effectively increases simultaneously
The water resistance of lacquer.
In the present embodiment, the preparation method of the environment-friendly type lacquer, steps are as follows:
1) water is weighed according to parts by weight to put into dispersion machine, sequentially add coalescing agent, antifreezing agent while stirring and kill
Microbial inoculum carries out ultrasonic disperse 15min after mixing with the supersonic frequency of 15kHz, obtains mixture A；
2) silicone acrylic emulsion is weighed according to parts by weight, mixture A obtained in step 1) is added while stirring, after mixing
Prefabricated material, pH adjusting agent, defoaming agent and alkali-swelling type thickener are sequentially added, mechanical stirring 25min obtains mixture B；
3) it weighs modified gangue and pandermite to be added after mixing into mixture B obtained in step 2), machine
Tool stirs 15min, obtains mixture C；
4) mixture C obtained in step 3) is put into blender, natural colour sand is added while stirring, mixing is equal
It is even to get.
Comparative example 1
Compared with Example 7, modified gangue is free of, other are same as Example 7.
Comparative example 2
Compared with Example 7, pandermite is free of, other are same as Example 7.
Comparative example 3
Compared with Example 7, modified gangue and pandermite are free of, other are same as Example 7.
Performance test
The environment-friendly type lacquer of the preparation of embodiment 7 and comparative example 1-3 is detected, specifically according to Chinese architecture industry
Professional standard JG/T24-2000 " synthetic resin emulsion sand wall-like construction material " is detected, wherein initial dry cracking resistance
Technical standard is flawless, and the technical standard of drying time (surface drying) is≤4h, the technical standard of water resistance be 96h coating without
Drum, cracking are played, peels off and (compared with not impregnating part, allows color slight change), specific test result is shown in Table 1.
It, can from can be seen that the present invention in the data comparison of embodiment 7 and comparative example 1 by addition modified gangue
Effectively improve the water resistance of material；White boron calcium is added from can be seen that the present invention in the data comparison of embodiment 7 and comparative example 2
Stone can effectively improve the water resistance of material；In addition, as can be seen that originally from the data comparison of embodiment 7 and comparative example 1-3
Invention is cooperated by modified gangue and pandermite, is played synergistic effect, can be effectively improved material
Water resistance.
1 testing result table of table
| Group | Initial dry cracking resistance | Drying time | Water resistance |
| Embodiment 7 | Flawless | 1.4 | 192h is without exception |
| Comparative example 1 | Flawless | 2.2 | 144h slightly whitens |
| Comparative example 2 | Flawless | 2 | 144h slightly whitens |
| Comparative example 3 | Flawless | 3 | 120h slightly whitens |
As can be seen that environment-friendly type lacquer prepared by the present invention has good water resistance, the present invention from result above
By adding the cellulose for using soybean stalk to prepare to reduce the use of alkali-swelling type thickener, and by being carried out to gangue
Modified to be used in lacquer, energy conservation and environmental protection while improving lacquer water resistance also passes through modified gangue and white boron calcium
Stone cooperates, and plays synergistic effect, can effectively improve the water resistance of material.
Environment-friendly type lacquer prepared by the present invention has good water resistance, and the present invention uses soybean stalk system by addition
Standby cellulose is to reduce the use of alkali-swelling type thickener, and by being used in lacquer after being modified to gangue,
Energy conservation and environmental protection while improving lacquer water resistance, reduces the usage amount of color sand, also passes through modified gangue and pandermite
It cooperates, plays synergistic effect, the water resistance of material can be effectively improved, had a vast market foreground.
Better embodiment of the invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party
Formula within the knowledge of one of ordinary skill in the art can also be without departing from the purpose of the present invention
Various changes can be made.There is no necessity and possibility to exhaust all the enbodiments.And it thus amplifies out apparent
Variation or variation be still in the protection scope of this invention.
Claims (10)
1. a kind of environment-friendly type lacquer, which is characterized in that including below according to the raw material of parts by weight: 70-95 parts of water, prefabricated material
50-70 parts, 210-290 parts of silicone acrylic emulsion, 4-9 parts of coalescing agent, 0.5-2 parts of antifreezing agent, 0.5-2 parts of fungicide, defoaming agent
0.5-2 parts, 0.5-2 parts of alkali-swelling type thickener, 0.5-2.5 parts of pH adjusting agent, 600-750 parts of natural colour sand, modified gangue
14-25 parts, 12-22 parts of pandermite；Wherein, the preparation method of the prefabricated material is to weigh 110 parts of water according to parts by weight to be added
Into container, it is slowly added to 3 parts of celluloses while stirring, is stirred 10-24 minutes with 1000-1400 revs/min of speed,
It adds ammonium hydroxide and adjusts pH to 8-9 to get the prefabricated material.
2. environment-friendly type lacquer according to claim 1, which is characterized in that including below according to the raw material of parts by weight: water
80-90 parts, material 55-65 parts prefabricated, 230-270 parts of silicone acrylic emulsion, 5-7 parts of coalescing agent, 1-1.5 parts of antifreezing agent, fungicide
0.8-1.2 parts, 0.8-1.2 parts of defoaming agent, 1-1.5 parts of alkali-swelling type thickener, 1-2 parts of pH adjusting agent, natural colour sand 650-720
Part, 18-22 parts of modified gangue, 16-20 parts of pandermite.
3. environment-friendly type lacquer according to claim 2, which is characterized in that including below according to the raw material of parts by weight: water
84 parts, 62 parts of prefabricated material, 254 parts of silicone acrylic emulsion, 6 parts of coalescing agent, 1.2 parts of antifreezing agent, 1 part of fungicide, 1 part of defoaming agent, alkali
1.1 parts of swelling type thickener, 1.4 parts of pH adjusting agent, 700 parts of natural colour sand, 20 parts of modified gangue, 18 parts of pandermite.
4. environment-friendly type lacquer according to claim 1 or 2 or 3, which is characterized in that the preparation method of the cellulose is
Soybean stalk is dried, chitosan is added after crushing and is mixed, mould is then introduced and carries out spontaneous fermentation processing,
Negative pressure filtration is carried out after fermentation, is then fed into disc mill and is carried out defibrination process, carries out low-temperature vacuum drying after the completion of defibrination,
Then it is etherified with ethylene oxide as etherifying agent in the presence of isopropanol, 40 mesh is ground to after vacuum drying to get described
Cellulose.
5. environment-friendly type lacquer according to claim 4, which is characterized in that the coalescing agent is alcohol ester 12；It is described
One of antifreezing agent propylene glycol or ethylene glycol；The defoaming agent is one of silicon ether copolymerization or organosiloxane.
6. environment-friendly type lacquer according to claim 4, which is characterized in that the natural color is by red serial color sand, Huang
Color system color sand and white series color sand are mixed according to the ratio that weight ratio is 4:3:2.
7. environment-friendly type lacquer according to claim 4, which is characterized in that the preparation method of the modified gangue is will
Sulfuric acid solution is added after crushing in gangue, mechanical stirring 20-40min, filters, vacuum drying, then will obtain after vacuum drying
Powder is warming up to 260 DEG C and keeps the temperature 2h, then cools to room temperature, and grind into powder is stated polystyrene is added in powder further along
Sodium sulfonate, mechanical stirring are uniformly mixed, and carry out ultraviolet light irradiation 10-20min then to get the modified gangue.
8. a kind of preparation method of environment-friendly type lacquer as claimed in claim 1, which is characterized in that steps are as follows:
1) water is weighed according to parts by weight to put into dispersion machine, sequentially add coalescing agent, antifreezing agent and fungicide while stirring,
Ultrasonic disperse 10-20min is carried out after mixing, obtains mixture A；
2) silicone acrylic emulsion is weighed according to parts by weight, mixture A obtained in step 1) is added while stirring, after mixing successively
Prefabricated material, pH adjusting agent, defoaming agent and alkali-swelling type thickener is added, mechanical stirring 20-30min obtains mixture B；
3) it weighs modified gangue and pandermite to be added after mixing into mixture B obtained in step 2, machinery stirs
10-20min is mixed, mixture C is obtained；
4) mixture C obtained in step 3) is put into blender, natural colour sand is added while stirring, be uniformly mixed, i.e.,
?.
9. the preparation method of environment-friendly type lacquer according to claim 8, which is characterized in that in step 1), the ultrasound
The supersonic frequency of dispersion is 10-20kHz.
10. a kind of purposes of environment-friendly type lacquer as claimed in claim 1 in preparation lacquer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810760955.5A CN108929608A (en) | 2018-07-12 | 2018-07-12 | A kind of environment-friendly type lacquer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810760955.5A CN108929608A (en) | 2018-07-12 | 2018-07-12 | A kind of environment-friendly type lacquer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108929608A true CN108929608A (en) | 2018-12-04 |
Family
ID=64447431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810760955.5A Pending CN108929608A (en) | 2018-07-12 | 2018-07-12 | A kind of environment-friendly type lacquer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108929608A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101368328A (en) * | 2008-08-04 | 2009-02-18 | 东华大学 | Preparation method for hydroxyethyl group chitosan fiber |
| CN104130034A (en) * | 2014-06-19 | 2014-11-05 | 临沂市清宇环境资源综合利用研究院 | Method for producing fiber board and organic fertilizer by utilizing garden waste |
| CN104164009A (en) * | 2014-07-15 | 2014-11-26 | 滁州市富力克斯电线电缆有限公司 | Modified coal gangue for polyvinyl chloride cable materials and preparation method thereof |
| CN104250495A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Preparation process of natural color sand really stone paint |
| CN105368237A (en) * | 2015-11-27 | 2016-03-02 | 陕西鼎鑫新材料科技有限公司 | Ultraviolet and stain resistant natural stone paint and preparation method thereof |
| CN106046958A (en) * | 2016-06-12 | 2016-10-26 | 安徽快来防水防腐有限公司 | Anti-cracking waterproof butyl coating and preparation method thereof |
| CN106543828A (en) * | 2016-12-09 | 2017-03-29 | 辽宁法库陶瓷工程技术研究中心 | Flexible porcelain tendre tapestry brick prepared by a kind of utilization gangue and preparation method thereof |
| CN106590268A (en) * | 2016-11-14 | 2017-04-26 | 北京卫星制造厂 | Real-stone paint and preparation method thereof |
-
2018
- 2018-07-12 CN CN201810760955.5A patent/CN108929608A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101368328A (en) * | 2008-08-04 | 2009-02-18 | 东华大学 | Preparation method for hydroxyethyl group chitosan fiber |
| CN104130034A (en) * | 2014-06-19 | 2014-11-05 | 临沂市清宇环境资源综合利用研究院 | Method for producing fiber board and organic fertilizer by utilizing garden waste |
| CN104164009A (en) * | 2014-07-15 | 2014-11-26 | 滁州市富力克斯电线电缆有限公司 | Modified coal gangue for polyvinyl chloride cable materials and preparation method thereof |
| CN104250495A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Preparation process of natural color sand really stone paint |
| CN105368237A (en) * | 2015-11-27 | 2016-03-02 | 陕西鼎鑫新材料科技有限公司 | Ultraviolet and stain resistant natural stone paint and preparation method thereof |
| CN106046958A (en) * | 2016-06-12 | 2016-10-26 | 安徽快来防水防腐有限公司 | Anti-cracking waterproof butyl coating and preparation method thereof |
| CN106590268A (en) * | 2016-11-14 | 2017-04-26 | 北京卫星制造厂 | Real-stone paint and preparation method thereof |
| CN106543828A (en) * | 2016-12-09 | 2017-03-29 | 辽宁法库陶瓷工程技术研究中心 | Flexible porcelain tendre tapestry brick prepared by a kind of utilization gangue and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104151975B (en) | A kind of aqueous reflective insulation stone-like coating and preparation method thereof | |
| CN108440704B (en) | Boiling water resistant high-adhesion double-component acrylate emulsion and preparation method thereof | |
| CN105199606B (en) | A kind of high stability is imitative to burn stone material water burnt-in sand environmental protection coating material and preparation method thereof | |
| CN104402320A (en) | High-waterproof colorful stone-like paint | |
| CN102876143A (en) | Marble paint and preparation method thereof | |
| CN110028860A (en) | A kind of absorption haze, air-purification type lacquer and preparation method thereof | |
| CN106280806A (en) | A kind of aqueous reflective insulation water burnt-in sand imitates bush-hammered face coating and preparation method thereof | |
| CN113480898A (en) | Quick-drying transparent primer and preparation method thereof | |
| CN108034305A (en) | A kind of iron oxide pigment mill base and preparation method thereof | |
| CN109735233A (en) | A kind of coating and its preparation method and application | |
| CN107227111A (en) | A kind of new type water burnt-in sand coating and preparation method thereof | |
| CN106478861A (en) | A kind of modified aqueous acrylic acid resin and the method preparing manually color sand using it | |
| CN106634082A (en) | Adsorbing odor-removing environment-friendly fireproof coating and preparation method thereof | |
| CN105565736A (en) | Preparation method for ultraviolet resistant functional mortar | |
| CN104530868A (en) | Environment-friendly water-based glass paint and preparation method thereof | |
| CN108929608A (en) | A kind of environment-friendly type lacquer and preparation method thereof | |
| CN103289497B (en) | Efficiently spray true mineral varnish and preparation method thereof | |
| CN102850861A (en) | Brick paint and preparation method thereof | |
| CN104559590A (en) | Exterior wall paint used in high-temperature, high-humidity and strong ultraviolet region and production method thereof | |
| CN108219661A (en) | A kind of high anti-foaming Extra-clear transparent primer of the net tastes of PU and preparation method thereof | |
| CN108793835A (en) | A kind of new type natural lacquer and preparation method thereof | |
| CN113930148A (en) | Woodware sealing primer and preparation method and application thereof | |
| CN109233513B (en) | Environment-friendly stone-like paint with high water resistance and preparation method thereof | |
| CN113122089A (en) | Reflective heat-insulation composite rock slice paint and preparation method thereof | |
| CN106366742A (en) | Water-based multicolor stone like coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181204 |