CN108926964A - A kind of Thermal Power Station's timesharing collecting carbonic anhydride storage system - Google Patents

A kind of Thermal Power Station's timesharing collecting carbonic anhydride storage system Download PDF

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Publication number
CN108926964A
CN108926964A CN201810929014.XA CN201810929014A CN108926964A CN 108926964 A CN108926964 A CN 108926964A CN 201810929014 A CN201810929014 A CN 201810929014A CN 108926964 A CN108926964 A CN 108926964A
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carbon dioxide
holding vessel
storage system
pipeline
rich solution
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CN201810929014.XA
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CN108926964B (en
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郭丛
徐玉杰
汪翔
陈海生
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Institute of Engineering Thermophysics of CAS
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Institute of Engineering Thermophysics of CAS
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1475Removing carbon dioxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

Abstract

The present invention discloses a kind of Thermal Power Station's timesharing collecting carbonic anhydride storage system, can effectively pass through the electricity consumption of peak valley moment and steam extraction of reasonable arrangement power plant, improve effect of the power plant to power grid peak load shifting, accommodates more renewable energy online.The device mainly includes the components such as lean solution holding vessel, rich solution holding vessel, absorption tower, Analytic Tower, reboiler, separator, carbon-dioxide gas compressor, carbon dioxide cooler.In peak times of power consumption, the system runs on carbon dioxide absorption operating condition, by the carbon dioxide capture in flue gas and is stored in rich solution (absorbing the absorbing liquid of carbon dioxide) in the case where consuming a small amount of station service at this time;In the low power consumption phase, the system runs on carbon dioxide parsing operating condition, needs to consume a large amount of extracted steam from turbine at this time for the carbon dioxide in rich solution and is parsed into gaseous state, and consumes a large amount of station services and gaseous carbon dioxide under normal pressure is compressed into high pressure conditions and is stored.

Description

A kind of Thermal Power Station's timesharing collecting carbonic anhydride storage system
Technical field
The invention belongs to energy storage, field of energy-saving technology, be related to a kind of collecting carbonic anhydride storage system, in particular to one Kind Thermal Power Station's timesharing collecting carbonic anhydride storage system, the carbon dioxide capture system utilize power plant in low power consumption simultaneously The thermal energy that phase electricity power and low power consumption phase extracted steam from turbine have.In peak times of power consumption by the carbon dioxide in flue gas Be stored in carbon dioxide absorbent solution, in the low power consumption phase using thermal energy and electric energy extra in power plant by carbon dioxide from dioxy Change to be precipitated and compress in carbon absorption liquid and store.Compared to non-time-sharing system, the peak load shifting of electric energy may be implemented, accommodate more Renewable energy online.
Background technique
China in industrialization extensive development critical phase, the consumption of the energy also keep increasing stably and rapidly.China Non-renewable energy based on fossil energy so that the CO2 emissions rapid development in China, this also causes China in the whole world The relevant international negotiation of climate change faces the increasing pressure, and repeatedly how world climate change meeting will all control How the developing countries such as state, India should realize that important agenda has been put in the emission reduction of greenhouse gases.Therefore the titanium dioxide of China Carbon emission reduction and to global warming gas control for become particularly important and crucial.
Existing collecting carbonic anhydride technology includes multiple technologies form, wherein capturing the main needle of CO 2 technology after burning The smoke evacuation of energy power system tail portion is separated and trapped, one important feature of the technology is that carbon dioxide capture equipment is only The main equipment of motive power system is stood on, more flexible can use or equipment is in diverse dynamical system, therefore It is widely used in the power device using power station as representative.
A step in carbon dioxide capture system is that carbon dioxide is precipitated from liquid, this needs a large amount of heat Amount.The origin of heat is the steam extraction of steam turbine, so this will affect the acting of steam turbine and then influences generated energy.Meanwhile by two Carbonoxide compression storage or compression transport need a large amount of electric energy.
Summary of the invention
It needs to consume in links such as the compressions and precipitation of carbon dioxide in existing post combustion carbon dioxide trapping system The problem of a large amount of thermal energy and electric energy, the purpose of the present invention is according to resident and commercial power changing rule, in power-plant flue gas Carbon dioxide carry out timesharing trapping, while using power plant in low power consumption phase electricity power and low power consumption phase steam turbine The thermal energy that steam extraction has, by the electricity consumption of peak valley moment and steam extraction of reasonable arrangement power plant, this facilitates to power grid peak load shifting, So as to dissolve the online of the renewable energy such as more wind-powered electricity generations, photoelectricity, alleviate power supply and demand relationship.
The technical solution that the present invention is taken by realization its technical purpose are as follows:
A kind of Thermal Power Station's timesharing collecting carbonic anhydride storage system, including lean solution holding vessel, absorption tower, rich solution storage Tank, reboiler, Analytic Tower, separator, carbon-dioxide gas compressor and high-pressure carbon dioxide storage system, which is characterized in that
The lean solution holding vessel absorbs dioxy to store to store carbon dioxide absorbent solution, the rich solution holding vessel Change the absorbing liquid of carbon,
The gas inlet of the absorption tower lower part is connected to the smoke-exhaust pipeline of Thermal Power Station,
The carbon dioxide absorbent solution import on the absorption tower top is connected to the lean solution holding vessel,
Exhanst gas outlet at the top of the absorption tower is connected to the chimney of Thermal Power Station,
The rich solution outlet of the absorb the bottom of the tower is connected to the inlet of the rich solution holding vessel,
In peak times of power consumption, power-plant flue gas is passed through in the absorption tower, in the absorption tower, power-plant flue gas and titanium dioxide Carbon absorption liquid is in contact, and the carbon dioxide in flue gas is changed into rich solution by carbon dioxide absorbent solution absorption, and the rich solution passes through The rich solution outlet of the absorb the bottom of the tower enters in the rich solution holding vessel, and remaining flue gas goes out from the flue gas at the top of the absorption tower Mouth enters chimney;
The rich solution import on the Analytic Tower top is connected to the liquid outlet of the rich solution holding vessel,
Mixed gas outlet at the top of the Analytic Tower is connected to by pipeline with the separator,
The liquid outlet of the parsing tower bottom is connected to by pipeline with the liquid-inlet of the reboiler,
The carbon dioxide gas outlet of the separator passes through the inlet communication of pipeline and the carbon-dioxide gas compressor, institute The outlet for stating carbon-dioxide gas compressor is connected to by pipeline with the high-pressure carbon dioxide storage system;The condensation of the separator Water out passes through the condensed water inlet communication of pipeline and the Analytic Tower top;
The steam inlet of the reboiler is connected to power plant steam turbine bleed steam pipework, and the gas vent of the reboiler passes through Pipeline is connected to the gas feed of the Analytic Tower lower part, and the lean solution outlet of the reboiler is stored by pipeline and the lean solution Tank connection;
In the low power consumption phase, into the rich solution in the Analytic Tower be resolved to the gaseous mixture of carbon dioxide and water vapour with And remaining liq, the carbon dioxide gas isolated in the separator is transported in the carbon-dioxide gas compressor, described The high-pressure carbon dioxide that carbon-dioxide gas compressor generates is transported to the high-pressure carbon dioxide storage system;In the separator The water recovery Cheng Shuihou isolated is returned in the Analytic Tower by pipeline;The remaining liq generated in the Analytic Tower It is transported in the reboiler, the steam inlet of the reboiler is connected to power plant steam turbine bleed steam pipework, is boiled again described The remaining liq generated in Analytic Tower described in device is changed into lean solution and gas, the lean solution after contacting with power plant steam turbine steam extraction For the absorbing liquid for having parsed carbon dioxide, the gas is returned in the Analytic Tower by pipeline, and the lean solution passes through pipeline It is transported in the lean solution holding vessel.
Preferably, the electric energy needed for the low power consumption phase, the carbon-dioxide gas compressor is mentioned by the extra electric energy of Thermal Power Station For.
Preferably, the outlet of the carbon-dioxide gas compressor after a carbon dioxide cooler with the high-pressure carbon dioxide Storage system connection.
Preferably, the communicating pipe between the lean solution holding vessel and the carbon dioxide absorbent solution import on the absorption tower top Road is equipped with a transfer tube.
Preferably, the flue gas inlet tube road of the absorption tower lower part is equipped with a flue gas blower.
Preferably, the connecting pipeline between the rich solution outlet of the absorb the bottom of the tower and the inlet of the rich solution holding vessel It is equipped with a transfer tube.
Preferably, the rich solution inlet ductwork on the Analytic Tower top is equipped with a transfer tube.
Preferably, the connecting pipeline between the lean solution outlet and the lean solution holding vessel of the reboiler is equipped with a driving Pump.
Preferably, the series of the carbon-dioxide gas compressor is 1.
Preferably, in non-electricity peak non-electricity trough period, the system is still run.
Heating power power plant timesharing collecting carbonic anhydride storage system of the invention, basic structure are as follows: 1. in peak times of power consumption, Through flue gas blower and absorption tower, by the carbon dioxide storage in the smoke evacuation of power plant in carbon dioxide absorbent solution;2. in electricity consumption Trough period, using the thermal energy of power plant's electric energy and extracted steam from turbine, by the effect of reboiler and Analytic Tower, by carbon dioxide absorption Carbon dioxide in liquid is parsed into gaseous state, and compresses storage.
It is compared compared with power-plant flue gas collecting carbonic anhydride technology, heating power power plant timesharing collecting carbonic anhydride of the invention is deposited Storage system its advantages: 1. realizing the peak load shifting of electric energy, and the compression storage of carbon dioxide is carried out in the low power consumption phase, is had Help alleviate imbalance between power supply and demand and accommodates more renewable energy online;2. can be in the compression storage for carrying out carbon dioxide The steam extraction of Steam Turbine is consumed, so as to reduce Steam Turbine acting, further realizes the effect to electric energy peak load shifting.
Detailed description of the invention
Fig. 1 is carbon dioxide absorption operating condition (peak times of power consumption) operation schematic diagram;
Fig. 2 is that carbon dioxide parses operating condition (low power consumption phase) operation schematic diagram.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention more comprehensible, with reference to the accompanying drawings and examples, in detail Thin description through the foregoing embodiment, completely effectively realizes the purpose of the present invention.Person skilled in art is understood that this Invention includes but is not limited to content described in attached drawing and the above specific embodiment.Although the present invention is just it is now recognized that the most real With and preferred embodiment be illustrated, it is any without departing from this hair it should be understood that the present invention is not limited to the disclosed embodiments The modification of bright function and structure principle is intended to be included in the range of claims.
As shown in Figure 1, 2, Thermal Power Station's timesharing collecting carbonic anhydride storage system of the invention, with existing thermal power generation Factory is used cooperatively, and the system can utilize flue gas, chimney of electric plant, the extra electric energy of extracted steam from turbine and power plant of Thermal Power Station. The system is by lean solution holding vessel 1, pump 2, flue gas blower 3, absorption tower 4, pump 5, rich solution holding vessel 6, pump 7, reboiler 8, parsing The components composition such as tower 9, separator 10, pump 11, carbon-dioxide gas compressor 12 and carbon dioxide cooler 13.Lean solution holding vessel 1 is used To store carbon dioxide absorbent solution, rich solution holding vessel 6 absorbs the absorbing liquid of carbon dioxide to store.
As shown in Figure 1, the gas inlet of 4 lower part of absorption tower is connected to the smoke-exhaust pipeline of Thermal Power Station, and in smoke exhaust pipe Road is equipped with flue gas blower 3;The carbon dioxide absorbent solution import on 4 top of absorption tower is connected to lean solution holding vessel 1, and therebetween Connecting pipeline be equipped with kinetic pump 2;The exhanst gas outlet at 4 top of absorption tower is connected to the chimney of Thermal Power Station;4 bottom of absorption tower The rich solution outlet in portion is connected to the inlet of rich solution holding vessel 6, and connecting pipeline between the two is equipped with kinetic pump 5;With Electric peak period, power-plant flue gas are passed through in absorption tower 4, and in absorption tower 4, power-plant flue gas is in contact with carbon dioxide absorbent solution, Carbon dioxide in flue gas is changed into rich solution by carbon dioxide absorbent solution absorption, and rich solution passes through the rich solution outlet of 4 bottom of absorption tower Into in rich solution holding vessel 6, remaining flue gas enters chimney from the exhanst gas outlet at 4 top of absorption tower.
As shown in Fig. 2, the rich solution import on 9 top of Analytic Tower is connected to the liquid outlet of rich solution holding vessel 6, and between the two Connecting pipeline is equipped with kinetic pump 7;The mixed gas outlet at 9 top of Analytic Tower is connected to by pipeline with separator 10,9 bottom of Analytic Tower The liquid outlet in portion is connected to by pipeline with the liquid-inlet of reboiler 8, and the carbon dioxide gas outlet of separator 10 passes through pipe It is deposited by pipeline and high-pressure carbon dioxide the outlet of the inlet communication on road and carbon-dioxide gas compressor 12, carbon-dioxide gas compressor 12 Storage system connection, and connecting pipeline between the two is equipped with a carbon dioxide cooler 13;The condensation water out of separator 10 Pass through the condensed water inlet communication of pipeline and 9 top of Analytic Tower;The steam inlet and power plant steam turbine bleed steam pipework of reboiler 8 connect Logical, the gas vent of reboiler 8 is connected to by pipeline with the gas feed of 9 lower part of Analytic Tower, and the lean solution outlet of reboiler 8 passes through Pipeline is connected to lean solution holding vessel 1, and connecting pipeline between the two is equipped with kinetic pump 11.In the low power consumption phase, into solution Rich solution in analysis tower 9 is resolved to the gaseous mixture and remaining liq of carbon dioxide and water vapour, isolates in separator 10 Carbon dioxide gas is transported in carbon-dioxide gas compressor 12, and the high-pressure carbon dioxide that carbon-dioxide gas compressor 12 generates is defeated It send to high-pressure carbon dioxide storage system;The water recovery Cheng Shuihou isolated in separator 10 returns to parsing by pipeline In tower 9;The remaining liq generated in Analytic Tower 9 is transported in reboiler 8, the steam inlet and power plant steam turbine of reboiler 8 Bleed steam pipework connection, the remaining liq generated in Analytic Tower 9 in reboiler 8 is changed into poor after contacting with power plant steam turbine steam extraction Liquid and gas, lean solution are to have parsed the absorbing liquid of carbon dioxide, and gas is returned in Analytic Tower 9 by pipeline, and lean solution passes through pipe Road is transported in lean solution holding vessel 1.
Thermal Power Station's timesharing collecting carbonic anhydride storage system of the invention, in peak times of power consumption, carbon dioxide is in Absorb operating condition.Power-plant flue gas enters flue gas blower 3 by pipeline, subsequently into absorption tower 4.It is poor in lean solution holding vessel 1 simultaneously Liquid, i.e. carbon dioxide absorbent solution first pass through pump 2, also enter absorption tower 4.In absorption tower 4, flue gas and carbon dioxide absorbent solution hair Raw to contact, the carbon dioxide in flue gas is absorbed by carbon dioxide absorbent solution, and carbon dioxide absorbent solution becomes rich solution and (absorbs dioxy Change the absorbing liquid of carbon).Remaining flue gas is discharged from the top on absorption tower 4, into chimney.Rich solution is by pump 5, into rich solution holding vessel 6 store.
Thermal Power Station's timesharing collecting carbonic anhydride storage system of the invention, in the low power consumption phase, carbon dioxide is in Parse operating condition.Rich solution in rich solution holding vessel 6 is by pump 7, into Analytic Tower 9.Extracted steam from turbine enters reboiler by pipeline 8, it is contacted with the liquid flowed out in Analytic Tower 9.The gas generated in reboiler 8 enters Analytic Tower 9, reboiler by pipeline The liquid generated in 8 i.e. lean solution (absorbing liquid for having parsed carbon dioxide) is by pump 11, into lean solution holding vessel 1.In Analytic Tower 9 Gas (containing water vapour and carbon dioxide) separator 10 is entered by pipeline, in separator 10, water recovery Cheng Shui Back to Analytic Tower 9, carbon dioxide gas then passes through pipeline and enters carbon-dioxide gas compressor 12.The electricity of carbon-dioxide gas compressor 12 Electric energy that can be extra from low power consumption phase power plant.The carbon dioxide being compressed by temperature after carbon dioxide cooler 13 It reduces, is stored in high-pressure carbon dioxide stocking system.
Through the foregoing embodiment, the purpose of the present invention is completely effectively realized.Person skilled in art is understood that The present invention includes but is not limited to content described in attached drawing and the above specific embodiment.Although the present invention is just it is now recognized that the most Practical and preferred embodiment is illustrated, it should be understood that the present invention is not limited to the disclosed embodiments, it is any without departing from this The modification of the function and structure principle of invention is intended to be included in the range of claims.

Claims (10)

1. a kind of Thermal Power Station's timesharing collecting carbonic anhydride storage system, including lean solution holding vessel, absorption tower, rich solution storage Tank, reboiler, Analytic Tower, separator, carbon-dioxide gas compressor and high-pressure carbon dioxide storage system, which is characterized in that
The lean solution holding vessel absorbs carbon dioxide to store to store carbon dioxide absorbent solution, the rich solution holding vessel Absorbing liquid,
The gas inlet of the absorption tower lower part is connected to the smoke-exhaust pipeline of Thermal Power Station,
The carbon dioxide absorbent solution import on the absorption tower top is connected to the lean solution holding vessel,
Exhanst gas outlet at the top of the absorption tower is connected to the chimney of Thermal Power Station,
The rich solution outlet of the absorb the bottom of the tower is connected to the inlet of the rich solution holding vessel,
In peak times of power consumption, power-plant flue gas is passed through in the absorption tower, and in the absorption tower, power-plant flue gas and carbon dioxide are inhaled It receives liquid to be in contact, the carbon dioxide in flue gas is changed into rich solution by carbon dioxide absorbent solution absorption, and the rich solution passes through described The rich solution outlet of absorb the bottom of the tower enter the rich solution holding vessel in, remaining flue gas from the exhanst gas outlet at the top of the absorption tower into Enter chimney;
The rich solution import on the Analytic Tower top is connected to the liquid outlet of the rich solution holding vessel,
Mixed gas outlet at the top of the Analytic Tower is connected to by pipeline with the separator,
The liquid outlet of the parsing tower bottom is connected to by pipeline with the liquid-inlet of the reboiler,
The carbon dioxide gas outlet of the separator is by the inlet communication of pipeline and the carbon-dioxide gas compressor, and described two The outlet of carbonoxide compressor is connected to by pipeline with the high-pressure carbon dioxide storage system;The condensed water of the separator goes out Mouth passes through the condensed water inlet communication of pipeline and the Analytic Tower top;
The steam inlet of the reboiler is connected to power plant steam turbine bleed steam pipework, and the gas vent of the reboiler passes through pipeline It is connected to the gas feed of the Analytic Tower lower part, the lean solution outlet of the reboiler is connected by pipeline and the lean solution holding vessel It is logical;
In the low power consumption phase, the gaseous mixture of carbon dioxide and water vapour is resolved into the rich solution in the Analytic Tower and is remained Extraction raffinate body, the carbon dioxide gas isolated in the separator are transported in the carbon-dioxide gas compressor, the dioxy Change the high-pressure carbon dioxide that carbon compressor generates and is transported to the high-pressure carbon dioxide storage system;It is separated in the separator Water recovery Cheng Shuihou out is returned in the Analytic Tower by pipeline;The remaining liq generated in the Analytic Tower is defeated It send into the reboiler, the steam inlet of the reboiler is connected to power plant steam turbine bleed steam pipework, in the reboiler The remaining liq generated in the Analytic Tower is changed into lean solution and gas after contacting with power plant steam turbine steam extraction, the lean solution is solution The absorbing liquid of carbon dioxide is analysed, the gas is returned in the Analytic Tower by pipeline, and the lean solution is defeated by pipeline It send into the lean solution holding vessel.
2. Thermal Power Station's timesharing collecting carbonic anhydride storage system according to the claims, it is characterised in that: Low power consumption phase, electric energy needed for the carbon-dioxide gas compressor are provided by the extra electric energy of Thermal Power Station.
3. Thermal Power Station's timesharing collecting carbonic anhydride storage system according to the claims, it is characterised in that: institute The outlet for stating carbon-dioxide gas compressor is connected to after a carbon dioxide cooler with the high-pressure carbon dioxide storage system.
4. Thermal Power Station's timesharing collecting carbonic anhydride storage system according to the claims, it is characterised in that: institute The connecting pipeline stated between lean solution holding vessel and the carbon dioxide absorbent solution import on the absorption tower top is equipped with a transfer tube.
5. Thermal Power Station's timesharing collecting carbonic anhydride storage system according to the claims, it is characterised in that: institute The flue gas inlet tube road for stating absorption tower lower part is equipped with a flue gas blower.
6. Thermal Power Station's timesharing collecting carbonic anhydride storage system according to the claims, it is characterised in that: institute The connecting pipeline stated between the rich solution outlet of absorb the bottom of the tower and the inlet of the rich solution holding vessel is equipped with a transfer tube.It is excellent The rich solution inlet ductwork of selection of land, the Analytic Tower top is equipped with a transfer tube.Preferably, the reboiler lean solution outlet with Connecting pipeline between the lean solution holding vessel is equipped with a transfer tube.
7. Thermal Power Station's timesharing collecting carbonic anhydride storage system according to the claims, it is characterised in that: institute The series for stating carbon-dioxide gas compressor is 1.
8. Thermal Power Station's timesharing collecting carbonic anhydride storage system according to the claims, it is characterised in that: Non-electricity peak non-electricity trough period, the system are still run.
9. Thermal Power Station's timesharing collecting carbonic anhydride storage system according to the claims, it is characterised in that: institute System is stated to be in when absorbing operating condition, the liquid in the lean solution holding vessel gradually decreases, the liquid in the rich solution holding vessel by Cumulative to add, the only described lean solution holding vessel, rich solution holding vessel, absorption tower are in operating status.
10. Thermal Power Station's timesharing collecting carbonic anhydride storage system according to the claims, it is characterised in that: institute When stating system in parsing operating condition, only above-mentioned lean solution holding vessel, rich solution holding vessel, Analytic Tower, reboiler, separator, dioxy Change carbon compressor and carbon dioxide cooler is in operating status.
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