CN108926492A - A kind of preparation method of acidic oxidized electric potential water pasteurization towelette - Google Patents

A kind of preparation method of acidic oxidized electric potential water pasteurization towelette Download PDF

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Publication number
CN108926492A
CN108926492A CN201710376095.0A CN201710376095A CN108926492A CN 108926492 A CN108926492 A CN 108926492A CN 201710376095 A CN201710376095 A CN 201710376095A CN 108926492 A CN108926492 A CN 108926492A
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electric potential
potential water
oxidized electric
acidic oxidized
pasteurization towelette
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Inventor
杨黎明
舒国欣
杨海
娄九航
舒庆东
杨智强
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Beijing Armor Biotechnology Co Ltd
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Beijing Armor Biotechnology Co Ltd
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Priority to CN201710376095.0A priority Critical patent/CN108926492A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/20Halogens; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208Tissues; Wipes; Patches
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/18Liquid substances or solutions comprising solids or dissolved gases
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B1/00Cleaning by methods involving the use of tools
    • B08B1/10Cleaning by methods involving the use of tools characterised by the type of cleaning tool
    • B08B1/14Wipes; Absorbent members, e.g. swabs or sponges
    • B08B1/143Wipes

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Biomedical Technology (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)

Abstract

The invention discloses a kind of preparation methods of acidic oxidized electric potential water pasteurization towelette.It is by physical and chemical index:PH2.0~3.0,25~70mg/L of effective chlorine, oxidation-reduction potential >=1100mV acidic oxidized electric potential water, directly immersion preprepared non-woven fabrics, then upper facial tissues machine packaging is produced into acidic oxidized electric potential water pasteurization towelette product.Any preservative, essence and other chemical bactericides are not added in pasteurization towelette.Pasteurization towelette has mmic package and multi-disc packaging, carries out detection by the standard of national health articles and complies fully with requirement.The wet tissue resting period is long, and good sterilization effect is non-stimulated, pollution-free, not allergy, can be directly used for the disinfection and sterilization of hand, skin and mucous membrane, it can also be used to the body surfaces cleaning disinfection such as various utensils.

Description

A kind of preparation method of acidic oxidized electric potential water pasteurization towelette
Technical field
The present invention relates to a kind of preparation methods of acidic oxidized electric potential water pasteurization towelette.It discloses a kind of by physical and chemical index For:PH2.0~3.0,25~70mg/L of effective chlorine, oxidation-reduction potential >=1100mV acidic oxidized electric potential water directly impregnate Then non-woven fabrics is prepared into pasteurization towelette product.
This pasteurization towelette belongs to amenities.Ethyl alcohol and any chemical bactericide is wherein not added.The wet tissue complies fully with state The requirement of family's amenities standard.The wet tissue resting period is long, and good sterilization effect is non-stimulated, pollution-free, not allergy, uses Safety, can be directly used for the disinfection and sterilization of hand, skin and mucous membrane, it can also be used to the body surfaces cleaning disinfection such as various utensils.
Background technique
Acidic oxidized electric potential water (electrolyzed-oxidizing water, abbreviation EOW), is a kind of novel green ring Protect disinfectant.Experimental study proves:Its sterilization mechanism is the comprehensive synergistic effect of physics and chemistry.Light, sky are met after use Gas and organic matter effect are reduced into light water, therefore noresidue, pollution-free.To mucocutaneous non-stimulated, not sensitization, no when use It is carcinogenic, it has no toxic side effect, and drug resistance is not generated to bacterium.
1980, acidic oxidized electric potential water was made and is applied earliest by Japanese, found that it (has " super thin MRSA at that time Bacterium " title methicillin-resistant staphylococcus aureus) have obvious sterilizing effect, and at first be used for field of medicaments.1993 Year is used for Medical Devices sterilization of instruments, is mainly used for the cleaning and sterilizing of endoscopy disinfection and hand.EOW is as wound within 1994 Disinfectant is infected in the prevention of the surface of a wound, obtains recognizing for the World Health Organization, and answered in Rwanda's peace-keeping operations With.1998, U.S.'s approval used acidic oxidized electric potential water.Nineteen ninety-five, acidic oxidized electric potential water product enter China and start On probation in hospital, bactericidal effect and environmental protection characteristic are generally had an optimistic view of.2002, China《Disinfection technology standard》Also acid oxygen Change electric potential water and is included in medical use scope.Disclose acidic oxidized electric potential water generator safety and sanitary standard within 2012 GB28234——2011.Acidic oxidized electric potential water SARS prevention and control, hand-foot-and-mouth disease prevention and control, earthquakes in Sichuan calamity after epidemic prevention, Special role has been played in the major events such as the 2008 Beijing Olympic Games and the food safety guarantee in National Day military parade village in 2009.
Acidic oxidized electric potential water is reduced into water after using as a kind of new disinfectant, do not remain, and will not make to environment At pollution, this is its most outstanding advantages.But the unstability of acidic oxidized electric potential water also influences its broader applications.Cause This, can only generate machine with acidic oxidized electric potential water, use in production, acidic oxidized electric potential water cannot be stored.If can solve it Storage stability, this popularization and application to acidic oxidized electric potential water, it will play great role.
A kind of stable acidic oxidized electric potential water (201310250032.2) has been trial-produceed successfully, while also solving storage life Problem (201110149127.6) develops acidic oxidized electric potential water one kind, two class sterile products.It is insulated using height PET composite material makes package bottle special, using high resistant oxygen isolation method, injects carbon dioxide, acidic oxidized electric potential water can be made to exist Closed preservation 1 year or more under room temperature.This provides reliable guarantee to preparing pasteurization towelette with acidic oxidized electric potential water.
Acidic oxidized electric potential water be it is a kind of safely, effectively, noresidue, environmentally protective disinfectant, be widely used in doctor Treatment field endoscope, the disinfection of haemodialysis equipment and the disinfection of environment, the disinfecting of hand, bedsore, burning in daily life Wound, surface of a wound cleaning.China's version in 2002《Disinfection technology standard》Acidic oxidized electric potential water is included in medical use scope.This Outside, the application of acidic oxidized electric potential water has been expanded to amenities and agriculturally, the disinfection and sterilization of production green non-pollution product.
Acidic oxidized electric potential water wide sterilization spectrum, sterilization are rapid.Domestic and international multinomial research has shown that:Acidic oxidized electric potential water is not only Bacterial propagule, virus can be killed, moreover it is possible to kill the multiple pathogenic microorganisms such as bacterial spore, environmental type of being known as disinfection Sterilized water does not safely and effectively cause environmental pollution.
The pH value of acidic oxidized electric potential water is 2.0~3.0, and available chlorine content is 25~80mg/L, reduction potential (ORP) >= When 1100mV, killing microorganism effect can reach 100%.Its bactericidal mechanism, more generally accepted viewpoint are:Acidic oxidized electric potential water Bactericidal effect be coordination with the synthesis sexual factor, including chemically and physically act on two aspect.Containing certain in acidic oxidized electric potential water The hypochlorous acid of amount is a kind of strong oxidizer, can kill each quasi-microorganism, and high reduction potential can play the role of physical sterilization, Neng Goucong It forcibly obtains electronics above the cell wall of bacterium and sterilizes, to accelerate chemical sterilization, low ph value plays apparent association again With the effect of sterilization.Therefore, acidic oxidized electric potential water is a kind of efficient, quick fungicide.
Oxidation-reduction potential (ORP) sterilizing principle of acidic oxidized electric potential water is:It is pathogenic microorganism cell, unicellular Biological (prokaryotic cell) since hydrogen ion, sodium ion, potassium ion etc. are different in the inside and outside distribution of cell membrane, and is formed centainly The inside and outside current potential of film, reaching has certain potential difference when dynamic equilibrium.Microorganism ORP value is about -400mV~+900mV, and EOW ORP value reach+1100mV or more, its electronics is very insufficient.In the moment for touching microorganism, electronics is just captured, has interfered The balance of its film, changes cell transmembrane potential difference, the permeability of film and the osmotic pressure inside and outside film, causes the broken of cell membrane It splits, cytoplasm is excessive and the change of ultra microstructure;EOW further functions as sterilization and kills into the activity of obstruction enzyme after people's cell Virus function, to keep pathogenic cell (prokaryotic cell) dead.After EOW took electronics by force, oxidation-reduction potential declines rapidly, effect It disappears.
The effect of the pH value of acidic oxidized electric potential water is:The pH value for being most suitable for microbe survival is 3.0~10.0 (acidophilias Except the pH value 2 one 3 that bacterium is liked).And pH value is the scope that 2.7 EOW below have been more than any pathogenic microorganism, because This, the pathogenic microorganisms such as various bacteriums, virus can not all survive in this environment, can inactivate.The gastric juice pH of this and people It is similar for 1~3 bactericidal effect.But the hydrochloric acid ratio EOW sterilizing ability that in contrast, pH value is 2.6 is much weaker, and acidity makes Substance denaturation inactivation takes a long time, therefore pH value is only EOW and provides booster action.
The effect of acidic oxidized electric potential water active oxygen is:Because when electrolytic saltwater, producing active oxygen, and active oxygen can Sterilization.But active oxygen is unstable substance, and the holding time, long acting oxygen was difficult to exist.Someone passes through experiment detection:Save 3 A month EOW still has bactericidal effect, although active oxygen is not the sterilization leading role of EOW, can play booster action, sterilize EOW Ability is stronger.
The effect of Active Chlorine is in acidic oxidized electric potential water:Active Chlorine bactericidal effect is infallible.Containing activity in EOW Chlorine is few, can entrance, enter nose, it is non-stimulated, harmless.It is simultaneously also to have certain bactericidal effect.
Hypochlorous act on is in acidic oxidized electric potential water:It can directly be contacted with enzyme by being impregnated with the cell membrane of cell, Its activity is set to stop and play bactericidal effect.There is research to confirm that hypochlorous acid plays important bactericidal effect, therefore, EOW in EOW With very strong prompt effect, red saccharomycete, Candida albicans, bud branch mould, hair moss bacterium can be killed in 30s;In 2min Kill bacillus cereus.
In conclusion EOW is a kind of Novel sterilizing fungicide based on physical disinfection, supplemented by chemical disinfection.It is to each The pathogenic microorganisms such as kind bacterium, virus can rapid inactivation.It is a kind of disinfectant with extensive prospect.EOW's disappears Malicious bactericidal effect is mainly the comprehensive effect based on high redox potential, supplemented by hypochlorous acid, pH value, active oxygen, Active Chlorine Fruit.Be a kind of wide spectrum, rapidly, the disinfectant of strength, safety.
The sterilization effect of acidic oxidized electric potential water:Staphylococcus aureus, escherichia coli and hay bacillus black are become The killing effect of kind brood cell, EOW stoste act on 2min to staphylococcus aureus and escherichia coli, and killing rate can reach 99.99%;10min is acted on, killing rate can reach 100%.EOW stoste acts on 10min to bacillus subtilis black variety bud cell, kills Rate go out up to 97.00%;30min is acted on, killing rate is up to 100%
The pasteurization towelette of production and sales currently on the market is many kinds of, but has not seen acidic oxidized electric potential water so far Pasteurization towelette.It is most of in these miscellaneous pasteurization towelettes to be added to alcohol, essence and some chemosterilants, such as acetic acid Chlorhexidine, double-chain quaternary ammonium salt, triclosan (the chloro- 2 '-dihydroxy diphenyl ether of 2.4.4 '-three, i.e. DP300) etc., some wet tissues are additionally added Surfactant.The sterilization effect of these wet tissues is unsatisfactory, if being used for a long time can also bring skin to become dry etc. Side effect.Since most of this kind of pasteurization towelette is added to alcohol, there are security risks, are carrying use by air, by plane and in high-speed rail It is all restricted, is also forbidden to use this kind of pasteurization towelette in the Kindergartens kindergarten of child's aggregation.
There are also some wet tissues, attempt to reach Disinfection Effect using a variety of methods.Such as a kind of disinfection by ultraviolet light paper towel box (CN103829867A), the ultraviolet radiator of one 20~29nm is provided in disinfection space, paper roll formula paper handkerchief is inserted in disinfection by ultraviolet light Paper towel box disinfection.A kind of disinfected paper napkin (CN102987967A), with the disinfected paper napkin of the raw material soakings such as radix scutellariae extracting solution.One kind contains The disinfected paper napkin (CN102505183A) of the filament fiber material preparation of lactic acid.A kind of sterilizing paper handkerchief or the scraps of paper (CN 201120531225.1), bottom surface disinfection and sterilization is sprayed at carbamide peroxide layer.In contrast, all not exclusively has acid The outstanding advantages of property electrolyzed oxidizing water wet tissue.
Summary of the invention
The invention discloses a kind of preparation methods with acidic oxidized electric potential water pasteurization towelette.It is by stable acidic oxidation Electric potential water, physical and chemical index control are:PH2.0~3.0,25~70mg/L of effective chlorine, oxidation-reduction potential >=1100mV.It is then straight It connects and impregnates preprepared cleaning non-woven fabrics, then upper facial tissues machine is packed, and production becomes acidic oxidized electric potential water and sterilizes Wet tissue product.
Any preservative, essence and other chemical bactericides are not added in acidic oxidized electric potential water pasteurization towelette.Pasteurization towelette There are mmic package and multi-disc packaging, is detected by the standard of national health articles, quality index is made to comply fully with requirement.This is wet The towel resting period is long, and good sterilization effect is non-stimulated, pollution-free, not allergy, can be directly used in hand, skin and mucous membrane extensively Disinfection and sterilization, it can also be used to the body surfaces cleaning disinfection such as various utensils.
Specific embodiment
Firstly, preparing acidic oxidized electric potential water.Acidic oxidized electric potential water process units is opened, is added on the electrode of sour water slot Forward voltage, on the electrode of buck slot plus backward voltage, the production pure water by pre-processing enter acid from bottom of device Sink and buck slot, under the action of voltage, the chloride ion in saline slot enters sour water slot, and is oxidized and generates acidic oxidation electricity Position water, then flows out from sour sink top.
Using common double constant-current supplies when operation, tank voltage is set to be maintained at 10V hereinafter, Faradaic current is constant always, water flow For 2L/min, pH value is always maintained in saline slot as neutrality.It is carried out continuously 50 hours, guarantees to produce qualified acidic oxidation electricity Position water.
To the acidic oxidized electric potential water produced, detected respectively with relevant test equipment and chemical analysis method, Controlling its physical and chemical index is:PH≤2.9, reduction potential ORP >=1100mV, effective chlorine density reach Acc=60 ± 10mg/L.
By production pasteurization towelette technological process of production requirement, clean non-woven fabrics is got out in advance, by acidic oxidation Electric potential water impregnates 2 minutes, allows non-woven fabrics sufficiently to soak, is then sent directly into wet tissue manufacturing machine, can produce acidic oxidation electricity Position water sterilization wet tissue.Its production process carries out in clean environment, to guarantee product quality.

Claims (5)

1. a kind of preparation method of acidic oxidized electric potential water pasteurization towelette is:By pH2.0~3.0,25~70mg/L of effective chlorine, oxygen Change reduction potential >=1100mV acidic oxidized electric potential water, directly impregnates non-woven fabrics and pasteurization towelette is made.It is free of in pasteurization towelette Other any chemical addition agents, the pasteurization towelette meet the quality criteria requirements of national health articles.
2. as described in claim 1, acidic oxidized electric potential water pasteurization towelette, acidic oxidized electric potential water used, physical and chemical index For:PH2.0~3.0,25~70mg/L of effective chlorine, oxidation-reduction potential >=1100mV.
3. as described in claim 1, acidic oxidized electric potential water pasteurization towelette is to use non-woven fabrics as the disinfection and sterilization health of carrier Articles.
4. as described in claim 1, being killed in acidic oxidized electric potential water pasteurization towelette without any preservative, essence and other chemistry Microbial inoculum.
5. it is quasi- to comply fully with national health articles for as described in claim 1, the quality standard of acidic oxidized electric potential water pasteurization towelette Target requirement.
CN201710376095.0A 2017-05-25 2017-05-25 A kind of preparation method of acidic oxidized electric potential water pasteurization towelette Pending CN108926492A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113171307A (en) * 2021-04-20 2021-07-27 福州美美环保科技有限公司 Manufacturing technology of acidic oxidation potential water disinfection wet tissue
CN114097818A (en) * 2020-08-25 2022-03-01 张宝生 High-efficiency disinfectant and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005065383A3 (en) * 2003-12-30 2006-04-27 Oculus Innovative Sciences Inc Oxidative reductive potential water solution, processes for producing same and methods of using the same
CN2798826Y (en) * 2005-05-27 2006-07-26 蒋立成 Disinfected wet tissue
CN102631165A (en) * 2012-05-03 2012-08-15 张玉 Wet tissue containing slightly acidic electrolyzed water
CN105581913A (en) * 2015-08-26 2016-05-18 北京建元天地环保科技有限公司 Manufacturing method for novel function liquid disinfectant wet wipes harmless to human body

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005065383A3 (en) * 2003-12-30 2006-04-27 Oculus Innovative Sciences Inc Oxidative reductive potential water solution, processes for producing same and methods of using the same
CN2798826Y (en) * 2005-05-27 2006-07-26 蒋立成 Disinfected wet tissue
CN102631165A (en) * 2012-05-03 2012-08-15 张玉 Wet tissue containing slightly acidic electrolyzed water
CN105581913A (en) * 2015-08-26 2016-05-18 北京建元天地环保科技有限公司 Manufacturing method for novel function liquid disinfectant wet wipes harmless to human body

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114097818A (en) * 2020-08-25 2022-03-01 张宝生 High-efficiency disinfectant and preparation method thereof
CN113171307A (en) * 2021-04-20 2021-07-27 福州美美环保科技有限公司 Manufacturing technology of acidic oxidation potential water disinfection wet tissue

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Application publication date: 20181204