CN108912993A - A kind of high-performance coating of glass and preparation method thereof - Google Patents
A kind of high-performance coating of glass and preparation method thereof Download PDFInfo
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- CN108912993A CN108912993A CN201810605289.8A CN201810605289A CN108912993A CN 108912993 A CN108912993 A CN 108912993A CN 201810605289 A CN201810605289 A CN 201810605289A CN 108912993 A CN108912993 A CN 108912993A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of high-performance coating of glass, the raw material including following parts by weight：34-38 parts of waterborne polyurethane resin, 15-19 parts of styrene-acrylic emulsion, 16-22 parts of acrylate and vinyl acetate emulsion, 6-10 parts of modified polycarbonate, 4-8 parts of adhesion promoter, 3-5 parts of polysiloxanes powder hydrophober, 2-5 parts of nano-organosilicon lotion, 6-10 parts of nano zine oxide.The object of the present invention is to provide a kind of high-performance coatings of glass, and the glass coating is nontoxic environmentally protective, water-tolerant, use value with higher and good application prospect.
Description
Technical field
The present invention relates to glass coating technical fields, and in particular to a kind of high-performance coating of glass and its preparation side
Method.
Background technique
Glass is amorphous inorganic non-metallic material, and usually with a variety of inorganic minerals, (such as quartz sand, borax, boric acid, weight are brilliant
Stone, barium carbonate, lime stone, feldspar, soda ash etc.) be primary raw material, additionally incorporate made of a small amount of auxiliary material, it is main at
It is divided into silica and other oxides, the chemical composition of simple glass is Na2SiO3, CaSiO3, SiO2 or Na2OCaO
6SiO2 etc., main component are silicate double salt, are a kind of non-crystalline solids of random structure, are widely used in building, are used
To belong to mixture every wind light transmission, separately there is the oxide for being mixed into certain metals or salt and shows the coloured glass of color
Some transparent plastics, are also referred to as organic glass sometimes by glass, and the tempered glass as made from the method for physics or chemistry etc.
Glass.
Existing Chinese patent literature (publication number：CN105273593B a kind of aqueous one-component glass coating) is disclosed, by
Following raw material is made：Epoxy resin, methyl trichlorosilane, polyaminoester emulsion, ATO dispersion liquid, acrylic modified epoxy resin, ammonia
Base resin, glycol ether, diethylamine, non-ionic associative type polyurethane, dimethyl silicone polymer, deionized water, the glass coating
Middle methyl trichlorosilane is pungent stench, and coating is not environmental type, easily deliquesces, and reduces coating property.
Chinese patent literature (publication number：CN104293027B a kind of emulsion-type glass coating, the emulsion-type) are disclosed
Glass coating is made of following component, is very calculated as by weight：Acrylate polymer emulsion, 40-60%；Modified epoxy tree
Rouge, 0.1-1%；Curing agent, 1-6%；Cosolvent, 3-25%；Auxiliary agent, 0.1-1%；Acidic catalyst, 0.5-5%；Mill base, 1-
10%；Coupling agent, 1-1.5%, the glass water resistance is poor, still needs to further improve.
Summary of the invention
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of high-performance coating of glass, which is applied
Expect nontoxic environmentally protective, water-tolerant, use value with higher and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that：
The present invention provides a kind of high-performance coating of glass, the raw material including following parts by weight：
34-38 parts of waterborne polyurethane resin, 15-19 parts of styrene-acrylic emulsion, 16-22 parts of acrylate and vinyl acetate emulsion, modified polycarbonate 6-
10 parts, 4-8 parts of adhesion promoter, 3-5 parts of polysiloxanes powder hydrophober, 2-5 parts of nano-organosilicon lotion, nano zine oxide
6-10 parts.
Preferably, the high-performance coating of the glass includes the raw material of following parts by weight：
36 parts of waterborne polyurethane resin, 17 parts of styrene-acrylic emulsion, 19 parts of acrylate and vinyl acetate emulsion, 8 parts of modified polycarbonate, attachment are made every effort to promote
Into 6 parts of agent, 4 parts of polysiloxanes powder hydrophober, 3.5 parts of nano-organosilicon lotion, 8 parts of nano zine oxide.
Preferably, the acrylate and vinyl acetate emulsion is using vinylacetate as hard monomer, n-butyl acrylate, acrylic acid isooctyl
It is made as soft monomer by emulsion polymerization.
Preferably, the modified polycarbonate preparation method is that graphene is added in the concentrated sulfuric acid, ultrasonic disperse 1-2h,
Concentrated nitric acid then is added, magnetic agitation 45-55min is heated under 150 DEG C of oil baths, is then centrifuged, is cleaned with ethyl alcohol to solution
Neutrality, re-dry obtain acidifying graphite, by polycarbonate, acidifying graphite, acetone be mixed, be subsequently sent in drying box into
Row drying keeps the temperature 45-55min to get modified polycarbonate.
Preferably, the concentrated sulfuric acid, concentrated nitric acid substance mass ratio be 3:1.
Preferably, the adhesion promoter is silane coupling agent.
Preferably, the silane coupling agent structure is RSi (OM)3, wherein M is methyl, and R is that epoxy-modified saturation is organic
Group.
Preferably, the filler is nano-glass pearl powder.
The present invention provides a kind of preparation methods of the high-performance coating of glass, include the following steps：
Step 1 weighs each component raw material as required；
Waterborne polyurethane resin, styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, modified polycarbonate are placed under vacuum state by step 2
Stirring, mixing speed 150-170r/min, mixing time 25-35min obtain mixture A；
Step 2 is obtained mixture A, adhesion promoter, polysiloxanes powder hydrophober, nano-organosilicon by step 3
Lotion, nano zine oxide are added in high-speed mixer and mix, mixing speed 1200-1300r/min, mixing time 65-
75min, then carries out vacuum defoamation, resolidification to get glass of the invention high-performance coating.
Compared with prior art, the present invention has following beneficial effect：
(1) present invention is arranged in pairs or groups with waterborne polyurethane resin coordinates styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, and waterborne polyurethane resin is mechanical
Have excellent performance, compatibility it is good, mutually cooperateed with styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, improve waterproof performance, be collocated with each other between raw material, group
At coating comprehensive performance can be effectively improved.
(2) acrylate and vinyl acetate emulsion price is low, environment-protecting and non-poisonous, but water-alkali resistance is poor, therefore changes its function monomer and prepare vinegar third
Lotion, waterproof performance is good, and styrene-acrylic emulsion replaces methyl acrylate, therefore its good waterproof performance with styrene in the course of the polymerization process, and two
Person can play synergistic effect, improve waterproof effect.
(3) polycarbonate light transmission with higher, weatherability is good, but water resistance is poor, and acidifying graphite alkene introduces hydroxyl
Base, carboxyl improve its activity, and the two is composite modified, easily combine with styrene-acrylic emulsion, acrylate and vinyl acetate emulsion etc., then improve on the whole and prevent
Water, light transmission.
(4) it is obtained from embodiment 3 and comparative example 1-4, being not added with the water-fast number of days of acrylate and vinyl acetate emulsion reduces five days, is not added with and changes
Property polycarbonate light transmittance reduces 2.9%, and embodiment 3 improves 4.0% relative to 4 light transmittance of comparative example, and water-fast number of days mentions
6 days high, increase rate 60%, water resistance, which has, to be significantly improved.
Specific embodiment
Combined with specific embodiments below, technical scheme in the embodiment of the invention is clearly and completely described, shows
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Embodiment 1.
The present embodiment the present invention provides a kind of high-performance coating of glass, the raw material including following parts by weight：
34 parts of waterborne polyurethane resin, 15 parts of styrene-acrylic emulsion, 16 parts of acrylate and vinyl acetate emulsion, 6 parts of modified polycarbonate, attachment are made every effort to promote
Into 4 parts of agent, 3 parts of polysiloxanes powder hydrophober, 2 parts of nano-organosilicon lotion, 6 parts of nano zine oxide.
The acrylate and vinyl acetate emulsion of the present embodiment is using vinylacetate as hard monomer, n-butyl acrylate, acrylic acid isooctyl
It is made as soft monomer by emulsion polymerization.
The modified polycarbonate preparation method of the present embodiment is that graphene is added in the concentrated sulfuric acid, ultrasonic disperse 1h, with
After add concentrated nitric acid, magnetic agitation 45min is heated under 150 DEG C of oil baths, then be centrifuged, cleaned with ethyl alcohol to solution neutral,
Re-dry obtains acidifying graphite, and polycarbonate, acidifying graphite, acetone are mixed, are subsequently sent to be done in drying box
It is dry, 45min is kept the temperature to get modified polycarbonate.
The concentrated sulfuric acid of the present embodiment, the mass ratio of concentrated nitric acid substance are 3:1.
The adhesion promoter of the present embodiment is silane coupling agent.
The silane coupling agent structure of the present embodiment is RSi (OM)3, wherein M is methyl, and R is the epoxy-modified organic group of saturation.
The filler of the present embodiment is nano-glass pearl powder.
A kind of preparation method of the high-performance coating of glass of the present embodiment, includes the following steps：
Step 1 weighs each component raw material as required；
Waterborne polyurethane resin, styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, modified polycarbonate are placed under vacuum state by step 2
Stirring, mixing speed 150r/min, mixing time 25min obtain mixture A；
Step 2 is obtained mixture A, adhesion promoter, polysiloxanes powder hydrophober, nano-organosilicon by step 3
Lotion, nano zine oxide are added in high-speed mixer and mix, mixing speed 1200r/min, mixing time 65min, with laggard
Row vacuum defoamation, resolidification to get glass of the invention high-performance coating.
Embodiment 2.
The present embodiment the present invention provides a kind of high-performance coating of glass, the raw material including following parts by weight：
38 parts of waterborne polyurethane resin, 19 parts of styrene-acrylic emulsion, 22 parts of acrylate and vinyl acetate emulsion, 10 parts of modified polycarbonate, adhesive force
8 parts of promotor, 5 parts of polysiloxanes powder hydrophober, 5 parts of nano-organosilicon lotion, 10 parts of nano zine oxide.
The acrylate and vinyl acetate emulsion of the present embodiment is using vinylacetate as hard monomer, n-butyl acrylate, acrylic acid isooctyl
It is made as soft monomer by emulsion polymerization.
The modified polycarbonate preparation method of the present embodiment is that graphene is added in the concentrated sulfuric acid, ultrasonic disperse 2h, with
After add concentrated nitric acid, magnetic agitation 55min is heated under 150 DEG C of oil baths, then be centrifuged, cleaned with ethyl alcohol to solution neutral,
Re-dry obtains acidifying graphite, and polycarbonate, acidifying graphite, acetone are mixed, are subsequently sent to be done in drying box
It is dry, 55min is kept the temperature to get modified polycarbonate.
The concentrated sulfuric acid of the present embodiment, the mass ratio of concentrated nitric acid substance are 3:1.
The adhesion promoter of the present embodiment is silane coupling agent.
The silane coupling agent structure of the present embodiment is RSi (OM)3, wherein M is methyl, and R is the epoxy-modified organic group of saturation.
The filler of the present embodiment is nano-glass pearl powder.
A kind of preparation method of the high-performance coating of glass of the present embodiment, includes the following steps：
Step 1 weighs each component raw material as required；
Waterborne polyurethane resin, styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, modified polycarbonate are placed under vacuum state by step 2
Stirring, mixing speed 170r/min, mixing time 35min obtain mixture A；
Step 2 is obtained mixture A, adhesion promoter, polysiloxanes powder hydrophober, nano-organosilicon by step 3
Lotion, nano zine oxide are added in high-speed mixer and mix, mixing speed 1300r/min, mixing time 75min, with laggard
Row vacuum defoamation, resolidification to get glass of the invention high-performance coating.
Embodiment 3.
The present embodiment the present invention provides a kind of high-performance coating of glass, the raw material including following parts by weight：
36 parts of waterborne polyurethane resin, 17 parts of styrene-acrylic emulsion, 19 parts of acrylate and vinyl acetate emulsion, 8 parts of modified polycarbonate, attachment are made every effort to promote
Into 6 parts of agent, 4 parts of polysiloxanes powder hydrophober, 3.5 parts of nano-organosilicon lotion, 8 parts of nano zine oxide.
The acrylate and vinyl acetate emulsion of the present embodiment is using vinylacetate as hard monomer, n-butyl acrylate, acrylic acid isooctyl
It is made as soft monomer by emulsion polymerization.
The modified polycarbonate preparation method of the present embodiment is that graphene is added in the concentrated sulfuric acid, ultrasonic disperse 1.5h,
Concentrated nitric acid then is added, magnetic agitation 50min is heated under 150 DEG C of oil baths, is then centrifuged, is cleaned with ethyl alcohol into solution
Property, re-dry obtains acidifying graphite, polycarbonate, acidifying graphite, acetone is mixed, is subsequently sent to carry out in drying box
It is dry, 50min is kept the temperature to get modified polycarbonate.
The concentrated sulfuric acid of the present embodiment, the mass ratio of concentrated nitric acid substance are 3:1.
The adhesion promoter of the present embodiment is silane coupling agent.
The silane coupling agent structure of the present embodiment is RSi (OM)3, wherein M is methyl, and R is the epoxy-modified organic group of saturation.
The filler of the present embodiment is nano-glass pearl powder.
A kind of preparation method of the high-performance coating of glass of the present embodiment, includes the following steps：
Step 1 weighs each component raw material as required；
Waterborne polyurethane resin, styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, modified polycarbonate are placed under vacuum state by step 2
Stirring, mixing speed 160r/min, mixing time 30min obtain mixture A；
Step 2 is obtained mixture A, adhesion promoter, polysiloxanes powder hydrophober, nano-organosilicon by step 3
Lotion, nano zine oxide are added in high-speed mixer and mix, mixing speed 1250r/min, mixing time 70min, with laggard
Row vacuum defoamation, resolidification to get glass of the invention high-performance coating.
Comparative example 1.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that being not added with acrylate and vinyl acetate emulsion.
Comparative example 2.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that being not added with modified polycarbonate.
Comparative example 3.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that being not added with nano-organosilicon lotion.
Comparative example 4.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that (open using Chinese patent literature
Number：CN105273593B the raw material and method of embodiment 1 in a kind of aqueous one-component glass coating) are disclosed.
Embodiment 3 and comparative example 1-4 the performance test results are as follows
It is obtained from embodiment 3 and comparative example 1-4, being not added with the water-fast number of days of acrylate and vinyl acetate emulsion reduces five days, is not added with modification
Polycarbonate light transmittance reduces 2.9%, and embodiment 3 improves 4.0% relative to 4 light transmittance of comparative example, and water-fast number of days improves
6 days, increase rate 60%, water resistance, which has, to be significantly improved.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (9)
1. a kind of high-performance coating of glass, which is characterized in that the raw material including following parts by weight：
34-38 parts of waterborne polyurethane resin, 15-19 parts of styrene-acrylic emulsion, 16-22 parts of acrylate and vinyl acetate emulsion, 6-10 parts of modified polycarbonate,
4-8 parts of adhesion promoter, 3-5 parts of polysiloxanes powder hydrophober, 2-5 parts of nano-organosilicon lotion, nano zine oxide 6-10
Part.
2. a kind of high-performance coating of glass according to claim 1, which is characterized in that the high-performance of the glass
Coating includes the raw material of following parts by weight：
36 parts of waterborne polyurethane resin, 17 parts of styrene-acrylic emulsion, 19 parts of acrylate and vinyl acetate emulsion, 8 parts of modified polycarbonate, adhesion promoter
6 parts, 4 parts of polysiloxanes powder hydrophober, 3.5 parts of nano-organosilicon lotion, 8 parts of nano zine oxide.
3. a kind of high-performance coating of glass according to claim 1, which is characterized in that the acrylate and vinyl acetate emulsion uses vinegar
Vinyl acetate is made as soft monomer by emulsion polymerization as hard monomer, n-butyl acrylate, acrylic acid isooctyl.
4. a kind of high-performance coating of glass according to claim 1, which is characterized in that the modified polycarbonate system
Preparation Method is that graphene is added in the concentrated sulfuric acid, and ultrasonic disperse 1-2h then adds concentrated nitric acid, magnetic agitation 45-
55min is heated under 150 DEG C of oil baths, is then centrifuged, is cleaned with ethyl alcohol to solution neutral, re-dry, obtain acidifying graphite, will
Polycarbonate, acidifying graphite, acetone are mixed, and are subsequently sent to be dried in drying box, keep the temperature 45-55min to get modification
Polycarbonate.
5. a kind of high-performance coating of glass according to claim 4, which is characterized in that the concentrated sulfuric acid, concentrated nitric acid
The mass ratio of substance is 3:1.
6. a kind of high-performance coating of glass according to claim 1, which is characterized in that the adhesion promoter is
Silane coupling agent.
7. a kind of high-performance coating of glass according to claim 6, which is characterized in that the silane coupling agent structure
For RSi (OM)3, wherein M is methyl, and R is the epoxy-modified organic group of saturation.
8. a kind of high-performance coating of glass according to claim 1, which is characterized in that the filler is that nanoscale is precious
Pearl powder.
9. a kind of method for the high-performance coating for preparing glass as claimed in claim 1 or 2, which is characterized in that including with
Lower step：
Step 1 weighs each component raw material as required；
Waterborne polyurethane resin, styrene-acrylic emulsion, acrylate and vinyl acetate emulsion, modified polycarbonate are placed under vacuum state and stir by step 2,
Mixing speed 150-170r/min, mixing time 25-35min obtain mixture A；
Step 2 is obtained mixture A, adhesion promoter, polysiloxanes powder hydrophober, nano-organosilicon cream by step 3
Liquid, nano zine oxide are added in high-speed mixer and mix, mixing speed 1200-1300r/min, mixing time 65-75min,
Then carry out vacuum defoamation, resolidification to get glass of the invention high-performance coating.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810605289.8A CN108912993A (en) | 2018-06-13 | 2018-06-13 | A kind of high-performance coating of glass and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810605289.8A CN108912993A (en) | 2018-06-13 | 2018-06-13 | A kind of high-performance coating of glass and preparation method thereof |
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| CN108912993A true CN108912993A (en) | 2018-11-30 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112405734A (en) * | 2020-11-10 | 2021-02-26 | 漳州市德根工贸有限公司 | Plywood production process and equipment thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250368A (en) * | 2007-02-20 | 2008-08-27 | 关西油漆株式会社 | Aqueous bottom paint composition and coating method employing the same |
| CN103804876A (en) * | 2014-01-28 | 2014-05-21 | 盐城纳新天地新材料科技有限公司 | High-strength high-heat-conductive modified polycarbonate master batch and preparation method thereof |
| CN104342003A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Dustproof and bactericidal type aqueous coating material for glass doors and preparation method thereof |
| CN108084860A (en) * | 2017-12-31 | 2018-05-29 | 长沙善道新材料科技有限公司 | A kind of environment-friendly heat insulating coating and preparation method thereof |
-
2018
- 2018-06-13 CN CN201810605289.8A patent/CN108912993A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250368A (en) * | 2007-02-20 | 2008-08-27 | 关西油漆株式会社 | Aqueous bottom paint composition and coating method employing the same |
| CN103804876A (en) * | 2014-01-28 | 2014-05-21 | 盐城纳新天地新材料科技有限公司 | High-strength high-heat-conductive modified polycarbonate master batch and preparation method thereof |
| CN104342003A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Dustproof and bactericidal type aqueous coating material for glass doors and preparation method thereof |
| CN108084860A (en) * | 2017-12-31 | 2018-05-29 | 长沙善道新材料科技有限公司 | A kind of environment-friendly heat insulating coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112405734A (en) * | 2020-11-10 | 2021-02-26 | 漳州市德根工贸有限公司 | Plywood production process and equipment thereof |
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Application publication date: 20181130 |