CN108912467A - A kind of high performance cable material and preparation method thereof modified based on ferrocene - Google Patents
A kind of high performance cable material and preparation method thereof modified based on ferrocene Download PDFInfo
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- CN108912467A CN108912467A CN201810470972.5A CN201810470972A CN108912467A CN 108912467 A CN108912467 A CN 108912467A CN 201810470972 A CN201810470972 A CN 201810470972A CN 108912467 A CN108912467 A CN 108912467A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of high performance cable material modified based on ferrocene, the raw material including following parts by weight：36-42 parts of base-material, 26-30 parts of stabilizing reinforcer, 24-28 parts of alumina fibre, fire-retardant light stablize composite fortifier 16-22 parts, ceramic 10-14 parts of dickite mixed powder, 8-12 parts of lauryl mercaptan, 6-10 parts of toughener, 1-3 parts of silane coupling agent KH-560.The object of the present invention is to provide a kind of high performance cable material modified based on ferrocene, the CABLE MATERIALS is stablized, and is used for a long time under high temperature, humidity, acid or alkali environment, will not impact to CABLE MATERIALS, long service life, use value with higher and good application prospect.
Description
Technical field
The present invention relates to CABLE MATERIALS technical fields, and in particular to a kind of high performance cable material modified based on ferrocene and its
Preparation method.
Background technique
Wire cable insulating and sheath are commonly called as CABLE MATERIALS with plastics, and which includes a variety of product such as rubber, plastics, nylon
Kind, CABLE MATERIALS manufacturing enterprise is with cable manufacturing enterprise for user, has the market of CABLE MATERIALS as long as live wire cabling requirements, electricity
Insulating layer mouth is almost required in addition to the bare wires product such as steel-cored aluminium strand, electromagnetic wire in line cable product, at present China's live wire
Nearly 5000 of cable manufacturing enterprise, and have upgrading urban and rural power grids, development of the West Regions and communications facility large area upgrading to electricity
The great demand of line cable product, thus from the point of view of for a period of time, CABLE MATERIALS has extensive market development prospect in China；Closely
In the past few years, CABLE MATERIALS manufacturing enterprise in China's has a great development, especially some private enterprises, in production scale, product knot
The market demand is complied in structure adjustment and new product development, improves a lot, in terms of high voltage cable material, is still some worlds
Renowned company is in occupation of CABLE MATERIALS.
Existing CABLE MATERIALS stability is not very well, to be used for a long time under high temperature, humidity, acid or alkali environment, CABLE MATERIALS can be broken
Skin causes cable core to leak outside, and shortens service life, increases cost, limits the development of CABLE MATERIALS technology.
Summary of the invention
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of high performance cables modified based on ferrocene
Material, the CABLE MATERIALS are stablized, are used for a long time under high temperature, humidity, acid or alkali environment, will not impact to CABLE MATERIALS, use the longevity
Life length, use value with higher and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that：
The present invention provides a kind of high performance cable material modified based on ferrocene, the raw material including following parts by weight：
36-42 parts of base-material, 26-30 parts of stabilizing reinforcer, 24-28 parts of alumina fibre, fire-retardant light stablize composite fortifier 16-22
Part, ceramic 10-14 parts of dickite mixed powder, 8-12 parts of lauryl mercaptan, 6-10 parts of toughener, silane coupling agent KH-560
1-3 parts；
The stabilizing reinforcer includes following raw material：
Pre-process ferrocene 18-24 parts, 14-20 parts of hydrogenated bisphenol A epoxy resin, 8-12 parts of superchlorinated polyvinyl chloride resin, polyester resin
4-10 parts, 6-10 parts of polyurethane resin, 4-10 parts of polyvinyl chloride, 8-12 parts of ethylene chlorotrifluoroethylene, silane coupling agent
2-4 parts of KH-550；
The pretreatment ferrocene preparation method is that ferrocene is sent into ball mill to carry out ball milling, crosses 20 meshes, is then added
Ultrasonic disperse is carried out into benzene, polyethylene glycol, coupling agent is then added in ultrasonic disperse 5-15min, continue to stir 15-25min,
PH to 2-4 is then adjusted, reacts 5min to get pretreatment ferrocene；
It includes following raw material that the fire-retardant light, which stablizes composite fortifier,：
22-28 parts of aluminium hydroxide, 18-20 parts of magnesium hydroxide, 14-18 parts of titanium dioxide, 8-12 parts of zinc oxide, 6-10 parts of carbon black,
2-4 parts of stearic acid, 1-3 parts of sodium tripolyphosphate, 18-24 parts of sodium bentonite, 4-8 parts of mica powder, 3-5 parts of hydrotalcite.
Preferably, the high performance cable material modified based on ferrocene includes the raw material of following parts by weight：
39 parts of base-material, 28 parts of stabilizing reinforcer, 26 parts of alumina fibre, fire-retardant light are stablized 19 parts of reinforcing agent of mixing, ceramic are opened
12 parts of stone mixed powder, 10 parts of lauryl mercaptan, 8 parts of toughener, 2 parts of silane coupling agent KH-560.
Preferably, the base-material is ethylene vinyl acetate copolymer, vinyl acetate in ethylene vinyl acetate copolymer
Content is 8 ~ 16%.
Preferably, in the ethylene vinyl acetate copolymer vinyl acetate content 12%
Preferably, the stabilizing reinforcer preparation method is that will pre-process ferrocene, silane resin acceptor kh-550, hydrogenated bisphenol A
Epoxy resin, superchlorinated polyvinyl chloride resin, polyester resin are added in high-speed mixer, speed of agitator 155-175r/min, stirring
45-55min is then added polyurethane resin, polyvinyl chloride, continues in ethylene chlorotrifluoroethylene to stir 25-35min,
It is subsequently sent to be squeezed out in Twin screw extruder to get stabilizing reinforcer.
Preferably, it includes following raw material that the fire-retardant light, which stablizes composite fortifier,：
25 parts of aluminium hydroxide, 19 parts of magnesium hydroxide, 16 parts of titanium dioxide, 10 parts of zinc oxide, 8 parts of carbon black, 3 parts of stearic acid, trimerization
2 parts of sodium phosphate, 21 parts of sodium bentonite, 6 parts of mica powder, 4 parts of hydrotalcite.
Preferably, the ceramic dickite mixed powder is ceramics, dickite according to weight ratio 5:The mixture of 3 compositions.
Preferably, the toughener is haloflex.
The present invention also provides a kind of methods of high performance cable material modified based on ferrocene, include the following steps：
Step 1 weighs prepare each component raw material as required；
Base-material, stabilizing reinforcer, alumina fibre, fire-retardant light are stablized composite fortifier and are added in high-speed mixer by step 2,
Revolving speed is 150-250r/min, stirs 15-25min, and mixture A is made；
Mixture A made from step 2, ceramic dickite mixed powder, silane coupling agent KH-560 are mixed to join by step 3
It is kneaded in kneading machine, melting temperature is 135-145 DEG C, and mixing time is 55-65 minutes, obtains epoxy glue B；
Epoxy glue B obtained, lauryl mercaptan, toughener are sequentially sent in double screw extruder by step 4, adjust PH
It is worth 8.0-9.0, extruding pelletization is to get the high performance cable material modified based on ferrocene of the invention.
Preferably, four operating temperatures of the step 4 double screw extruder point, the first operating temperature are 126-132 DEG C,
Second operating temperature is 132-138 DEG C, and third operating temperature is 138-148 DEG C, and the 4th operating temperature is 148-158 DEG C.
Compared with prior art, the present invention has following beneficial effect：
（1）A kind of high performance cable material modified based on ferrocene of the invention, uses base-material to help the CABLE MATERIALS prepared with auxiliary material,
Stabilizing reinforcer is matched using plurality of raw materials, and ferrocene activity after pretreatment increases, while ferrocene heat itself is steady
The performances such as fixed, chemically-resistant are good, carry out improving the stability of CABLE MATERIALS again with base composition after suitably matching with auxiliary material.
（2）A kind of high performance cable material modified based on ferrocene of the invention, fire-retardant light are stablized composite fortifier and are used
Inorganic fire retardants and light, which are stablized, carries out the compound raw material prepared, one multi-purpose, working efficiency can be improved, while CABLE MATERIALS is comprehensive
Performance is greatly improved.
（3）A kind of high performance cable material based on ferrocene modification of the invention, ceramic dickite mixed powder use ceramics,
Dickite carries out proportion as CABLE MATERIALS filler, so that CABLE MATERIALS component is closely combined, then can further play raw material
Between interact, reach improve CABLE MATERIALS stability.
（4）A kind of high performance cable material modified based on ferrocene of the invention, which stablizes, in high temperature, tide
It is used for a long time, CABLE MATERIALS will not be impacted, long service life under wet, acid or alkali environment, use value with higher and good
Good application prospect.
Specific embodiment
Combined with specific embodiments below, technical scheme in the embodiment of the invention is clearly and completely described, shows
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of high performance cable material modified based on ferrocene of the present embodiment, the raw material including following parts by weight：
36 parts of base-material, 26 parts of stabilizing reinforcer, 24 parts of alumina fibre, fire-retardant light are stablized 16 parts of composite fortifier, ceramic are opened
10 parts of stone mixed powder, 8 parts of lauryl mercaptan, 6 parts of toughener, 1 part of silane coupling agent KH-560；
The stabilizing reinforcer includes following raw material：
Pre-process 18 parts of ferrocene, 14 parts of hydrogenated bisphenol A epoxy resin, 8 parts of superchlorinated polyvinyl chloride resin, 4 parts of polyester resin, polyurethane
6 parts of resin, 4 parts of polyvinyl chloride, 8 parts of ethylene chlorotrifluoroethylene, 2 parts of silane resin acceptor kh-550；
The pretreatment ferrocene preparation method is that ferrocene is sent into ball mill to carry out ball milling, crosses 20 meshes, is then added
Ultrasonic disperse is carried out into benzene, polyethylene glycol, coupling agent is then added in ultrasonic disperse 5min, continues to stir 15min, then adjust
PH to 2 is saved, reacts 5min to get pretreatment ferrocene；
It includes following raw material that the fire-retardant light, which stablizes composite fortifier,：
22 parts of aluminium hydroxide, 18 parts of magnesium hydroxide, 14 parts of titanium dioxide, 8 parts of zinc oxide, 6 parts of carbon black, 2 parts of stearic acid, trimerization phosphorus
1 part of sour sodium, 18 parts of sodium bentonite, 4 parts of mica powder, 3 parts of hydrotalcite.
The base-material of the present embodiment is ethylene vinyl acetate copolymer, and vinyl acetate contains in ethylene vinyl acetate copolymer
Amount is 8%.
The stabilizing reinforcer preparation method of the present embodiment is that will pre-process ferrocene, silane resin acceptor kh-550, hydrogenation pair
Phenol A epoxy resin, superchlorinated polyvinyl chloride resin, polyester resin are added in high-speed mixer, speed of agitator 155r/min, stirring
45min is then added polyurethane resin, polyvinyl chloride, continues in ethylene chlorotrifluoroethylene to stir 25min, then send
Enter in Twin screw extruder and is squeezed out to get stabilizing reinforcer.
The ceramic dickite mixed powder of the present embodiment is ceramics, dickite according to weight ratio 5:The mixture of 3 compositions.
The toughener of the present embodiment is haloflex.
A kind of method of high performance cable material modified based on ferrocene of the present embodiment, includes the following steps：
Step 1 weighs prepare each component raw material as required；
Base-material, stabilizing reinforcer, alumina fibre, fire-retardant light are stablized composite fortifier and are added in high-speed mixer by step 2,
Revolving speed is 150r/min, stirs 15min, and mixture A is made；
Mixture A made from step 2, ceramic dickite mixed powder, silane coupling agent KH-560 are mixed to join by step 3
It is kneaded in kneading machine, melting temperature is 135 DEG C, and mixing time is 55 minutes, obtains epoxy glue B；
Epoxy glue B obtained, lauryl mercaptan, toughener are sequentially sent in double screw extruder by step 4, adjust PH
It is worth 8.0, extruding pelletization is to get the high performance cable material modified based on ferrocene of the invention.
Four double screw extruder of the step of the present embodiment point, four operating temperatures, the first operating temperature are 126 DEG C, the second work
Making temperature is 132 DEG C, and third operating temperature is 138 DEG C, and the 4th operating temperature is 148 DEG C.
Embodiment 2.
A kind of high performance cable material modified based on ferrocene of the present embodiment, the raw material including following parts by weight：
42 parts of base-material, 30 parts of stabilizing reinforcer, 28 parts of alumina fibre, fire-retardant light are stablized 22 parts of composite fortifier, ceramic are opened
14 parts of stone mixed powder, 12 parts of lauryl mercaptan, 10 parts of toughener, 3 parts of silane coupling agent KH-560；
The stabilizing reinforcer includes following raw material：
Pre-process 24 parts of ferrocene, 20 parts of hydrogenated bisphenol A epoxy resin, 12 parts of superchlorinated polyvinyl chloride resin, 10 parts of polyester resin, poly- ammonia
10 parts of ester resin, 10 parts of polyvinyl chloride, 12 parts of ethylene chlorotrifluoroethylene, 4 parts of silane resin acceptor kh-550；
The pretreatment ferrocene preparation method is that ferrocene is sent into ball mill to carry out ball milling, crosses 20 meshes, is then added
Ultrasonic disperse is carried out into benzene, polyethylene glycol, coupling agent is then added in ultrasonic disperse 15min, continues to stir 25min, then adjust
PH to 4 is saved, reacts 5min to get pretreatment ferrocene；
It includes following raw material that the fire-retardant light, which stablizes composite fortifier,：
28 parts of aluminium hydroxide, 20 parts of magnesium hydroxide, 18 parts of titanium dioxide, 12 parts of zinc oxide, 10 parts of carbon black, 4 parts of stearic acid, trimerization
3 parts of sodium phosphate, 24 parts of sodium bentonite, 8 parts of mica powder, 5 parts of hydrotalcite.
The base-material of the present embodiment is ethylene vinyl acetate copolymer, and vinyl acetate contains in ethylene vinyl acetate copolymer
Amount is 16%.
The stabilizing reinforcer preparation method of the present embodiment is that will pre-process ferrocene, silane resin acceptor kh-550, hydrogenation pair
Phenol A epoxy resin, superchlorinated polyvinyl chloride resin, polyester resin are added in high-speed mixer, speed of agitator 175r/min, stirring
55min is then added polyurethane resin, polyvinyl chloride, continues in ethylene chlorotrifluoroethylene to stir 35min, then send
Enter in Twin screw extruder and is squeezed out to get stabilizing reinforcer.
The ceramic dickite mixed powder of the present embodiment is ceramics, dickite according to weight ratio 5:The mixture of 3 compositions.
The toughener of the present embodiment is haloflex.
A kind of method of high performance cable material modified based on ferrocene of the present embodiment, includes the following steps：
Step 1 weighs prepare each component raw material as required；
Base-material, stabilizing reinforcer, alumina fibre, fire-retardant light are stablized composite fortifier and are added in high-speed mixer by step 2,
Revolving speed is 250r/min, stirs 25min, and mixture A is made；
Mixture A made from step 2, ceramic dickite mixed powder, silane coupling agent KH-560 are mixed to join by step 3
It is kneaded in kneading machine, melting temperature is 145 DEG C, and mixing time is 65 minutes, obtains epoxy glue B；
Epoxy glue B obtained, lauryl mercaptan, toughener are sequentially sent in double screw extruder by step 4, adjust PH
It is worth 9.0, extruding pelletization is to get the high performance cable material modified based on ferrocene of the invention.
Four double screw extruder of the step of the present embodiment point, four operating temperatures, the first operating temperature are 132 DEG C, the second work
Making temperature is 138 DEG C, and third operating temperature is 148 DEG C, and the 4th operating temperature is 158 DEG C.
Embodiment 3.
A kind of high performance cable material modified based on ferrocene of the present embodiment, the raw material including following parts by weight：
39 parts of base-material, 28 parts of stabilizing reinforcer, 26 parts of alumina fibre, fire-retardant light are stablized 19 parts of composite fortifier, ceramic are opened
12 parts of stone mixed powder, 10 parts of lauryl mercaptan, 8 parts of toughener, 2 parts of silane coupling agent KH-560；
The stabilizing reinforcer includes following raw material：
Pre-process 21 parts of ferrocene, 17 parts of hydrogenated bisphenol A epoxy resin, 10 parts of superchlorinated polyvinyl chloride resin, 7 parts of polyester resin, poly- ammonia
8 parts of ester tree, 7 parts of polyvinyl chloride, 10 parts of ethylene chlorotrifluoroethylene, 3 parts of silane resin acceptor kh-550；
The pretreatment ferrocene preparation method is that ferrocene is sent into ball mill to carry out ball milling, crosses 20 meshes, is then added
Ultrasonic disperse is carried out into benzene, polyethylene glycol, coupling agent is then added in ultrasonic disperse 10min, continues to stir 20min, then adjust
PH to 3 is saved, reacts 5min to get pretreatment ferrocene；
It includes following raw material that the fire-retardant light, which stablizes composite fortifier,：
25 parts of aluminium hydroxide, 19 parts of magnesium hydroxide, 16 parts of titanium dioxide, 10 parts of zinc oxide, 8 parts of carbon black, 3 parts of stearic acid, trimerization
2 parts of sodium phosphate, 21 parts of sodium bentonite, 6 parts of mica powder, 4 parts of hydrotalcite.
The base-material of the present embodiment is ethylene vinyl acetate copolymer, and vinyl acetate contains in ethylene vinyl acetate copolymer
Amount is 12%.
The stabilizing reinforcer preparation method of the present embodiment is that will pre-process ferrocene, silane resin acceptor kh-550, hydrogenation pair
Phenol A epoxy resin, superchlorinated polyvinyl chloride resin, polyester resin are added in high-speed mixer, speed of agitator 160r/min, stirring
50min is then added polyurethane resin, polyvinyl chloride, continues in ethylene chlorotrifluoroethylene to stir 30min, then send
Enter in Twin screw extruder and is squeezed out to get stabilizing reinforcer.
The ceramic dickite mixed powder of the present embodiment is ceramics, dickite according to weight ratio 5:The mixture of 3 compositions.
The toughener of the present embodiment is haloflex.
A kind of method of high performance cable material modified based on ferrocene of the present embodiment, includes the following steps：
Step 1 weighs prepare each component raw material as required；
Base-material, stabilizing reinforcer, alumina fibre, fire-retardant light are stablized composite fortifier and are added in high-speed mixer by step 2,
Revolving speed is 200r/min, stirs 20min, and mixture A is made；
Mixture A made from step 2, ceramic dickite mixed powder, silane coupling agent KH-560 are mixed to join by step 3
It is kneaded in kneading machine, melting temperature is 140 DEG C, and mixing time is 60 minutes, obtains epoxy glue B；
Epoxy glue B obtained, lauryl mercaptan, toughener are sequentially sent in double screw extruder by step 4, adjust PH
It is worth 85, extruding pelletization is to get the high performance cable material modified based on ferrocene of the invention.
Four double screw extruder of the step of the present embodiment point, four operating temperatures, the first operating temperature are 129 DEG C, the second work
Making temperature is 135 DEG C, and third operating temperature is 143 DEG C, and the 4th operating temperature is 153 DEG C.
Comparative example 1.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that not adding stabilizing reinforcer.
Comparative example 2.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that not adding pretreatment two in stabilizing reinforcer
Luxuriant iron.
Comparative example 3.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that not adding fire-retardant light stablizes composite fortifier.
Embodiment 1 to 3 and the high performance cable material acid and alkali-resistance of comparative example 1-3 preparation are tested to obtain the performance test results
It is as follows
| 80 DEG C of acid resistances | 90 DEG C of acid resistances | 100 DEG C of acid resistances | 110 DEG C of acid resistances | |
| Embodiment 1 | It is excellent | It is excellent | It is excellent | It is excellent |
| Embodiment 2 | It is excellent | It is excellent | It is excellent | It is excellent |
| Embodiment 3 | It is excellent | It is excellent | It is excellent | It is excellent |
| Comparative example 1 | It is excellent | Well | It is qualified | It is qualified |
| Comparative example 2 | It is excellent | It is excellent | Well | Well |
| Comparative example 3 | It is excellent | It is excellent | It is excellent | It is excellent |
It draws a conclusion by many experiments and performance test, a kind of high performance cable material modified based on ferrocene of the invention,
The CABLE MATERIALS is stablized, and is used for a long time under high temperature, humidity, acid or alkali environment, will not impact to CABLE MATERIALS, service life
It is long, use value with higher and good application prospect.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (10)
1. a kind of high performance cable material modified based on ferrocene, which is characterized in that the raw material including following parts by weight：
36-42 parts of base-material, 26-30 parts of stabilizing reinforcer, 24-28 parts of alumina fibre, fire-retardant light stablize composite fortifier 16-22
Part, ceramic 10-14 parts of dickite mixed powder, 8-12 parts of lauryl mercaptan, 6-10 parts of toughener, silane coupling agent KH-560
1-3 parts；
The stabilizing reinforcer includes following raw material：
Pre-process ferrocene 18-24 parts, 14-20 parts of hydrogenated bisphenol A epoxy resin, 8-12 parts of superchlorinated polyvinyl chloride resin, polyester resin
4-10 parts, 6-10 parts of polyurethane resin, 4-10 parts of polyvinyl chloride, 8-12 parts of ethylene chlorotrifluoroethylene, silane coupling agent
2-4 parts of KH-550；
The pretreatment ferrocene preparation method is that ferrocene is sent into ball mill to carry out ball milling, crosses 20 meshes, is then added
Ultrasonic disperse is carried out into benzene, polyethylene glycol, coupling agent is then added in ultrasonic disperse 5-15min, continue to stir 15-25min,
PH to 2-4 is then adjusted, reacts 5min to get pretreatment ferrocene；
It includes following raw material that the fire-retardant light, which stablizes composite fortifier,：
22-28 parts of aluminium hydroxide, 18-20 parts of magnesium hydroxide, 14-18 parts of titanium dioxide, 8-12 parts of zinc oxide, 6-10 parts of carbon black,
2-4 parts of stearic acid, 1-3 parts of sodium tripolyphosphate, 18-24 parts of sodium bentonite, 4-8 parts of mica powder, 3-5 parts of hydrotalcite.
2. a kind of high performance cable material modified based on ferrocene according to claim 1, which is characterized in that described to be based on
The modified high performance cable material of ferrocene includes the raw material of following parts by weight：
39 parts of base-material, 28 parts of stabilizing reinforcer, 26 parts of alumina fibre, fire-retardant light are stablized 19 parts of reinforcing agent of mixing, ceramic are opened
12 parts of stone mixed powder, 10 parts of lauryl mercaptan, 8 parts of toughener, 2 parts of silane coupling agent KH-560.
3. a kind of high performance cable material modified based on ferrocene according to claim 1 or 2, which is characterized in that described
Base-material is ethylene vinyl acetate copolymer, and vinyl acetate content is 8 ~ 16% in ethylene vinyl acetate copolymer.
4. a kind of high performance cable material modified based on ferrocene according to claim 3, which is characterized in that the ethylene
Vinyl acetate content is 12% in vinyl acetate copolymer.
5. a kind of high performance cable material modified based on ferrocene according to claim 1, which is characterized in that the stabilization
Reinforcing agent preparation method is that will pre-process ferrocene, silane resin acceptor kh-550, hydrogenated bisphenol A epoxy resin, Vinylidene Chloride tree
Rouge, polyester resin are added in high-speed mixer, speed of agitator 155-175r/min, stir 45-55min, are then added poly-
Urethane resin, polyvinyl chloride continue in ethylene chlorotrifluoroethylene to stir 25-35min, are subsequently sent to Twin screw extruder
In squeezed out to get stabilizing reinforcer.
6. a kind of high performance cable material modified based on ferrocene according to claim 1, which is characterized in that described fire-retardant
It includes following raw material that light, which stablizes composite fortifier,：
25 parts of aluminium hydroxide, 19 parts of magnesium hydroxide, 16 parts of titanium dioxide, 10 parts of zinc oxide, 8 parts of carbon black, 3 parts of stearic acid, trimerization
2 parts of sodium phosphate, 21 parts of sodium bentonite, 6 parts of mica powder, 4 parts of hydrotalcite.
7. a kind of high performance cable material modified based on ferrocene according to claim 1, which is characterized in that the ceramics
Dickite mixed powder is ceramics, dickite according to weight ratio 5:The mixture of 3 compositions.
8. a kind of high performance cable material modified based on ferrocene according to claim 1, which is characterized in that the toughening
Agent is haloflex.
9. a kind of prepare the method such as the described in any item high performance cable material modified based on ferrocene of claim 1-8,
It is characterized in that, includes the following steps：
Step 1 weighs prepare each component raw material as required；
Base-material, stabilizing reinforcer, alumina fibre, fire-retardant light are stablized composite fortifier and are added in high-speed mixer by step 2,
Revolving speed is 150-250r/min, stirs 15-25min, and mixture A is made；
Mixture A made from step 2, ceramic dickite mixed powder, silane coupling agent KH-560 are mixed to join by step 3
It is kneaded in kneading machine, melting temperature is 135-145 DEG C, and mixing time is 55-65 minutes, obtains epoxy glue B；
Epoxy glue B obtained, lauryl mercaptan, toughener are sequentially sent in double screw extruder by step 4, adjust PH
It is worth 8.0-9.0, extruding pelletization is to get the high performance cable material modified based on ferrocene of the invention.
10. a kind of preparation method of high performance cable material modified based on ferrocene according to claim 9, feature exist
In four operating temperatures of the step 4 double screw extruder point, the first operating temperature is 126-132 DEG C, the second operating temperature
It is 132-138 DEG C, third operating temperature is 138-148 DEG C, and the 4th operating temperature is 148-158 DEG C.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265739A (en) * | 2013-04-27 | 2013-08-28 | 安徽省康利亚实业有限公司 | Flame retardant cable sheath material |
| CN103509349A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Rubber-sheathed cable material for coal mines and preparation method thereof |
| CN103509235A (en) * | 2013-10-12 | 2014-01-15 | 绿宝电缆（集团）有限公司 | Environment-friendly polyethylene cable material and preparation method thereof |
-
2018
- 2018-05-17 CN CN201810470972.5A patent/CN108912467A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265739A (en) * | 2013-04-27 | 2013-08-28 | 安徽省康利亚实业有限公司 | Flame retardant cable sheath material |
| CN103509349A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Rubber-sheathed cable material for coal mines and preparation method thereof |
| CN103509235A (en) * | 2013-10-12 | 2014-01-15 | 绿宝电缆（集团）有限公司 | Environment-friendly polyethylene cable material and preparation method thereof |
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Application publication date: 20181130 |