CN108384143A - Anti-freezing flame-retardant cable material and preparation method thereof - Google Patents
Anti-freezing flame-retardant cable material and preparation method thereof Download PDFInfo
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- CN108384143A CN108384143A CN201810158737.4A CN201810158737A CN108384143A CN 108384143 A CN108384143 A CN 108384143A CN 201810158737 A CN201810158737 A CN 201810158737A CN 108384143 A CN108384143 A CN 108384143A
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- Prior art keywords
- parts
- cable material
- mixing
- freeze proof
- resistant cable
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- 239000000463 material Substances 0.000 title claims abstract description 45
- 239000003063 flame retardant Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 6
- 238000007710 freezing Methods 0.000 title abstract 2
- 239000011347 resin Substances 0.000 claims abstract description 32
- 229920005989 resin Polymers 0.000 claims abstract description 32
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 30
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 30
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 20
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 20
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 239000004014 plasticizer Substances 0.000 claims abstract description 18
- 239000011521 glass Substances 0.000 claims abstract description 16
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010445 mica Substances 0.000 claims abstract description 13
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 13
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 13
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 12
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 12
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 12
- 239000008116 calcium stearate Substances 0.000 claims abstract description 12
- 239000006229 carbon black Substances 0.000 claims abstract description 12
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 12
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 12
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 8
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 36
- 230000009970 fire resistant effect Effects 0.000 claims description 29
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 24
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 17
- -1 ethylamino-ethyl Chemical group 0.000 claims description 16
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 12
- HOOANQZZUGPTRH-UHFFFAOYSA-N molybdenum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Mo+3].[Mo+3] HOOANQZZUGPTRH-UHFFFAOYSA-N 0.000 claims description 12
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 12
- 235000019260 propionic acid Nutrition 0.000 claims description 12
- 235000012241 calcium silicate Nutrition 0.000 claims description 11
- 239000011812 mixed powder Substances 0.000 claims description 10
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 8
- 238000003723 Smelting Methods 0.000 claims description 7
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 7
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 239000007822 coupling agent Substances 0.000 claims description 6
- 229920001971 elastomer Polymers 0.000 claims description 6
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 6
- 239000005060 rubber Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 235000011132 calcium sulphate Nutrition 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000741 silica gel Substances 0.000 claims description 4
- 229910002027 silica gel Inorganic materials 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 2
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 claims 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical group NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical class ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 1
- 125000002252 acyl group Chemical group 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 239000012965 benzophenone Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 239000000395 magnesium oxide Substances 0.000 claims 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 abstract 2
- 239000002250 absorbent Substances 0.000 abstract 1
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 239000000378 calcium silicate Substances 0.000 abstract 1
- 229910052918 calcium silicate Inorganic materials 0.000 abstract 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 description 14
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 4
- XLRUBBLFUXKSTB-UHFFFAOYSA-N NCCC(O[Si](OC)(OC)CCC)(N)CCN Chemical group NCCC(O[Si](OC)(OC)CCC)(N)CCN XLRUBBLFUXKSTB-UHFFFAOYSA-N 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001596 poly (chlorostyrenes) Polymers 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention discloses an anti-freezing flame-retardant cable material and a preparation method thereof, relating to the technical field of cable materials and comprising the following raw materials in parts by weight: 45-55 parts of modified polyvinyl chloride resin, 15-25 parts of butadiene rubber, 12-24 parts of mica, 10-18 parts of montmorillonite, 9-18 parts of calcium silicate, 4-9 parts of calcium sulfate, 5-10 parts of calcium stearate, 10-16 parts of antimony trioxide, 8-15 parts of molybdenum trioxide, 5-12 parts of aluminum hydroxide, 5-12 parts of magnesium hydroxide, 4-10 parts of carbon black, 4-7 parts of a silane coupling agent, 3-6 parts of an antioxidant, 3-6 parts of an ultraviolet absorbent, 4-7 parts of a flame retardant and 3-6 parts of a plasticizer; the cable material disclosed by the invention is excellent in low-temperature and high-temperature resistance, good in flame retardant property and tensile property, simple in preparation method, and the glass beads are adopted to improve the polyvinyl chloride resin, so that the compactness and the structural stability of the polyvinyl chloride resin are enhanced, and the aging resistance of the material is improved.
Description
Technical field
The present invention relates to CABLE MATERIALS technical fields, and in particular to a kind of freeze proof fire-resistant cable material and preparation method thereof.
Background technology
Wire cable insulating and sheath are commonly called as CABLE MATERIALS with plastics, and which includes a variety of product such as rubber, plastics, nylon
Kind.CABLE MATERIALS manufacturing enterprise is with cable manufacturing enterprise for user, there is the market of CABLE MATERIALS as long as live wire cabling requirements.Electricity
In line cable product insulating layer mouth is almost required in addition to the bare wires product such as steel-cored aluminium strand, electromagnetic wire.China's live wire at present
Nearly 5000 of cable manufacturing enterprise, and have upgrading urban and rural power grids, development of the West Regions and communications facility large area upgrading to electricity
The great demand of line cable product, thus from the point of view of for a period of time, CABLE MATERIALS has extensive market development foreground in China.
Electric wire needs to be chronically exposed in external environment, needs stronger freeze proof high temperature resistance.As society is right
The concern of fire hazard is more and more closer, and fireproofing of cable performance also requires higher.CABLE MATERIALS in the prior art is mainly PVC
CABLE MATERIALS has that easy to aging, anti-flammability is not high.
Invention content
For problems of the prior art, the present invention provides a kind of freeze proof fire-resistant cable material and preparation method thereof,
CABLE MATERIALS low-temperature resistance and high-temperature behavior of the present invention are excellent, and flame retardant property and tensile property are good, and preparation method is simple, micro- using glass
Pearl improves Corvic, and glass microballoon filling polyvinyl chloride resin internal structure enhances the densification of Corvic
Property and structural stability, improve the ageing resistance of material.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of freeze proof fire-resistant cable material includes the raw material of following parts by weight meter：
45-55 parts of modified PVC resin, 15-25 parts of butadiene rubber, 12-24 parts of mica, 10-18 parts of montmorillonite, silicon
Sour calcium 9-18 parts, 4-9 parts of calcium sulfate, 5-10 parts of calcium stearate, 10-16 parts of antimony oxide, 8-15 parts of molybdenum sesquioxide, hydrogen-oxygen
Change 5-12 parts of aluminium, 5-12 parts of magnesium hydroxide, 4-10 parts of carbon black, 4-7 parts of silane coupling agent, 3-6 parts of antioxidant, ultraviolet absorber 3-
3-6 parts of 6 parts, 4-7 parts of fire retardant and plasticizer；
The preparation method of the modified polyvinyl chloride resin is：By the glass of Corvic and its weight 15%-20%
The vinyltrimethoxysilane of glass microballon and 2%-4% mix, and are warming up to 200-300 degrees Celsius, 40-50 points of high-speed stirred
Clock is put into mixing in mixer after mixing, 120-150 degrees Celsius of smelting temperature, and mixing time 10-15 minutes is to get changing
Property Corvic.
Preferably, include the raw material of following parts by weight meter：51 parts of modified PVC resin, 20 parts of butadiene rubber, mica
18 parts, 15 parts of montmorillonite, 14 parts of calcium silicates, 6 parts of calcium sulfate, 8 parts of calcium stearate, 13 parts of antimony oxide, molybdenum sesquioxide 12
Part, 8 parts of aluminium hydroxide, 8 parts of magnesium hydroxide, 4 parts of carbon black, 5.8 parts of silane coupling agent, 4.5 parts of antioxidant, ultraviolet absorber 4.8
4.7 parts of part, 5.6 parts of fire retardant and plasticizer；
The preparation method of the modified polyvinyl chloride resin is：By the glass microballoon of Corvic and its weight 18%
Vinyltrimethoxysilane with 3.4% mixes, and is warming up to 260 degrees Celsius, high-speed stirred 46 minutes after mixing, is put
Enter mixing in mixer, 135 degrees Celsius of smelting temperature, mixing time 13 minutes is to get modified PVC resin.
Preferably, the silane coupling agent is aminoethyl aminoethyl amino propyl trimethoxy silane, three (beta-methoxy of vinyl
Ethyoxyl) silane, one or more of N- ethoxy acyl ethylamino-ethyl aminoethyl amino propyl trimethoxy silanes combine.
Preferably, the antioxidant be four (β-(3,5- di-t-butyl 4- hydroxy phenyls) propionic acid) pentaerythritol esters, β-(3,
5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol ester and phosphite be according to mass ratio 2:2:1 mixing composition.
Preferably, the ultraviolet absorber be 2-hydroxy-4-n-octoxybenzophenone and hexamethylphosphoric acid triamide according to
Mass ratio 3:1 mixing composition.
Preferably, the fire retardant is that one or more of silicate, silica gel and talcum powder combine.
Preferably, the plasticizer is one kind or several in phthalic acid ester, fatty group dibasic acid and polyol ester
Kind mixing.
The invention also discloses a kind of preparation methods of above-mentioned freeze proof fire-resistant cable material specifically to include the following steps：
(1) each raw material is weighed according to the parts by weight of raw materials of freeze proof fire-resistant cable material；
(2) by mica, montmorillonite, calcium silicates, calcium sulfate, calcium stearate, antimony oxide, molybdenum sesquioxide, hydroxide
It is ground in aluminium, magnesium hydroxide, carbon black mixing input grinder, then crosses 100-200 and sieve to get mixed-powder, it is spare；
(3) mixed-powder is made in modified PVC resin, poly- fourth rubber silicon and alkane coupling agent and step (2) to mix, is risen
Temperature is to 78-95 degrees Celsius, with 1000-2000 revs/min, stirring 25-40 minutes to get mixture M, it is spare；
(4) mixture N and antioxidant, ultraviolet absorber, fire retardant and plasticizer are mixed to be put into mixer and is kneaded, mixed
85-95 degrees Celsius of temperature is refined, mixing time 15-30 minutes is to get mixture N；
(5) extruding pelletization, 65-80 degrees Celsius of extrusion temperature in mixture N input double screw extruders are cooled to room
Temperature screens out substandard products, packaging to get the freeze proof fire-resistant cable material.
The present invention has following advantageous effect：
(1) CABLE MATERIALS low-temperature resistance and high-temperature behavior of the present invention are excellent, and flame retardant property and tensile property are good, preparation method letter
It is single, Corvic is improved using glass microballoon, glass microballoon filling polyvinyl chloride resin internal structure enhances polychlorostyrene second
The compactness and structural stability of olefine resin, improve the ageing resistance of material.
(2) present invention is added with modified PVC resin, and glass microballoon light specific gravity volume is big, and density is approximately traditional filling
Ten parts for expecting density of particle, can mitigate the base weight of product significantly after filling, substitute and save more production resins,
Reduce product cost.Glass microballoon has the advantages that insulation, water absorption rate are low simultaneously, and filling not only increases with Corvic
The strong compactness and structural stability of Corvic, while enhancing the insulating properties and water proofing property of Corvic.
It can be used as a kind of coupling agent, reinforcing glass microballon and Corvic simultaneously added with a small amount of vinyltrimethoxysilane
Binding force and structure space stability.
(3) oxidant added in raw material of the present invention is four (β-(3,5- di-t-butyl 4- hydroxy phenyls) propionic acid) Ji Wusi
Alcohol ester, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol esters and phosphite are according to mass ratio 2:2:1 mixing
Composition, two kinds of alcohol esters have extremely strong stability and inoxidizability as main anti-oxidant, phosphite as auxiliary oxidant, in conjunction with
It uses, antioxidant effect is made to be optimal.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of freeze proof fire-resistant cable material includes the raw material of following parts by weight meter：
45 parts of modified PVC resin, 15 parts of butadiene rubber, 12 parts of mica, 10 parts of montmorillonite, 9 parts of calcium silicates, sulfuric acid
4 parts of calcium, 5 parts of calcium stearate, 10 parts of antimony oxide, 8 parts of molybdenum sesquioxide, 5 parts of aluminium hydroxide, 5 parts of magnesium hydroxide, carbon black 4
Part, 4 parts of silane coupling agent, 3 parts of antioxidant, 3 parts of ultraviolet absorber, 4 parts of fire retardant and 3 parts of plasticizer；
The preparation method of modified polyvinyl chloride resin is：
Corvic and the glass microballoon of its weight 15% and 2% vinyltrimethoxysilane are mixed, risen
Temperature is to 200 degrees Celsius, and high-speed stirred 40 minutes is put into mixing in mixer after mixing, and 120 degrees Celsius of smelting temperature is close
10 minutes time is refined to get modified PVC resin.
Silane coupling agent is aminoethyl aminoethyl amino propyl trimethoxy silane and vinyl three (beta-methoxy ethyoxyl) silicon
Alkane is according to mass ratio 1:1 mixing composition.
Antioxidant is four (β-(3,5- di-t-butyl 4- hydroxy phenyls) propionic acid) pentaerythritol esters, β-(3,5- di-t-butyls-
4- hydroxy phenyls) propionic acid n-octadecyl alcohol ester and phosphite be according to mass ratio 2:2:1 mixing composition.
Ultraviolet absorber is 2-hydroxy-4-n-octoxybenzophenone and hexamethylphosphoric acid triamide according to mass ratio 3:1 is mixed
It is combined into.
Fire retardant is sodium metasilicate and silica gel according to mass ratio 1:1 mixing composition.
Plasticizer is phthalic acid ester.
A kind of preparation method of above-mentioned freeze proof fire-resistant cable material is also disclosed in the present embodiment, specifically, including following step
Suddenly：
(1) each raw material is weighed according to the parts by weight of raw materials of freeze proof fire-resistant cable material；
(2) by mica, montmorillonite, calcium silicates, calcium sulfate, calcium stearate, antimony oxide, molybdenum sesquioxide, hydroxide
It is ground in aluminium, magnesium hydroxide, carbon black mixing input grinder, then crosses 100 and sieve to get mixed-powder, it is spare；
(3) mixed-powder is made in modified PVC resin, poly- fourth rubber silicon and alkane coupling agent and step (2) to mix, is risen
Temperature is to 78 degrees Celsius, with 1000 revs/min, stirring 25 minutes to get mixture M, it is spare；
(4) mixture N and antioxidant, ultraviolet absorber, fire retardant and plasticizer are mixed to be put into mixer and is kneaded, mixed
85 degrees Celsius of temperature is refined, mixing time 15 minutes is to get mixture N；
(5) extruding pelletization, 65 degrees Celsius of extrusion temperature in mixture N input double screw extruders are cooled to room temperature, are sieved
Choosing falls substandard products, packaging to get the freeze proof fire-resistant cable material.
Embodiment 2
A kind of freeze proof fire-resistant cable material includes the raw material of following parts by weight meter：
55 parts of modified PVC resin, 25 parts of butadiene rubber, 24 parts of mica, 18 parts of montmorillonite, 18 parts of calcium silicates, sulfuric acid
9 parts of calcium, 10 parts of calcium stearate, 16 parts of antimony oxide, 15 parts of molybdenum sesquioxide, 12 parts of aluminium hydroxide, 12 parts of magnesium hydroxide, charcoal
6 parts of black 10 parts, 7 parts of silane coupling agent, 6 parts of antioxidant, 6 parts of ultraviolet absorber, 7 parts of fire retardant and plasticizer；
The preparation method of modified polyvinyl chloride resin is：
Corvic and the glass microballoon of its weight 20% and 4% vinyltrimethoxysilane are mixed, risen
Temperature is to 300 degrees Celsius, and high-speed stirred 50 minutes is put into mixing in mixer after mixing, and 150 degrees Celsius of smelting temperature is close
15 minutes time is refined to get modified PVC resin.
Silane coupling agent is N- ethoxy acyl ethylamino-ethyl aminoethyl amino propyl trimethoxy silanes.
Antioxidant is four (β-(3,5- di-t-butyl 4- hydroxy phenyls) propionic acid) pentaerythritol esters, β-(3,5- di-t-butyls-
4- hydroxy phenyls) propionic acid n-octadecyl alcohol ester and phosphite be according to mass ratio 2:2:1 mixing composition.
Ultraviolet absorber is 2-hydroxy-4-n-octoxybenzophenone and hexamethylphosphoric acid triamide according to mass ratio 3:1 is mixed
It is combined into.
Fire retardant is silica gel and talcum powder according to mass ratio 3:1 mixing composition.
Plasticizer is fatty group dibasic acid.
A kind of preparation method of above-mentioned freeze proof fire-resistant cable material is also disclosed in the present embodiment, specifically, including following step
Suddenly：
(1) each raw material is weighed according to the parts by weight of raw materials of freeze proof fire-resistant cable material；
(2) by mica, montmorillonite, calcium silicates, calcium sulfate, calcium stearate, antimony oxide, molybdenum sesquioxide, hydroxide
It is ground in aluminium, magnesium hydroxide, carbon black mixing input grinder, then crosses 200 and sieve to get mixed-powder, it is spare；
(3) mixed-powder is made in modified PVC resin, poly- fourth rubber silicon and alkane coupling agent and step (2) to mix, is risen
Temperature is to 95 degrees Celsius, with 2000 revs/min, stirring 40 minutes to get mixture M, it is spare；
(4) mixture N and antioxidant, ultraviolet absorber, fire retardant and plasticizer are mixed to be put into mixer and is kneaded, mixed
95 degrees Celsius of temperature is refined, mixing time 30 minutes is to get mixture N；
(5) extruding pelletization, 80 degrees Celsius of extrusion temperature in mixture N input double screw extruders are cooled to room temperature, are sieved
Choosing falls substandard products, packaging to get the freeze proof fire-resistant cable material.
Embodiment 3
A kind of freeze proof fire-resistant cable material includes the raw material of following parts by weight meter：
51 parts of modified PVC resin, 20 parts of butadiene rubber, 18 parts of mica, 15 parts of montmorillonite, 14 parts of calcium silicates, sulfuric acid
6 parts of calcium, 8 parts of calcium stearate, 13 parts of antimony oxide, 12 parts of molybdenum sesquioxide, 8 parts of aluminium hydroxide, 8 parts of magnesium hydroxide, carbon black 4
Part, 5.8 parts of silane coupling agent, 4.5 parts of antioxidant, 4.8 parts of ultraviolet absorber, 5.6 parts of fire retardant and 4.7 parts of plasticizer；
The preparation method of the modified polyvinyl chloride resin is：
Corvic and the glass microballoon of its weight 18% and 3.4% vinyltrimethoxysilane are mixed,
It is warming up to 260 degrees Celsius, high-speed stirred 46 minutes is put into mixing in mixer after mixing, 135 degrees Celsius of smelting temperature,
Mixing time 13 minutes is to get modified PVC resin.
Silane coupling agent is aminoethyl aminoethyl amino propyl trimethoxy silane and N- ethoxy acyl ethylamino-ethyl aminoethyls
Aminopropyl trimethoxysilane is according to mass ratio 2:1 mixing composition.
Antioxidant is four (β-(3,5- di-t-butyl 4- hydroxy phenyls) propionic acid) pentaerythritol esters, β-(3,5- di-t-butyls-
4- hydroxy phenyls) propionic acid n-octadecyl alcohol ester and phosphite be according to mass ratio 2:2:1 mixing composition.
Ultraviolet absorber is 2-hydroxy-4-n-octoxybenzophenone and hexamethylphosphoric acid triamide according to mass ratio 3:1 is mixed
It is combined into.
Fire retardant is sodium metasilicate and talcum powder according to mass ratio 1:1 mixing composition.
Plasticizer is polyol ester.
A kind of preparation method of above-mentioned freeze proof fire-resistant cable material is also disclosed in the present embodiment, specifically, including following step
Suddenly：
(1) each raw material is weighed according to the parts by weight of raw materials of freeze proof fire-resistant cable material；
(2) by mica, montmorillonite, calcium silicates, calcium sulfate, calcium stearate, antimony oxide, molybdenum sesquioxide, hydroxide
It is ground in aluminium, magnesium hydroxide, carbon black mixing input grinder, then crosses 180 and sieve to get mixed-powder, it is spare；
(3) mixed-powder is made in modified PVC resin, poly- fourth rubber silicon and alkane coupling agent and step (2) to mix, is risen
Temperature is to 88 degrees Celsius, with 1600 revs/min, stirring 32 minutes to get mixture M, it is spare；
(4) mixture N and antioxidant, ultraviolet absorber, fire retardant and plasticizer are mixed to be put into mixer and is kneaded, mixed
92 degrees Celsius of temperature is refined, mixing time 25 minutes is to get mixture N；
(5) extruding pelletization, 75 degrees Celsius of extrusion temperature in mixture N input double screw extruders are cooled to room temperature, are sieved
Choosing falls substandard products, packaging to get the freeze proof fire-resistant cable material.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of freeze proof fire-resistant cable material, which is characterized in that including following raw material by weight：
45-55 parts of modified PVC resin, 15-25 parts of butadiene rubber, 12-24 parts of mica, 10-18 parts of montmorillonite, calcium silicates
9-18 parts, 4-9 parts of calcium sulfate, 5-10 parts of calcium stearate, 10-16 parts of antimony oxide, 8-15 parts of molybdenum sesquioxide, aluminium hydroxide
5-12 parts, 5-12 parts of magnesium hydroxide, 4-10 parts of carbon black, 4-7 parts of silane coupling agent, 3-6 parts of antioxidant, 3-6 parts of ultraviolet absorber,
3-6 parts of 4-7 parts of fire retardant and plasticizer；
The preparation method of the modified polyvinyl chloride resin is：The glass of Corvic and its weight 15%-20% is micro-
The vinyltrimethoxysilane of pearl and 2%-4% mix, and are warming up to 200-300 degrees Celsius, and high-speed stirred 40-50 minutes is mixed
After closing uniformly, it is put into mixing in mixer, 120-150 degrees Celsius of smelting temperature, mixing time is gathered for 10-15 minutes to get modified
Vinyl chloride resin.
2. freeze proof fire-resistant cable material according to claim 1, which is characterized in that include the raw material of following parts by weight meter：Change
Property 51 parts of Corvic, 20 parts of butadiene rubber, 18 parts of mica, 15 parts of montmorillonite, 14 parts of calcium silicates, 6 parts of calcium sulfate, stearic
8 parts of sour calcium, 13 parts of antimony oxide, 12 parts of molybdenum sesquioxide, 8 parts of aluminium hydroxide, 8 parts of magnesium hydroxide, 4 parts of carbon black, silane are even
Join 4.7 parts of 5.8 parts of agent, 4.5 parts of antioxidant, 4.8 parts of ultraviolet absorber, 5.6 parts of fire retardant and plasticizer；
The preparation method of the modified polyvinyl chloride resin is：By the glass microballoon of Corvic and its weight 18% and
3.4% vinyltrimethoxysilane mixing, is warming up to 260 degrees Celsius, high-speed stirred 46 minutes after mixing, is put into
Mixing in mixer, 135 degrees Celsius of smelting temperature, mixing time 13 minutes is to get modified PVC resin.
3. freeze proof fire-resistant cable material according to claim 1, which is characterized in that the silane coupling agent is aminoethyl ammonia second
Base aminopropyl trimethoxysilane, vinyl three (beta-methoxy ethyoxyl) silane, N- ethoxy acyl ethylamino-ethyl aminoethyls ammonia third
One or more of base trimethoxy silane combines.
4. freeze proof fire-resistant cable material according to claim 1, which is characterized in that the antioxidant is four (β-(3,5- bis- uncles
Butyl 4- hydroxy phenyls) propionic acid) pentaerythritol ester, β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid n-octadecyl alcohol esters and
Phosphite is according to mass ratio 2:2:1 mixing composition.
5. freeze proof fire-resistant cable material according to claim 1, which is characterized in that the ultraviolet absorber is 2- hydroxyls -4-
Oxy-octyl benzophenone and hexamethylphosphoric acid triamide are according to mass ratio 3:1 mixing composition.
6. freeze proof fire-resistant cable material according to claim 1, which is characterized in that the fire retardant be silicate, silica gel and
One or more of talcum powder combines.
7. freeze proof fire-resistant cable material according to claim 1, which is characterized in that the plasticizer be phthalic acid ester,
One or more of fatty group dibasic acid and polyol ester mix.
8. a kind of preparing the preparation method such as the freeze proof fire-resistant cable material of claim 1-7 any one of them, which is characterized in that packet
Include following steps：
(1) each raw material is weighed according to the parts by weight of raw materials of freeze proof fire-resistant cable material；
(2) by mica, montmorillonite, calcium silicates, calcium sulfate, calcium stearate, antimony oxide, molybdenum sesquioxide, aluminium hydroxide, hydrogen
It is ground in magnesia, carbon black mixing input grinder, then crosses 100-200 and sieve to get mixed-powder, it is spare；
(3) mixed-powder is made in modified PVC resin, poly- fourth rubber silicon and alkane coupling agent and step (2) to mix, is warming up to
78-95 degrees Celsius, with 1000-2000 revs/min, stirring 25-40 minutes to get mixture M, it is spare；
(4) mixture N and antioxidant, ultraviolet absorber, fire retardant and plasticizer are mixed to be put into mixer and is kneaded, be kneaded temperature
85-95 degrees Celsius of degree, mixing time 15-30 minutes is to get mixture N；
(5) extruding pelletization, 65-80 degrees Celsius of extrusion temperature in mixture N input double screw extruders are cooled to room temperature, are sieved
Choosing falls substandard products, packaging to get the freeze proof fire-resistant cable material.
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| CN201810158737.4A CN108384143A (en) | 2018-02-26 | 2018-02-26 | Anti-freezing flame-retardant cable material and preparation method thereof |
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| CN201810158737.4A CN108384143A (en) | 2018-02-26 | 2018-02-26 | Anti-freezing flame-retardant cable material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110655742A (en) * | 2019-10-15 | 2020-01-07 | 高静静 | Modified PVC cable material and preparation method thereof |
| CN112111113A (en) * | 2020-09-25 | 2020-12-22 | 镇江市华银仪表电器有限公司 | Waterproof heat-resistant polyvinyl chloride cable material and preparation method thereof |
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| CN103509281A (en) * | 2013-09-06 | 2014-01-15 | 安徽华通电缆集团有限公司 | Antifreeze cable material |
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| CN107226976A (en) * | 2017-06-20 | 2017-10-03 | 合肥博创机械制造有限公司 | A kind of Antifreeze cable material and preparation method thereof |
| CN107236185A (en) * | 2017-06-29 | 2017-10-10 | 合肥达户电线电缆科技有限公司 | A kind of novel flame-retardant cable material and preparation method thereof |
| CN107266829A (en) * | 2017-08-04 | 2017-10-20 | 苏州亨利通信材料有限公司 | A kind of charging pile cable polyvinyl chloride elastomer cable material and preparation method thereof |
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| CN103509281A (en) * | 2013-09-06 | 2014-01-15 | 安徽华通电缆集团有限公司 | Antifreeze cable material |
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Application publication date: 20180810 |