CN105153694A - Nylon 66/polyaminated bismaleimide composite for inner sheaths of heat-resisting power lines and preparation method of nylon 66/polyaminated bismaleimide composite - Google Patents
Nylon 66/polyaminated bismaleimide composite for inner sheaths of heat-resisting power lines and preparation method of nylon 66/polyaminated bismaleimide composite Download PDFInfo
- Publication number
- CN105153694A CN105153694A CN201510536411.7A CN201510536411A CN105153694A CN 105153694 A CN105153694 A CN 105153694A CN 201510536411 A CN201510536411 A CN 201510536411A CN 105153694 A CN105153694 A CN 105153694A
- Authority
- CN
- China
- Prior art keywords
- parts
- polyaminated
- nylon
- pabm
- bismaleimide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/303—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups H01B3/38 or H01B3/302
- H01B3/305—Polyamides or polyesteramides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Multicomponent Fibers (AREA)
Abstract
The invention discloses a nylon 66/polyaminated bismaleimide composite for inner sheaths of heat-resisting power lines and a preparation method of the nylon 66/polyaminated bismaleimide composite. The nylon 66/polyaminated bismaleimide composite comprises, by weight, 39-57 parts of nylon 66, 18-26 parts of polyaminated bismaleimide, 15-25 parts of poly(2(phenoxy) accidentally phosphorus nitrene), 24-32 parts of blast furnace water slag micro-powder, 2-4 parts of stannous chloride, 3-5 parts of N-methyl-p-toluenesulfonamide, 5-10 parts of potassium fluozirconate, 10-15 parts of dimethyl maleate, 4-8 parts of zinc hydroxystannate, 3-5 parts of cuproous bromide, 4-6 parts of oxidized polyethylene wax, 5-8 parts of perfluopolyether, 15-25 parts of colloidal graphite powder and 18-27 parts of flame retardant particles. The nylon 66/polyaminated bismaleimide is good in mechanical property, wear-resisting property and aging resistance.
Description
Technical field
The present invention relates to a kind of heat-resisting supply lead inner sheath nylon66 fiber/PABM matrix material and preparation method thereof, belong to processing of high molecular material technical field.
Background technology
Supply lead is the electric wire of transmission current, and it is primarily of oversheath, inner sheath, conductor composition.Inner sheath, be one deck macromolecular material of parcel cable between screen layer and core, be generally igelite or vinyon, also have low-smoke halogen-free material, its effect be make insulation layer can not with water, air or other object contacts, avoid humidified insulation and insulation layer not by mechanical wounding.Supply lead inner sheath material category is various in the market, but along with the fast development of science and technology, the thermotolerance of existing supply lead inner sheath material more and more cannot meet the demand in market.
Summary of the invention
The object of the invention is to for prior art not enough, a kind of heat-resisting supply lead inner sheath nylon66 fiber/PABM matrix material and preparation method thereof is provided.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of heat-resisting supply lead inner sheath nylon66 fiber/PABM matrix material, is made up of the raw material of following weight part: nylon66 fiber 39-57, PABM 18-26, poly-(two (phenoxy group) phosphazo alkene) 15-25, blast furnace granulated slag micro mist 24-32, tin protochloride 2-4, N-methyl para toluene sulfonamide 3-5, potassium fluozirconate 5-10, dimethyl maleate 10-15, zinc hydroxyl stannate 4-8, cuprous bromide 3-5, oxidized polyethlene wax 4-6, PFPE 5-8, oildag powder 15-25, fire-retardant particle 18-27;
The preparation method of described fire-retardant particle is as follows: a, get the raw material of following weight part: colemanite 24-36, brucite 16-28, boehmite 12-24, expanded graphite 10-15, Sodium Aluminium Carbonate Basic 6-12, basic magnesium chloride 5-10, brominated bisphenol-A epoxy resin 24-32, polyacrylic acid pentabromo-benzyl ester 25-35, hexaphenoxycyclotriphosphazene 10-15, dipentaerythritol diphosphites 5-10, chlorinatedpolyethylene 35-45; B, get colemanite, brucite, boehmite, expanded graphite mix, pulverize, together drop in stirrer with Sodium Aluminium Carbonate Basic, basic magnesium chloride after crossing 100-150 mesh sieve, add brominated bisphenol-A epoxy resin, dipentaerythritol diphosphites again, be uniformly mixed when reaching 70-80 DEG C to temperature of charge, add chlorinatedpolyethylene, polyacrylic acid pentabromo-benzyl ester, hexaphenoxycyclotriphosphazene again, continue to be uniformly mixed, stop stirring when temperature of charge reaches 90-100 DEG C, then material is proceeded to extruding pelletization in twin screw extruder.
Above-mentioned fire-retardant particle adopts colemanite, brucite, boehmite, expanded graphite, Sodium Aluminium Carbonate Basic, the inorganic combustion inhibitor compound uses such as basic magnesium chloride, and adopt brominated bisphenol-A epoxy resin, polyacrylic acid pentabromo-benzyl ester, hexaphenoxycyclotriphosphazene, dipentaerythritol diphosphites, the high molecular weight flame retardants such as chlorinatedpolyethylene are to its blending and modifying, the two is synergy mutually, not only significantly can improve the interface performance of inorganic combustion inhibitor, improve the consistency of itself and supply lead macromolecule matrix, the flame retardant effect of high molecular weight flame retardant can also be improved, in a word, this fire-retardant particle has excellent flame retardant properties, applied widely, most of Polymer Systems can be applied to.
A kind of preparation method of heat-resisting supply lead inner sheath nylon66 fiber/PABM matrix material, comprises the following steps:
(1) nylon66 fiber, blast furnace granulated slag micro mist, N-methyl para toluene sulfonamide, oxidized polyethlene wax are added in mixing roll, mixing 4-8min at 100-110 DEG C of temperature, discharging;
(2) PABM, poly-(two (phenoxy group) phosphazo alkene), oildag powder, dimethyl maleate are added in mixing roll, mixing 3-5min at 110-120 DEG C of temperature, discharging;
(3) material that material above-mentioned steps (1) mixed, step (2) mix joins in twin screw extruder together with fire-retardant particle, PFPE, tin protochloride, potassium fluozirconate, zinc hydroxyl stannate, cuprous bromide, be 215-230 DEG C at barrel temperature, screw speed is blending extrusion under the condition of 70-80r/min, pelletizing after water cooling, dry, get product.
Beneficial effect of the present invention:
The present invention uses nylon 66 material and PABM compound, and with the addition of the mineral filler such as blast furnace granulated slag micro mist, oildag powder, it is made to show the incomparable thermotolerance of other macromolecular material, in high temperature environments, there is outstanding mechanical property, wear resisting property and ageing resistance, the poly-raw material such as (two (phenoxy group) phosphazo alkene), zinc hydroxyl stannate, fire-retardant particle simultaneously added, can significantly improve the flame retardant properties of material.
Embodiment
A kind of heat-resisting supply lead inner sheath nylon66 fiber/PABM matrix material, is made up of the raw material of following weight (kg): nylon66 fiber 46, PABM 22, poly-(two (phenoxy group) phosphazo alkene) 20, blast furnace granulated slag micro mist 28, tin protochloride 3, N-methyl para toluene sulfonamide 4, potassium fluozirconate 8, dimethyl maleate 12, zinc hydroxyl stannate 6, cuprous bromide 4, oxidized polyethlene wax 5, PFPE 7, oildag powder 20, fire-retardant particle 23;
The preparation method of described fire-retardant particle is as follows: a, get the raw material of following weight (kg): colemanite 32, brucite 26, boehmite 18, expanded graphite 12, Sodium Aluminium Carbonate Basic 8, basic magnesium chloride 7, brominated bisphenol-A epoxy resin 28, polyacrylic acid pentabromo-benzyl ester 30, hexaphenoxycyclotriphosphazene 12, dipentaerythritol diphosphites 8, chlorinatedpolyethylene 40; B, get colemanite, brucite, boehmite, expanded graphite mix, pulverize, together drop in stirrer with Sodium Aluminium Carbonate Basic, basic magnesium chloride after crossing 100 mesh sieves, add brominated bisphenol-A epoxy resin, dipentaerythritol diphosphites again, be uniformly mixed when reaching 70 DEG C to temperature of charge, add chlorinatedpolyethylene, polyacrylic acid pentabromo-benzyl ester, hexaphenoxycyclotriphosphazene again, continue to be uniformly mixed, stop stirring when temperature of charge reaches 90 DEG C, then material is proceeded to extruding pelletization in twin screw extruder.
A kind of preparation method of heat-resisting supply lead inner sheath nylon66 fiber/PABM matrix material, comprises the following steps:
(1) nylon66 fiber, blast furnace granulated slag micro mist, N-methyl para toluene sulfonamide, oxidized polyethlene wax are added in mixing roll, mixing 4-8min at 100-110 DEG C of temperature, discharging;
(2) PABM, poly-(two (phenoxy group) phosphazo alkene), oildag powder, dimethyl maleate are added in mixing roll, mixing 3-5min at 110-120 DEG C of temperature, discharging;
(3) material that material above-mentioned steps (1) mixed, step (2) mix joins in twin screw extruder together with fire-retardant particle, PFPE, tin protochloride, potassium fluozirconate, zinc hydroxyl stannate, cuprous bromide, be 215-230 DEG C at barrel temperature, screw speed is blending extrusion under the condition of 70-80r/min, pelletizing after water cooling, dry, get product.
The performance test results of heat-resisting supply lead inner sheath nylon66 fiber/PABM matrix material that above-described embodiment is obtained is as shown in the table:
The performance test results of the heat-resisting supply lead inner sheath nylon66 fiber/PABM matrix material of table 1
Claims (2)
1. heat-resisting supply lead inner sheath nylon66 fiber/PABM matrix material, it is characterized in that, be made up of the raw material of following weight part: nylon66 fiber 39-57, PABM 18-26, poly-(two (phenoxy group) phosphazo alkene) 15-25, blast furnace granulated slag micro mist 24-32, tin protochloride 2-4, N-methyl para toluene sulfonamide 3-5, potassium fluozirconate 5-10, dimethyl maleate 10-15, zinc hydroxyl stannate 4-8, cuprous bromide 3-5, oxidized polyethlene wax 4-6, PFPE 5-8, oildag powder 15-25, fire-retardant particle 18-27;
The preparation method of described fire-retardant particle is as follows: a, get the raw material of following weight part: colemanite 24-36, brucite 16-28, boehmite 12-24, expanded graphite 10-15, Sodium Aluminium Carbonate Basic 6-12, basic magnesium chloride 5-10, brominated bisphenol-A epoxy resin 24-32, polyacrylic acid pentabromo-benzyl ester 25-35, hexaphenoxycyclotriphosphazene 10-15, dipentaerythritol diphosphites 5-10, chlorinatedpolyethylene 35-45; B, get colemanite, brucite, boehmite, expanded graphite mix, pulverize, together drop in stirrer with Sodium Aluminium Carbonate Basic, basic magnesium chloride after crossing 100-150 mesh sieve, add brominated bisphenol-A epoxy resin, dipentaerythritol diphosphites again, be uniformly mixed when reaching 70-80 DEG C to temperature of charge, add chlorinatedpolyethylene, polyacrylic acid pentabromo-benzyl ester, hexaphenoxycyclotriphosphazene again, continue to be uniformly mixed, stop stirring when temperature of charge reaches 90-100 DEG C, then material is proceeded to extruding pelletization in twin screw extruder.
2. the preparation method of the heat-resisting supply lead inner sheath nylon66 fiber/PABM matrix material of one according to claim 1, is characterized in that, comprise the following steps:
(1) nylon66 fiber, blast furnace granulated slag micro mist, N-methyl para toluene sulfonamide, oxidized polyethlene wax are added in mixing roll, mixing 4-8min at 100-110 DEG C of temperature, discharging;
(2) PABM, poly-(two (phenoxy group) phosphazo alkene), oildag powder, dimethyl maleate are added in mixing roll, mixing 3-5min at 110-120 DEG C of temperature, discharging;
(3) material that material above-mentioned steps (1) mixed, step (2) mix joins in twin screw extruder together with fire-retardant particle, PFPE, tin protochloride, potassium fluozirconate, zinc hydroxyl stannate, cuprous bromide, be 215-230 DEG C at barrel temperature, screw speed is blending extrusion under the condition of 70-80r/min, pelletizing after water cooling, dry, get product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510536411.7A CN105153694A (en) | 2015-08-25 | 2015-08-25 | Nylon 66/polyaminated bismaleimide composite for inner sheaths of heat-resisting power lines and preparation method of nylon 66/polyaminated bismaleimide composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510536411.7A CN105153694A (en) | 2015-08-25 | 2015-08-25 | Nylon 66/polyaminated bismaleimide composite for inner sheaths of heat-resisting power lines and preparation method of nylon 66/polyaminated bismaleimide composite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105153694A true CN105153694A (en) | 2015-12-16 |
Family
ID=54794760
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510536411.7A Pending CN105153694A (en) | 2015-08-25 | 2015-08-25 | Nylon 66/polyaminated bismaleimide composite for inner sheaths of heat-resisting power lines and preparation method of nylon 66/polyaminated bismaleimide composite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105153694A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802110A (en) * | 2016-04-08 | 2016-07-27 | 苏州锦腾电子科技有限公司 | High-dielectric insulating plate |
| CN106751765A (en) * | 2017-03-08 | 2017-05-31 | 株洲时代新材料科技股份有限公司 | A kind of wear-resisting High impact nylon composite and its preparation method and application |
| CN110511562A (en) * | 2018-05-22 | 2019-11-29 | 上海杰事杰新材料(集团)股份有限公司 | A kind of Antistatic flame-retardant nylon composite material and preparation method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101341560A (en) * | 2006-04-25 | 2009-01-07 | 昭和电工株式会社 | Electric double-layered capacitor |
| CN102660108A (en) * | 2012-04-11 | 2012-09-12 | 才塑高分子材料（上海）有限公司 | Weatherable irradiation crosslinking cable material |
| CN103483809A (en) * | 2013-09-24 | 2014-01-01 | 株洲时代工程塑料制品有限责任公司 | High-flowability polyamide based halogen-free flame-retardant heat-conducting composite material and preparation method thereof |
-
2015
- 2015-08-25 CN CN201510536411.7A patent/CN105153694A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101341560A (en) * | 2006-04-25 | 2009-01-07 | 昭和电工株式会社 | Electric double-layered capacitor |
| CN102660108A (en) * | 2012-04-11 | 2012-09-12 | 才塑高分子材料（上海）有限公司 | Weatherable irradiation crosslinking cable material |
| CN103483809A (en) * | 2013-09-24 | 2014-01-01 | 株洲时代工程塑料制品有限责任公司 | High-flowability polyamide based halogen-free flame-retardant heat-conducting composite material and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802110A (en) * | 2016-04-08 | 2016-07-27 | 苏州锦腾电子科技有限公司 | High-dielectric insulating plate |
| CN106751765A (en) * | 2017-03-08 | 2017-05-31 | 株洲时代新材料科技股份有限公司 | A kind of wear-resisting High impact nylon composite and its preparation method and application |
| CN106751765B (en) * | 2017-03-08 | 2019-06-14 | 株洲时代新材料科技股份有限公司 | A kind of wear-resisting High impact nylon composite material and preparation method and application |
| CN110511562A (en) * | 2018-05-22 | 2019-11-29 | 上海杰事杰新材料(集团)股份有限公司 | A kind of Antistatic flame-retardant nylon composite material and preparation method |
| CN110511562B (en) * | 2018-05-22 | 2022-10-04 | 上海杰事杰新材料(集团)股份有限公司 | Antistatic flame-retardant nylon composite material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102964724B (en) | Thin-wall insulated wire material for automobile and preparation method thereof | |
| CN101608033B (en) | Irradiated crosslinking low-smoke halogen-free flame-retardant isolating compound and sheathing compound for solar cables | |
| CN108239331B (en) | Thermoplastic halogen-free flame-retardant material and preparation method thereof | |
| CN103928172B (en) | Fire retardant crosslinked polyethylene insulated power cable | |
| CN105153694A (en) | Nylon 66/polyaminated bismaleimide composite for inner sheaths of heat-resisting power lines and preparation method of nylon 66/polyaminated bismaleimide composite | |
| CN101928440B (en) | Halogen-free flame resistance resin composition, manufacture method thereof, and wire and cable using halogen-free flame resistance resin composition | |
| CN105086029A (en) | Stretch-resistant rubber material for inner sheaths of aviation power lines and method for manufacturing stretch-resistant rubber material | |
| CN104893085A (en) | Soft halogen-free flame-retardant insulation material for home appliances and preparation method thereof | |
| CN103524853B (en) | A kind of formula of cable insulation material of excellent performance | |
| CN103554636B (en) | A kind of preparation technology of cable insulation material of excellent performance | |
| CN109280299A (en) | PVC Sheathing Compound pellet and preparation method thereof | |
| CN102731896A (en) | Highly oil-resistant, low-smoke, halogen-free and radiation cross-linked sheath material and preparation method thereof | |
| CN105131559A (en) | Polyphenyl ether material for outer sheath of power line in humid environment and preparation method for polyphenyl ether material | |
| CN105131575A (en) | Jamproof shielding-enhanced sheath material for subway communication cable and preparation method of sheath material | |
| CN111675860A (en) | Low-temperature-resistant oil-resistant torsion-resistant high-flame-retardant sheath material and preparation method thereof | |
| CN105176099A (en) | Wear-resistant and oil-resistant rubber material for inner sheath of mining power cable and preparation method for rubber material | |
| CN106543599A (en) | A kind of environment-friendlyfilled filled cable material and preparation method thereof | |
| CN105820467A (en) | PVC (polyvinyl chloride) cable material and preparation method thereof | |
| CN105111667A (en) | Novel halogen-free flame retardant modification thermoplastic elastomer data line sheath material and manufacturing method thereof | |
| CN105602080A (en) | High-flame-resistance and high-temperature-resistant low-smoke cable material and preparation method thereof | |
| CN109880204A (en) | Modified low smoke halogen-free flame-retardant polyolefin semiconductive material of a kind of graphene and preparation method thereof | |
| CN104893086A (en) | High-insulativity halogen-free flame-retardant insulation material for household appliances and preparation method thereof | |
| CN105820390B (en) | A kind of cable insulation material of water-tolerant | |
| CN105111646A (en) | Waterproof and corrosion-resistant rubber material for power line jacket of marine transportation vehicle and preparation method of waterproof and corrosion-resistant rubber material | |
| CN103951891B (en) | High-flame-retardance cable coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151216 |