CN108911006A - A kind of application of active carbon layer in Wastewater from Pig Farm processing - Google Patents

A kind of application of active carbon layer in Wastewater from Pig Farm processing Download PDF

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Publication number
CN108911006A
CN108911006A CN201810690083.XA CN201810690083A CN108911006A CN 108911006 A CN108911006 A CN 108911006A CN 201810690083 A CN201810690083 A CN 201810690083A CN 108911006 A CN108911006 A CN 108911006A
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CN
China
Prior art keywords
active carbon
wastewater
carbon layer
pig farm
application
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810690083.XA
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Chinese (zh)
Inventor
刘家松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hongkang Specialized Breeding And Aquaculture Cooperative In Puding County
Original Assignee
Hongkang Specialized Breeding And Aquaculture Cooperative In Puding County
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Hongkang Specialized Breeding And Aquaculture Cooperative In Puding County filed Critical Hongkang Specialized Breeding And Aquaculture Cooperative In Puding County
Priority to CN201810690083.XA priority Critical patent/CN108911006A/en
Publication of CN108911006A publication Critical patent/CN108911006A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48Sorbents characterised by the starting material used for their preparation
    • B01J2220/4875Sorbents characterised by the starting material used for their preparation the starting material being a waste, residue or of undefined composition
    • B01J2220/4887Residues, wastes, e.g. garbage, municipal or industrial sludges, compost, animal manure; fly-ashes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Housing For Livestock And Birds (AREA)

Abstract

The present invention relates to a kind of application of active carbon layer in Wastewater from Pig Farm processing, the Char Residues Structure is among two layers of mesh, accumulation filling active carbon particle, excrement is discarded using pig factory and prepares active carbon, and the active carbon particle that pattern is completed and has some strength is obtained by prilling and stoving process;Active carbon particle is effectively accumulated again, is placed in Wastewater from Pig Farm processing unit, absorption is filtered to sewage, Colority of Sewage Water is substantially reduced after absorption.The present invention reduces the discharges of pollutant, improve the resource utilization during pig-breeding.

Description

A kind of application of active carbon layer in Wastewater from Pig Farm processing
Technical field
The invention belongs to pig-breeding field of environmental technology, more particularly to utilize the active carbon of pig manure preparation in breeding process Layer material.
Background technique
Live pig is the maximum breed variety of animal husbandry, and the specific gravity that the live pig amount of delivering for sale accounts for the national always amount of delivering for sale reaches 92.06%, China's live pig localization of production is laid out to be formed, and advantage producing region is prominent.With the increase of animal husbandry environmental protection pressure, many livestock and poultry Field increasingly wishes that fecaluria can decompose in livestock and poultry farm with regard to carrying out consumption completely, avoids waste outlet and leak to cause environment Harm.
Excrement, sewage, foul gas and the pollutants such as live pig corpse of dying of illness generated during pig-breeding, without nothing Evilization processing is directly discharged into environment, will seriously pollute to generations such as water body, air, soil.
Pig breeding pollution object mainly includes organic pollution, microbial contamination, venomous injurant to the pollution of water body environment The three classes such as pollution.1. organic pollution.The hydrocarbon that contains in pig-breeding waste especially sewage nitrogenous, phosphorous has After not being discharged into rivers, lake natural water by the nutriment that live pig digests in machine object and feed, water body can be changed Physics, chemistry, biocoene composition, rise water body solid suspension (SS), biochemical oxygen demand (BOD) (BOD), chemical oxygen consumption (COC) (COD) It is high.After being more than the self-purification capacity and pollutional load of water body, water quality deterioration will lead to, the aquatile sensitive to organic pollution Will be gradually dead, fish pond and river are gradually weakened using function, are occurred water body " eutrophication ".2. microbial contamination is primarily referred to as Comprising after the pathogenic microorganism in pig-breeding pollutant enters water body with excrement and urine waste, water quality is polluted, is caused with water shortage, Jeopardize human and livestock health and brings economic loss.3. venomous injurant pollution is primarily referred to as feed, additive, the antibiosis in veterinary drug Element, minerals, forbidden amphetamine and the cleaning agent on pig farm, disinfectant etc. are discharged into pollution caused by it after water body with waste
Active carbon is most important material in wastewater treatment, is applied to absorption dimethylbenzene, dyestuff, heavy metal at present Ion etc..Using the absorption and De contamination principle of active carbon, the best choosing of Wastewater from Pig Farm low cost circulation treatment can be used as It selects.
In order to reduce the environmental pollution in pig-breeding, active carbon is prepared using the pig manure that live pig factory generates, for reducing The development of efficient green aquaculture industry is realized in the pollution of pig farm exhaust gas and discharge of wastewater to environment, and the present invention provides one kind Absorbent charcoal material.
Summary of the invention
In order to solve the above technical problems, the answering in Wastewater from Pig Farm processing the present invention provides a kind of absorbent charcoal material With.
The present invention is achieved by the following technical programs.
The present invention provides a kind of application of active carbon layer in Wastewater from Pig Farm processing, it is characterised in that:
The waste water that pig farm is generated passes through active carbon layer,
The active carbon layer structure is the accumulation filling active carbon particle among two layers of mesh,
The accumulation mode is that the direction that active carbon particle prolongs perpendicular to net is filled in the way of layer heap product, the layer heap Product is the multilayer that the superposition multilayer that grain diameter is gradually increased or grain diameter size are overlapped mutually.
The preparation step of the active carbon includes:
1. the swine excrement soaking fermentation 12-36h that will be collected during intensive culture;
2. adjusting dejecta moisture, addition bentonite, kaolin, clay, concave convex rod adjust stool consistency, make it easily Grain;
3. soft grain granulation:By step, 2. treated that excrement directly uses soft grain granulation machine granulation formation,
4. being heat-treated:The above-mentioned soft particle being granulated into is subjected to heat treatment process, active carbon particle material is made;
5. sieving:4. granular materials that step is obtained obtains the active carbon particle of certain partial size by screening machine.
The net is metal mesh, plastic wire, to the supporting layer as absorbent charcoal material, and due to having centainly strong Degree and flexibility, feature easy to process can be used as the carrier layer of wastewater and waste gas treatment device.For example, the metal mesh is Stainless (steel) wire or wire netting, the plastic wire are carbon fibre web or plastic fiber net.
Efficiently accumulation is the key that realize poisonous and harmful heavy metallic, organic matter in effectively absorption waste water.
The particle size range of the active carbon is 0.01mm-10mm.Ulking thickness is 1-100mm.
The mode for adjusting dejecta moisture be the excrement that will have been cleaned add water or be dehydrated make dejecta moisture up to 10~ 70% (weight percent).
The heat treatment process is first to air-dry 1-12h at 0-30 DEG C finally to exist then in 40-80 DEG C of heating 1-12h 120-200 DEG C of drying 1-12h is basically unchanged granule-morphology after drying.
The purpose of heat treatment is after drying pig manure particle, and wherein organic matter is gradually carbonized, and keeps the pattern of particle, It does not crush.
80.1% is organic matter in the dry matter of pig manure, and easy decomposability organic C is 27.3%, hemicellulose and cellulose Content is lower, and the content of crude fat and lignin is higher, than conveniently as the source of active carbon.
Contain bulk gas in pig manure after fermentation, form porous structure after granulating and drying, this is dirty for activated carbon adsorption Aqueous medium provides good carrier;Active carbon table due to content of organic matter accounting nearly 1/3 in pig manure, after calcining drying Area is larger, is very suitable for adsorbed gas processing.The present invention obtains pattern by prilling and completes and with certain strong The pig manure particle of degree, by high-temperature heating, particle carbonization.The adjustable different faecal pellets of partial size can be obtained by being granulated.
The present invention has manufactured certain structural strength and suction by the stratum reticulare with some strength by efficiently accumulation mode The active carbon layer of attached performance, the layer of charcoal not only can be adapted for administering the contaminated wastewater that farm generates, also improve live pig and support Resource utilization during growing.
Detailed description of the invention:
Fig. 1:The top view of active carbon layer.
Fig. 2:The side view of active carbon layer.
Specific embodiment
Technical solution of the present invention is described further below, but claimed range is not limited to.
Specific embodiment:As illustrated in fig. 1 and 2, active carbon layer is wrapped up by net materials, and upper layer and lower layer are net, central filler Active carbon can alternately be filled according to active carbon particle size, can be according to radially being filled according to particle size shown in Fig. 2.
Embodiment 1:Make acticarbon:
1, the swine excrement soaking fermentation collected for 24 hours, is added 5% weight and kaolin and concave convex rod is divided to adjust viscosity;
2, then natural drying dehydration;Make moisture content up to 15% (weight percent), stirring-granulating;
3, the soft grain granulation machine of pig manure for adjusting moisture content and viscosity is granulated,
4, by the above-mentioned soft particle of the pig manure being granulated into 20 DEG C of drying 1h, then in 80 DEG C of heating 2h, then 200 DEG C are warming up to Heat 4h;Pig manure active carbon particle is obtained after screening, can be used for the absorption of pig factory exhaust gas.
Embodiment 2:Make active carbon layer:
1, the carbon fibre web of 2 1m*1m is cut;
2, the active carbon particle that selection example 1 is sieving through first fills the active carbon that partial size is 1mm on carbon fibre web Layer refills the active carbon layer that partial size is 2mm, refills the active carbon layer that partial size is 3mm, refills the activity that partial size is 4mm Layer of charcoal is covering one layer of carbon fibre web.
Embodiment 3:Wastewater from Pig Farm processing
1, obtained active carbon layer is fixed, is placed in Wastewater from Pig Farm blowdown apparatus.
2, filtered sewage is adsorbed by active carbon layer prepared by multiple embodiments 2, flow 200m3/h, comparison Absorption front and back, it can be seen that Colority of Sewage Water is substantially reduced, and meets discharge standard.

Claims (5)

1. a kind of application of active carbon layer in Wastewater from Pig Farm processing, it is characterised in that:
The waste water that pig farm is generated passes through active carbon layer,
The active carbon layer structure is the accumulation filling active carbon particle among two layers of mesh,
The accumulation mode is that the direction that active carbon particle prolongs perpendicular to net is filled in the way of layer heap product, and the layer heap product is The multilayer that the superposition multilayer or grain diameter size that grain diameter is gradually increased are overlapped mutually.
The preparation step of the active carbon includes:
1. the swine excrement soaking fermentation 12-36h that will be collected during intensive culture;
2. adjusting dejecta moisture, addition bentonite, kaolin, clay, concave convex rod adjust stool consistency, are granulated it easily;
3. soft grain granulation:By step, 2. treated that excrement directly uses soft grain granulation machine granulation formation,
4. being heat-treated:The above-mentioned soft particle being granulated into is subjected to heat treatment process, active carbon particle material is made;
5. sieving:4. granular materials that step is obtained obtains the active carbon particle of certain partial size by screening machine.
2. application of the active carbon layer as described in claim 1 in Wastewater from Pig Farm processing, it is characterised in that:The net is gold Belong to net, plastic wire.
3. application of the active carbon layer as described in claim 1 in Wastewater from Pig Farm processing, it is characterised in that:The metal mesh For stainless (steel) wire or wire netting, the plastic wire is carbon fibre web or plastic fiber net.
4. application of the active carbon layer as described in claim 1 in Wastewater from Pig Farm processing, it is characterised in that:The active carbon Particle size range be 0.01mm-10mm.
5. application of the active carbon layer as described in claim 1 in Wastewater from Pig Farm processing, it is characterised in that:The active carbon Layer with a thickness of 1mm-100mm.
CN201810690083.XA 2018-06-28 2018-06-28 A kind of application of active carbon layer in Wastewater from Pig Farm processing Pending CN108911006A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810690083.XA CN108911006A (en) 2018-06-28 2018-06-28 A kind of application of active carbon layer in Wastewater from Pig Farm processing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810690083.XA CN108911006A (en) 2018-06-28 2018-06-28 A kind of application of active carbon layer in Wastewater from Pig Farm processing

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Publication Number Publication Date
CN108911006A true CN108911006A (en) 2018-11-30

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Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000185992A (en) * 1998-12-21 2000-07-04 Kiyohiko Hibino Organic fertilizer and its production
CN101143721A (en) * 2006-09-14 2008-03-19 李洪溪 Method for preparing active carbon from cattle dung and sawdust
US20110209355A1 (en) * 2004-04-02 2011-09-01 Ecocombustion Energy Systems Corporation Biomass converters and processes
CN103843674A (en) * 2012-12-06 2014-06-11 徐州旭盛猪业有限公司 Pigsty padding
CN104355357A (en) * 2014-11-25 2015-02-18 中南林业科技大学 Filter unit for fecal wastewater treatment of farm
CN104445192A (en) * 2013-09-25 2015-03-25 重庆工商大学 Novel method for preparing activated carbon from cattle manure
CN104773718A (en) * 2015-04-01 2015-07-15 湖南泰谷生物科技股份有限公司 Biochar and preparation method
CN105478080A (en) * 2015-12-25 2016-04-13 常州大学 Preparation method of biological charcoal
CN106186161A (en) * 2016-08-11 2016-12-07 嘉应学院 A kind of pig manure charcoal is utilized to remove the method for lead in polluted-water
CN106912699A (en) * 2017-01-21 2017-07-04 广西神龙王农牧食品集团有限公司 A kind of pig feed for reducing pig manure stink and preparation method thereof
CN107162373A (en) * 2017-06-21 2017-09-15 福建禹环境科技有限公司 A kind of pig manure method of comprehensive utilization based on carbonization pyrolytic technique
CN107161975A (en) * 2017-05-31 2017-09-15 广东维清环境工程有限公司 A kind of preparation method of pig manure charcoal
CN107312583A (en) * 2017-08-04 2017-11-03 曾召禄 A kind of swine excrement biomass fuel and preparation method thereof
CN107382382A (en) * 2016-05-16 2017-11-24 朱沪生 One kind wet process for making granular fertilizer from excrement

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000185992A (en) * 1998-12-21 2000-07-04 Kiyohiko Hibino Organic fertilizer and its production
US20110209355A1 (en) * 2004-04-02 2011-09-01 Ecocombustion Energy Systems Corporation Biomass converters and processes
CN101143721A (en) * 2006-09-14 2008-03-19 李洪溪 Method for preparing active carbon from cattle dung and sawdust
CN103843674A (en) * 2012-12-06 2014-06-11 徐州旭盛猪业有限公司 Pigsty padding
CN104445192A (en) * 2013-09-25 2015-03-25 重庆工商大学 Novel method for preparing activated carbon from cattle manure
CN104355357A (en) * 2014-11-25 2015-02-18 中南林业科技大学 Filter unit for fecal wastewater treatment of farm
CN104773718A (en) * 2015-04-01 2015-07-15 湖南泰谷生物科技股份有限公司 Biochar and preparation method
CN105478080A (en) * 2015-12-25 2016-04-13 常州大学 Preparation method of biological charcoal
CN107382382A (en) * 2016-05-16 2017-11-24 朱沪生 One kind wet process for making granular fertilizer from excrement
CN106186161A (en) * 2016-08-11 2016-12-07 嘉应学院 A kind of pig manure charcoal is utilized to remove the method for lead in polluted-water
CN106912699A (en) * 2017-01-21 2017-07-04 广西神龙王农牧食品集团有限公司 A kind of pig feed for reducing pig manure stink and preparation method thereof
CN107161975A (en) * 2017-05-31 2017-09-15 广东维清环境工程有限公司 A kind of preparation method of pig manure charcoal
CN107162373A (en) * 2017-06-21 2017-09-15 福建禹环境科技有限公司 A kind of pig manure method of comprehensive utilization based on carbonization pyrolytic technique
CN107312583A (en) * 2017-08-04 2017-11-03 曾召禄 A kind of swine excrement biomass fuel and preparation method thereof

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Application publication date: 20181130