CN108909106A - Elastic composite cloth - Google Patents

Elastic composite cloth Download PDF

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Publication number
CN108909106A
CN108909106A CN201810635536.9A CN201810635536A CN108909106A CN 108909106 A CN108909106 A CN 108909106A CN 201810635536 A CN201810635536 A CN 201810635536A CN 108909106 A CN108909106 A CN 108909106A
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elastic
layer
composite cloth
water
age resister
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CN201810635536.9A
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CN108909106B (en
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不公告发明人
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Jiaxing Deyong Textiles Co ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B23/00—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
    • B32B23/04—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B23/046—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B23/00—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
    • B32B23/04—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B23/08—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10—Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/20—Layered products comprising a layer of natural or synthetic rubber comprising silicone rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
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    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12—Aldehydes; Ketones
    • D06M13/123—Polyaldehydes; Polyketones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/392—Nitroso compounds; Nitro compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12—Processes in which the treating agent is incorporated in microcapsules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0223—Vinyl resin fibres
    • B32B2262/0238—Vinyl halide, e.g. PVC, PVDC, PVF, PVDF
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    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
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    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
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    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
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    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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  • Engineering & Computer Science (AREA)
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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Cosmetics (AREA)

Abstract

A kind of elastic composite cloth, it is characterised in that：The elastic composite cloth is double-layer structure, one layer is resilient material made of nylon fiber, another layer is material strips made of cellulose fibre, it is combined between two layers by high polymer elastic layer, it is described through being diamond shape to the gap between elastic webbing and broadwise elastic webbing, the high polymer elastic layer includes at least thermoplastic elastomer (TPE) or thermo-setting elastomer using high polymer elastic material.

Description

Elastic composite cloth
The application is entitled a kind of permanent seal cooling elastic composite application No. is 2016106277820, the applying date For the divisional application of 20160803 application for a patent for invention.
Technical field
The invention belongs to elastic composite fields.
Background technique
It 2009 " Bedjump ", runs away rapidly on website, Chinese is translated into " trampoline " or " trampoline ".It is gathered around in all parts of the world There are numerous fans for growing tender of this movement.Fan would generally select the bed that elasticity is good, jump up, and make in the sky various dynamic Make.Trampoline is mainly equipped with a fabric tightened by most springs in the frame for the foot prop support that lands, and stands on for user Constantly spring carries out interest movement on spring face.Trampoline in the prior art has the following defects：1. the frame body of trampoline Product is larger, thus after manufacturer produces bouncer products, each assembled trampoline has sizable volume, no Finished product is only stored up in factory can occupy the confined space in factory, and when export trade also will increase transportation cost, furthermore, no matter the quotient of exhibition sale Shop or personal use person, trampoline are intended to occupy sizable interior space under without using state.2. current trampoline uses bullet Spring is as its elastic force source, for the sake of security, needs to be laid with neonychium above spring, avoids unexpected generation.It is so this Neonychium needs to increase the cost of trampoline；Built-up time is increased, simultaneously as spring can generate flexible deformation, is not made originally Used time neonychium is tightly to cover, but after the flexible deformation of spring, neonychium deviates, cause covering uneven and Expose spring, so as to will increase the incidence of safety accident.3. again due to being to utilize guarantor as elastic component using spring Protection pad covering is laid with, and greatly reduces effective usable floor area of trampoline, the space of actually jumping of trampoline has been limited in the presence of spring. Useful elastical cloth substitution spring in the prior art, but there are elastical cloth service lifes it is short, cloth cover uniform elastic is poor the problems such as.
Summary of the invention
To solve the above-mentioned problems, technical scheme is as follows：
A kind of permanent seal cooling elastic composite, it is characterised in that：Composite material is double-layer structure, wherein one layer anti-ageing to have carried out Change the resilient material arranged, arrangement process includes：1）The preparation of age resister；2）The preparation of microcapsules and finishing fluid；3）With The finishing fluid prepared carries out anti-aging arrangement to nylon elastic material strips.
Elastic composite cloth is double-layer structure, and one layer is resilient material made of nylon fiber, and another layer is fiber Material strips made of cellulose fiber are combined between two layers by high polymer elastic layer；Every layer all from through to elastic webbing and broadwise Elastic webbing composition, it is described through being diamond shape to the gap between elastic webbing and broadwise elastic webbing；The gap is 10 to 25 flat Square millimeter；It is described through being 2-5 millimeters to the spacing between elastic webbing；Spacing between the broadwise elastic webbing is 3-6 milli Rice；The high polymer elastic layer includes at least thermoplastic elastomer (TPE) or thermoset elastic using high polymer elastic material Body；Wherein thermoplastic elastomer (TPE) includes thermoplastic, Polyurethane, polyvinyl chloride；Thermo-setting elastomer then includes silica gel.It is described Nylon elastic material strips have passed through anti-aging processing, processing step is：
1）The preparation of age resister
Under nitrogen protection, by 3,4- chloro-2-methyl aniline or 2- naphthylamines or 4- amino -3,2- dimethyl azobenzene or 2- ammonia Base -4- nitrotoleune, is added in the water of the sodium hydroxide of 1.5 ~ 4 mol/L and the mixed solution of ethyl alcohol, stirs and adds by several times Enter reducing agent lithium aluminium hydride reduction, at 75 ~ 80 DEG C react 0.5 ~ 3h after be cooled to room temperature, be added sulfuric acid by pH value adjust 5~6 it Between, it filters, dries in the shade, re-dry after recrystallization obtains functional modifier crude product, then by functional modifier crude product, hydrogen fluorine Acid and concentrated nitric acid are added in reaction vessel, after being heated to 45 ~ 50 DEG C of 1.5~2.0h of reaction, Off-white product are obtained by filtration, through cold But it filters, dries in the shade, recrystallize and dry, obtain age resister；
2）The preparation of anti-ageing microcapsules and age resister finishing fluid
Using deionized water as solvent, in a solvent age resister dispersion, whipping temp is room temperature, controls whipping process medium-rate For 500~1000r/min, being dispersed with stirring the time is 50~65min, and age resister molecule is enable to form suspension in aqueous solution Then system adds hydroxyethyl cellulose and is dissolved, then carries out high-speed stirred dispersion, whipping temp is 35~40 DEG C, stirs Mixing rate is 3400~3600r/min, and mixing time is 10~15min, then adds butane tetracarboxylic acid and carries out chitosan friendship Connection, then curing 10min is carried out under the conditions of 85~90 DEG C, thick modified capsule is obtained by filtration, then be dried in vacuo at 60 DEG C After for 24 hours, the modification capsule containing age resister is obtained；Its sandwich layer is age resister, and cystoblast is hydroxyethylcellulose materials, wherein The thickness of cystoblast and sandwich layer ratio is 1: 18；By manufactured age resister microcapsules 3-6%（owf）, penetrating agent JFC 1-2g/l, pH value For 7-7.5, it is made into age resister finishing fluid；
The volume ratio of water and ethyl alcohol in the mixed solution of the water and ethyl alcohol is 1: 2；The lithium aluminium hydride reduction and 3,4- are chloro- The molar ratio of 2-aminotoluene or 2- naphthylamines or 4- amino -3,2- dimethyl azobenzene or 2- amino -4- nitrotoleune is 2: 1.5；The molar ratio 2: 2.2: 1.1 of the functional modifier crude product, hydrofluoric acid and concentrated nitric acid.
The age resister additive amount is 3.5-16% relative to the mass fraction of water；
The hydroxyethyl cellulose additive amount is 2.0-8% relative to the mass fraction of water；
The weight average molecular weight of the hydroxyethyl cellulose is 20000~25000, and molar substitution is 1.8~1.9.
The butane tetracarboxylic acid is 0.3% relative to the mass fraction of chitosan.
The diameter of modified capsule is 2~5 μm, is conducive to capsule and passes through spinneret orifice, and guarantees capsule and fiber Be firmly combined, the mechanical performance of fiber can't be influenced.
The capsule of modified capsule/core guarantees that microcapsules have certain mechanical strength and heat-resisting than being generally higher than equal to 1: 10 Property.
The effect of modified capsule is, plays the role of the anti-aging functional particles of slow release, is conducive to its anti-aging function Effect is able to permanent holding.
3）Anti-aging arrangement is carried out to nylon elastic material strips with the finishing fluid prepared.
Nylon elastic material strips are put into age resister finishing fluid and are impregnated, bath raio 1:It is soaked at 20-50,40 ~ 50 DEG C Stain 30-80 minutes, washing drying；Then the band arranged by age resister is pressed 1 with fixed liquid:The bath raio of 20-30 immerses solid In liquid, after permeating completely under room temperature, two leachings two are rolled, and pick-up 70-90% is dried in 80 DEG C, and 100-140 DEG C bake 2-3 points Clock is washed, is soaped, is dried；The composition of the fixation liquid includes glyoxal, magnesium chloride, tartaric acid and water, and concentration is 40% second Dialdehyde content in every liter of water is 20-50g, and magnesium chloride content in every liter of water is 2-5g, and tartaric acid content in every liter of water is 1-3g, the mixed liquor stirred evenly at room temperature.
Elastic composite material cloth has following beneficial effect compared with the prior art in the present invention：
（1）Using Double-layer elastic material, the composite structure shape constituted between elastic woven material is set to by high polymer elastic layer State, and can be simultaneously for making present invention control prior art by the cooperation of nylon elastic layer and cellulose material bilayer Elasticity and durability and gas permeability, the uniformity of elasticity are enhanced with different degrees of elastic telescopic power；
（2）Age resister synthesized by the present invention has the anti-aging property of excellent absorption living radical, preparation process letter Single, yield is high, and is easily isolated, and raw material employed in preparation process and solvent are environmentally protective；Using with reactive end hydroxyl The age resister of base functional group is coated by the method for microcapsules with hydroxyethyl cellulose, and age resister is both improved Dispersibility and stability, while the dispersibility of organic aging agent in the material is also achieved, realize the evenly dispersed of age resister With the high performance purpose of few additive；Since benzotriazole functional group is with excellent in the age resister molecule generated simultaneously Anti-aging property, being particularly due to radiation makes material generate living radical, makes under the action of age resister active free Base inactivation, to improve the ageing-resistant performance of material；Hydroxyethyl cellulose wall material and the compatibility of basis material are preferable, conducive to changing Property microencapsulation material nylon material in disperse, spinning and fibrous mechanical property are influenced it is few, on the basis for guaranteeing fibre property On, improve the anti-aging property of material.
Specific embodiment
Embodiment 1
Nylon elastic material strips first be have passed through into anti-aging processing, processing step is：
1）The preparation of age resister
Under nitrogen protection, by 3,4- chloro-2-methyl aniline, it is added to the mixing of the water and ethyl alcohol of the sodium hydroxide of 4 mol/L In solution, stirs and reducing agent lithium aluminium hydride reduction is added by several times, be cooled to room temperature after reacting 3h at 80 DEG C, sulfuric acid is added by pH value It adjusts between 6, filters, dry in the shade, re-dry after recrystallization obtains functional modifier crude product, then that functional modifier is thick Product, hydrofluoric acid and concentrated nitric acid are added in reaction vessel, and after being heated to 50 DEG C of reaction 1.5h, Off-white product is obtained by filtration, and pass through It is cooling to filter, it dries in the shade, recrystallizes and dry, obtain age resister；
2）The preparation of anti-ageing microcapsules and age resister finishing fluid
Using deionized water as solvent, in a solvent age resister dispersion, whipping temp is room temperature, controls whipping process medium-rate For 1000r/min, being dispersed with stirring the time is 65min, so that age resister molecule is formed suspension system in aqueous solution, then It adds hydroxyethyl cellulose to be dissolved, then carries out high-speed stirred dispersion, whipping temp is 40 DEG C, and stirring rate is 3600r/min, mixing time 15min, then add butane tetracarboxylic acid carry out it is chitosan crosslinked, then under the conditions of 85 DEG C into Row curing 10min is obtained by filtration thick modified capsule, then after 60 DEG C are dried in vacuo for 24 hours, obtains changing containing age resister Property capsule；Its sandwich layer is age resister, and cystoblast is hydroxyethylcellulose materials, wherein the thickness of cystoblast and sandwich layer ratio is 1: 18； By manufactured age resister microcapsules 3.6%（owf）, penetrating agent JFC 1.2g/l, pH value 7 is made into age resister finishing fluid；
The volume ratio of water and ethyl alcohol in the mixed solution of the water and ethyl alcohol is 1: 2；The lithium aluminium hydride reduction and 3,4- are chloro- The molar ratio of 2-aminotoluene is 2: 1.5；The molar ratio 2: 2.2 of the functional modifier crude product, hydrofluoric acid and concentrated nitric acid ∶1.1。
The age resister additive amount is 8% relative to the mass fraction of water；
The hydroxyethyl cellulose additive amount is 2. 8% relative to the mass fraction of water；
The weight average molecular weight of the hydroxyethyl cellulose is 28000, molar substitution 1.8.
The butane tetracarboxylic acid is 0.3% relative to the mass fraction of chitosan.
The diameter of modified capsule is 4 μm, is conducive to capsule and passes through spinneret orifice, and guarantees capsule and fiber It is firmly combined, the mechanical performance of fiber can't be influenced.
The capsule of modified capsule/core guarantees that microcapsules have certain mechanical strength and heat-resisting than being generally higher than equal to 1: 10 Property.
3）Anti-aging arrangement is carried out to nylon elastic material strips with the finishing fluid prepared.
Nylon elastic material strips are put into age resister finishing fluid and are impregnated, bath raio 1:46 points are impregnated at 25,44 DEG C Clock, washing drying；Then the band arranged by age resister is pressed 1 with fixed liquid:25 bath raio immerses in fixed liquid, under room temperature Completely after infiltration, two leachings two are rolled, and pick-up 89% is dried in 80 DEG C, and 130 DEG C bake 3 minutes, are washed, soaped, dried；It is described The composition of fixed liquid includes glyoxal, magnesium chloride, tartaric acid and water, and concentration is that 40% glyoxal content in every liter of water is 26g, Magnesium chloride content in every liter of water is 2.5g, and tartaric acid content in every liter of water is 1.3g, the mixing stirred evenly at room temperature Liquid.
It is material strips made of cellulose fibre by another layer of resilient material made of nylon fiber, passes through between two layers High polymer elastic layer is combined；Every layer all from through being formed to elastic webbing and broadwise elastic webbing, it is described through to elastic webbing and latitude It is diamond shape to the gap between elastic webbing；The gap is 18 square millimeters；It is described through being to the spacing between elastic webbing 2.5 millimeter；Spacing between the broadwise elastic webbing is 3.6 millimeters；The high polymer elastic layer is using macromolecule Elastic material, including polyvinyl chloride.
Elastic trampoline cloth is used for trampoline.
Embodiment 2
Nylon elastic material strips first be have passed through into anti-aging processing, processing step is：
1）The preparation of age resister
Under nitrogen protection, it by 2- naphthylamines, is added in the water of the sodium hydroxide of 1.5mol/L and the mixed solution of ethyl alcohol, stirs Mix and by several times be added reducing agent lithium aluminium hydride reduction, at 80 DEG C react 3h after be cooled to room temperature, be added sulfuric acid by pH value adjust 6 it Between, it filters, dries in the shade, re-dry after recrystallization obtains functional modifier crude product, then by functional modifier crude product, hydrogen fluorine Acid and concentrated nitric acid are added in reaction vessel, and after being heated to 50 DEG C of reaction 2.0h, Off-white product is obtained by filtration, and filter through cooling, It dries in the shade, recrystallizes and dry, obtain age resister；
2）The preparation of anti-ageing microcapsules and age resister finishing fluid
Using deionized water as solvent, in a solvent age resister dispersion, whipping temp is room temperature, controls whipping process medium-rate For 1000r/min, being dispersed with stirring the time is 50min, so that age resister molecule is formed suspension system in aqueous solution, then It adds hydroxyethyl cellulose to be dissolved, then carries out high-speed stirred dispersion, whipping temp is 40 DEG C, and stirring rate is 3600r/min, mixing time 15min, then add butane tetracarboxylic acid carry out it is chitosan crosslinked, then under the conditions of 90 DEG C into Row curing 10min is obtained by filtration thick modified capsule, then after 60 DEG C are dried in vacuo for 24 hours, obtains changing containing age resister Property capsule；Its sandwich layer is age resister, and cystoblast is hydroxyethylcellulose materials, wherein the thickness of cystoblast and sandwich layer ratio is 1: 18； By manufactured age resister microcapsules 3%（owf）, penetrating agent JFC 2g/l, pH value 7 is made into age resister finishing fluid；
The volume ratio of water and ethyl alcohol in the mixed solution of the water and ethyl alcohol is 1: 2；The lithium aluminium hydride reduction and 2- naphthylamines Molar ratio be 2: 1.5；The molar ratio 2: 2.2: 1.1 of the functional modifier crude product, hydrofluoric acid and concentrated nitric acid.
The age resister additive amount is 3.5% relative to the mass fraction of water；
The hydroxyethyl cellulose additive amount is 2.0% relative to the mass fraction of water；
The weight average molecular weight of the hydroxyethyl cellulose is 20000, molar substitution 1.8.
The butane tetracarboxylic acid is 0.3% relative to the mass fraction of chitosan.
The diameter of modified capsule is 2 μm, is conducive to capsule and passes through spinneret orifice, and guarantees capsule and fiber It is firmly combined, the mechanical performance of fiber can't be influenced.
The capsule of modified capsule/core guarantees that microcapsules have certain mechanical strength and heat-resisting than being generally higher than equal to 1: 10 Property.
3）Anti-aging arrangement is carried out to nylon elastic material strips with the finishing fluid prepared.
Nylon elastic material strips are put into age resister finishing fluid and are impregnated, bath raio 1:30 points are impregnated at 20,50 DEG C Clock, washing drying；Then the band arranged by age resister is pressed 1 with fixed liquid:20 bath raio immerses in fixed liquid, under room temperature Completely after infiltration, two leachings two are rolled, and pick-up 90% is dried in 80 DEG C, and 140 DEG C bake 2 minutes, are washed, soaped, dried；Institute The composition for stating fixed liquid includes glyoxal, magnesium chloride, tartaric acid and water, and concentration is that 40% glyoxal content in every liter of water is 50g, magnesium chloride content in every liter of water are 5g, and tartaric acid content in every liter of water is 3g, the mixing stirred evenly at room temperature Liquid.
It is material strips made of cellulose fibre by another layer of resilient material made of nylon fiber, passes through between two layers High polymer elastic layer is combined；Every layer all from through being formed to elastic webbing and broadwise elastic webbing, it is described through to elastic webbing and latitude It is diamond shape to the gap between elastic webbing；The gap is 15 square millimeters；It is described through being 5 to the spacing between elastic webbing Millimeter；Spacing between the broadwise elastic webbing is 4 millimeters；The high polymer elastic layer is using high polymer elastic material Matter, including silica gel.
Elastic trampoline cloth is used for trampoline.
Comparative example 1
Capsule will be modified and polypropylene particles carry out melt spinning, modified polypropene silk is obtained, then again by modified polypropene silk It is woven into yarn, elastic trampoline cloth is made by yarn；
The mass fraction of modification capsule in the modified polypropene silk is 2%.
The preparation method of modified capsule, the specific steps are that：
(a) to the preparation of dihydroxy Pyrogentisinic Acid's base phosphine
Using Phenylphosphine and paraformaldehyde as raw material, using water and isopropyl alcohol mixture as solvent, parent occurs under the action of catalyst And addition reaction, control reaction temperature are 35~50 DEG C, the reaction time is 3~4h；Dihydroxymethyl phenyl phosphine is prepared, then At 85~95 DEG C, the mixed solution that hydrogen peroxide and the concentrated sulfuric acid is added is strong oxidizer, and 45~60min of oxidation is prepared into To dihydroxymethyl phenyl phosphine oxide, by the hydroquinol base phosphine of synthesis, bromine water and iron powder are added in reaction vessel, are heated to Kermesinus product is obtained by filtration after 65~75 DEG C of 0.5~1.75h of reaction, it is added to the hydrogen-oxygen of 0.2mol/L at normal temperature Change in potassium and ethyl alcohol potassium solution, in 80~95 DEG C of 1~3h of reaction after being completely dissolved, then product recrystallized in steam bath, In triplicate, obtain white to dihydroxy Pyrogentisinic Acid's base phosphine；
The molar ratio of the Phenylphosphine and paraformaldehyde is 1: 2.1；
Catalyst is vanadic anhydride, and the Phenylphosphine and catalyst molar ratio value are 1: 0.03；
The volume ratio of the water and isopropanol is 1: 0.75；
The mass fraction of the paraformaldehyde is 10%；
The mass values of the strong oxidizer and Phenylphosphine are 1: 2.5；
The mass fraction of the hydrogen peroxide is 20%；
Hydrogen peroxide and concentrated sulfuric acid volume ratio are 1: 1 in the hydrogen peroxide and concentrated sulfuric acid solution；
The hydroquinol base phosphine, the molar ratio 1: 1.2: 0.01 of bromine water and iron powder；
The molar ratio of the potassium hydroxide and potassium ethoxide is 1: 2.5；
(b) preparation of ortho-nitraniline diazonium salt
Ortho-nitraniline is stirred strongly in the concentrated nitric acid of 12mol/L and is quickly cooled to 0 DEG C, 4mol/L is added after 1.5h Potassium nitrite aqueous solution filters after reacting 0.5~1.0h at 0~5 DEG C, obtains ortho-nitraniline diazonium salt；
(c) preparation of azo-compound
By step (a) preparation dihydroxy Pyrogentisinic Acid's base phosphine is added into the mixed solution of isopropanol and distilled water, keep molten 5~10 DEG C of liquid temperature, the ortho-nitraniline diazonium salt of step (b) preparation is instilled by several times, is filtered, washing, dry azo compounds Object is rediance crystal；
The volume ratio of isopropanol and distilled water in the mixed solution of the isopropanol and distilled water is 1: 0.75；
Described is 4% in the mass fraction of isopropanol and the mixed solution of distilled water to dihydroxy Pyrogentisinic Acid's base phosphine；
The molar ratio to dihydroxy Pyrogentisinic Acid's base phosphine and ortho-nitraniline diazonium salt is 1: 1；
(d) preparation of age resister
Under nitrogen protection, azo-compound prepared by step (c) is added to the water and ethyl alcohol of the sodium hydroxide of 3.0mol/L Mixed solution in, stir and by several times be added reducing agent lithium aluminium hydride reduction, at 60~65 DEG C react 2h after be cooled to room temperature, add Enter nitric acid pH to adjust between 5~6, filter, dry in the shade, re-dry after recrystallization obtains functional modifier crude product, then will Functional modifier crude product, hydrofluoric acid and concentrated nitric acid are added in reaction vessel, after being heated to 65~75 DEG C of 0.5~1.0h of reaction, Off-white product is obtained by filtration, is filtered through cooling, dries in the shade, recrystallize and dry, obtain age resister；
The volume ratio of water and ethyl alcohol in the mixed solution of the water and ethyl alcohol is 1: 1；
The molar ratio of the lithium aluminium hydride reduction and azo-compound is 1: 0.5；
The molar ratio 1: 1.2: 0.01 of the functional modifier crude product, hydrofluoric acid and concentrated nitric acid；
(e) preparation of modified capsule
Using deionized water as solvent, in a solvent age resister dispersion, whipping temp is room temperature, controls whipping process middling speed Rate is 800~1200r/min, and being dispersed with stirring the time is 30~45min, and age resister molecule is enable to be formed in aqueous solution Then suspension system adds hydroxyethyl cellulose and is dissolved, then carries out high-speed stirred dispersion, whipping temp is 45~55 DEG C, stirring rate is 2000~3300r/min, and mixing time is 20~30min, then adds butane tetracarboxylic acid and carries out shell Glycan crosslinking, then curing 30min is carried out under the conditions of 65~80 DEG C, thick modified capsule is obtained by filtration, then in 60 DEG C of progress vacuum After drying for 24 hours, the modification capsule containing age resister is obtained；Its sandwich layer is age resister, and cystoblast is hydroxyethylcellulose materials, Wherein, the thickness of cystoblast and sandwich layer ratio is 1: 15.
The age resister additive amount is 3.5% relative to the mass fraction of water；
The hydroxyethyl cellulose additive amount is 2.0% relative to the mass fraction of water；
The weight average molecular weight of the hydroxyethyl cellulose is 20000~25000, and molar substitution is 1.8~1.9.
The butane tetracarboxylic acid is 0.3% relative to the mass fraction of chitosan.
The diameter of modified capsule is 2~5 μm, is conducive to capsule and passes through spinneret orifice, and guarantees capsule and fiber Be firmly combined, the mechanical performance of fiber can't be influenced.
The capsule of modified capsule/core guarantees that microcapsules have certain mechanical strength and heat-resisting than being generally higher than equal to 1: 10 Property.
Elastic trampoline cloth is used for trampoline.
Comparative example 2
Only with the nylon elastic band that age resister is handled, cellulose fibre belt is not contained, i.e., does not use composite construction layer.Its Remaining step is the same as embodiment 2.
After trampoline spring 100,1000,10000 times, measuring center point recess situation, it can be found that the embodiment of the present application The obvious resilient material deformation of 1-2 wants small, and durability is good.
Table 1
100 times（mm） 1000 times（mm） 10000 times（mm）
Embodiment 1 0 0 2.9
Embodiment 2 0 0 3.9
Comparative example 1 0 2 56
Comparative example 2 0 4 79
Same people is measured in central point and trampoline surrounding jumping height, finds jumping height difference average value embodiment 1-2 It is smaller, illustrate that the application elastic webbing elasticity is balanced.
Table 2
Difference in height average value（%）
Embodiment 1 2.4
Embodiment 2 3.6
Comparative example 1 6
Comparative example 2 9.7

Claims (6)

1. a kind of elastic composite cloth, it is characterised in that：The elastic composite cloth is double-layer structure, and one layer fine for nylon Resilient material made of tieing up, another layer are material strips made of cellulose fibre, between two layers by high polymer elastic layer into Row combines, described through being diamond shape to the gap between elastic webbing and broadwise elastic webbing, what the high polymer elastic layer used It is high polymer elastic material, includes at least thermoplastic elastomer (TPE) or thermo-setting elastomer.
2. elastic composite cloth as described in claim 1, it is characterised in that：The gap is 10 to 25 square millimeters； It is described through being 2-5 millimeters to the spacing between elastic webbing；Spacing between the broadwise elastic webbing is 3-6 millimeters.
3. elastic composite cloth as described in claim 1, it is characterised in that：Wherein thermoplastic elastomer (TPE) includes thermoplasticity modeling Material, Polyurethane, polyvinyl chloride；Thermo-setting elastomer then includes silica gel.
4. elastic composite cloth as claimed in claim 2, it is characterised in that：In the mixed solution of the water and ethyl alcohol Water and ethyl alcohol volume ratio be 1: 2；The lithium aluminium hydride reduction and 3,4- chloro-2-methyl aniline or 2- naphthylamines or amino -3 4-, The molar ratio of 2- dimethyl azobenzene or 2- amino -4- nitrotoleune is 2: 1.5；The functional modifier crude product, hydrogen fluorine The molar ratio 2: 2.2: 1.1 of acid and concentrated nitric acid.
5. elastic composite cloth as claimed in claim 2, it is characterised in that：The nylon elastic material strips have passed through anti- Aging process.
6. elastic composite cloth as claimed in claim 2, it is characterised in that：Using Double-layer elastic material, pass through macromolecule Elastic layer is set to the composite structure form constituted between elastic woven material, and double by nylon elastic layer and cellulose material The cooperation of layer.
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CN102230256A (en) * 2011-06-02 2011-11-02 稳健实业(深圳)有限公司 Elastic non-woven fabric, production method thereof and elastic product
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