CN108527982A - elastic composite cloth - Google Patents
elastic composite cloth Download PDFInfo
- Publication number
- CN108527982A CN108527982A CN201810284174.3A CN201810284174A CN108527982A CN 108527982 A CN108527982 A CN 108527982A CN 201810284174 A CN201810284174 A CN 201810284174A CN 108527982 A CN108527982 A CN 108527982A
- Authority
- CN
- China
- Prior art keywords
- elastic
- layer
- water
- age resister
- composite cloth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000004744 fabric Substances 0.000 title claims abstract description 18
- 239000002131 composite material Substances 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 19
- 229920001778 nylon Polymers 0.000 claims abstract description 18
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 239000012858 resilient material Substances 0.000 claims abstract description 7
- 229920003043 Cellulose fiber Polymers 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 43
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 28
- 239000013013 elastic material Substances 0.000 claims description 15
- 239000004677 Nylon Substances 0.000 claims description 14
- 235000019441 ethanol Nutrition 0.000 claims description 14
- 239000003607 modifier Substances 0.000 claims description 13
- 239000012043 crude product Substances 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 12
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 11
- 229910017604 nitric acid Inorganic materials 0.000 claims description 11
- 239000012280 lithium aluminium hydride Substances 0.000 claims description 9
- 230000009467 reduction Effects 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 8
- 150000005004 2-naphthylamines Chemical class 0.000 claims description 5
- 229910003460 diamond Inorganic materials 0.000 claims description 4
- 239000010432 diamond Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 239000000741 silica gel Substances 0.000 claims description 3
- 229910002027 silica gel Inorganic materials 0.000 claims description 3
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 239000000806 elastomer Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920001187 thermosetting polymer Polymers 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 239000002775 capsule Substances 0.000 description 33
- 239000007788 liquid Substances 0.000 description 26
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 18
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 18
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 18
- 230000003712 anti-aging effect Effects 0.000 description 16
- 238000002360 preparation method Methods 0.000 description 16
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 14
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 13
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 12
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000003094 microcapsule Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000003756 stirring Methods 0.000 description 11
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 9
- 239000000654 additive Substances 0.000 description 9
- 230000000996 additive effect Effects 0.000 description 9
- 239000002585 base Substances 0.000 description 9
- 239000000835 fiber Substances 0.000 description 9
- 238000001914 filtration Methods 0.000 description 9
- GGAUUQHSCNMCAU-ZXZARUISSA-N (2s,3r)-butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C[C@H](C(O)=O)[C@H](C(O)=O)CC(O)=O GGAUUQHSCNMCAU-ZXZARUISSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 210000001940 cystoblast Anatomy 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 8
- 229920001661 Chitosan Polymers 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000011975 tartaric acid Substances 0.000 description 6
- 235000002906 tartaric acid Nutrition 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 229940015043 glyoxal Drugs 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- RPGWZZNNEUHDAQ-UHFFFAOYSA-N phenylphosphine Chemical compound PC1=CC=CC=C1 RPGWZZNNEUHDAQ-UHFFFAOYSA-N 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 238000001953 recrystallisation Methods 0.000 description 4
- 238000006467 substitution reaction Methods 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 3
- 229930040373 Paraformaldehyde Natural products 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000009191 jumping Effects 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229920002866 paraformaldehyde Polymers 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical group O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Inorganic materials Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- RNVCVTLRINQCPJ-UHFFFAOYSA-N o-toluidine Chemical compound CC1=CC=CC=C1N RNVCVTLRINQCPJ-UHFFFAOYSA-N 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- UFPRGLVFRAVEIT-UHFFFAOYSA-N C1(=CC=CC=C1)P(C(O)O)=O Chemical compound C1(=CC=CC=C1)P(C(O)O)=O UFPRGLVFRAVEIT-UHFFFAOYSA-N 0.000 description 1
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- AZFNGPAYDKGCRB-XCPIVNJJSA-M [(1s,2s)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene Chemical compound [Ru+]Cl.CC(C)C1=CC=C(C)C=C1.C1=CC(C)=CC=C1S(=O)(=O)[N-][C@@H](C=1C=CC=CC=1)[C@@H](N)C1=CC=CC=C1 AZFNGPAYDKGCRB-XCPIVNJJSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- UQAKMQOKLZITTL-UHFFFAOYSA-N phenylphosphanylmethanediol Chemical compound OC(O)PC1=CC=CC=C1 UQAKMQOKLZITTL-UHFFFAOYSA-N 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- RPDAUEIUDPHABB-UHFFFAOYSA-N potassium ethoxide Chemical compound [K+].CC[O-] RPDAUEIUDPHABB-UHFFFAOYSA-N 0.000 description 1
- 235000010289 potassium nitrite Nutrition 0.000 description 1
- 239000004304 potassium nitrite Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
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- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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- B32B23/04—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B23/046—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
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- B32B23/00—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
- B32B23/04—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B23/08—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/20—Layered products comprising a layer of natural or synthetic rubber comprising silicone rubber
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/123—Polyaldehydes; Polyketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
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Abstract
A kind of elastic composite cloth, it is characterised in that：The elastic composite cloth is double-layer structure, and one layer is resilient material made of nylon fiber, and another layer is material strips made of cellulose fibre, is combined by high polymer elastic layer between two layers.
Description
The application is entitled a kind of permanent seal cooling elastic composite application No. is 2016106277820, the applying date
For the divisional application of 20160803 application for a patent for invention.
Technical field
The invention belongs to elastic composite fields.
Background technology
2009 " Bedjump ", runs away rapidly on website, and Chinese is translated into " trampoline " or " trampoline ".It is gathered around in all parts of the world
There are numerous fans for growing tender of this movement.The bed that fan would generally select elasticity good, jumps up, and makes in the air various dynamic
Make.Trampoline is mainly equipped with a fabric tightened by most springs in the frame for the tripod support that lands, and is stood on for user
Constantly spring carries out interesting movement on spring face.Trampoline in the prior art has the following defects：1. the frame body of trampoline
Product is larger, thus after manufacturer produces bouncer products, each assembled trampoline has sizable volume, no
Finished product is stored up only in factory can occupy the confined space in factory, and when export trade can also increase transportation cost, furthermore, no matter the quotient of exhibition sale
Shop or personal use person, trampoline are intended to occupy sizable interior space under without using state.2. current trampoline uses bullet
Spring is as its elastic force source, for the sake of security, needs to be laid with neonychium above spring, avoids unexpected generation.It is so this
Neonychium needs to increase the cost of trampoline；Built-up time is increased, simultaneously as spring will produce flexible deformation, is not made originally
Used time neonychium is tightly to cover, but after the flexible deformation of spring, neonychium deviates, cause covering uneven and
Spring is set to expose, so as to will increase the incidence of safety accident.3. again due to being to utilize guarantor as elastic component using spring
Protection pad covering is laid with, and so that effective usable floor area of trampoline is greatly reduced, the space of actually jumping of trampoline has been limited in the presence of spring.
Useful elastical cloth substitutes spring in the prior art, but there are elastical cloth service lifes it is short, cloth cover uniform elastic is poor the problems such as.
Invention content
To solve the above-mentioned problems, technical scheme is as follows：
A kind of permanent seal cooling elastic composite, it is characterised in that：Composite material is double-layer structure, wherein one layer anti-ageing to have carried out
Change the resilient material arranged, arrangement process includes：1）The preparation of age resister；2）The preparation of microcapsules and dressing liquid；3）With
The dressing liquid prepared carries out anti-aging arrangement to nylon elastic material strips.
Elastic composite cloth is double-layer structure, and one layer is resilient material made of nylon fiber, and another layer is fiber
Material strips made of cellulose fiber are combined by high polymer elastic layer between two layers；Every layer all by warp-wise elastic webbing and broadwise
Elastic webbing forms, and the gap between the warp-wise elastic webbing and broadwise elastic webbing is diamond shape；The gap is 10 to 25 flat
Square millimeter；Spacing between the warp-wise elastic webbing is 2-5 millimeters；Spacing between the broadwise elastic webbing is 3-6 millis
Rice；The high polymer elastic layer includes at least thermoplastic elastomer (TPE) or thermoset elastic using high polymer elastic material
Body；Wherein thermoplastic elastomer (TPE) includes thermoplastic, Polyurethane, polyvinyl chloride；Thermo-setting elastomer includes then silica gel.It is described
Nylon elastic material strips have passed through anti-aging processing, processing step is：
1）The preparation of age resister
Under nitrogen protection, by 3,4- chloro-2-methyl anilines or 2- naphthylamines or 4- amino -3,2- dimethyl azobenzenes or 2- ammonia
Base -4- nitrotoleunes, are added in the water of the sodium hydroxide of 1.5 ~ 4 mol/L and the mixed solution of ethyl alcohol, stir and add by several times
Enter reducing agent lithium aluminium hydride reduction, 0.5 ~ 3h postcoolings reacted at 75 ~ 80 DEG C to room temperature, be added sulfuric acid by pH value adjust 5~6 it
Between, it filters, dries in the shade, re-dry after recrystallization obtains functional modifier crude product, then by functional modifier crude product, hydrogen fluorine
Acid and concentrated nitric acid are added in reaction vessel, after being heated to 45 ~ 50 DEG C of 1.5~2.0h of reaction, Off-white product are obtained by filtration, through cold
But it filters, dries in the shade, recrystallize and dry, obtain age resister；
2）The preparation of anti-ageing microcapsules and age resister dressing liquid
Using deionized water as solvent, in a solvent age resister dispersion, whipping temp is room temperature, controls whipping process medium-rate
For 500~1000r/min, it is 50~65min to be dispersed with stirring the time, and age resister molecule is enable to form suspension in aqueous solution
Then system adds hydroxyethyl cellulose and is dissolved, then carries out high-speed stirred dispersion, whipping temp is 35~40 DEG C, is stirred
It is 3400~3600r/min to mix rate, and mixing time is 10~15min, then adds butane tetracarboxylic acid and carries out chitosan friendship
Connection, then curing 10min is carried out under the conditions of 85~90 DEG C, thick modified capsule is obtained by filtration, then be dried in vacuo at 60 DEG C
After for 24 hours, the modification capsule containing age resister is obtained；Its sandwich layer is age resister, and cystoblast is hydroxyethylcellulose materials, wherein
The thickness of cystoblast and sandwich layer ratio is 1: 18；By manufactured age resister microcapsules 3-6%（owf）, penetrating agent JFC 1-2g/l, pH value
For 7-7.5, it is made into age resister dressing liquid；
The volume ratio of water and ethyl alcohol in the mixed solution of the water and ethyl alcohol is 1: 2；The lithium aluminium hydride reduction and 3,4- are chloro-
The molar ratio of 2-aminotoluene or 2- naphthylamines or 4- amino -3,2- dimethyl azobenzenes or 2- amino -4- nitrotoleunes is 2:
1.5；The molar ratio 2: 2.2: 1.1 of the functional modifier crude product, hydrofluoric acid and concentrated nitric acid.
The age resister additive amount is 3.5-16% relative to the mass fraction of water；
The hydroxyethyl cellulose additive amount is 2.0-8% relative to the mass fraction of water；
The weight average molecular weight of the hydroxyethyl cellulose is 20000~25000, and molar substitution is 1.8~1.9.
The butane tetracarboxylic acid is 0.3% relative to the mass fraction of chitosan.
A diameter of 2~5 μm of modified capsule, are conducive to capsule and pass through spinneret orifice, and ensure capsule and fiber
Be firmly combined with, the mechanical performance of fiber can't be influenced.
The capsule of modified capsule/core ensures that microcapsules have certain mechanical strength and heat-resisting than being generally higher than equal to 1: 10
Property.
The effect of modified capsule is, plays the role of the anti-aging functional particles of slow release, is conducive to its anti-aging work(
Effect is able to permanent holding.
3）Anti-aging arrangement is carried out to nylon elastic material strips with the dressing liquid prepared.
Nylon elastic material strips are put into age resister dressing liquid and are impregnated, bath raio 1:It is soaked at 20-50,40 ~ 50 DEG C
Stain 30-80 minutes, washing drying；Then the band arranged by age resister is pressed 1 with fixed liquid:The bath raio of 20-30 immerses solid
It in liquid, after being permeated completely under room temperature, two leachings two are rolled, pick-up 70-90%, and in 80 DEG C of drying, 100-140 DEG C bake 2-3 points
Clock, through washing, soaping, dry；The composition of the fixation liquid includes glyoxal, magnesium chloride, tartaric acid and water, a concentration of 40% second
Dialdehyde content in every liter of water is 20-50g, and magnesium chloride content in every liter of water is 2-5g, and tartaric acid content in every liter of water is
1-3g, the mixed liquor stirred evenly at room temperature.
Elastic composite material cloth has following advantageous effect compared with the prior art in the present invention：
（1）Using Double-layer elastic material, the composite structure shape constituted between elastic woven material is set to by high polymer elastic layer
State, and can be simultaneously for making present invention control prior art by the cooperation of nylon elastic layer and cellulose material bilayer
Elasticity and durability and gas permeability, the uniformity of elasticity are enhanced with different degrees of elastic telescopic power；
（2）Age resister synthesized by the present invention has the anti-aging property of excellent absorption living radical, preparation process letter
Single, yield is high, and is easily isolated, and the raw material and solvent employed in preparation process are environmentally protective；Using with reactive end hydroxyl
The age resister of base functional group is coated by the method for microcapsules with hydroxyethyl cellulose, and age resister is both improved
Dispersibility and stability, while the dispersibility of organic aging agent in the material is also achieved, realize the evenly dispersed of age resister
With the high performance purpose of few additive；Since benzotriazole functional group is with excellent in the age resister molecule generated simultaneously
Anti-aging property, being particularly due to radiation makes material generate living radical, makes under the action of age resister active free
Base inactivates, to improve the ageing-resistant performance of material；Hydroxyethyl cellulose wall material and the compatibility of basis material are preferable, conducive to changing
Property microencapsulation material nylon material in disperse, spinning and fibrous mechanical property are influenced it is few, on the basis for ensureing fibre property
On, improve the anti-aging property of material.
Specific implementation mode
Embodiment 1
Nylon elastic material strips first be have passed through into anti-aging processing, processing step is：
1）The preparation of age resister
Under nitrogen protection, by 3,4- chloro-2-methyl anilines, it is added to the mixing of the water and ethyl alcohol of the sodium hydroxide of 4 mol/L
It in solution, stirs and reducing agent lithium aluminium hydride reduction is added by several times, 3h postcoolings are reacted at 80 DEG C to room temperature, sulfuric acid is added by pH value
It adjusts between 6, filters, dry in the shade, re-dry after recrystallization obtains functional modifier crude product, then that functional modifier is thick
Product, hydrofluoric acid and concentrated nitric acid are added in reaction vessel, after being heated to 50 DEG C of reaction 1.5h, Off-white product are obtained by filtration, passes through
It is cooling to filter, it dries in the shade, recrystallizes and dry, obtain age resister；
2）The preparation of anti-ageing microcapsules and age resister dressing liquid
Using deionized water as solvent, in a solvent age resister dispersion, whipping temp is room temperature, controls whipping process medium-rate
For 1000r/min, it is 65min to be dispersed with stirring the time, so that age resister molecule is formed suspension system in aqueous solution, then
It adds hydroxyethyl cellulose to be dissolved, then carries out high-speed stirred dispersion, whipping temp is 40 DEG C, and stir speed (S.S.) is
3600r/min, mixing time 15min, then add butane tetracarboxylic acid carry out it is chitosan crosslinked, then under the conditions of 85 DEG C into
Row curing 10min is obtained by filtration thick modified capsule, then after 60 DEG C are dried in vacuo for 24 hours, obtains changing containing age resister
Property capsule；Its sandwich layer is age resister, and cystoblast is hydroxyethylcellulose materials, wherein the thickness of cystoblast and sandwich layer ratio is 1: 18；
By manufactured age resister microcapsules 3.6%（owf）, penetrating agent JFC 1.2g/l, pH value 7 is made into age resister dressing liquid；
The volume ratio of water and ethyl alcohol in the mixed solution of the water and ethyl alcohol is 1: 2；The lithium aluminium hydride reduction and 3,4- are chloro-
The molar ratio of 2-aminotoluene is 2: 1.5；The molar ratio 2: 2.2 of the functional modifier crude product, hydrofluoric acid and concentrated nitric acid
∶1.1。
The age resister additive amount is 8% relative to the mass fraction of water；
The hydroxyethyl cellulose additive amount is 2. 8% relative to the mass fraction of water；
The weight average molecular weight of the hydroxyethyl cellulose is 28000, molar substitution 1.8.
The butane tetracarboxylic acid is 0.3% relative to the mass fraction of chitosan.
A diameter of 4 μm of modified capsule, are conducive to capsule and pass through spinneret orifice, and ensure capsule and fiber
It is firmly combined with, the mechanical performance of fiber can't be influenced.
The capsule of modified capsule/core ensures that microcapsules have certain mechanical strength and heat-resisting than being generally higher than equal to 1: 10
Property.
3）Anti-aging arrangement is carried out to nylon elastic material strips with the dressing liquid prepared.
Nylon elastic material strips are put into age resister dressing liquid and are impregnated, bath raio 1:46 points are impregnated at 25,44 DEG C
Clock, washing drying；Then the band arranged by age resister is pressed 1 with fixed liquid:25 bath raio immerses in fixed liquid, under room temperature
Completely after infiltration, two leachings two are rolled, pick-up 89%, and in 80 DEG C of drying, 130 DEG C bake 3 minutes, through washing, soaping, dry；It is described
The composition of fixed liquid includes glyoxal, magnesium chloride, tartaric acid and water, and a concentration of 40% glyoxal content in every liter of water is 26g,
Magnesium chloride content in every liter of water is 2.5g, and tartaric acid content in every liter of water is 1.3g, the mixing stirred evenly at room temperature
Liquid.
It is material strips made of cellulose fibre by another layer of resilient material made of nylon fiber, passes through between two layers
High polymer elastic layer is combined；Every layer is all made of warp-wise elastic webbing and broadwise elastic webbing, the warp-wise elastic webbing and latitude
It is diamond shape to the gap between elastic webbing；The gap is 18 square millimeters；Spacing between the warp-wise elastic webbing is
2.5 millimeter；Spacing between the broadwise elastic webbing is 3.6 millimeters；The high polymer elastic layer is using macromolecule
Elastic material, including polyvinyl chloride.
Elastic trampoline cloth is used for trampoline.
Embodiment 2
Nylon elastic material strips first be have passed through into anti-aging processing, processing step is：
1）The preparation of age resister
Under nitrogen protection, it by 2- naphthylamines, is added in the water of the sodium hydroxide of 1.5mol/L and the mixed solution of ethyl alcohol, stirs
Mix and reducing agent lithium aluminium hydride reduction be added by several times, 3h postcoolings are reacted at 80 DEG C to room temperature, be added sulfuric acid by pH value adjust 6 it
Between, it filters, dries in the shade, re-dry after recrystallization obtains functional modifier crude product, then by functional modifier crude product, hydrogen fluorine
Acid and concentrated nitric acid are added in reaction vessel, and after being heated to 50 DEG C of reaction 2.0h, Off-white product is obtained by filtration, is filtered through cooling,
It dries in the shade, recrystallizes and dry, obtain age resister；
2）The preparation of anti-ageing microcapsules and age resister dressing liquid
Using deionized water as solvent, in a solvent age resister dispersion, whipping temp is room temperature, controls whipping process medium-rate
For 1000r/min, it is 50min to be dispersed with stirring the time, so that age resister molecule is formed suspension system in aqueous solution, then
It adds hydroxyethyl cellulose to be dissolved, then carries out high-speed stirred dispersion, whipping temp is 40 DEG C, and stir speed (S.S.) is
3600r/min, mixing time 15min, then add butane tetracarboxylic acid carry out it is chitosan crosslinked, then under the conditions of 90 DEG C into
Row curing 10min is obtained by filtration thick modified capsule, then after 60 DEG C are dried in vacuo for 24 hours, obtains changing containing age resister
Property capsule；Its sandwich layer is age resister, and cystoblast is hydroxyethylcellulose materials, wherein the thickness of cystoblast and sandwich layer ratio is 1: 18；
By manufactured age resister microcapsules 3%（owf）, penetrating agent JFC 2g/l, pH value 7 is made into age resister dressing liquid；
The volume ratio of water and ethyl alcohol in the mixed solution of the water and ethyl alcohol is 1: 2；The lithium aluminium hydride reduction and 2- naphthylamines
Molar ratio be 2: 1.5；The molar ratio 2: 2.2: 1.1 of the functional modifier crude product, hydrofluoric acid and concentrated nitric acid.
The age resister additive amount is 3.5% relative to the mass fraction of water；
The hydroxyethyl cellulose additive amount is 2.0% relative to the mass fraction of water；
The weight average molecular weight of the hydroxyethyl cellulose is 20000, molar substitution 1.8.
The butane tetracarboxylic acid is 0.3% relative to the mass fraction of chitosan.
A diameter of 2 μm of modified capsule, are conducive to capsule and pass through spinneret orifice, and ensure capsule and fiber
It is firmly combined with, the mechanical performance of fiber can't be influenced.
The capsule of modified capsule/core ensures that microcapsules have certain mechanical strength and heat-resisting than being generally higher than equal to 1: 10
Property.
3）Anti-aging arrangement is carried out to nylon elastic material strips with the dressing liquid prepared.
Nylon elastic material strips are put into age resister dressing liquid and are impregnated, bath raio 1:30 points are impregnated at 20,50 DEG C
Clock, washing drying；Then the band arranged by age resister is pressed 1 with fixed liquid:20 bath raio immerses in fixed liquid, under room temperature
Completely after infiltration, two leachings two are rolled, pick-up 90%, and in 80 DEG C of drying, 140 DEG C bake 2 minutes, through washing, soaping, dry；Institute
The composition for stating fixed liquid includes glyoxal, magnesium chloride, tartaric acid and water, and a concentration of 40% glyoxal content in every liter of water is
50g, magnesium chloride content in every liter of water are 5g, and tartaric acid content in every liter of water is 3g, the mixing stirred evenly at room temperature
Liquid.
It is material strips made of cellulose fibre by another layer of resilient material made of nylon fiber, passes through between two layers
High polymer elastic layer is combined；Every layer is all made of warp-wise elastic webbing and broadwise elastic webbing, the warp-wise elastic webbing and latitude
It is diamond shape to the gap between elastic webbing；The gap is 15 square millimeters；Spacing between the warp-wise elastic webbing is 5
Millimeter；Spacing between the broadwise elastic webbing is 4 millimeters；The high polymer elastic layer is using high polymer elastic material
Matter, including silica gel.
Elastic trampoline cloth is used for trampoline.
Comparative example 1
Capsule will be modified and polypropylene particles carry out melt spinning, modified polypropene silk is obtained, then again by modified polypropene silk
It is woven into yarn, elastic trampoline cloth is made by yarn；
The mass fraction of modification capsule in the modified polypropene silk is 2%.
The preparation method of modified capsule, the specific steps are：
(a) to the preparation of dihydroxy Pyrogentisinic Acid's base phosphine
Using Phenylphosphine and paraformaldehyde as raw material, using water and isopropyl alcohol mixture as solvent, parent occurs under the action of catalyst
And addition reaction, controlling reaction temperature are 35~50 DEG C, the reaction time is 3~4h；Dihydroxymethyl phenyl phosphine is prepared, then
At 85~95 DEG C, the mixed solution that hydrogen peroxide and the concentrated sulfuric acid is added is strong oxidizer, and 45~60min of oxidation is prepared into
To dihydroxymethyl phenyl phosphine oxide, by the hydroquinol base phosphine of synthesis, bromine water and iron powder are added in reaction vessel, are heated to
Kermesinus product is obtained by filtration after 65~75 DEG C of 0.5~1.75h of reaction, it is added to the hydrogen-oxygen of 0.2mol/L at normal temperatures
Change potassium with ethyl alcohol potassium solution, react 1~3h in 80~95 DEG C after being completely dissolved, then product is recrystallized in steam bath,
In triplicate, obtain white to dihydroxy Pyrogentisinic Acid's base phosphine；
The molar ratio of the Phenylphosphine and paraformaldehyde is 1: 2.1；
Catalyst is vanadic anhydride, and the Phenylphosphine is 1: 0.03 with catalyst molar ratio value；
The volume ratio of the water and isopropanol is 1: 0.75；
The mass fraction of the paraformaldehyde is 10%；
The mass values of the strong oxidizer and Phenylphosphine are 1: 2.5；
The mass fraction of the hydrogen peroxide is 20%；
Hydrogen peroxide and concentrated sulfuric acid volume ratio are 1: 1 in the hydrogen peroxide and concentrated sulfuric acid solution；
The hydroquinol base phosphine, the molar ratio 1: 1.2: 0.01 of bromine water and iron powder；
The molar ratio of the potassium hydroxide and potassium ethoxide is 1: 2.5；
(b) preparation of ortho-nitraniline diazol
Ortho-nitraniline is stirred strongly in the concentrated nitric acid of 12mol/L and is quickly cooled to 0 DEG C, 4mol/L is added after 1.5h
Potassium nitrite aqueous solution filters after reacting 0.5~1.0h at 0~5 DEG C, obtains ortho-nitraniline diazol；
(c) preparation of azo-compound
Dihydroxy Pyrogentisinic Acid's base phosphine is added into the mixed solution of isopropanol and distilled water by prepared by step (a), is kept molten
5~10 DEG C of liquid temperature instills ortho-nitraniline diazol prepared by step (b), filters, washing, dry azo compounds by several times
Object is rediance crystal；
The volume ratio of isopropanol and distilled water in the mixed solution of the isopropanol and distilled water is 1: 0.75；
Described is 4% in the mass fraction of isopropanol and the mixed solution of distilled water to dihydroxy Pyrogentisinic Acid's base phosphine；
The molar ratio to dihydroxy Pyrogentisinic Acid's base phosphine and ortho-nitraniline diazol is 1: 1；
(d) preparation of age resister
Under nitrogen protection, azo-compound prepared by step (c) is added to the water and ethyl alcohol of the sodium hydroxide of 3.0mol/L
Mixed solution in, stir and by several times be added reducing agent lithium aluminium hydride reduction, at 60~65 DEG C react 2h postcoolings to room temperature, add
Enter nitric acid pH to adjust between 5~6, filter, dry in the shade, re-dry after recrystallization obtains functional modifier crude product, then will
Functional modifier crude product, hydrofluoric acid and concentrated nitric acid are added in reaction vessel, after being heated to 65~75 DEG C of 0.5~1.0h of reaction,
Off-white product is obtained by filtration, is filtered through cooling, dries in the shade, recrystallize and dry, obtain age resister；
The volume ratio of water and ethyl alcohol in the mixed solution of the water and ethyl alcohol is 1: 1；
The molar ratio of the lithium aluminium hydride reduction and azo-compound is 1: 0.5；
The molar ratio 1: 1.2: 0.01 of the functional modifier crude product, hydrofluoric acid and concentrated nitric acid；
(e) preparation of modified capsule
Using deionized water as solvent, in a solvent age resister dispersion, whipping temp is room temperature, controls whipping process middling speed
Rate is 800~1200r/min, and it is 30~45min to be dispersed with stirring the time, and age resister molecule is enable to be formed in aqueous solution
Then suspension system adds hydroxyethyl cellulose and is dissolved, then carries out high-speed stirred dispersion, whipping temp is 45~55
DEG C, stir speed (S.S.) is 2000~3300r/min, and mixing time is 20~30min, then adds butane tetracarboxylic acid and carries out shell
Glycan is crosslinked, then carries out curing 30min under the conditions of 65~80 DEG C, thick modified capsule is obtained by filtration, then vacuum is carried out at 60 DEG C
After drying for 24 hours, the modification capsule containing age resister is obtained；Its sandwich layer is age resister, and cystoblast is hydroxyethylcellulose materials,
Wherein, the thickness of cystoblast and sandwich layer ratio is 1: 15.
The age resister additive amount is 3.5% relative to the mass fraction of water；
The hydroxyethyl cellulose additive amount is 2.0% relative to the mass fraction of water；
The weight average molecular weight of the hydroxyethyl cellulose is 20000~25000, and molar substitution is 1.8~1.9.
The butane tetracarboxylic acid is 0.3% relative to the mass fraction of chitosan.
A diameter of 2~5 μm of modified capsule, are conducive to capsule and pass through spinneret orifice, and ensure capsule and fiber
Be firmly combined with, the mechanical performance of fiber can't be influenced.
The capsule of modified capsule/core ensures that microcapsules have certain mechanical strength and heat-resisting than being generally higher than equal to 1: 10
Property.
Elastic trampoline cloth is used for trampoline.
Comparative example 2
Only with the nylon elastic band that age resister is handled, cellulose fibre belt is not contained, i.e., does not use composite construction layer.Its
Remaining step is the same as embodiment 2.
After being bounced 100,1000,10000 times with trampoline, measuring center point recess situation, it can be found that the embodiment of the present application
The apparent resilient material deformations of 1-2 want small, and durability is good.
Table 1
| 100 times（mm） | 1000 times（mm） | 10000 times（mm） | |
| Embodiment 1 | 0 | 0 | 2.9 |
| Embodiment 2 | 0 | 0 | 3.9 |
| Comparative example 1 | 0 | 2 | 56 |
| Comparative example 2 | 0 | 4 | 79 |
Same people is measured in central point and trampoline surrounding jumping height, finds jumping height difference average value embodiment 1-2
It is smaller, illustrate that the application elastic webbing elasticity is balanced.
Table 2
| Difference in height average value（%） | |
| Embodiment 1 | 2.4 |
| Embodiment 2 | 3.6 |
| Comparative example 1 | 6 |
| Comparative example 2 | 9.7 |
Claims (5)
1. a kind of elastic composite cloth, it is characterised in that：The elastic composite cloth is double-layer structure, and one layer fine for nylon
Resilient material made of dimension, another layer are material strips made of cellulose fibre, between two layers by high polymer elastic layer into
Row combines.
2. every layer is all made of warp-wise elastic webbing and broadwise elastic webbing, the sky between the warp-wise elastic webbing and broadwise elastic webbing
Gap is diamond shape.
3. high polymer elastic layer described in includes at least thermoplastic elastomer (TPE) or thermosetting property bullet using high polymer elastic material
Property body.
4. elastic composite cloth as claimed in claim 2, it is characterised in that：Wherein thermoplastic elastomer (TPE) includes thermoplasticity modeling
Material, Polyurethane, polyvinyl chloride；Thermo-setting elastomer includes then silica gel.
5. elastic composite cloth as claimed in claim 2, it is characterised in that：In the mixed solution of the water and ethyl alcohol
Water and ethyl alcohol volume ratio be 1: 2；The lithium aluminium hydride reduction and 3,4- chloro-2-methyl anilines or 2- naphthylamines or amino -3 4-,
The molar ratio of 2- dimethyl azobenzene or 2- amino -4- nitrotoleunes is 2: 1.5；The functional modifier crude product, hydrogen fluorine
The molar ratio 2: 2.2: 1.1 of acid and concentrated nitric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810284174.3A CN108527982A (en) | 2016-08-03 | 2016-08-03 | elastic composite cloth |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610627782.0A CN106283671B (en) | 2016-08-03 | 2016-08-03 | A kind of permanent seal cooling elastic composite |
| CN201810284174.3A CN108527982A (en) | 2016-08-03 | 2016-08-03 | elastic composite cloth |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610627782.0A Division CN106283671B (en) | 2016-08-03 | 2016-08-03 | A kind of permanent seal cooling elastic composite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108527982A true CN108527982A (en) | 2018-09-14 |
Family
ID=57664425
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610627782.0A Active CN106283671B (en) | 2016-08-03 | 2016-08-03 | A kind of permanent seal cooling elastic composite |
| CN201810635536.9A Active CN108909106B (en) | 2016-08-03 | 2016-08-03 | Elastic composite material cloth |
| CN201810284174.3A Withdrawn CN108527982A (en) | 2016-08-03 | 2016-08-03 | elastic composite cloth |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610627782.0A Active CN106283671B (en) | 2016-08-03 | 2016-08-03 | A kind of permanent seal cooling elastic composite |
| CN201810635536.9A Active CN108909106B (en) | 2016-08-03 | 2016-08-03 | Elastic composite material cloth |
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| Country | Link |
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| CN (3) | CN106283671B (en) |
Citations (6)
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|---|---|---|---|---|
| CN101780319A (en) * | 2009-01-17 | 2010-07-21 | 欧洲特拉普蹦床-科特哈克股份有限公司 | Trampoline |
| CN102230256A (en) * | 2011-06-02 | 2011-11-02 | 稳健实业(深圳)有限公司 | Elastic non-woven fabric, production method thereof and elastic product |
| CN203267375U (en) * | 2013-05-27 | 2013-11-06 | 莆田市华峰工贸有限公司 | Elastic net fabric |
| CN103656960A (en) * | 2013-11-07 | 2014-03-26 | 青岛乐谷休闲游乐设备有限公司 | Safe child amusement trampoline |
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| US3485711A (en) * | 1966-06-23 | 1969-12-23 | Du Pont | Low-density web-like cushioning structure of cellular filamentary material |
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| CN1600541A (en) * | 2004-10-12 | 2005-03-30 | 天惠有机硅(深圳)有限公司 | Elastic waterproof cloth, production facility and technique |
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| CN101629015B (en) * | 2009-08-03 | 2012-05-09 | 深圳长园电子材料有限公司 | Polyamide elastomer thermal shrinkable material, polyamide elastomer double-layer material |
| CN202242194U (en) * | 2011-09-22 | 2012-05-30 | 张会媛 | High-performance elastic braided ribbon |
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2016
- 2016-08-03 CN CN201610627782.0A patent/CN106283671B/en active Active
- 2016-08-03 CN CN201810635536.9A patent/CN108909106B/en active Active
- 2016-08-03 CN CN201810284174.3A patent/CN108527982A/en not_active Withdrawn
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Also Published As
| Publication number | Publication date |
|---|---|
| CN106283671A (en) | 2017-01-04 |
| CN108909106B (en) | 2020-05-19 |
| CN106283671B (en) | 2019-02-22 |
| CN108909106A (en) | 2018-11-30 |
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