CN108893614A - A kind of electrolytic cell carbon slag refines the apparatus and method for that electrolyte and aluminium ash utilize - Google Patents

A kind of electrolytic cell carbon slag refines the apparatus and method for that electrolyte and aluminium ash utilize Download PDF

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Publication number
CN108893614A
CN108893614A CN201810621034.0A CN201810621034A CN108893614A CN 108893614 A CN108893614 A CN 108893614A CN 201810621034 A CN201810621034 A CN 201810621034A CN 108893614 A CN108893614 A CN 108893614A
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fixed
electrolyte
furnace body
interior
aluminium ash
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CN108893614B (en
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王会智
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Inner Mongolia Hmhj Aluminum Electricity Co ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/04Working-up slag
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/001Dry processes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

The invention discloses a kind of electrolytic cell carbon slags to refine the equipment that electrolyte and aluminium ash utilize, including pedestal, the upper end quadrangle of the pedestal is respectively and fixedly provided with first support bar, and two first support bars of the same side are one group, the upper end of same group of two first support bars is fixed with electric sliding rail jointly, the upper end of two electric sliding rails is respectively mounted there are two sliding block, the upper end of four sliding blocks is fixed with feeding device jointly, the upper end of the pedestal is fixed with bracket, the upper end of the bracket is fixed with furnace body, and one end of the furnace body is obliquely installed;The invention also provides a kind of electrolytic cell carbon slags to refine the method that electrolyte and aluminium ash utilize.The present invention has reached carbon slag purity by the design to furnace body and has improved, carbon granules recoverable, aluminium recovery is up to absolutely in aluminium ash, and aluminium ash Inner electrolysis matter and aluminium oxide can recycle completely, and a furnace can solve the problems, such as aluminium manufacturer and aluminum fabrication plant generates waste problems and a large amount of raw material of buying.

Description

A kind of electrolytic cell carbon slag refines the apparatus and method for that electrolyte and aluminium ash utilize
Technical field
Electrolyte is refined the present invention relates to electrolytic cell carbon slag and aluminium ash utilizes technical field more particularly to a kind of electrolytic cell carbon Slag refines the apparatus and method for that electrolyte and aluminium ash utilize.
Background technique
Electrolytic aluminium factory electrolytic cell can be due to quality problems in daily production process carbon block, the phenomenon that occurring carbon slag, its meeting Influence the slot condition of electrolytic cell.It must be pulled out and.But carbon slag pulled out itself has inside many holes with a large amount of electrolysis Matter.The electrolyte of recycling is used due to second-rate few people.But annual electrolyte is in great demand.Molten aluminum is from potroom Foundry is drawn, is poured into holding furnace, the impurity of molten aluminum is to draw the electrolyte come out of electrolytic cell.When foundry produces Slagging-off operation is carried out, after deslagging agent is added in surface electrolyte, becomes aluminium ash as rubbish.Handling aluminium ash is major Foundry Works A great problem.Then the intermediate aluminium of normal handling method recycling becomes garbage disposal, some is made into addition water and is made into protection ring, To protect steel pawl.But effect is poor, is not the use of many aluminium manufacturers, and aluminium ash and carbon slag need to handle every year hundreds of thousands even upper nearly hundred Ten thousand tons.The problem of environmental problem is always electrolytic aluminium and aluminium deep processing maximum, most headache.There are two types of methods for processing carbon slag at present; 1, floatation.After electrolyte is removed iron, into fine-powdered in ball milling face, enters back into floatation equipment and carry out flotation.Into flotation fluid Carbon dust lighter in weight is swum in afterwards, and electrolyte density is larger to be sunk in the following, after electrolyte separation, carries out oil removing, dehydration, drying Or it dries.Product purity difference color burnt hair is produced, environmental pollution is big;2, baking.Common anti-projection furnace melts, a lattice in furnace For fuel combustion, a lattice are molten bath.Carbon slag is put into molten bath, fuel generates high temperature and reaches 1200 degree or more, high temperature in burner hearth And heat radiation makes the fusing of carbon slag Inner electrolysis matter flow to molten bath bottom.After when molten bath, Inner electrolysis matter liquid reaches certain height, open Fire door releases high-temperature electrolysis matter.And beat surface scum.Since the electrolyte of bath is mixed with carbon dust, decomposition is not thorough, The electrolyte flowed out from fire door does not separate also just to be solidified quickly, and surface whiteness is preferable, hence it is evident that better than the product of floating washing method.But it generates Penetrating odor is big.Heat utilization rate is low.Carbon granules can also burn, aluminium ash processing method:A, ball mill is milled, aluminium therein Grain becomes smaller aluminium flake under the rolling of steel ball.Again aluminium flake is screened out to come.Become garbage disposal, some progress are in next step:Aluminium ash adds Water wheels grind, are slurried, extrusion forming, drying.Then it is made into annulus again into protection ring protection steel pawl.The disadvantage is that producing kind dust It is larger, penetrating odor is larger when doing protection ring.B, blender heating stirring.Coal dust, carbon is added in the aluminium ash for just having taken off out The pyrogens such as powder make aluminum shot become liquid aluminium outflow at high temperature.But a large amount of aluminium ashes become garbage disposal.It will not recycling benefit With.We devise a kind of electrolytic cell carbon slag and refine the apparatus and method for that electrolyte and aluminium ash utilize to solve above-mentioned ask thus Topic.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of electrolytic cell carbon slag proposed refines The apparatus and method for that electrolyte and aluminium ash utilize.
To achieve the goals above, present invention employs following technical solutions:
A kind of electrolytic cell carbon slag refines the equipment that electrolyte and aluminium ash utilize, including pedestal, the upper end quadrangle of the pedestal are solid Surely there is first support bar, and two first support bars of the same side are one group, the upper end of same group of two first support bars is total With being fixed with electric sliding rail, the upper end of two electric sliding rails is respectively mounted that there are two sliding blocks, and the upper end of four sliding blocks is fixed with jointly Feeding device, the upper end of the pedestal are fixed with bracket, and the upper end of the bracket is fixed with furnace body, one end inclination of the furnace body Setting, described intracorporal one end of furnace, which is equipped with, prepares chamber, and the intracorporal other end of furnace is equipped with combustion chamber, is equipped in the furnace body molten Pond, the molten bath be located at prepares between chamber and combustion chamber, one end side wall in the molten bath be equipped with the first fire door, described first The side of fire door is equipped with the second slideway, is equipped with the first fire door, first fire door and the first fire door on second slideway Corresponding, the bottom side in the molten bath is equipped with discharge port, described prepare intracavitary top and be equipped with feed inlet, the furnace body it is upper End two sides are respectively and fixedly provided with support plate, and the opposite side of two support plates is equipped with third slideway, pacifies jointly in two third slideways Equipped with third fire door, the third fire door and feed inlet are corresponding, and the side of the furnace body is equidistantly set there are three the second fire door, The side of second fire door is equipped with the first slideway, and the upper end of first slideway is equipped with the second fire door, second fire door It is corresponding with the second fire door, it is described to prepare intracavitary bottom equipped with furnace bottom, transition is fixed between the furnace bottom and the second fire door Block, the upper end of the furnace bottom are equidistantly equipped with multiple grooves, and one end of the groove extends on one end side wall in molten bath, institute It states and is fixed with fire bars in the opposing sidewalls in combustion chamber jointly, the wherein side of the furnace body is from top to bottom sequentially installed with combustion gas Combustor and air blower, the gas burner system and air blower are arranged with combustion chamber perforation, and gas burner system is located at fire bars Upper end, the air blower is located at the lower end of fire bars, and the other side of the furnace body, which is run through, is equipped with exhaust pipe, sets on the exhaust pipe There is cooling device, one end of the exhaust pipe is equipped with device for reducing dust, and the other side of the furnace body is equipped with support frame, support frame as described above Upper end be equipped with closing device.
Preferably, the feeding device includes the car body for being fixed on four upper end of slide block, and the upper end side of the car body is solid Surely there is the second guard box, the first driving motor, the upper end of the car body are fixed on one end side wall in second guard box It is fixed that there are two the supporting block that is parallel to each other, the opposite side common rotation of two supporting blocks is connected with the first rotating roller, and described the The output shaft of one driving motor is on the other end side wall in the second guard box and side and the fixation of one of supporting block The second drawstring is wound on one end of the first rotating roller, first rotating roller, second drawstring runs through the upper end of car body And the lower end of car body is extended to, one end of second drawstring is connected with pulley blocks, and one end of the pulley blocks is connected to car body Lower end, the other end of the pulley blocks is connected with charging box, and the upper end of the charging box is equipped with feed opening, the charging box Lower end is equipped with the first opening, and the two sides of first opening are hinged with closure door, and the two sides of the charging box are rotatably connected to oil The piston-rod end of cylinder, the oil cylinder is rotatably connected on the side of closure door.
Preferably, the cooling device includes the cooling box for being fixed on support frame upper end side, and the exhaust pipe is through drop The side of incubator simultaneously extends to the other side, and the side perforation of described cooling box one end is equipped with filler pipe, one end of the filler pipe It is connected with water pump, the side of the water pump is connected with water inlet pipe, and the side in support frame as described above is equipped with circulating box, the water inlet pipe One end extend to the bottom end in circulating box, the other side perforation of described cooling box one end is equipped with outlet pipe, the outlet pipe One end extends in circulating box.
Preferably, the device for reducing dust includes the cyclone dust collectors that exhaust pipe one end is arranged in perforation, the cyclone dust removal The upper end perforation of device is fixed with screen pipe, and the other side in support frame as described above is equipped with water tank with strainer, and one end of the screen pipe is prolonged It extends in water tank with strainer, one end of the screen pipe is fixed with diffuser, and the lower end side of the cyclone dust collectors is equipped with second The side of opening, second opening is hinged with capping.
Preferably, the closing device includes two fixed links for being fixed on support frame mountain end two sides, two fixed links Upper end is fixed with carrier bar jointly, and the side of the carrier bar is fixed with sleeve, and sliding sleeve is connected to link block in the sleeve, institute The side for stating link block is fixed with pull rod, and one end of the pull rod is fixed on the side of third fire door, the bottom in the sleeve It is fixed with spring, one end of the spring is fixed on the other side of link block, and the other side of the carrier bar is fixed with the first guarantor Protecting box is fixed with the second driving motor on one end side wall in first guard box, and the other side of the carrier bar is fixed with Two two rotor plates being parallel to each other, the opposite side common rotation of two rotor plates are connected with the second rotating roller, and described The side of other end side wall and one of rotor plate of the output shaft end of two driving motors in the first guard box is simultaneously solid It is scheduled on one end of the second rotating roller, the first drawstring is wound in second rotating roller, one end of first drawstring, which is run through, holds It carries the other side of bar and the bottom end of sleeve and extends in sleeve, one end of first drawstring is fixed on the another of link block End, the side of the sleeve is fixed, and there are two second support bars, and one end of two second support bars is separately fixed at two fixations The side of bar.
Preferably, the tapered setting of the furnace body.
Preferably, the arc-shaped setting in the upper end of the furnace bottom and furnace body.
Preferably, the exhaust pipe is made of cast steel.
Preferably, the furnace body is successively made of refractory brick, insulating brick and heat-preservation cotton from the inside to the outside.
The invention also provides a kind of electrolytic cell carbon slags to refine the method that electrolyte and aluminium ash utilize, and includes the following steps:
S1 opens air blower and gas burner system to heating in furnace body, or add carbon block, coke and coal powder to furnace in fire bars It is heated in vivo;
S2 will need the electrolytic cell carbon slag processed or aluminium ash to be added in furnace body by the second fire door, or is added by feed opening Into charging box, charging box is moved at feed inlet by pulley blocks, and oil cylinder opens closure door, and electrolytic cell carbon slag or aluminium ash are put into In furnace body;
S3, after carbon slag enters furnace body, first carrying out preheating can be energy saving, then through high-temperature baking, under high temperature action, when carbon slag table After electrolyte outflow in layer or upper layer, electrolysis flows to bath after being changed into trench bottom aggregation of the liquid in furnace bottom, and carbon slag is not Can follow and flows because of electrolyte flow, reduce the output of taking off of carbon slag in molten bath, carbon slag can secondary use or directly after cooling It connects and makees fuel applications with pyrocarbon slag, the electrolyte in molten bath will do it layering in high temperature, and the meeting of the smaller impurity of specific gravity is swum in Surface ensure that the purity of electrolyte;
S4, in the production of aluminium ash, the hot aluminium ash or aluminium ash just produced is put into furnace body, and for aluminium ash under the baking of high temperature, molten aluminum is first Carry out fusing and molten bath entered by groove, secondly, main component is electrolyte, aluminium, aluminium oxide in aluminium ash, also contain deslagging agent and Electrolyte and oxygen reactants, the electrolysis mass-energy dissolved oxygen aluminium of molten condition, aluminium oxide are fusing into molten bath at high temperature, will Aluminium ash is substantially all to be utilized as raw materials recovery, saves consumption reduction;
The gas of S5, generation enter dedusting in cyclone dust collectors after cooling of the exhaust pipe in cold-zone device, the gas after dedusting Body is passed into water tank with strainer through screen pipe, and gas is dispersed into countless small bubbles through diffuser, is increased the contact with water and is handed over Area is changed, enters the pernicious gas in flue gas in water and is filtered, carries out acid-base neutralization when the water of water tank with strainer reaches concentration Reaction and harmless treatment guarantee ultra-clean discharge.
In the present invention, in use, opening air blower and gas burner system to heating in furnace body, or carbon is added in fire bars Block, coke and coal powder are added to heating in furnace body, by the electrolytic cell carbon slag for needing to process or aluminium ash by the second fire door It is added in charging box into furnace body, or through feed opening, electric sliding rail band movable slider is mobile, and car body is moved to charging by sliding block The upper end of mouth, the second driving motor drive the rotation of the second rotating roller, and the second rotating roller drives the first drawstring to shrink, the first drawstring band Dynamic link block slides in sleeve, and link block drives pull rod mobile, and pull rod drives third fire door is mobile to open feed inlet, and first drives Dynamic motor drives the rotation of the first rotating roller, and it is flexible that the first rotating roller drives the second drawstring, thus moved up and down with running block, it is sliding Charging box is moved at feed inlet by wheel group, and oil cylinder opens closure door, electrolytic cell carbon slag or aluminium ash is put into, the second driving motor Out of service, spring, which restores, pushes link block mobile, and link block pushing drawing rod, pull rod pushes third fire door is mobile to block charging Mouthful, the gas of generation enters dedusting in cyclone dust collectors after cooling of the exhaust pipe in cold-zone device, the gas warp after dedusting Screen pipe is passed into water tank with strainer, and gas is dispersed into countless small bubbles through diffuser, increases the contact exchange face with water Product, enters the pernicious gas in flue gas in water and is filtered, and carries out acid-base neutralization reaction when the water of water tank with strainer reaches concentration And harmless treatment, guarantee ultra-clean discharge, the present invention has reached carbon slag purity by the design to furnace body and improved, and carbon granules can return It receives and utilizes, aluminium recovery is up to absolutely in aluminium ash, and aluminium ash Inner electrolysis matter and aluminium oxide can recycle completely, and a furnace can Solve the problems, such as that aluminium manufacturer and aluminum fabrication plant generate waste problems and a large amount of raw material of buying.
Detailed description of the invention
Fig. 1 is the structural representation that a kind of electrolytic cell carbon slag proposed by the present invention refines the equipment that electrolyte and aluminium ash utilize Figure;
Fig. 2 is the top view that a kind of electrolytic cell carbon slag proposed by the present invention refines the equipment that electrolyte and aluminium ash utilize;
Fig. 3 is the fire bars structural representation that a kind of electrolytic cell carbon slag proposed by the present invention refines the equipment that electrolyte and aluminium ash utilize Figure;
Fig. 4 is the molten bath structural representation that a kind of electrolytic cell carbon slag proposed by the present invention refines the equipment that electrolyte and aluminium ash utilize Figure;
Fig. 5 is that a kind of electrolytic cell carbon slag proposed by the present invention refines schematic enlarged-scale view at the B for the equipment that electrolyte and aluminium ash utilize;
Fig. 6 is that a kind of electrolytic cell carbon slag proposed by the present invention refines schematic enlarged-scale view at the A for the equipment that electrolyte and aluminium ash utilize.
In figure:1 pedestal, 2 air blowers, 3 gas burner systems, 4 first fire doors, 5 first support bars, 6 first slideways, 7 furnace bodies, 8 second fire doors, 9 feed inlets, 10 support plates, 11 electric sliding rails, 12 screen pipes, 13 support frames, 14 water tank with strainer, 15 diffusers, 16 cappings, 17 circulating boxes, 18 brackets, 19 discharge ports, 20 second slideways, 21 first fire doors, 22 second fire doors, 23 pull rods, 24 connect Connect block, 25 first drawstrings, 26 third slideways, 27 third fire doors, 28 water inlet pipes, 29 springs, 30 sleeves, 31 fixed links, 32 first Guard box, 33 water pumps, 34 outlet pipes, 35 cooling box, 36 cyclone dust collectors, 37 exhaust pipes, 38 rotor plates, 39 carrier bars, 40 furnaces Bottom, 41 molten baths, 42 grooves, 43 transition blocks, 44 fire bars, 45 oil cylinders, 46 closure doors, 47 feed openings, 48 pulley blocks, 49 second drawstrings, 50 second guard boxs, 51 first driving motors, 52 supporting blocks, 53 first rotating rollers, 54 second support bars, 55 car bodies, 56 sliding blocks, 57 charging boxs.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.
Referring to Fig.1-6, a kind of electrolytic cell carbon slag refines the equipment that electrolyte and aluminium ash utilize, including pedestal 1, pedestal 1 Upper end quadrangle is respectively and fixedly provided with first support bar 5, supports feeding device, convenient to feed from the top of furnace body 7, and two of the same side First support bar 5 is one group, and the upper end of same group of two first support bars 5 is fixed with electric sliding rail 11 jointly, facilitates car body 55 movement, the upper end of two electric sliding rails 11 are respectively mounted there are two sliding block 56, and the upper end of four sliding blocks 56 is fixed with jointly to be added Expect device, the upper end of pedestal 1 is fixed with bracket 18, supports furnace body 7, the upper end of bracket 18 is fixed with furnace body 7, one end of furnace body 7 It is obliquely installed, is flowed into molten bath 41 convenient for the liquid of fusing, one end in furnace body 7 is equipped with and prepares chamber, the other end in furnace body 7 Equipped with combustion chamber, can using the materials such as carbon block, coke, natural gas, liquefied gas, water-gas, fuel oil, coal powder to furnace body 7 into Row heating, is easy to use, and molten bath 41 is equipped in furnace body 7, and molten bath 41, which is located at, to be prepared between chamber and combustion chamber, one end in molten bath 41 Side wall is equipped with the first fire door 21, and use when skimming to molten bath 41, the side of the first fire door 21 is equipped with the second slideway 20, convenient to beat It opens, the first fire door 4 is installed, the first fire door 4 and the first fire door 21 are corresponding, the bottom side in molten bath 41 on second slideway 20 Equipped with discharge port 19, the material prepared is taken out, prepares intracavitary top equipped with feed inlet 9, the upper end two sides of furnace body 7 are fixed There is support plate 10, the opposite side of two support plates 10 is equipped with third slideway 26, is equipped with jointly in two third slideways 26 Third fire door 27, is easy to open, and third fire door 27 and feed inlet 9 are corresponding, and the side of furnace body 7 is equidistantly set there are three the second furnace The side of mouth 22, the second fire door 22 is equipped with the first slideway 6, and the upper end of the first slideway 6 is equipped with the second fire door 8,8 He of the second fire door Second fire door 22 is corresponding, prepares intracavitary bottom equipped with furnace bottom 40, is fixed with transition block between furnace bottom 40 and the second fire door 22 43, furnace bottom 7 is than the low 100-300mm of the second fire door 22, and convenient for skimming, the upper end of furnace bottom 40 is equidistantly equipped with multiple transition block 43 Groove 42 flows into molten bath 41 convenient for 42 bottom of liquid runs down groove of fusing, and one end of groove 42 extends in molten bath 41 On the side wall of one end, fire bars 44 is fixed in the opposing sidewalls in combustion chamber jointly, carbon block, coke and coal are added in fire bars 44 For powder to heating in furnace body 7, the wherein side of furnace body 7 is from top to bottom sequentially installed with gas burner system 3 and air blower 2, combustion Gas combustor 3 and air blower 2 are arranged with combustion chamber perforation, and gas burner system 3 is located at the upper end of fire bars 44, and air blower 2 In the lower end of fire bars 44, heat is sent into furnace body 7, the other side of furnace body 7, which is run through, is equipped with exhaust pipe 37, and exhaust pipe 37 is equipped with Cooling device cools down the gas of high temperature, and one end of exhaust pipe 37 is equipped with device for reducing dust, to the dust of output in furnace body 7 Depositing dust processing is carried out, the other side of furnace body 7 is equipped with support frame 13, and the upper end of support frame 13 is equipped with closing device.
In the present invention, feeding device includes the car body 55 for being fixed on four 56 upper ends of sliding block, and the upper end side of car body 55 is solid Surely there is the second guard box 50, protect the first driving motor 51, be fixed with the first driving on one end side wall in the second guard box 50 Motor 51, the upper end of car body 55 is fixed, and there are two the supporting block 52 that is parallel to each other, the opposite side common rotations of two supporting blocks 52 It is connected with the first rotating roller 53, the first driving motor 51 drives the rotation of the first rotating roller 53, the output shaft of the first driving motor 51 On the other end side wall in the second guard box 50 and the side of one of supporting block 52 and it is fixed on the first rotating roller 53 One end, be wound with the second drawstring 49 in the first rotating roller 53, the second drawstring 49 through car body 55 upper end and extend to car body 55 lower end, one end of the second drawstring 49 are connected with pulley blocks 48, and pulley blocks 48 are 1/5th province's wheels groups, the first rotating roller 53 drive the second drawstring 49 flexible, to move up and down with running block 48, one end of pulley blocks 48 is connected under car body 55 End, the other end of pulley blocks 48 are connected with charging box 57, and the upper end of charging box 57 is equipped with feed opening 47, the electrolysis that needs are processed Slot carbon slag or aluminium ash are added in furnace body 7 by the second fire door 22, or are added in charging box 57 by feed opening 47, charging box 57 lower end is equipped with the first opening, and the two sides of the first opening are hinged with closure door 46, and the first driving motor 51 drives the first rotating roller 53 rotations, it is flexible that the first rotating roller 53 drives the second drawstring 49, to move up and down with running block 48, pulley blocks 48 will feed Case 57 is moved at feed inlet 9, and oil cylinder 45 opens closure door 46, electrolytic cell carbon slag or aluminium ash is put into, the two sides of charging box 57 It is rotatably connected to oil cylinder 45, the piston-rod end of oil cylinder 45 is rotatably connected on the side of closure door 46, and cooling device includes fixing Cooling box 35 in 13 upper end side of support frame, exhaust pipe 37 run through the side of cooling box 35 and extend to the other side, cooling box The side perforation of 35 one end is equipped with filler pipe, and one end of filler pipe is connected with water pump 33, and the side of water pump 33 is connected with water inlet pipe 28, the side in support frame 13 is equipped with circulating box 17, and one end of water inlet pipe 28 extends to the bottom end in circulating box 17, and water pump 33 makes Water in cooling box 35 is recycled, fast cooling, and the other side perforation of 35 one end of cooling box is equipped with outlet pipe 34, outlet pipe 34 One end extend in circulating box 17, device for reducing dust includes that the cyclone dust collectors 36 of 37 one end of exhaust pipe are arranged in perforation, is had The upper end perforation of good dust removing effects, cyclone dust collectors 36 is fixed with screen pipe 12, and the other side in support frame 13 was equipped with Water filtering tank 14, one end of screen pipe 12 are extended to the in water filtering tank 14, and one end of screen pipe 12 is fixed with diffuser 15, gas warp Diffuser 15 is dispersed into countless small bubbles, increases the contact exchange area with water, the pernicious gas in flue gas is made to enter water In be filtered, carry out acid-base neutralization reaction and harmless treatment when the water of water tank with strainer 14 reaches concentration, guarantee ultra-clean row It puts, the lower end side of cyclone dust collectors 36 is equipped with the second opening, and the side of the second opening is hinged with capping 16, dust is recycled, Closing device includes two fixed links 31 for being fixed on 13 mountain end two sides of support frame, and the upper end of two fixed links 31 is fixed with jointly Carrier bar 39, the side of carrier bar 39 are fixed with sleeve 30, and sliding sleeve is connected to link block 24, the side of link block 24 in sleeve 30 It is fixed with pull rod 23, one end of pull rod 23 is fixed on the side of third fire door 27, and the bottom in sleeve 30 is fixed with spring 29, bullet One end of spring 29 is fixed on the other side of link block 24, and the other side of carrier bar 39 is fixed with the first guard box 32, the first protection The second driving motor is fixed on one end side wall in case 32, the other side of carrier bar 39 is fixed, and there are two two be parallel to each other Rotor plate 38, the opposite side common rotation of two rotor plates 38 are connected with the second rotating roller, the output shaft of the second driving motor The side of other end side wall and one of rotor plate 38 of the end in the first guard box 32 is simultaneously fixed on the second rotating roller One end, the second driving motor drive the second rotating roller rotation, the second rotating roller drive the first drawstring 25 shrink, the second rotating roller On be wound with the first drawstring 25, one end of the first drawstring 25 through the other side of carrier bar 39 and the bottom end of sleeve 30 and extends to In sleeve 30, one end of the first drawstring 25 is fixed on the other end of link block 24, and the first drawstring 25 drives link block 24 in sleeve Sliding in 30, link block 24 drive pull rod 23 mobile, and pull rod 23 drives third fire door 27 is mobile to open feed inlet 9, sleeve 30 Side is fixed, and there are two second support bars 54, and one end of two second support bars 54 is separately fixed at the one of two fixed links 31 Side, Auxiliary support, the tapered setting of furnace body 7 keep temperature in furnace body 7, the upper end of furnace bottom 40 and furnace body 7 to assemble heat Arc-shaped setting, the furnace bottom 40 convenient for the liquid runs down arc of fusing flow into molten bath 41, and exhaust pipe 37 uses cast steel It is made, high temperature resistant, furnace body 7 is successively made of refractory brick, insulating brick and heat-preservation cotton from the inside to the outside, heat-insulation and heat-preservation.
The invention also provides a kind of electrolytic cell carbon slags to refine the method that electrolyte and aluminium ash utilize, and includes the following steps:
S1 opens air blower 2 and gas burner system 3 to heating in furnace body 7, or adds carbon block, coke and coal in fire bars 44 Powder in furnace body 7 to heating;
S2 will need the electrolytic cell carbon slag processed or aluminium ash to be added in furnace body 7 by the second fire door 22, or pass through feed opening 47 It is added in charging box 57, charging box 57 is moved at feed inlet 9 by pulley blocks 48, and oil cylinder 45 opens closure door 46, will be electrolysed Slot carbon slag or aluminium ash are put into furnace body 7;
S3, after carbon slag enters furnace body 7, first carrying out preheating can be energy saving, then through high-temperature baking, under high temperature action, when carbon slag After electrolyte outflow in surface layer or upper layer, electrolysis is changed into liquid and flows to bath after 42 bottom of the groove aggregation in furnace bottom 40 41, carbon slag will not be followed because of electrolyte flow to be flowed, and reduces the output of taking off of carbon slag in molten bath 41, and carbon slag can two after cooling Secondary utilization directly makees fuel applications with pyrocarbon slag, and the electrolyte in molten bath 41 will do it layering in high temperature, and specific gravity is smaller miscellaneous The meeting of matter swims in surface, ensure that the purity of electrolyte;
S4, in the production of aluminium ash, the hot aluminium ash or aluminium ash just produced is put into furnace body 7, aluminium ash is under the baking of high temperature, molten aluminum It first carries out fusing and molten bath 41 is entered by groove 42, secondly, main component is electrolyte, aluminium, aluminium oxide in aluminium ash, also contains and remove Slag agent and electrolyte and oxygen reactants, the electrolysis mass-energy dissolved oxygen aluminium of molten condition, aluminium oxide are fusing at high temperature Aluminium ash is substantially all and utilizes as raw materials recovery by molten bath 41, saves consumption reduction;
The gas of S5, generation enter dedusting in cyclone dust collectors 36 after cooling of the exhaust pipe 37 in cold-zone device, after dedusting Gas through screen pipe 12, be passed into water tank with strainer 14, gas is dispersed into countless small bubbles through diffuser 15, increase with The contact exchange area of water enters the pernicious gas in flue gas in water and is filtered, when the water of water tank with strainer 14 reaches concentration Acid-base neutralization reaction and harmless treatment are carried out, guarantees ultra-clean discharge.
In the present invention, in use, opening air blower 2 and gas burner system 3 to heating in furnace body 7, or add in fire bars 44 Add carbon block, coke and coal powder to heating in furnace body 7, the electrolytic cell carbon slag for needing to process or aluminium ash are passed through into the second fire door 22 are added in furnace body 7, or are added in charging box 57 by feed opening 47, and electric sliding rail 11 is mobile with movable slider 56, sliding block 56 are moved to car body 55 upper end of feed inlet 9, and the second driving motor drives the rotation of the second rotating roller, and the second rotating roller drives the One drawstring 25 is shunk, and the first drawstring 25 drives link block 24 to slide in sleeve 30, and link block 24 drives pull rod 23 mobile, pull rod 23 drive third fire door 27 is mobile to open feed inlet 9, and the first driving motor 51 drives the rotation of the first rotating roller 53, the first rotating roller 53 drive the second drawstring 49 flexible, to move up and down with running block 48, charging box 57 is moved to feed inlet 9 by pulley blocks 48 Closure door 46 is opened, electrolytic cell carbon slag or aluminium ash is put by place, oil cylinder 45, and the second driving motor is out of service, and spring 29 restores Push link block 24 mobile, 24 pushing drawing rod 23 of link block, pull rod 23 pushes third fire door 27 is mobile to block feed inlet 9, generates Gas enter dedusting in cyclone dust collectors 36 after cooling of the exhaust pipe 37 in cold-zone device, the gas after dedusting is through filtering Pipe 12 is passed into water tank with strainer 14, and gas is dispersed into countless small bubbles through diffuser 15, increases the contact exchange with water Area enters the pernicious gas in flue gas in water and is filtered, and carries out acid-base neutralization when the water of water tank with strainer 14 reaches concentration Reaction and harmless treatment guarantee ultra-clean discharge.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (10)

1. a kind of electrolytic cell carbon slag refines the equipment that electrolyte and aluminium ash utilize, including pedestal(1), which is characterized in that the bottom Seat(1)Upper end quadrangle be respectively and fixedly provided with first support bar(5), and two first support bars of the same side(5)It is one group, same group Two first support bars(5)Upper end be fixed with electric sliding rail jointly(11), two electric sliding rails(11)Upper end be respectively mounted There are two sliding blocks(56), four sliding blocks(56)Upper end be fixed with feeding device, the pedestal jointly(1)Upper end be fixed with branch Frame(18), the bracket(18)Upper end be fixed with furnace body(7), the furnace body(7)One end be obliquely installed, the furnace body(7) Interior one end is equipped with and prepares chamber, the furnace body(7)The interior other end is equipped with combustion chamber, the furnace body(7)It is interior to be equipped with molten bath(41), The molten bath(41)Positioned at preparing between chamber and combustion chamber, the molten bath(41)Interior one end side wall is equipped with the first fire door (21), first fire door(21)Side be equipped with the second slideway(20), second slideway(20)On the first furnace is installed Door(4), first fire door(4)With the first fire door(21)It is corresponding, the molten bath(41)Bottom side be equipped with discharge port (19), described to prepare intracavitary top equipped with feed inlet(9), the furnace body(7)Upper end two sides be respectively and fixedly provided with support plate(10), Two support plates(10)Opposite side be equipped with third slideway(26), two third slideways(26)Third furnace is inside installed jointly Door(27), the third fire door(27)And feed inlet(9)It is corresponding, the furnace body(7)Side equidistantly set there are three second Fire door(22), second fire door(22)Side be equipped with the first slideway(6), first slideway(6)Upper end be equipped with Two fire doors(8), second fire door(8)With the second fire door(22)It is corresponding, it is described to prepare intracavitary bottom equipped with furnace bottom(40), The furnace bottom(40)With the second fire door(22)Between be fixed with transition block(43), the furnace bottom(40)Upper end be equidistantly equipped with it is more A groove(42), the groove(42)One end extend to molten bath(41)It is opposite in the combustion chamber on interior one end side wall Fire bars is fixed on side wall jointly(44), the furnace body(7)Wherein side be from top to bottom sequentially installed with gas burner system(3) And air blower(2), the gas burner system(3)And air blower(2)It is arranged with combustion chamber perforation, and gas burner system(3)Position In fire bars(44)Upper end, the air blower(2)Positioned at fire bars(44)Lower end, the furnace body(7)The other side through being equipped with Exhaust pipe(37), the exhaust pipe(37)It is equipped with cooling device, the exhaust pipe(37)One end be equipped with device for reducing dust, it is described Furnace body(7)The other side be equipped with support frame(13), support frame as described above(13)Upper end be equipped with closing device.
2. a kind of electrolytic cell carbon slag according to claim 1 refines the equipment that electrolyte and aluminium ash utilize, which is characterized in that The feeding device includes being fixed on four sliding blocks(56)The car body of upper end(55), the car body(55)Upper end side be fixed with Second guard box(50), second guard box(50)The first driving motor is fixed on interior one end side wall(51), the vehicle Body(55)Fixed there are two the supporting blocks that is parallel to each other for upper end(52), two supporting blocks(52)Opposite side common rotation connection There is the first rotating roller(53), first driving motor(51)Output shaft run through the second guard box(50)Interior other end side wall Upper and one of supporting block(52)Side and be fixed on the first rotating roller(53)One end, first rotating roller(53)On It is wound with the second drawstring(49), second drawstring(49)Through car body(55)Upper end and extend to car body(55)Lower end, Second drawstring(49)One end be connected with pulley blocks(48), the pulley blocks(48)One end be connected to car body(55)Under End, the pulley blocks(48)The other end be connected with charging box(57), the charging box(57)Upper end be equipped with feed opening(47), The charging box(57)Lower end be equipped with first opening, it is described first opening two sides be hinged with closure door(46), the charging box (57)Two sides be rotatably connected to oil cylinder(45), the oil cylinder(45)Piston-rod end be rotatably connected on closure door(46)One Side.
3. a kind of electrolytic cell carbon slag according to claim 1 refines the equipment that electrolyte and aluminium ash utilize, which is characterized in that The cooling device includes being fixed on support frame(13)The cooling box of upper end side(35), the exhaust pipe(37)Through cooling box (35)Side and extend to the other side, the cooling box(35)The side perforation of one end is equipped with filler pipe, the filler pipe One end is connected with water pump(33), the water pump(33)Side be connected with water inlet pipe(28), support frame as described above(13)Interior side Equipped with circulating box(17), the water inlet pipe(28)One end extend to circulating box(17)Interior bottom end, the cooling box(35)One The other side perforation at end is equipped with outlet pipe(34), the outlet pipe(34)One end extend to circulating box(17)It is interior.
4. a kind of electrolytic cell carbon slag according to claim 1 refines the equipment that electrolyte and aluminium ash utilize, which is characterized in that The device for reducing dust includes that perforation is arranged in exhaust pipe(37)The cyclone dust collectors of one end(36), the cyclone dust collectors(36)'s Upper end perforation is fixed with screen pipe(12), support frame as described above(13)The interior other side is equipped with water tank with strainer(14), the screen pipe (12)One end be extended to the over water filtering tank(14)It is interior, the screen pipe(12)One end be fixed with diffuser(15), the whirlwind Deduster(36)Lower end side be equipped with second opening, it is described second opening side be hinged with capping(16).
5. a kind of electrolytic cell carbon slag according to claim 1 refines the equipment that electrolyte and aluminium ash utilize, which is characterized in that The closing device includes being fixed on support frame(13)Two fixed links of mountain end two sides(31), two fixed links(31)Upper end It is fixed with carrier bar jointly(39), the carrier bar(39)Side be fixed with sleeve(30), the sleeve(30)Interior sliding sleeve It is connected to link block(24), the link block(24)Side be fixed with pull rod(23), the pull rod(23)One end be fixed on Three fire doors(27)Side, the sleeve(30)Interior bottom is fixed with spring(29), the spring(29)One end be fixed on Link block(24)The other side, the carrier bar(39)The other side be fixed with the first guard box(32), first guard box (32)The second driving motor, the carrier bar are fixed on interior one end side wall(39)Fixed there are two be parallel to each other for the other side Two rotor plates(38), two rotor plates(38)Opposite side common rotation be connected with the second rotating roller, described second drives The output shaft end of dynamic motor runs through the first guard box(32)Interior other end side wall and one of rotor plate(38)Side And it is fixed on one end of the second rotating roller, the first drawstring is wound in second rotating roller(25), first drawstring(25) One end run through carrier bar(39)The other side and sleeve(30)Bottom end and extend to sleeve(30)It is interior, first drawstring (25)One end be fixed on link block(24)The other end, the sleeve(30)Fixed there are two second support bars for side (54), two second support bars(54)One end be separately fixed at two fixed links(31)Side.
6. a kind of electrolytic cell carbon slag according to claim 1 refines the equipment that electrolyte and aluminium ash utilize, which is characterized in that The furnace body(7)Tapered setting.
7. a kind of electrolytic cell carbon slag according to claim 1 refines the equipment that electrolyte and aluminium ash utilize, which is characterized in that The furnace bottom(40)And furnace body(7)The arc-shaped setting in upper end.
8. a kind of electrolytic cell carbon slag according to claim 1 refines the equipment that electrolyte and aluminium ash utilize, which is characterized in that The exhaust pipe(37)It is made of cast steel.
9. a kind of electrolytic cell carbon slag according to claim 1 refines the equipment that electrolyte and aluminium ash utilize, which is characterized in that The furnace body(7)It is successively made of from the inside to the outside refractory brick, insulating brick and heat-preservation cotton.
10. a kind of electrolytic cell carbon slag refines the method that electrolyte and aluminium ash utilize, which is characterized in that include the following steps:
S1 opens air blower(2)And gas burner system(3)To furnace body(7)Interior heating, or in fire bars(44)Interior addition carbon block, coke Charcoal and coal powder are to furnace body(7)Inside heated;
The electrolytic cell carbon slag for needing to process or aluminium ash are passed through the second fire door by S2(22)It is added to furnace body(7)It is interior, or pass through charging Mouthful(47)It is added to charging box(57)It is interior, pulley blocks(48)By charging box(57)It is moved to feed inlet(9)Place, oil cylinder(45)It will envelope Door(46)It opens, electrolytic cell carbon slag or aluminium ash is put into furnace body(7)In;
S3, carbon slag enter furnace body(7)Afterwards, first carrying out preheating can be energy saving, then works as carbon under high temperature action through high-temperature baking After electrolyte outflow in slag surface layer or upper layer, electrolyte melting is at liquid in furnace bottom(40)In groove(42)It is flowed after the aggregation of bottom To bath(41), carbon slag will not be followed because of electrolyte flow to be flowed, and molten bath is reduced(41)Interior carbon slag takes off output, and carbon slag exists Secondary use or directly it can make fuel applications, molten bath with pyrocarbon slag after cooling(41)Interior electrolyte will do it point in high temperature Layer, the meeting of the smaller impurity of specific gravity swim in surface, ensure that the purity of electrolyte;
S4, in the production of aluminium ash, the hot aluminium ash or aluminium ash just produced is put into furnace body(7)Interior, aluminium ash is under the baking of high temperature, aluminium Liquid first carries out fusing and passes through groove(42)Into molten bath(41), secondly, main component is electrolyte, aluminium, aluminium oxide in aluminium ash, go back Containing deslagging agent and electrolyte and oxygen reactants, the electrolysis mass-energy dissolved oxygen aluminium of molten condition, aluminium oxide are molten at high temperature Change and enters molten bath(41), aluminium ash is substantially all and is utilized as raw materials recovery, consumption reduction is saved;
S5, the gas of generation is through exhaust pipe(37)Cyclone dust collectors are entered after the cooling of cold-zone device(36)Interior dedusting, is removed Gas after dirt is through screen pipe(12), it is passed into water tank with strainer(14)In, gas is through diffuser(15)It is dispersed into countless small gas Bubble, increases the contact exchange area with water, enters the pernicious gas in flue gas in water and be filtered, work as water tank with strainer(14) Water reach concentration and carry out acid-base neutralization reaction and harmless treatment, guarantee ultra-clean discharge.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110195241A (en) * 2019-06-04 2019-09-03 甘肃东兴铝业有限公司 A kind of technique that fluidized bed extracts electrolyte in carbon slag in Aluminium electrolysis
CN114772553A (en) * 2022-04-06 2022-07-22 江苏省化工设计院有限公司 High-temperature purification system for fluoride salt in anode carbon slag

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CN101839631A (en) * 2009-07-21 2010-09-22 中国恩菲工程技术有限公司 Electrothermal copper-smelting slag depleted furnace
CN103831285A (en) * 2014-03-12 2014-06-04 郑州经纬科技实业有限公司 Aluminum electrolyzed waste carbon residue innocent treatment system and method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101839631A (en) * 2009-07-21 2010-09-22 中国恩菲工程技术有限公司 Electrothermal copper-smelting slag depleted furnace
CN103831285A (en) * 2014-03-12 2014-06-04 郑州经纬科技实业有限公司 Aluminum electrolyzed waste carbon residue innocent treatment system and method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110195241A (en) * 2019-06-04 2019-09-03 甘肃东兴铝业有限公司 A kind of technique that fluidized bed extracts electrolyte in carbon slag in Aluminium electrolysis
CN114772553A (en) * 2022-04-06 2022-07-22 江苏省化工设计院有限公司 High-temperature purification system for fluoride salt in anode carbon slag

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