CN108865483A - A kind of laundry sheet and preparation method thereof - Google Patents

A kind of laundry sheet and preparation method thereof Download PDF

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Publication number
CN108865483A
CN108865483A CN201810592664.XA CN201810592664A CN108865483A CN 108865483 A CN108865483 A CN 108865483A CN 201810592664 A CN201810592664 A CN 201810592664A CN 108865483 A CN108865483 A CN 108865483A
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China
Prior art keywords
laundry sheet
factor
mixed liquor
nanosurface
softener
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Pending
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CN201810592664.XA
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Chinese (zh)
Inventor
谭新明
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Guangzhou Xinting Biological Technology Co Ltd
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Guangzhou Xinting Biological Technology Co Ltd
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Priority to CN201810592664.XA priority Critical patent/CN108865483A/en
Publication of CN108865483A publication Critical patent/CN108865483A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0086Laundry tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • C11D3/2013Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/381Microorganisms
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Microbiology (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to cleaning chemical products technical fields more particularly to a kind of laundry sheet and preparation method thereof, include following component according to mass fraction:Nanosurface active matter 15%~16%, potent nanometer goes the stain factor 5%~7%, anionic surfactant 10%~12%, nonionic surfactant 10%~12%, clear water ion sterilizing object 5%~7%, softener 5%~7%, the fragrant atmosphere factor 2.5%~3.5%, anti-mite element 2.5%~3.5% and deionized water 20%~35%, its not only low manufacture cost, environment protection health is harmless, it is not phosphorous, fluorescer, the close neutrality of pH value, mildly, protect both hands, easily rinse, it reduces and uses water, it is more environmentally friendly, it is mould proof, it is mothproof, care health, the antibacterial time is long, and have mould proof, mothproof effect, it can satisfy the demand of people.

Description

A kind of laundry sheet and preparation method thereof
Technical field
The present invention relates to cleaning chemical products technical fields more particularly to a kind of laundry sheet and preparation method thereof.
Background technique
Laundry sheet is a kind of completely new cleaning product, changes the form of previous cleaning product, light is its maximum spy Point, because it does not contain fluorescent whitening agent, the harmful components such as phosphorus, it is one that gradually fashionable European & American Market, which becomes cleaning product of new generation, The neutral synthetic detergent of kind.The quantitative washing that laundry sheet is realized, overcome traditional washing powder, measure in liquid detergent use it is numerous It is trivial, that is, articles for washing has been saved, the environmental protection characteristic of low bubble hyperconcetration has been saved again uses water, it is expected to be promoted at home, with The raising of living standards of the people, requirement of the people to laundry sheet product quality is also higher and higher, and the demand of laundry sheet will Increasing, quality requirement is also higher and higher, active matter is high, it is multi-functional, using simplicity by be laundry sheet development trend.
But not only preparation process is cumbersome for laundry sheet on the market now, required higher cost, clean effect is general, cleaning Clothing afterwards can lose the color of script clothing, after cleaning clothing, it is also necessary to be impregnated, be increased using softeners such as gold spinnings Laundering step, waste water resource are unable to satisfy the demand of people.
Summary of the invention
For the deficiencies in the prior art, the purpose of the invention is to provide a kind of laundry sheet and its preparation sides Method, not only low manufacture cost, environment protection health is harmless, not phosphorous, fluorescer, and pH value is close to neutrality, mildly, protects both hands, pole Easily rinsing, reduce use water, it is more environmentally friendly, it is mould proof, mothproof, care health, the antibacterial time is long, and have effects that it is mould proof, mothproof, can To meet the needs of people.
To achieve the above object, the present invention is achieved by the following technical programs:
A kind of laundry sheet includes following component according to mass fraction:Nanosurface active matter 15%~16%, potent nanometer Go the stain factor 5%~7%, anionic surfactant 10%~12%, nonionic surfactant 10%~12%, clear water from Son sterilizing object 5%~7%, softener 5%~7%, the fragrant atmosphere factor 2.5%~3.5%, anti-mite element 2.5%~3.5% and go from Sub- water 20%~35%.
Further, the Nanosurface active matter is one or more of lauric alcohol or laruyl alcohol.
Further, it is hexadecyltrimethylammonium chloride that the potent nanometer, which goes the stain factor,.
Further, the anionic surfactant is laruyl alcohol.
Further, the nonionic surfactant is one or more of ethylene glycol or propylene glycol.
Further, the softener is ferment or one or more of coconut oil higher alcohol or hydroxymethyl cellulose.
A kind of preparation method of laundry sheet, includes the following steps:
(a), by Nanosurface active matter, potent nanometer removes the stain factor, anionic surfactant, non-ionic surface active Agent, clear water ion sterilizing object, softener, the fragrant atmosphere factor, anti-mite element and deionized water merge obtain mixed liquor in proportion;
(b), three equal parts will be divided into from mixed liquor obtained in step (a), and being sequentially placed into temperature is 90 degree It is stirred evenly in agitated kettle;
(c), after step (b), the temperature of mixed liquor is reduced to 40 degree, is then introduced into temperature and controls 80 The progress mixed liquor dispersion in the pelleter of 30r/s of degree and revolving speed control;
(d), the revolving speed of pelleter is improved to 50r/s, carries out film-making, obtains the coiled strip with a thickness of 80-90mm;
(e), it will be sliced from coiled strip obtained in (d) step by slicer, and obtain laundry sheet.
In conclusion it is an advantage of the invention that:It is instant that water is met by laundry sheet prepared by this preparation method:Cold water hot water is all It can be used, slices use, it is no longer necessary to which measuring cup is followed one's bent without spill and leakage, opens laundry new paragon;Various plants are living Property agent strength combine, detergency promotes 200%, can remove a variety of stains on clothing, allows clothing to keep clean beautiful, clearly Refreshing lasting, enables the real foam of clothes few, easily rinses, and reduces and uses water, saves more money, more environmentally friendly, proves by repetition test, does washing Piece can protect clothing without fading, to increase the number of wearing of clothing, the antibacterial time is longer, and have mould proof, mothproof function Effect, it is not phosphorous, fluorescer is free of, pH value is close to neutrality, mildly, protects both hands.
Specific embodiment
Invention is further described With reference to embodiment:
Embodiment one:
A kind of laundry sheet includes following component according to mass fraction:Nanosurface active matter 15%, potent nanometer go stain because Son 7%, anionic surfactant 12%, nonionic surfactant 12%, clear water ion sterilizing object 5%, softener 7%, The fragrant atmosphere factor 3.5%, anti-mite element 3.5% and deionized water 35%.
Wherein, the Nanosurface active matter is one or more of lauric alcohol or laruyl alcohol.
Wherein, it is hexadecyltrimethylammonium chloride that the potent nanometer, which goes the stain factor,.
Wherein, the anionic surfactant is laruyl alcohol.
Wherein, the nonionic surfactant is one or more of ethylene glycol or propylene glycol.
Wherein, the softener is ferment or one or more of coconut oil higher alcohol or hydroxymethyl cellulose.
A kind of preparation method of laundry sheet, includes the following steps:
(a), by Nanosurface active matter, potent nanometer removes the stain factor, anionic surfactant, non-ionic surface active Agent, clear water ion sterilizing object, softener, the fragrant atmosphere factor, anti-mite element and deionized water merge obtain mixed liquor in proportion;
(b), three equal parts will be divided into from mixed liquor obtained in step (a), and being sequentially placed into temperature is 90 degree It is stirred evenly in agitated kettle;
(c), after step (b), the temperature of mixed liquor is reduced to 40 degree, is then introduced into temperature and controls 80 The progress mixed liquor dispersion in the pelleter of 30r/s of degree and revolving speed control;
(d), the revolving speed of pelleter is improved to 50r/s, carries out film-making, obtains the coiled strip with a thickness of 80-90mm;
(e), it will be sliced from coiled strip obtained in (d) step by slicer, and obtain laundry sheet.
Embodiment two:
A kind of laundry sheet includes following component according to mass fraction:Nanosurface active matter 15.5%, potent nanometer go stain The factor 6.5%, anionic surfactant 11%, nonionic surfactant 12%, clear water ion sterilizing object 7%, softener 7%, the fragrant atmosphere factor 3.5%, anti-mite element 3.5% and deionized water 34%.
Wherein, the Nanosurface active matter is one or more of lauric alcohol or laruyl alcohol.
Wherein, it is hexadecyltrimethylammonium chloride that the potent nanometer, which goes the stain factor,.
Wherein, the anionic surfactant is laruyl alcohol.
Wherein, the nonionic surfactant is one or more of ethylene glycol or propylene glycol.
Wherein, the softener is ferment or one or more of coconut oil higher alcohol or hydroxymethyl cellulose.
A kind of preparation method of laundry sheet, includes the following steps:
(a), by Nanosurface active matter, potent nanometer removes the stain factor, anionic surfactant, non-ionic surface active Agent, clear water ion sterilizing object, softener, the fragrant atmosphere factor, anti-mite element and deionized water merge obtain mixed liquor in proportion;
(b), three equal parts will be divided into from mixed liquor obtained in step (a), and being sequentially placed into temperature is 90 degree It is stirred evenly in agitated kettle;
(c), after step (b), the temperature of mixed liquor is reduced to 40 degree, is then introduced into temperature and controls 80 The progress mixed liquor dispersion in the pelleter of 30r/s of degree and revolving speed control;
(d), the revolving speed of pelleter is improved to 50r/s, carries out film-making, obtains the coiled strip with a thickness of 80-90mm;
(e), it will be sliced from coiled strip obtained in (d) step by slicer, and obtain laundry sheet.
Embodiment three:
A kind of laundry sheet includes following component according to mass fraction:Nanosurface active matter 16%, potent nanometer go stain because Son 5%, anionic surfactant 12%, nonionic surfactant 12%, clear water ion sterilizing object 6%, softener 7%, The fragrant atmosphere factor 3.5%, anti-mite element 3.5% and deionized water 35%.
Wherein, the Nanosurface active matter is one or more of lauric alcohol or laruyl alcohol.
Wherein, it is hexadecyltrimethylammonium chloride that the potent nanometer, which goes the stain factor,.
Wherein, the anionic surfactant is laruyl alcohol.
Wherein, the nonionic surfactant is one or more of ethylene glycol or propylene glycol.
Wherein, the softener is ferment or one or more of coconut oil higher alcohol or hydroxymethyl cellulose.
A kind of preparation method of laundry sheet, includes the following steps:
(a), by Nanosurface active matter, potent nanometer removes the stain factor, anionic surfactant, non-ionic surface active Agent, clear water ion sterilizing object, softener, the fragrant atmosphere factor, anti-mite element and deionized water merge obtain mixed liquor in proportion;
(b), three equal parts will be divided into from mixed liquor obtained in step (a), and being sequentially placed into temperature is 90 degree It is stirred evenly in agitated kettle;
(c), after step (b), the temperature of mixed liquor is reduced to 40 degree, is then introduced into temperature and controls 80 The progress mixed liquor dispersion in the pelleter of 30r/s of degree and revolving speed control;
(d), the revolving speed of pelleter is improved to 50r/s, carries out film-making, obtains the coiled strip with a thickness of 80-90mm;
(e), it will be sliced from coiled strip obtained in (d) step by slicer, and obtain laundry sheet.
In conclusion this product is formulated by a variety of high effective surface active plant enzymes, formed using newest nanosecond science and technology Superconcentrated washing piece, the liquid detergent for being up to 80% with the heavy sack washing powder easily spread or water content from this are said goodbye, and water is met It is instant:Cold water hot water all can be used, and slices use, it is no longer necessary to which measuring cup is followed one's bent without spill and leakage, and it is new to open laundry Mode;
It is cleaner:Laundry sheet contains various plants activating agent, and by dissolubility decontamination, energy deeper cleans clothing, gives you Different cleaning;
It is small in size:Volume only has the 1/5 of other articless for washing, and transportation cost is greatly decreased, and it is extremely convenient to carry, not duty Between, go on business, travel with;
It is easy to store:Solid shaped product, storage is more convenient, agglomerates without having to worry about washing powder, liquid detergent low temperature is at paste etc. Problem;
Various plants activating agent adds natural pomelo antibacterial:Clean cloud plant enzyme laundry sheet uses the additional day of various plants composition Right shaddock is antibacterial, not only carries out dissolubility decontamination by plant promoting agent, the fungi eliminated on clothes also can be effectively suppressed, really The healthy living of consumer is responsible for, completely new washing formula, care of laundry items keeps clothing submissiveer, economic benefits and social benefits unification.
For those skilled in the art, it is various corresponding that other can be made according to above technical scheme and design Change and deformation, and all these change and modification all should belong within the scope of protection of the claims of the present invention.

Claims (7)

1. a kind of laundry sheet, which is characterized in that according to mass fraction include following component:Nanosurface active matter 15%~ 16%, potent nanometer removes the stain factor 5%~7%, anionic surfactant 10%~12%, nonionic surfactant 10% ~12%, clear water ion sterilizing object 5%~7%, softener 5%~7%, the fragrant atmosphere factor 2.5%~3.5%, anti-mite element 2.5% ~3.5% and deionized water 20%~35%.
2. a kind of laundry sheet according to claim 1, which is characterized in that the Nanosurface active matter is lauric alcohol or the moon One or more of cinnamic alcohol.
3. a kind of laundry sheet according to claim 1, which is characterized in that it is cetyl that the potent nanometer, which goes the stain factor, Trimethyl ammonium chloride.
4. a kind of laundry sheet according to claim 1, which is characterized in that the anionic surfactant is laruyl alcohol.
5. a kind of laundry sheet according to claim 1, which is characterized in that the nonionic surfactant be ethylene glycol or One or more of propylene glycol.
6. a kind of laundry sheet according to claim 1, which is characterized in that the softener is ferment or coconut oil higher alcohol Or one or more of hydroxymethyl cellulose.
7. a kind of preparation method of laundry sheet, which is characterized in that include the following steps:
(a), by Nanosurface active matter, potent nanometer goes the stain factor, anionic surfactant, nonionic surfactant, Clear water ion sterilizing object, softener, the fragrant atmosphere factor, anti-mite element and deionized water merge obtain mixed liquor in proportion;
(b), three equal parts will be divided into from mixed liquor obtained in step (a), and be sequentially placed into the stirring that temperature is 90 degree It is stirred evenly in pot;
(c), after step (b), the temperature of mixed liquor is reduced to 40 degree, be then introduced into temperature control at 80 degree and Revolving speed control carries out mixed liquor dispersion in the pelleter of 30r/s;
(d), the revolving speed of pelleter is improved to 50r/s, carries out film-making, obtains the coiled strip with a thickness of 80-90mm;
(e), it will be sliced from coiled strip obtained in (d) step by slicer, and obtain laundry sheet.
CN201810592664.XA 2018-06-11 2018-06-11 A kind of laundry sheet and preparation method thereof Pending CN108865483A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201810592664.XA CN108865483A (en) 2018-06-11 2018-06-11 A kind of laundry sheet and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108865483A true CN108865483A (en) 2018-11-23

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1268558A (en) * 1999-03-24 2000-10-04 尹小林 Multifunctional disposable cleaning film
CN1524938A (en) * 2003-09-16 2004-09-01 刘仁豪 Method of preparing cleanser
CN105462733A (en) * 2016-01-29 2016-04-06 王君美 Clothes washing pieces and preparation method thereof
CN105886145A (en) * 2016-06-01 2016-08-24 茗燕生物科技(上海)有限公司 Super-concentrated washing piece and preparation method thereof
CN106010820A (en) * 2016-06-01 2016-10-12 茗燕生物科技(上海)有限公司 Plant enzyme environment-friendly laundry detergent sheet and preparation method thereof
CN106190675A (en) * 2016-07-14 2016-12-07 湖北立天生物工程有限公司 A kind of antibacterial repellent acarid laundry sheet and preparation method thereof
CN106811329A (en) * 2016-12-08 2017-06-09 江苏金太阳纺织科技股份有限公司 A kind of laundry sheet of antibiosis anti-acarien and preparation method thereof
CN107057899A (en) * 2017-06-06 2017-08-18 济南雅诗生物科技有限公司 A kind of instant, Quan Rong, superelevation concentrated fabric wash the preparation method of film
CN107177429A (en) * 2016-03-11 2017-09-19 华北制药秦皇岛有限公司 It is a kind of be easy to carry, laundry sheet easy to use and its preparation technology
CN107723132A (en) * 2017-10-26 2018-02-23 诺圆环保科技(苏州)有限公司 A kind of lustration type laundry sheet

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1268558A (en) * 1999-03-24 2000-10-04 尹小林 Multifunctional disposable cleaning film
CN1524938A (en) * 2003-09-16 2004-09-01 刘仁豪 Method of preparing cleanser
CN105462733A (en) * 2016-01-29 2016-04-06 王君美 Clothes washing pieces and preparation method thereof
CN107177429A (en) * 2016-03-11 2017-09-19 华北制药秦皇岛有限公司 It is a kind of be easy to carry, laundry sheet easy to use and its preparation technology
CN105886145A (en) * 2016-06-01 2016-08-24 茗燕生物科技(上海)有限公司 Super-concentrated washing piece and preparation method thereof
CN106010820A (en) * 2016-06-01 2016-10-12 茗燕生物科技(上海)有限公司 Plant enzyme environment-friendly laundry detergent sheet and preparation method thereof
CN106190675A (en) * 2016-07-14 2016-12-07 湖北立天生物工程有限公司 A kind of antibacterial repellent acarid laundry sheet and preparation method thereof
CN106811329A (en) * 2016-12-08 2017-06-09 江苏金太阳纺织科技股份有限公司 A kind of laundry sheet of antibiosis anti-acarien and preparation method thereof
CN107057899A (en) * 2017-06-06 2017-08-18 济南雅诗生物科技有限公司 A kind of instant, Quan Rong, superelevation concentrated fabric wash the preparation method of film
CN107723132A (en) * 2017-10-26 2018-02-23 诺圆环保科技(苏州)有限公司 A kind of lustration type laundry sheet

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* Cited by examiner, † Cited by third party
Title
洁云洗衣片: "什么是洁云植物酵素洗衣片", 《HTTP://BLOG.SINA.COM.CN/S/BLOG_15C6940D60102WFDN.HTML》 *

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Application publication date: 20181123