CN108865463A - A kind of room temperature glue cleaning agent and preparation method thereof - Google Patents

A kind of room temperature glue cleaning agent and preparation method thereof Download PDF

Info

Publication number
CN108865463A
CN108865463A CN201810920882.1A CN201810920882A CN108865463A CN 108865463 A CN108865463 A CN 108865463A CN 201810920882 A CN201810920882 A CN 201810920882A CN 108865463 A CN108865463 A CN 108865463A
Authority
CN
China
Prior art keywords
room temperature
cleaning agent
glue
methylene chloride
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810920882.1A
Other languages
Chinese (zh)
Inventor
周祖新
王爱民
何卫平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Institute of Technology
Original Assignee
Shanghai Institute of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Institute of Technology filed Critical Shanghai Institute of Technology
Priority to CN201810920882.1A priority Critical patent/CN108865463A/en
Publication of CN108865463A publication Critical patent/CN108865463A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • C11D3/181Hydrocarbons linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • C11D3/182Hydrocarbons branched
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/24Organic compounds containing halogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • C23G5/028Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of room temperature glue cleaning agents and preparation method thereof.Room temperature glue cleaning agent of the invention is grouped as by the group of following percent by weight:Methylene chloride 65~75%, ethylene glycol monobutyl ether, 12.5~20.0%, methanol, 6.5~10.5%, No. 120 solvent naphthas, 2.5~5.5%, phenylpropyl triazole, 0.25~0.45%, paraffin, 0.75~1.5%, neopelex 0.15~0.35%.The present invention is using methylene chloride as primary solvent, and ethylene glycol monobutyl ether, methanol and No. 120 solvent naphthas are cosolvent, and using neopelex as anionic surfactant, paraffin is bleeding agent;After it is sprayed onto glue film surface, part glue film is dissolved rapidly in film surface with primary solvent and other cosolvents, paraffin liquid penetrates into film rapidly, after evaporation of the solvent solidification rapidly, glue membrane and original surface isolation, so that virgin rubber moisture film is easy to remove.

Description

A kind of room temperature glue cleaning agent and preparation method thereof
Technical field
The invention belongs to chemical technology fields more particularly to a kind of room temperature glue cleaning agent and preparation method thereof.
Background technique
It is several below glue cleaning method (mainly 502 glue) currently used in the market:
1. being struck off with hard object, such as sharp blade.The disadvantage is that complicated surface or inner surface is difficult to strike off, surface has trace Mark damages surface.
2. dissolving glue with hot solvent (such as hot water).The equally complicated surface of disadvantage or inner surface are difficult except glue, in nothing The place of heating condition can not implement.
3. being dissolved with the strong solvents such as dimethylbenzene, acetone.The disadvantage is that solvent environmental burden is big, and if too late after glue dissolution When remove, be sticked to surface again after solvent volatilization.
Summary of the invention
For above-mentioned technical problem in the prior art, the present invention provides a kind of room temperature glue cleaning agent and its preparation sides Method.Preparation method of the present invention is simple, and glue cleaning agent obtained can realize quick, the complete cleaning of glue at normal temperature.
In the present invention, using methylene chloride as primary solvent, ethylene glycol monobutyl ether, methanol, No. 120 solvent naphthas are used as and help Solvent, neopelex is as anionic surfactant, and paraffin is as bleeding agent.The product is sprayed onto glue film surface Afterwards, part glue film is dissolved rapidly in film surface with methylene chloride solvent as main component and other cosolvents, paraffin liquid is fast Speed penetrates into film, after evaporation of the solvent solidification rapidly, and glue membrane and original surface isolation, virgin rubber moisture film is easy to remove at this time, It is easy to film be opened removing with hand or wipes de- tear off with soft cloth.
Technical solution of the present invention is specifically described as follows.
The present invention provides a kind of room temperature glue cleaning agent, consists of the following components in percentage by weight:
In the present invention, consist of the following components in percentage by weight:
The present invention also provides a kind of preparation methods of above-mentioned room temperature glue cleaning agent, and specific step is as follows:
(1) methanol, part methylene chloride, No. 120 solvent naphthas, phenylpropyl triazole and neopelex are mixed and is stirred Dissolution is mixed, as A ingredient;
(2) heating paraffin is melted, another part methylene chloride is added, be heated to reflux down and add ethylene glycol monobutyl ether work For B component;
(3) A ingredient and B component are uniformly mixing to obtain finished product.
Compared to the prior art, the invention has the advantages that:
Using methylene chloride, No. 120 solvent naphthas and methanol mixed solution and auxiliary material as A ingredient, heating paraffin is melted It is added methylene chloride afterwards as B component, composition one stablizes paraffin solution after A ingredient and B component mixing, due to containing a large amount of two Chloromethanes and ethylene glycol monobutyl ether, the liquid can rapidly permeate into glue layer, and as solvent evaporates, paraffin is precipitated, and keep glue layer de- It is removed from metal surface.
While glue cleaning agent of the invention can realize Rapid Cleaning (2.5~3.5h) of glue, complex surface cleaning Glue performance excellent effect, cleaning effect are good.
Specific embodiment
Specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art It can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as in this hair All by the protection of Patent Law in bright scope of the claims.
Examples 1 to 3
A kind of room temperature glue cleaning agent, by the material composition of following weight percent:Methylene chloride, ethylene glycol monobutyl ether, Methanol, No. 120 solvent naphthas, phenylpropyl triazole, paraffin and neopelex, by weight percentage such as the following table 1.
Room temperature glue cleaning agent preparation method is as follows:By methanol, part methylene chloride, No. 120 solvent naphthas, three nitrogen of phenylpropyl alcohol Azoles, neopelex are placed on stirring and dissolving in a container, and as A ingredient, heating paraffin is melted, and another part is added Methylene chloride is heated to reflux down and adds ethylene glycol monobutyl ether as B component, A ingredient is added, finished product is uniformly mixing to obtain.
Comparative example 1
A kind of room temperature glue cleaning agent, by the material composition of following weight percent:Methylene chloride, ethylene glycol monobutyl ether, Methanol, No. 120 solvent naphthas, phenylpropyl triazole and neopelex, by weight percentage such as the following table 1.
Glue cleaning agent preparation method is as follows:By methanol, part methylene chloride, No. 120 solvent naphthas, phenylpropyl triazole, ten Dialkyl benzene sulfonic acids sodium is placed on stirring and dissolving in a container, as A ingredient, by another part methylene chloride and ethylene glycol monobutyl ether It is heated to reflux as B component, A ingredient is added, finished product is uniformly mixing to obtain.
Comparative example 2
A kind of glue cleaning agent, by the material composition of following weight percent:Methylene chloride, methanol, No. 120 solvent naphthas, Phenylpropyl triazole, paraffin and neopelex, by weight percentage such as the following table 1.
Glue cleaning agent preparation method is as follows:By methanol, part methylene chloride, No. 120 solvent naphthas, phenylpropyl triazole, ten Dialkyl benzene sulfonic acids sodium is placed on stirring and dissolving in a container, and as A ingredient, heating paraffin is melted, and another part dichloro is added A ingredient is added as B component, is uniformly mixing to obtain finished product by methane.
Comparative example 3
A kind of glue cleaning agent, by the material composition of following weight percent:Methylene chloride, ethylene glycol monobutyl ether, No. 120 Solvent naphtha, phenylpropyl triazole, paraffin and neopelex SDBS, by weight percentage such as the following table 1.
Glue cleaning agent preparation method is as follows:By part methylene chloride, No. 120 solvent naphthas, phenylpropyl triazole, dodecyls Benzene sulfonic acid sodium salt is placed on stirring and dissolving in a container, and as A ingredient, heating paraffin is melted, and another part methylene chloride is added, adds Ethylene glycol monobutyl ether is added as B component under heat reflux, and A ingredient is added, finished product is uniformly mixing to obtain.
Using glue cleaning agent carry out can striping time test, the results are shown in Table 1;Note:The striping time it can refer to glue Film surface uniformly sprays cleaning agent (just there is moist feeling on surface when spray) to film and softens, can be easy to tear the required time off.
1 content of table and can the striping time

Claims (3)

1. a kind of room temperature glue cleaning agent, which is characterized in that it is consisted of the following components in percentage by weight:
The above total weight meets 100%.
2. room temperature glue cleaning agent as described in claim 1, which is characterized in that it is by following components in percentage by weight group At:
The above total weight meets 100%.
3. a kind of preparation method of room temperature glue cleaning agent as described in claim 1, which is characterized in that specific step is as follows:
(1) methanol, part methylene chloride, No. 120 solvent naphthas, phenylpropyl triazole and neopelex are mixed molten Solution, as A ingredient;
(2) heating paraffin is melted, another part methylene chloride is added, is heated to reflux down and adds ethylene glycol monobutyl ether as B Ingredient;
(3) A ingredient and B component are uniformly mixing to obtain finished product.
CN201810920882.1A 2018-08-14 2018-08-14 A kind of room temperature glue cleaning agent and preparation method thereof Pending CN108865463A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810920882.1A CN108865463A (en) 2018-08-14 2018-08-14 A kind of room temperature glue cleaning agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810920882.1A CN108865463A (en) 2018-08-14 2018-08-14 A kind of room temperature glue cleaning agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108865463A true CN108865463A (en) 2018-11-23

Family

ID=64317653

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810920882.1A Pending CN108865463A (en) 2018-08-14 2018-08-14 A kind of room temperature glue cleaning agent and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108865463A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110204949A (en) * 2019-06-21 2019-09-06 佛山市高明德健五金有限公司 A kind of metal surface pressure sensitive membrane remover and preparation method thereof
CN110257176A (en) * 2019-07-30 2019-09-20 锦州众尔泰实业有限公司 A kind of silicon material degumming cleaning agent
CN112143587A (en) * 2020-09-24 2020-12-29 苏州友祺电子科技有限公司 Cleaning agent for cleaning glue on surface of steel mesh and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445770A (en) * 2008-12-26 2009-06-03 中国人民解放军第五七一九工厂 Degumming agent composition for elimination of high temperature-resistant organic silicon sealant

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445770A (en) * 2008-12-26 2009-06-03 中国人民解放军第五七一九工厂 Degumming agent composition for elimination of high temperature-resistant organic silicon sealant

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
陈三斌: "《300种实用化工产品配方与制造》", 30 June 2006, 北京:金盾出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110204949A (en) * 2019-06-21 2019-09-06 佛山市高明德健五金有限公司 A kind of metal surface pressure sensitive membrane remover and preparation method thereof
CN110257176A (en) * 2019-07-30 2019-09-20 锦州众尔泰实业有限公司 A kind of silicon material degumming cleaning agent
CN112143587A (en) * 2020-09-24 2020-12-29 苏州友祺电子科技有限公司 Cleaning agent for cleaning glue on surface of steel mesh and preparation method thereof

Similar Documents

Publication Publication Date Title
CN108865463A (en) A kind of room temperature glue cleaning agent and preparation method thereof
CN109722672A (en) Water base adhesive remover
WO1995010570A1 (en) Improved paint stripper
CN101649140A (en) Water -emulsifiable nitrolacquer and preparation method thereof
BR102014020428A2 (en) transparent / semi-transparent colored dispersion, process for preparing the same
CN107286727A (en) A kind of watery paint remover and preparation method thereof
US7959767B2 (en) Dimethyl sulfoxide formulation in mixture with additive for lowering the crystallization point of same, and applications of said mixture
TWI718681B (en) Aqueous printing ink composition for gravure printing and manufacturing method thereof
CN104726238A (en) Adhesive sticker cleaning agent
CA2679133A1 (en) A method of applying a non-voc coating
EP0729496A1 (en) Aqueous anti-slip agent
CN101792621B (en) Preparation method of non-corrosive metal paint remover
US20160053203A1 (en) Synergistic mixed solvents-based compositions for removal of paint, varnish and stain coatings
CN107868729B (en) Degumming composition and preparation method and application thereof
CN106019863A (en) Photo-resistant stripping liquid for advanced-generation flat plate copper process
CN110229554A (en) Alkali environment-friendly paint stripper and its application method
WO1992013026A1 (en) Surface coating and method for applying same
JPS63199784A (en) Method of peeling adhesive sheet
JPS63213580A (en) Film-releasing agent
JP2742585B2 (en) Removal agent for asbestos construction layer
EP0616018A1 (en) Sprayable adhesive based on hydrogenated linear styrene block copolymers
JPH09100448A (en) Peeling method of adhesive sheet
CN107641561A (en) A kind of new and effective environment-friendly type scaling powder scavenger specially and preparation method thereof
JP4372433B2 (en) Oil and water resistant food heating wrapping paper and method for producing the same
EP2421922B1 (en) Paint stripping composition and device for application thereof for paint stripping by peel-off

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20181123

RJ01 Rejection of invention patent application after publication