CN108851214A - A kind of ramuscule cigarette holder stick and preparation method thereof containing single solid-state perfume (or spice) pearl particle - Google Patents
A kind of ramuscule cigarette holder stick and preparation method thereof containing single solid-state perfume (or spice) pearl particle Download PDFInfo
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- CN108851214A CN108851214A CN201810887483.XA CN201810887483A CN108851214A CN 108851214 A CN108851214 A CN 108851214A CN 201810887483 A CN201810887483 A CN 201810887483A CN 108851214 A CN108851214 A CN 108851214A
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- spice
- perfume
- pearl
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- particle
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0216—Applying additives to filter materials the additive being in the form of capsules, beads or the like
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Fats And Perfumes (AREA)
Abstract
A kind of ramuscule cigarette holder stick and preparation method thereof containing single solid-state perfume (or spice) pearl particle, it is related to essence spice for cigarette field, cigarette filter tip tow middle section is loaded with a solid-state perfume (or spice) pearl particle, the perfume pearl is to activate montmorillonite as primary raw material, the techniques such as formulated gel, crystallization, ball forming processed, attached perfume (or spice) are prepared, and provide approach to hold the addition of the weaker flavouring essence for tobacco of fragrant effect.In sucking process, the essence in mouth stick is not involved in burning, as flue gas slowly uniformly discharges, solves the problems, such as that the brought fragrance of burning is rotten.Advantage of the invention is that being applied in cigarette filter tip in the form of single solid-state perfume (or spice) pearl particle, structure is simple, non-toxic and tasteless, avoids consumer to the safety concerns of the tiny additive such as zeolite powder；Fragrant pearl preparation process is simple, and stable molding, fragrant pearl concentration entirety control rate are more stable, and more preferably compared with " quick-fried pearl ", and without additional addition solvent when attached perfume, elegant fragrance is sent out thoroughly for qualification rate, production stability.
Description
Technical field
The present invention relates to essence spice for cigarette field, in particular to a kind of ramuscule cigarette holder stick containing single solid-state perfume (or spice) pearl particle
And preparation method thereof.
Background technique
Ramuscule cigarette is that tobacco business is proposed a kind of new spec cigarette for being different from regular-size cigarette over nearly 5 years, thin compared with more
It is longer.The specification cigarette relatively positions middle and high end, therefore when designing and developing, and need to pay close attention to its flavouring essence quality and suction entertaining
Property.
In tobacco business, the development of cigarette solid meat flavor formulating technology is swift and violent, the new method, new technology especially in cigarette filter tip
Exploitation, including the quick-fried pearl of cigarette, microcapsules, nano particle, powdered granule etc..Currently, by the inspection of consumer market, cigarette is quick-fried
The whole acceptance of pearl is preferable, the patent of cigarette in Henan（A kind of quick-fried pearl raspberry essence of cigarette and its application in cigarette,
201710285349 .8 of application number）After raspberry essence is compounded by Fructus Rubi extract with solvent Glycerin, mixed triester with caprylic acid capric acid (ODO)
It is wrapped in quick-fried pearl, in cigarette smoking, may make fragrance to release by pinching brokenly the quick-fried pearl being placed in mouth stick.However, volume
There is also certain drawbacks for the addition of the quick-fried pearl of cigarette, dripping pill, low including ratio of briquetting, and higher cost needs to add solvent etc. and asks
Topic, and there are micro bad smells by quick-fried pearl, dripping pill solvent olive oil, ODO etc., so that quick-fried pearl is mainly used for wrapping up ginseng, peppermint
The flavors and fragrances of equal fragrance advantage.In addition, patent " the cigarette mouth containing silica gel perfume (or spice) pearl of Shanghai Juhua Technology Co., Ltd.
Stick and cigarette silica gel perfume (or spice) pearl preparation method "（Application number 201710990115.3）Using inorganic silica gel as carrier, and essence is adsorbed,
And " cigarette filter tip and cigarette containing zeolite perfume (or spice) pearl are prepared the patent of Shanghai Juhua Technology Co., Ltd. with zeolite perfume (or spice) pearl
Method "（201710990114 .9 of application number）Using many zeolite fine particles as essence absorption carrier, and with the shape of cavity
Formula is placed in cigarette filter tip, and this method can play certain essence slow release effect, but this type nano granular, powdered granule etc.
What tiny additive easily caused consumer sucks safety concerns.
On the basis of the above-mentioned prior art, the present invention develops a kind of solid-state perfume (or spice) pearl particle, and it is main for using montmorillonite
Raw material is prepared, and montmorillonite is that a kind of particle is tiny, natural layered silicate mineral with unordered transition structure, mainly at
It is divided into montmorillonite, be one kind of clay because of its distinctive skeleton structure is the good raw material for preparing porous material.By clay mine
The porous material of object preparation not only has catalyst high-specific surface area and pore volume, and structure, thermal stability are strong, good
Preventing from heavy metal ability.Montmorillonite also has good dispersion performance, and it is poly- as nanometer that high molecular material industry can be widely applied
The additive of object high molecular material is closed, shock resistance, antifatigue, dimensional stability and gas barrier property etc. are improved, to play
Enhance the effect of polymer comprehensive physical performance, while improving materiel machining performance.Currently, this kind of silicate mineral is chiefly used in making pottery
Prepared by the production of the porous materials such as porcelain, nontoxic, and the advantage with fire resisting, free from extraneous odour, can be used for opening for cigarette new material
Hair.
It is the solid-state perfume (or spice) pearl particle that primary raw material is prepared, Nantural non-toxic, low cost by montmorillonite；And it is fragrant with single solid-state
The form of pearl is applied in the ramuscule cigarette holder stick that circumference circle is 16.8mm, and simple and practical in structure, production stability is more preferable；It is porous
Structure makes solid-state perfume (or spice) pearl in terms of essence sustained release better than quick-fried pearl, and without pinching brokenly, solvent-free exudation, and 1~10 μm of micropore is slow
Release structure has significant advantage in this kind of use for holding the weaker flavouring essence for tobacco of fragrant effect of the fragrance of a flower.There are no this for existing market
Class mouth rod product is released, and the application of the mouth stick can innovation burst point after ingredient this kind of ramuscule cigarette listing.With porous structure
The cigarette filter tip of solid-state perfume (or spice) pearl particle holds adding for the weaker flavouring essence for tobacco of fragrant effect compared to traditional cigarette filter tip for the fragrance of a flower is this kind of
Add and provide desirable route, essence is slowly uniformly discharged with flue gas, solves the problems, such as that the brought fragrance of burning is rotten.
Summary of the invention
In view of the above technical problems, the present invention provides adaptation based on a kind of montmorillonite add other raw materials gel processed and
Subsequent technique, be not involved in burning, nontoxic, stable molding, fragrant pearl concentration entirety control rate is more stable, have essence slow-release function,
The ramuscule cigarette holder stick and preparation method thereof for the solid-state perfume (or spice) pearl that fragrance is unlikely to deteriorate.
To solve the above-mentioned problems, the technical scheme is that：
A kind of preparation method of the ramuscule cigarette holder stick containing solid-state perfume (or spice) pearl particle, by the mealy crystal system of the porous structure after crystallization
Ball forming, attached perfume (or spice), the solid-state perfume (or spice) pearl particle after attached perfume is added in the mouth stick tow of cigarette according to a certain percentage.
Further, it the described method comprises the following steps：
1）Configure gel：To activate montmorillonite as primary raw material, addition sodium metasilicate, aluminium oxide, distilled water and adjusting in gel are changed
Learn constitutive molar ratio SiO2：Al2O3：H2O is 2~10：1：50~80, according to molar ratio NaOH：H2O=1：10~50 addition solids
NaOH is added directed agents and accounts for the 0.1~0.2% of gross mass, preparation aluminosilicate gels are sufficiently stirred；
2）Crystallization：After gel at room temperature 4~12h of aging, it is transferred in the stainless steel cauldron with teflon lined, in
4~10h of crystallization at 90~100 DEG C, obtains the mealy crystal with porous structure；
3）Ball forming processed：By mealy crystal after washing, filtering, drying, the binder PVA of substrate quality 1.5~5% is added,
It is placed in ball forming processed in nodulizer, the diameter for controlling spherical particle is 2.75 ± 0.15mm；
4）Attached perfume (or spice)：By spherical particle and flavouring essence for tobacco according to 1:2 mass ratio is uniformly mixed, and is slowly stirred 6~12h, is used cigarette
Essence uniform adsorption air-dries 4~6h in the porous channel of spherical particle, at 40~50 DEG C, and solid-state perfume (or spice) pearl particle is made；
5）The molding of mouth stick：By solid-state perfume (or spice) pearl particle be added to cigarette mouth stick tow middle section molding to get.
Further, in the preparation gel step, SiO2：Al2O3：H2O molar ratio is 4~8：1：50~80 is best.By
In activation montmorillonite, SiO2 content is about 50%, Al2O3Content is about 16%, therefore in actual operation, according to the above ratio into
Row calculates material additive amount.In preparing gel process, when lacking silicon source in system, sodium metasilicate is added；When lacking in system
When silicon source, aluminium oxide is added.
Further, the directed agents are crystal structure directed agents, contain the atomic small crystalline substance with certain crystallographic structure
Core exists, and crystal can be accelerated to mushroom out, additive amount is generally the 0.1~0.2% of gel rubber system gross mass.
Further, in the crystallization steps, 6~12h of gel aging is optimal, and 6 ~ 10 h of crystallization time is optimal, must have
The mealy crystal of porous structure.
Further, the step 3）In, the diameter for designing spherical particle is 2.75 ± 0.15mm, the revolving speed one of nodulizer
As be 40~50 revs/min.
Further, the step 1）Middle activation montmorillonite density 2.1~2.5g/mL, SiO2Content 50~51%, Al2O3
The activating process of content 16~17%, montmorillonite is：By montmorillonite, solid sodium hydroxide, distilled water according to 12:5:60 quality
Ratio is uniformly mixed, and through 400~450 DEG C of 2~4h of roasting, is crushed after cooling, is crossed 300 meshes to obtain the final product.
Further, the step 4）Middle flavouring essence for tobacco is one of oil of aglaia odorate, oil of chamomile, the pure oil of white orchid or several
Kind.
Further, the step 4）In, the attached fragrant rate of solid-state perfume (or spice) pearl particle is controlled 18~25%, wherein and attached perfume rate=
（Weight before the attached perfume of weight-after attached perfume）/ it is attached it is fragrant before weight.
Further, the solid-state perfume (or spice) pearl particle is in microcosmic porous structure, is measured through scanning tunneling microscope, microcosmic porous
Average pore size at 1~10 μm.
A kind of ramuscule cigarette holder stick containing solid-state perfume (or spice) pearl particle, using above-mentioned preparation method, the cigarette filter tip is one
Kind ramuscule cigarette holder stick, mouth stick base circumference Zhou Changwei 16.8mm are loaded with a 2.75 ± 0.15mm's of diameter in tow middle section
Solid-state perfume (or spice) pearl particle, the perfume pearl are prepared using activating montmorillonite as primary raw material, are a kind of essence loads for having porous property
Body is adsorbed with light fragrant, volatile type flavouring essence for tobacco.
The application of a kind of ramuscule cigarette holder stick containing solid-state perfume (or spice) pearl particle in cigarette, using above-mentioned preparation method, institute
Ramuscule cigarette holder stick is stated to be applied to that fragrance of a flower class can be directed in the production for the cigarette that cigarette filter tip circumference circle is 16.8mm, hold fragrant effect
Bad flavouring essence for tobacco plays sustained release, extends and hold fragrant effect.
Compared with prior art, advantages of the present invention and generation good effect are：
1）Solid-state perfume (or spice) pearl particle in the mouth stick, is in porous structure, and average pore size has the absorption of good essence at 1~10 μm
And sustained release performance.Under preparation process condition of the invention, prepared in such a way that adaptation based on montmorillonite adds other raw materials
Gel, the techniques such as subsequent crystallization, ball forming processed, so that the attached fragrant rate of fragrant pearl is integrally controlled 18~25%, than existing fragrant pearl entirety
Control rate（Existing perfume pearl concentration entirety difference is big）More stable, absorption property is in a saturated state, in smoking property of cigarette mistake
Cheng Zhong can play sustained release fragrance, and this perfume (or spice) will not have an impact to cigarette；
2）It is applied in cigarette filter tip in the form of single solid-state perfume (or spice) pearl, it is intuitionistic and concise, nontoxic, relative to being added to micro- glue
It is thin to biological powdered carbon, silica white, zeolite powder, cyclodextrin granule etc. to avoid consumer for this kind of cigarette filter tip of capsule, powdered granule
Small additive sucks safety concerns；
3）Relative to quick-fried pearl, dripping pill class product is added to, the solid-state perfume (or spice) pearl granule preparing process is simple, using more in ramuscule cigarette
For convenience, it is easier to realize production, qualification rate, production stability are more preferable, and without additional addition solvent, fragrance when fragrant pearl is attached fragrant
It is purer；
4）The mouth stick is a kind of mouth stick applied to ramuscule cigarette, and mouth stick circumference circle is 16.8mm, and there are no such for existing market
Mouth rod product is released, and the application of the mouth stick can innovation burst point after ingredient this kind of ramuscule cigarette listing.The tow middle section of the mouth stick
Be loaded with the solid-state perfume (or spice) pearl particle of a 2.75 ± 0.15mm of diameter, the perfume pearl to activate montmorillonite as primary raw material preparation and
At preparing adsorption effect by technique of the present invention and be better than the prior art.
5）Compared with the quick-fried pearl of traditional cigarette, dripping pill, without pinching brokenly fragrant pearl, solvent-free exudation when consumer sucks cigarette.
Detailed description of the invention
Fig. 1 is cigarette filter tip schematic diagram；
Fig. 2 is the SEM figure of solid-state perfume (or spice) pearl particle in embodiment 4（500 times of Electronic Speculum）
Fig. 3 is the SEM figure of solid-state perfume (or spice) pearl particle in embodiment 4（3000 times of Electronic Speculum）
In figure：1- filter stick aspiration end, 2- bulky grain solid-state perfume (or spice) pearl, 3- cigarette bobbin paper, 4- pipe tobacco.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Embodiment 1
A kind of ramuscule cigarette holder stick containing solid-state perfume (or spice) pearl particle, the cigarette filter tip circumference circle 16.8mm add in tow middle section
It is loaded with the solid-state perfume (or spice) pearl particle of a 2.75 ± 0.15mm of diameter.This contains the preparation side of the cigarette filter tip of solid-state perfume (or spice) pearl particle
Method includes the following steps：
Step 1：Configure gel.According to molar ratio SiO2：Al2O3：H2O is 4：1：50 will activate montmorillonite, aluminium oxide, distilled water
Mixing, according to molar ratio NaOH：H2O=1：50 addition solid NaOH.I.e.：Take 480g montmorillonite, 25g Al2O3, distilled water 900g,
NaOH solid 40g is uniformly mixed, and 2.5g NaY type directed agents are added, preparation aluminosilicate gels are sufficiently stirred.
Step 2：Crystallization.After gel at room temperature aging 12h, it is transferred to the stainless steel with teflon lined
In reaction kettle, 10 h of crystallization at 100 DEG C obtains the mealy crystal with porous structure.
Step 3：Ball forming processed.By mealy crystal after washing, filtering, drying, addition substrate quality 1.5-5%'s is viscous
Agent PVA is tied, is placed in ball forming processed in nodulizer, 40 revs/min of nodulizer revolving speed, the diameter for controlling spherical particle is 2.75 ±
0.15mm。
Step 4：Attached perfume (or spice).By spherical particle and oil of aglaia odorate essence according to 1:2 mass ratio is uniformly mixed, and is slowly stirred
8h makes flavouring essence for tobacco uniform adsorption in the porous channel of spherical particle, and in 40 DEG C of air-dried 6h, solid-state perfume (or spice) pearl particle is made.
Step 5：The molding of mouth stick.By solid-state perfume (or spice) pearl particle be added to cigarette mouth stick tow middle section molding to get.
Wherein, 2.1~2.5 g/mL of activation montmorillonite density, the activating process of montmorillonite are：By montmorillonite, solid
Sodium hydroxide, distilled water are according to 12:5:60 mass ratio is uniformly mixed, and through 400~450 DEG C of roasting 4h, is crushed after cooling,
Cross 300 meshes to obtain the final product.
Embodiment 2
A kind of ramuscule cigarette holder stick containing solid-state perfume (or spice) pearl particle, which is characterized in that the cigarette filter tip circumference circle 16.8mm,
Tow middle section is loaded with the solid-state perfume (or spice) pearl particle of a 2.75 ± 0.15mm of diameter.This contains the cigarette filter tip of solid-state perfume (or spice) pearl particle
Preparation method, include the following steps：
Step 1：Configure gel.According to molar ratio SiO2：Al2O3：H2O is 5：1：50 will activate montmorillonite, aluminium oxide, distilled water
Mixing, according to molar ratio NaOH：H2O=1：50 addition solid NaOH.I.e.：Take 600g montmorillonite, 6g Al2O3, distilled water 900g,
NaOH solid 40g is uniformly mixed, and 2.5g NaY type directed agents are added, preparation aluminosilicate gels are sufficiently stirred.
Step 2：Crystallization.After gel at room temperature aging 12h, it is transferred to the stainless steel with teflon lined
In reaction kettle, 10 h of crystallization at 100 DEG C obtains the mealy crystal with porous structure.
Step 3：Ball forming processed.By mealy crystal after washing, filtering, drying, addition substrate quality 1.5-5%'s is viscous
Agent PVA is tied, is placed in ball forming processed in nodulizer, 40 revs/min of nodulizer revolving speed, the diameter for controlling spherical particle is 2.75 ±
0.15mm。
Step 4：Attached perfume (or spice).By spherical particle and oil of aglaia odorate essence according to 1:2 mass ratio is uniformly mixed, and is slowly stirred
12h makes flavouring essence for tobacco uniform adsorption in the porous channel of spherical particle, and in 40 DEG C of air-dried 6h, solid-state perfume (or spice) pearl particle is made.
Step 5：The molding of mouth stick.By solid-state perfume (or spice) pearl particle be added to cigarette mouth stick tow middle section molding to get.
Wherein, 2.1~2.5 g/mL of activation montmorillonite density, the activating process of montmorillonite are：By montmorillonite, solid
Sodium hydroxide, distilled water are according to 12:5:60 mass ratio is uniformly mixed, and through 400~450 DEG C of roasting 4h, is crushed after cooling,
Cross 300 meshes to obtain the final product.
Embodiment 3
A kind of ramuscule cigarette holder stick containing solid-state perfume (or spice) pearl particle, which is characterized in that the cigarette filter tip circumference circle 16.8mm,
Tow middle section is loaded with the solid-state perfume (or spice) pearl particle of a 2.75 ± 0.15mm of diameter.This contains the cigarette filter tip of solid-state perfume (or spice) pearl particle
Preparation method, include the following steps：
Step 1：Configure gel.According to molar ratio SiO2：Al2O3：H2O is 8：1：80 will activate montmorillonite, sodium metasilicate, distilled water
Mixing, according to molar ratio NaOH：H2O=1：50 addition solid NaOH.I.e.：Take 960g montmorillonite, 242g sodium metasilicate, distilled water
1440g, NaOH solid 40g are uniformly mixed, and 3.5g NaY type directed agents are added, preparation aluminosilicate gels are sufficiently stirred.
Step 2：Crystallization.After gel at room temperature aging 12h, it is transferred to the stainless steel with teflon lined
In reaction kettle, 10 h of crystallization at 100 DEG C obtains the mealy crystal with porous structure.
Step 3：Ball forming processed.By mealy crystal after washing, filtering, drying, addition substrate quality 1.5-5%'s is viscous
Agent PVA is tied, is placed in ball forming processed in nodulizer, 40 revs/min of nodulizer revolving speed, the diameter for controlling spherical particle is 2.75 ±
0.15mm。
Step 4：Attached perfume (or spice).By spherical particle and the pure oil essence of white orchid according to 1:2 mass ratio is uniformly mixed, and is slowly stirred
12h makes flavouring essence for tobacco uniform adsorption in the porous channel of spherical particle, and in 40 DEG C of air-dried 6h, solid-state perfume (or spice) pearl particle is made.
Step 5：The molding of mouth stick.By solid-state perfume (or spice) pearl particle be added to cigarette mouth stick tow middle section molding to get.
Wherein, 2.1~2.5 g/mL of activation montmorillonite density, the activating process of montmorillonite are：By montmorillonite, solid
Sodium hydroxide, distilled water are according to 12:5:60 mass ratio is uniformly mixed, and through 400~450 DEG C of roasting 4h, is crushed after cooling,
Cross 300 meshes to obtain the final product.
Embodiment 4
A kind of ramuscule cigarette holder stick containing solid-state perfume (or spice) pearl particle, which is characterized in that the cigarette filter tip circumference circle 16.8mm,
Tow middle section is loaded with the solid-state perfume (or spice) pearl particle of a 2.75 ± 0.15mm of diameter.This contains the cigarette filter tip of solid-state perfume (or spice) pearl particle
Preparation method, include the following steps：
Step 1：Configure gel.According to molar ratio SiO2：Al2O3：H2O is 5：1：50 will activate montmorillonite, aluminium oxide, distilled water
Mixing, according to molar ratio NaOH：H2O=1：50 addition solid NaOH.I.e.：Take 600g montmorillonite, 6g Al2O3, distilled water 900g,
NaOH solid 40g is uniformly mixed, and 2.5g NaY type directed agents are added, preparation aluminosilicate gels are sufficiently stirred.
Step 2：Crystallization.After gel at room temperature aging 12h, it is transferred to the stainless steel with teflon lined
In reaction kettle, 10 h of crystallization at 90 DEG C obtains the mealy crystal with porous structure.
Step 3：Ball forming processed.By mealy crystal after washing, filtering, drying, addition substrate quality 1.5-5%'s is viscous
Agent PVA is tied, is placed in ball forming processed in nodulizer, 45 revs/min of nodulizer revolving speed, the diameter for controlling spherical particle is 2.75 ±
0.15mm。
Step 4：Attached perfume (or spice).By spherical particle and the pure oil essence of white orchid according to 1:2 mass ratio is uniformly mixed, and is slowly stirred
12h makes flavouring essence for tobacco uniform adsorption in the porous channel of spherical particle, and in 50 DEG C of air-dried 4h, solid-state perfume (or spice) pearl particle is made.
Step 5：The molding of mouth stick.By solid-state perfume (or spice) pearl particle be added to cigarette mouth stick tow middle section molding to get.
Wherein, 2.1~2.5 g/mL of activation montmorillonite density, the activating process of montmorillonite are：By montmorillonite, solid
Sodium hydroxide, distilled water are according to 12:5:60 mass ratio is uniformly mixed, and through 400~450 DEG C of roasting 4h, is crushed after cooling,
Cross 300 meshes to obtain the final product.
Embodiment 5
A kind of ramuscule cigarette holder stick containing solid-state perfume (or spice) pearl particle, which is characterized in that the cigarette filter tip circumference circle 16.8mm,
Tow middle section is loaded with the solid-state perfume (or spice) pearl particle of a 2.75 ± 0.15mm of diameter.This contains the cigarette filter tip of solid-state perfume (or spice) pearl particle
Preparation method, include the following steps：
Step 1：Configure gel.According to molar ratio SiO2：Al2O3：H2O is 5：1：50 will activate montmorillonite, aluminium oxide, distilled water
Mixing, according to molar ratio NaOH：H2O=1：50 addition solid NaOH.I.e.：Take 600g montmorillonite, 6g Al2O3, distilled water 900g,
NaOH solid 40g is uniformly mixed, and 3g NaY type directed agents are added, preparation aluminosilicate gels are sufficiently stirred.
Step 2：Crystallization.After gel at room temperature aging 12h, it is transferred to the stainless steel with teflon lined
In reaction kettle, the crystallization 5h at 95 DEG C obtains the mealy crystal with porous structure.
Step 3：Ball forming processed.By mealy crystal after washing, filtering, drying, addition substrate quality 1.5-5%'s is viscous
Agent PVA is tied, is placed in ball forming processed in nodulizer, 50 revs/min of nodulizer revolving speed, the diameter for controlling spherical particle is 2.75 ±
0.15mm。
Step 4：Attached perfume (or spice).By spherical particle and the pure oil essence of white orchid according to 1:2 mass ratio is uniformly mixed, and is slowly stirred
6h makes flavouring essence for tobacco uniform adsorption in the porous channel of spherical particle, and in 50 DEG C of air-dried 4h, solid-state perfume (or spice) pearl particle is made.
Step 5：The molding of mouth stick.By solid-state perfume (or spice) pearl particle be added to cigarette mouth stick tow middle section molding to get.
Wherein, 2.1~2.5 g/mL of activation montmorillonite density, the activating process of montmorillonite are：By montmorillonite, solid
Sodium hydroxide, distilled water are according to 12:5:60 mass ratio is uniformly mixed, and through 400~450 DEG C of roasting 4h, is crushed after cooling,
Cross 300 meshes to obtain the final product.
Embodiment 6
A kind of ramuscule cigarette holder stick containing solid-state perfume (or spice) pearl particle, which is characterized in that the cigarette filter tip circumference circle 16.8mm,
Tow middle section is loaded with the solid-state perfume (or spice) pearl particle of a 2.75 ± 0.15mm of diameter.This contains the cigarette filter tip of solid-state perfume (or spice) pearl particle
Preparation method, include the following steps：
Step 1：Configure gel.According to molar ratio SiO2：Al2O3：H2O is 4：1：50 will activate montmorillonite, aluminium oxide, distilled water
Mixing, according to molar ratio NaOH：H2O=1：50 addition solid NaOH.I.e.：Take 480g montmorillonite, 25g Al2O3, distilled water 900g,
NaOH solid 40g is uniformly mixed, and 2.5g NaY type directed agents are added, preparation aluminosilicate gels are sufficiently stirred.
Step 2：Crystallization.After gel at room temperature aging 12h, it is transferred to the stainless steel with teflon lined
In reaction kettle, 10 h of crystallization at 95 DEG C obtains the mealy crystal with porous structure.
Step 3：Ball forming processed.By mealy crystal after washing, filtering, drying, addition substrate quality 1.5-5%'s is viscous
Agent PVA is tied, is placed in ball forming processed in nodulizer, 40 revs/min of nodulizer revolving speed, the diameter for controlling spherical particle is 2.75 ±
0.15mm。
Step 4：Attached perfume (or spice).By spherical particle and oil of chamomile essence according to 1:2 mass ratio is uniformly mixed, and is slowly stirred
12h makes flavouring essence for tobacco uniform adsorption in the porous channel of spherical particle, and in 40 DEG C of air-dried 6h, solid-state perfume (or spice) pearl particle is made.
Step 5：The molding of mouth stick.By solid-state perfume (or spice) pearl particle be added to cigarette mouth stick tow middle section molding to get.
Wherein, 2.1~2.5 g/mL of activation montmorillonite density, the activating process of montmorillonite are：By montmorillonite, solid
Sodium hydroxide, distilled water are according to 12:5:60 mass ratio is uniformly mixed, and through 400~450 DEG C of roasting 4h, is crushed after cooling,
Cross 300 meshes to obtain the final product.
Test effect：
It is applied in cigarette via the ramuscule cigarette holder stick containing solid-state perfume (or spice) pearl particle made from embodiment 1 ~ 6, cigarette filter tip circumference
Zhou Changwei 16.8mm.
Tissue has the smoke panel test expert of qualification of national cigarette and inhales and comment five ginsengs of group according to GB5606.4-2005《The 4th part of cigarette：
Sense organ technical requirements》With YC/T 497-2014《Cigarette Chinese-style cigarette style sensory evaluation method》To using the embodiment of the present invention 1
Cigarette made from ~ 6 mouth sticks is smoked panel test, and not use cigarette made from solid-state perfume (or spice) pearl particle mouth stick as control sample, is as a result seen
Table 1.
And SEM scanning is carried out for fragrant pearl in the optimal embodiment of effect, observe its porous structure.
1 cigarette sensory evaluation result of table
(the mouth stick circumference week of ramuscule cigarette made from the cigarette filter tip containing solid-state perfume (or spice) pearl particle using the embodiment of the present invention 1 ~ 6
A length of 16.8mm) for product compared with control sample, " fragrance of a flower " style is obvious, there is preferable slow release effect, the abundant journey of fragrance
Degree obviously increases, and the property sent out is promoted flue gas thoroughly.Using cigarette highest scoring made from 4 mouth stick of embodiment, main reason is that
The pure and fresh fresh deep and remote fragrance of a flower of the pure oil of white orchid is more coordinated with cigarette odor-absorbing, and since the sial proportion in embodiment 4 is moderate, so that solid
The sustained release performance of state perfume (or spice) pearl is more outstanding, it can be seen that, in fragrant pearl preparation process, feed molar proportion is SiO2：Al2O3：H2O=
5：1：When 50, product using effect is best.
Present invention is alternatively directed to the fragrant pearl particles in the optimal embodiment 4 of application effect to have carried out SEM scanning, to confirm that it is more
Pore structure.Wherein, Fig. 2 is the solid-state perfume (or spice) pearl particle SEM figure of 500 times of amplifications, and Fig. 3 is the solid-state perfume (or spice) pearl particle of 3000 times of amplifications
SEM figure, it can be seen that, fragrant hole of bead diameter is at 1 ~ 10 μm or so in the embodiment.
Above-described embodiment is only more excellent embodiment of the invention, is implemented according to the technical essence of the invention to above
Any simple modification and alternate variation that example is made, belong to technical solution of the present invention range.
Claims (7)
1. a kind of preparation method of the ramuscule cigarette holder stick containing single solid-state perfume (or spice) pearl particle, it is characterised in that：It will be porous after crystallization
The mealy crystal ball forming of structure, the solid-state perfume (or spice) pearl particle after attached perfume, is added to the mouth of cigarette by attached perfume (or spice) according to a certain percentage
In stick tow.
2. a kind of preparation method of ramuscule cigarette holder stick containing single solid-state perfume (or spice) pearl particle according to claim 1, feature
It is：It the described method comprises the following steps：
1）Configure gel：To activate montmorillonite as primary raw material, addition sodium metasilicate, aluminium oxide, distilled water and adjusting in gel are changed
Learn constitutive molar ratio SiO2：Al2O3：H2O is 2~10：1：50~80, according to molar ratio NaOH：H2O=1：10~50 addition solids
NaOH is added directed agents and accounts for the 0.1~0.2% of gross mass, preparation aluminosilicate gels are sufficiently stirred;
2）Crystallization：After gel at room temperature 4~12h of aging, it is transferred in the stainless steel cauldron with teflon lined, in
4~10h of crystallization at 90~100 DEG C, obtains the mealy crystal with porous structure；
3）Ball forming processed：By mealy crystal after washing, filtering, drying, the binder PVA of substrate quality 1.5~5% is added,
It is placed in ball forming processed in nodulizer, the diameter for controlling spherical particle is 2.75 ± 0.15mm；
4）Attached perfume (or spice)：By spherical particle and flavouring essence for tobacco according to 1:2 mass ratio is uniformly mixed, and is slowly stirred 6~12h, is used cigarette
Essence uniform adsorption air-dries 4~6h in the porous channel of spherical particle, at 40~50 DEG C, and solid-state perfume (or spice) pearl particle is made；
5）The molding of mouth stick：By solid-state perfume (or spice) pearl particle be added to cigarette mouth stick tow middle section molding to get.
3. the preparation method of the ramuscule cigarette holder stick according to claim 1 or 2 containing single solid-state perfume (or spice) pearl particle, feature exist
In：The step 1）Middle activation montmorillonite 2.1~2.5g/ml of density, the activating process of montmorillonite are：By montmorillonite, solid hydrogen
Sodium oxide molybdena, distilled water are according to 12:5:60 mass ratio is uniformly mixed, and through 400~450 DEG C of 2~4h of roasting, is crushed after cooling,
Cross 300 meshes to obtain the final product.
4. the preparation method of the ramuscule cigarette holder stick according to claim 1 or 2 containing single solid-state perfume (or spice) pearl particle, feature exist
In：The step 4）Middle flavouring essence for tobacco is one or more of oil of aglaia odorate, oil of chamomile, the pure oil of white orchid.
5. the preparation method of the ramuscule cigarette holder stick according to claim 1 or 2 containing single solid-state perfume (or spice) pearl particle, feature exist
In：The step 4）The attached fragrant rate of middle solid-state perfume (or spice) pearl particle is controlled 18~25%, wherein and attached perfume rate=（Weight-is attached after attached perfume
Weight before perfume (or spice)）/ it is attached it is fragrant before weight.
6. a kind of ramuscule cigarette holder stick containing single solid-state perfume (or spice) pearl particle, it is characterised in that：Using any one of such as claim 1-5 institute
The preparation method stated, the cigarette filter tip are a kind of ramuscule cigarette holder stick, mouth stick base circumference Zhou Changwei 16.8mm, in tow middle section
Be loaded with the solid-state perfume (or spice) pearl particle of a 2.75 ± 0.15mm of diameter, the perfume pearl to activate montmorillonite as primary raw material preparation and
At.
7. a kind of application of ramuscule cigarette holder stick containing single solid-state perfume (or spice) pearl particle in cigarette, it is characterised in that：Using such as right
It is required that the described in any item preparation methods of 1-5, the ramuscule cigarette holder stick is applied to the volume that cigarette filter tip circumference circle is 16.8mm
In the production of cigarette.
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| CN111713736A (en) * | 2020-06-28 | 2020-09-29 | 潮州市泥香陶瓷新材料有限公司 | Environment-friendly ceramic blasting bead for cigarettes and manufacturing method |
| CN112754069A (en) * | 2020-12-11 | 2021-05-07 | 贵州中烟工业有限责任公司 | Cigarette bead with rotary flavoring function and filter |
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| CN108851214B (en) | 2020-06-30 |
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