CN108849928A - The composition pesticide of isoxaflutole and its application - Google Patents
The composition pesticide of isoxaflutole and its application Download PDFInfo
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- CN108849928A CN108849928A CN201710332335.7A CN201710332335A CN108849928A CN 108849928 A CN108849928 A CN 108849928A CN 201710332335 A CN201710332335 A CN 201710332335A CN 108849928 A CN108849928 A CN 108849928A
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- polyoxyethylene ether
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
Abstract
The present invention provides a kind of herbicidal composition and its application, the active constituent of the herbicidal composition includes isoxaflutole and component A.Herbicidal composition of the invention, the herbicidal effect compared with its single dose significantly improve, and show fabulous synergistic effect, reduce pharmaceutical use, while reducing peasant's drug cost, reduce the influence to environment;Degrass spectrum is expanded simultaneously, and can effectively delay the generation and development of single dose resistance.
Description
Technical field
The present invention relates to pesticide fields, and in particular to a kind of composition pesticide containing isoxaflutole and its application.
Background technique
Isoxaflutole is to develop isoxazole herbicide by Rhone-Poulenc.Chemical name is:5- cyclopropyl
Base -1,2- oxazole -4- base (α, α, α,-trifluoromethyl -2- mesyl p-methylphenyl) ketone, molecular formula C15H12F3NO4S,
Molecular weight is 359.4, and structural formula is:
Isoxaflutole is medical midbodies of para (ortho)-hydroxybenzoic acetone acid esters dual oxide enzyme inhibitor, i.e. HPPD inhibitor.Its action character is
It can be used after activity of weeding, Miao Qianmiao with wide spectrum, death after albefaction occur in weeds.Though its symptom and carotenoid are raw
The effect symptom of object synthetic inhibitor is extremely similar, but its chemical structure feature such as polarity and degree of ionization and known carotenoids
Plain biosynthesis inhibitor etc. has apparent difference.Isoxaflutole mainly works via weeds young root Assimilation and conductivity, quick
Sense weeds pass through the synthesis for inhibiting p-hydroxybenzene pyruvic acid (HPP) ester dual oxide enzyme after absorbing this medicine, lead to the product of tyrosine
It is tired, so that the biosynthesis of plastid a kind of jade and tocopherol is obstructed, and then influence the biosynthesis of carotenoid.
Smetolachlor is the chloroacetanilide herbicides developed by Syngenta company.Chemical name is:(aRS,
1R) the chloro- 6 '-ethyl-N- of -2- (2- methoxyl group -1- Methylethyl) acetyl ortho-aminotoluene or the chloro- 6 '-ethyl-of (aRS, 1S) -2-
N- (2- methoxyl group -1- Methylethyl) acetyl ortho-aminotoluene, molecular formula C15H22ClNO2, molecular weight 283.8, structural formula
For:
Smetolachlor is mainly the growth by hindering the synthesis of protein to inhibit cell.Pass through the children of plant
The hypocotyl absorption conduction upwards of bud, that is, monocotyledonous plumule, dicotyledon, seed and root also Assimilation and conductivity, but suction
Receipts amount is less, and conduction of velocity is slow.Conduction upwards is absorbed mainly by root after emergence, inhibits the growth of young shoot and root.Susceptible weeds exist
After germination be unearthed before or just be unearthed be poisoned to death immediately, show as tooth sheath hard-pressed bale growing point, slightly thicker, radicle is thin and curved
Song, no fibrous root, gradually browning color, black rot growing point.
Isopropyl methoxalamine is the chloroacetanilide herbicides developed by Syngenta company.Chemical name is:(aRS,
1RS) the chloro- 6 '-ethyl-N- of -2- (2- methoxyl group -1- Methylethyl) its molecular formula of acetyl ortho-aminotoluene is C15H22ClNO2, point
Son amount is 283.8, and structural formula is:
Isopropyl methoxalamine is mainly the growth by hindering the synthesis of protein to inhibit cell.It is by the young shoot of plant
The hypocotyl absorption conduction upwards of monocotyledonous plumule, dicotyledon, seed and root also Assimilation and conductivity, but uptake
Less, conduction of velocity is slow.Conduction upwards is absorbed mainly by root after emergence, inhibits the growth of young shoot and root.Susceptible weeds are being germinateed
Be unearthed before being unearthed afterwards or just and be poisoned to death immediately, show as tooth sheath hard-pressed bale growing point, slightly thicker, radicle is thin and is bent,
Without fibrous root, gradually browning color, black rot growing point.
Propisochlor is by the chloro-acetyl amine herbicide of nitridation joint-stock company of Hungary exploitation.Chemical name is:2-
Chloro- 6 '-ethyl-N- isopropoxymethyl its molecular formula of acetyl ortho-aminotoluene is C15H22ClNO2, molecular weight 283.8, structural formula
For:
Propisochlor is mainly the growth by hindering the synthesis of protein to inhibit cell.Medicament is inhaled by plant plumule
Receive, into plant in protease inhibition synthesis, bud and root stop growing, and adventitious root can not be formed.Monocotyledon passes through embryo
Bud scale, dicotyledon then absorb through hypocotyl, conduct then up, seed and root also Assimilation and conductivity, but uptake is less, passes
It is slow to lead speed, root to be leaned on to absorb conduction upwards after emergence.If soil moisture is suitable for not being unearthed the weed bud phase to be killed.
Summary of the invention
The purpose of the present invention is to provide a kind of composition pesticide, the composition can be used as herbicide, and be killed
Grass spectrum is wide, has significant preventive effect to broadleaf weeds and gramineae weed,.
Specific summary of the invention is as follows:
A kind of composition pesticide, including isoxaflutole and component A, component A are Smetolachlor, isopropyl first grass
One of amine, propisochlor are a variety of;
The weight ratio of isoxaflutole and component A are 1~99 in the composition pesticide:99~1, preferably 1~20:20
~1;
The composition pesticide further includes carrier, the carrier be one of surfactant and/or auxiliary agent or a variety of,
The percentage composition that total weight of carrier accounts for composition pesticide is 5%~99.9%;
The surfactant includes one or more of emulsifier, dispersing agent and wetting agent.Wherein, the emulsifier
For phenethyl phenol polyoxyethylene polyoxy propylene ether, glyceryl monolaurate polyoxyethylene ether, styrylphenol polyoxyethylene ether,
Castor oil polyoxyethylene ether, ethoxy castor oil polyoxyethylene ether, alkyl phenol polyoxyethylene polyoxypropylene ether, styryl phenyl
Polyoxyethylene ether, secondary octyl phenol polyethenoxy ether, nonylphenol polyoxyethylene ether, alkyl-diethylene glycol ether-sodium sulfonate, fatty acid
Macrogol ester, fast penetration enhancer T, styrylphenol formaldehyde resin PULLRONIC F68 block type polyethers, anhydrous sorbitol
Aliphatic ester polyoxyethylene ether, aliphatic alcohol polyoxyethylene sulfonate, polyoxyethylene alkylphenol formaldehyde condensation products, dodecyl
Sulfoacid calcium, decyl alcohol polyoxyethylene ether sulfosuccinic acid sodium, alkyl phenol polyoxyethylene ether, trilaurin polyoxyethylene ether,
Two Bian xenyl polyoxyethylene ether, oleic acid polyethylene glycol 400 ester or fatty alcohol polyoxyethylene ether, alkyl phenol polyoxyethylene ether formaldehyde
Condensation product sodium sulphate, alkyl phenol polyoxyethylene ether succinate monoester sulfonate, alkylphenol-polyethenoxy phosphate, alkyl phenol polyoxy
Vinethene sulfosuccinates, polyoxyethylene fatty acid rouge, polymethyl acrylate, Polyoxyethylene fatty ammonia, ethoxy castor oil,
One or more of aliphatic acid polyethenoxy ether, polyoxyethylene aliphatic alcohol ether, alkylaryl polyoxyethylene poly-oxygen propylene aether;Institute
State dispersing agent be sodium methylene bis-naphthalene sulfonate, dispersing agent MF, polyvinylpyrrolidone, sodium lignin sulfonate,
Sodium metnylene bis-naphthalene sulfonate (dispersing agent NNO), alkamide taurine salt, calcium lignosulfonate, Sodium Polyacrylate, alkylnaphthalene sulphur
One or more of sodium salt and sodium methylene bis-naphthalene sulfonate formaldehyde condensation products of sour condensation polymer;The wetting agent is alkylnaphthalene sulphur
Sour sodium, fatty alcohol polyoxyethylene ether, Teepol, lauryl sodium sulfate, neopelex, poly alkyl alcohol second
Ether sulfates, nonylphenol polyoxyethylene ether, sorbitan fatty acid ester polyoxyethylene ether, alkyl naphthalene formaldehyde condensation product,
The mixture of alkylnaphthalene sulfonate and anion wetting agent.
The auxiliary agent includes solvent, cosolvent, suspending agent, thickener, capsule material, protective agent, defoaming agent, one in bleeding agent
Kind is several.Wherein the solvent includes one or more of organic solvent, vegetable oil, mineral oil, solvent naphtha or water;Specifically
Say that the organic solvent includes N-Methyl pyrrolidone, tetrahydrofuran, dimethyl sulfoxide, spectrasolv DMDA, N, N- in ground
Dimethylformamide, tetrahydrofurfuryl alcohol, tributyl phosphate, dimethylbenzene, Isosorbide-5-Nitrae-dioxane or cyclohexanone etc.;The vegetable oil is ring
Oxygen soybean oil, soybean oil, peanut oil, rapeseed oil, castor oil, corn oil or pine-seed oil etc.;The mineral oil be liquid wax, machine oil,
Kerosene or lubricating oil etc.;The solvent naphtha is solvent naphtha No. 100, No. 150, No. 180 or No. 200 etc..Above-mentioned solvent can also be made
For cosolvent use.
The antifreezing agent includes ethylene glycol, 1,2- propylene glycol, ammonium sulfate, glycerol or urea etc..
The thickener includes xanthan gum, polyvinyl alcohol, polyethylene glycol, white carbon black, sodium alginate, aluminum magnesium silicate, silicic acid
Aluminium sodium, carboxymethyl cellulose, diatomite, kaolin or organobentonite.
The suspending agent is colloidal silicon dioxide, carboxymethyl cellulose (CMC), sodium alginate or sodium carboxymethylcellulose
Deng.
The defoaming agent is organosiloxane, tributyl phosphate or silicone etc..
The dosage form of herbicidal composition of the invention is missible oil, aqueous emulsion, emulsifiable concentrate, wettable powder, oil-suspending agent.On
Stating dosage form can be prepared by the conventional method of this field.
The group of the missible oil weight percent becomes:Active constituent 0.1%~95%, helps emulsifier 0.5%~30%
Solvent 0%~30%, solvent make-up to 100%;
Preparation method is:Active constituent, emulsifier, cosolvent and solvent are mixed, homogeneous oil phase is become.
The group of the aqueous emulsion weight percent becomes:Active constituent 0.1%~95%, helps emulsifier 0.5~30%
Solvent 0%~30%, solvent 1%~30%, antifreezing agent 0%~20%, thickener 0.1%~5%, water are supplemented to 100%;
Preparation method is:Active constituent, emulsifier, cosolvent and solvent are mixed, homogeneous oil phase is become;By water,
The mixing such as antifreezing agent, thickener, makes it at homogeneous aqueous phase.Under high velocity agitation, water phase is added to oily phase or is added to oil
To water phase, the aqueous emulsion of favorable dispersibility is formed.
The group of the oil-suspending agent weight percent becomes:Active constituent 0.1%~95%, emulsifier 0.1%~
30%, thickener 0.01%~30%, oil complement to 100%;
Preparation method is:Using oil as medium, active constituent, surfactant and thickener etc. are added in sand milling kettle and ground
Carefully, oil-suspending agent is made.
The group of the emulsifiable concentrate weight percent becomes:Active constituent 0.1%~95%, helps emulsifier 1%~20%
Solvent 1%~30%, antifreezing agent 1%~20%, thickener 0.01%~5%, water is supplemented to 100%;
Preparation method is:Active constituent, cosolvent, emulsifier are mixed into homogeneous oil phase, water, antifreezing agent, thickening is added
Agent is through high-shear emulsion machine high speed shear up to emulsifiable concentrate.
Herbicidal combinations of the invention can be provided in the form of finished product preparation, i.e., each substance has mixed in composition;?
It can be provided with independent dosage form, voluntarily be mixed in bucket or tank using preceding, needed for concentrate is usually mixed to get with water
The concentration of active material.
Herbicidal composition of the invention is to prevent and kill off the crop fields such as corn, beet, sugarcane, orchard annual and perennial wealthy
Application in leaf weeds, gramineae weed.
The weeds of the annual and perennial broadleaf weeds and gramineae weed are:Piemarker, Siberian cocklebur, summer cypress, herba stellariae mediae, dragon
Certain herbaceous plants with big flowers, Veronica, datura, salsola collina, willow leaf thorn smartweed, lady's thumb, beggar-ticks, Amaranthus retroflexus, purslane, acalypha copperleaf, barnyard grass, Cowhells
Grass, shepherd's purse, smallflower galinsoga herb, Chenopodiaceae, small Chenopodiaceae, rat-tail amur foxtail, benbie, herba digitariae, knucklegrass, millet, semen euphorbiae, herba setariae viridis, towser tail
Grass.
Composition of the invention can also at other compound especially cauline leafs with weeding, desinsection or bactericidal property
The herbicide of reason is used in mixed way, can also be mixed with nematicide, protective agent, growth regulator, nutrient for plants or soil conditioner
It closes and uses.
Herbicidal composition application method of the invention is simple, before weed germination or after sprouting, to crop and work
The place of object growth is applied according to a conventional method, such as mixes soil, spraying, injection, casting, and amount of application is according to weather conditions or crop
Depending on state, generally in 5-200g (a.i.)/mu.Herbicidal composition of the invention, herbicidal effect is usually and in composition
The content of single compound is related, also related with extraneous factor such as weather, but can slow down gas by using dosage form appropriate
The influence of time.
Herbicidal combinations of the invention have the following advantages that:
1, the composition pesticide compounds within a certain ratio range shows fabulous synergistic effect, bright compared with single dose
It is aobvious to improve herbicidal effect, to reduce usage amount, while reducing peasant's drug cost, reduce the shadow to environment
It rings;
2, degrass spectrum is expanded, a kind of medicament is enabled to prevent and treat a variety of weeds simultaneously, provides one kind extremely easily and effectively
Means of prevention, broadleaf weeds and gramineae weed to the crop fields such as corn, beet, sugarcane and orchard etc. have good anti-
Except effect;
Specific embodiment
Technical solution of the present invention is further discussed in detail with reference to embodiments, it should be noted that implement
Example is only used for that the content of present invention is explained further, and facilitates those skilled in the art of the present technique to understand, is not intended to limit protection of the invention
Range, related personnel change to of the invention obvious, still the present invention claims protection scope within.
Embodiment 1 contains the missible oil of 0.2% active constituent
By isoxaflutole 0.1g, Smetolachlor 1.9g, castor oil polyoxyethylene ether 5g, two Bian xenyl polyoxies
Vinethene 15g, N-Methyl pyrrolidone are mended to 1kg, are mixed into homogeneous oil phase to get the missible oil containing 0.2% active constituent is arrived.
Embodiment 2 contains the missible oil of 0.2% active constituent
By isoxaflutole 1.9g, Smetolachlor 0.1g, N-Methyl pyrrolidone 50g, aliphatic acid polyethenoxy
Ether 50g, polyoxyethylene alkylphenol formaldehyde condensation products 50g, anhydrous methanol are mended to 1kg, are mixed into homogeneous oil phase to get to containing
The missible oil of 0.2% active constituent.
Embodiment 3 contains the missible oil of 50% active constituent
By isoxaflutole 200g, isopropyl methoxalamine 300g, solvent naphtha 180#200g, trilaurin polyoxyethylene
Ether 50g, ethoxy castor oil polyoxyethylene ether 50g, toluene are mended to 1kg, are mixed into homogeneous oil phase to get to containing 50% activity
The missible oil of ingredient.
Embodiment 4 contains the missible oil of 50% active constituent
By isoxaflutole 300g, isopropyl methoxalamine 200g, tetrahydrofurfuryl alcohol 100g, alkyl phenol polyoxyethylene ether formaldehyde condensation
Object sodium sulphate 50g, polyoxyethylene fatty acid rouge 50g, dimethylformamide are mended to 1kg, are mixed into homogeneous oil phase to get to containing
The emulsifiable concentrate of 50% active constituent.
Embodiment 5 contains the aqueous emulsion of 1% active constituent
Formula:Isoxaflutole 0.5g, propisochlor 9.5g, No. 200 50g of solvent naphtha, phenethyl phenol polyoxyethylene polyoxy
Propylene ether 50g, styrylphenol formaldehyde resin PULLRONIC F68 block type polyethers 50g, propylene glycol 80g, white carbon black
30g, water complement to 1kg.
Preparation method:By above-mentioned isoxaflutole, propisochlor, solvent naphtha 200, phenethyl phenol polyoxyethylene polyoxy third
Dilute ether, styrylphenol formaldehyde resin PULLRONIC F68 block type polyethers are mixed into homogeneous oil phase;Water, propylene glycol,
White carbon black is mixed into uniform water phase;Under high velocity agitation, water phase is added in oily phase, forms the living containing 1% of favorable dispersibility
The aqueous emulsion of property ingredient.
Embodiment 6 contains the aqueous emulsion of 1% active constituent
Formula:Isoxaflutole 9.5g, propisochlor 0.5g, N-Methyl pyrrolidone 50g, secondary octyl phenol polyethenoxy ether
30g, fatty alcohol polyoxyethylene ether 20g, glycerine 50g, xanthan gum 3g, water complement to 1kg.
Preparation method:By above-mentioned isoxaflutole, propisochlor, N-Methyl pyrrolidone, secondary octyl phenol polyethenoxy ether,
Fatty alcohol polyoxyethylene ether is mixed into homogeneous oil phase;Water, glycerine, xanthan gum are mixed into uniform water phase;Under high velocity agitation, will
Oil is added in water phase, forms the aqueous emulsion containing 1% active constituent of favorable dispersibility.
Embodiment 7 contains the aqueous emulsion of 35% active constituent
Formula:Isoxaflutole 175g, it Smetolachlor 175g, 1,4- dioxane 180g, peanut oil 10g, loses
Water Span polyoxyethylene ether 100g, ethoxy castor oil polyoxyethylene ether 50g, xanthan gum 3g, urea 50g,
Water complements to 1kg.
Preparation method:Above-mentioned isoxaflutole, Smetolachlor, peanut oil, sorbitan fatty acid ester are gathered
Oxyethylene group ether, ethoxy castor oil polyoxyethylene ether are mixed into homogeneous oil phase;Water, xanthan gum, urea are mixed into uniform water phase;
Under high velocity agitation, oil is added in water phase, forms the aqueous emulsion containing 45% active constituent of favorable dispersibility.
Embodiment 8 contains the aqueous emulsion of 60% active constituent
Formula:Isoxaflutole 5g, Smetolachlor 595g, oleic acid polyethylene glycol 400 ester or fatty alcohol polyoxy second
Alkene ether 30g, glyceryl monolaurate polyoxyethylene ether 40g, N-Methyl pyrrolidone 150g, xanthan gum 5g, urea 50g, water are mended
Enough to 1kg.
Preparation method:By above-mentioned isoxaflutole, Smetolachlor, oleic acid polyethylene glycol 400 ester or poly alkyl alcohol
Ethylene oxide ether, glyceryl monolaurate polyoxyethylene ether, N-Methyl pyrrolidone are mixed into homogeneous oil phase;Water, xanthan gum, urea
It is mixed into uniform water phase;Under high velocity agitation, water phase is added in oily phase, form favorable dispersibility contains 60% active constituent
Aqueous emulsion.
Embodiment 9 contains the oil-suspending agent of 10.8% active constituent
Formula:Isoxaflutole 80g, isopropyl methoxalamine 28g, alkylaryl polyoxyethylene poly-oxygen propylene aether 75g, fatty alcohol
Polyoxyethylene ether 50g, white carbon black 10g, soybean oil are mended to 1kg.
Preparation method:Using soybean oil as medium, by above-mentioned isoxaflutole, Acetochlor, alkylaryl polyoxyethylene polyoxy
Propylene ether, fatty alcohol polyoxyethylene ether, white carbon black are added the finely ground oil to get to 10.8% active constituent in sand milling kettle and suspend
Agent.
Embodiment 10 contains the oil-suspending agent of 10.8% active constituent
Formula:Isoxaflutole 8g, propisochlor 100g, fatty alcohol polyoxyethylene ether 100g, styryl phenyl polyoxy
Vinethene 50g, organobentonite 30g, methyl oleate are mended to 1kg.
Preparation method:Using methyl oleate as medium, by above-mentioned isoxaflutole, propisochlor, fatty alcohol polyoxyethylene ether,
Styryl phenyl polyoxyethylene ether, organobentonite are added finely ground to get outstanding to the oil of 10.8% active constituent in sand milling kettle
Floating agent.
Embodiment 11 contains the emulsifiable concentrate of 50% active constituent
Formula:By isoxaflutole 100g, S-metolachlor 400g, 1,4- dioxane 100g, cyclohexanone 200g, second
Oxygroup castor oil 50g, sorbitan fatty acid ester polyoxyethylene ether 200g, 1,2- propylene glycol 100g, polyvinyl alcohol 80g,
Water supplies 1000g.
Preparation method:Using water as medium, by above-mentioned isoxaflutole, S-metolachlor, Isosorbide-5-Nitrae-dioxane, hexamethylene
Ketone, ethoxy castor oil, sorbitan fatty acid ester polyoxyethylene ether are mixed and made into homogeneous oil phase, and water, 1,2- third is added
Glycol, polyvinyl alcohol contain the emulsifiable concentrate of 50% active constituent through high-shear emulsion machine high speed shear to obtain the final product.
The herbicidal effect comparative test of product and single dose by the following examples further illustrates the present invention.
The herbicidal composition of the invention of test example 1 is in the herbicidal effect in greenhouse and the comparative test of single dose
Using the herbicidal composition product of the method measurement experiment example 1-11 of potting to broadleaf weeds and standing grain in greenhouse
The preventive effect of undergraduate course weeds, and compared with single dose.
Test method:Test uses greenhouse pot culture method, and quantitative weed seed is sowed in disposable paper cup, is randomly divided into
Isoxaflutole group, acetamide-group herbicides group and test group carry out thinning, Mei Gezhi when 1.5~2 leaf phase after weeds are unearthed
Cup is selected and remain the more consistent weeds plant of 5 plants of growing ways and is cultivated, and periodically pours the aqueous solution of N, P, K compound fertilizer, to broad-leaved
Cauline leaf spraying treatment is carried out with crawler type crops sprayer when weeds length to 4~6 leaf phases, gramineae weed length to 2~5 leaf phase,
Isoxaflutole group sprays isoxaflutole single dose, acetamide-group herbicides group sprays acetamide-group herbicides single dose, test group sprays
The herbicidal composition product of test example 1-11 continues culture observation after spraying treatment, the herbicidal effect of each group is investigated after 20 days.
The results are shown in Table 1.
Preventive effect of the 1 embodiment composition pesticide of table to broadleaf weeds and gramineae weed
As can be seen from Table 1, compared with single dose, the composition pesticide of embodiment 1-11 is to weeds especially broad leaved weeds
Such as Commelina communis, the root of Beijing euphorbia, purslane preventive effect be significantly improved;Not only Pesticide use dosage significantly reduces, while agriculture
Drug composition also has apparent synergistic effect to grass family class weeds such as barnyard grass, reaches while preventing and kill off broadleaf weeds and grass family is miscellaneous
The purpose of grass.
Claims (10)
1. a kind of composition pesticide, including isoxaflutole and component A, wherein component A is Smetolachlor, isopropyl first grass
One of amine, propisochlor are a variety of.
2. composition pesticide according to claim 1, it is characterised in that isoxaflutole and group in the composition pesticide
The weight ratio for dividing A is 1~99:99~1, preferably 1~20:20~1.
3. composition pesticide according to claim 1, it is characterised in that the composition pesticide further includes carrier, the load
Body be one of surfactant and/or auxiliary agent or a variety of, total weight of carrier account for composition pesticide percentage composition be 5%~
99.9%.
4. composition pesticide according to claim 3, it is characterised in that the surfactant includes emulsifier, dispersing agent
One or more of with wetting agent;The auxiliary agent includes solvent, cosolvent, antifreezing agent, suspending agent, thickener, capsule material, protection
One or more of agent, defoaming agent, bleeding agent;
Wherein, the emulsifier is phenethyl phenol polyoxyethylene polyoxy propylene ether, glyceryl monolaurate polyoxyethylene ether, benzene second
Alkenyl benzene phenol polyethenoxy ether, castor oil polyoxyethylene ether, ethoxy castor oil polyoxyethylene ether, alkyl phenol polyoxypropylene polyoxy
Vinethene, styryl phenyl polyoxyethylene ether, secondary octyl phenol polyethenoxy ether, nonylphenol polyoxyethylene ether, alkyl-diethyl two
Alcohol ether-sodium sulfonate, fatty acid polyethylene glycol ester, fast penetration enhancer T, styrylphenol formaldehyde resin PULLRONIC F68 are embedding
Segment type polyethers, sorbitan fatty acid ester polyoxyethylene ether, aliphatic alcohol polyoxyethylene sulfonate, polyoxyethylene alkylphenol
Formaldehyde condensation products, dodecyl sodium sulfonate calcium, decyl alcohol polyoxyethylene ether sulfosuccinic acid sodium, alkyl phenol polyoxyethylene ether, glycerol three
Laurate polyoxyethylene ether, two Bian xenyl polyoxyethylene ether, oleic acid polyethylene glycol 400 ester or fatty alcohol polyoxyethylene ether,
APES formaldehyde condensation product sodium sulphate, alkyl phenol polyoxyethylene ether succinate monoester sulfonate, alkyl phenol polyoxy
Ethylene phosphate, alkyl phenol polyoxyethylene ether sulfosuccinates, polyoxyethylene fatty acid rouge, polymethyl acrylate, polyoxy second
Alkene fatty amine, ethoxy castor oil, aliphatic acid polyethenoxy ether, polyoxyethylene aliphatic alcohol ether, alkylaryl polyoxyethylene polyoxy
One or more of propylene ether;
The dispersing agent is sodium methylene bis-naphthalene sulfonate, dispersing agent MF, polyvinylpyrrolidone, sulfomethylated lignin
Sour sodium, sodium metnylene bis-naphthalene sulfonate (dispersing agent NNO), alkamide taurine salt, calcium lignosulfonate, Sodium Polyacrylate, alkane
One or more of sodium salt and sodium methylene bis-naphthalene sulfonate formaldehyde condensation products of base naphthalene sulfonic acids condensation polymer;
The wetting agent is Negel, fatty alcohol polyoxyethylene ether, Teepol, lauryl sodium sulfate, ten
Dialkyl benzene sulfonic acids sodium, fatty alcohol polyglycol ether sulfate, nonylphenol polyoxyethylene ether, sorbitan fatty acid ester polyoxy
Vinethene, alkyl naphthalene formaldehyde condensation product, alkylnaphthalene sulfonate and anion wetting agent mixture;
The solvent includes one or more of organic solvent, vegetable oil, mineral oil, solvent naphtha or water;Specifically, described
Organic solvent includes N-Methyl pyrrolidone, tetrahydrofuran, dimethyl sulfoxide, N, N- dimethyldecamide, N, N- dimethyl methyl
Amide, tetrahydrofurfuryl alcohol, tributyl phosphate, dimethylbenzene, Isosorbide-5-Nitrae-dioxane or cyclohexanone;The vegetable oil be epoxidized soybean oil,
Soybean oil, peanut oil, rapeseed oil, castor oil, corn oil or pine-seed oil;The mineral oil is liquid wax, machine oil, kerosene or lubrication
Oil;The solvent naphtha is solvent naphtha No. 100, No. 150, No. 180 or No. 200;Above-mentioned solvent can also be used as cosolvent use;
The antifreezing agent includes one of ethylene glycol, 1,2- propylene glycol, ammonium sulfate, glycerol or urea or a variety of;
The thickener include xanthan gum, polyvinyl alcohol, polyethylene glycol, white carbon black, sodium alginate, aluminum magnesium silicate, lagoriolite,
Carboxymethyl cellulose, diatomite, kaolin or organobentonite emphasis are one or more;
The suspending agent is one in colloidal silicon dioxide, carboxymethyl cellulose (CMC), sodium alginate or sodium carboxymethylcellulose
Kind is a variety of;
The defoaming agent is one of organosiloxane, tributyl phosphate or silicone or a variety of.
5. composition pesticide described in -4 any claims according to claim 1, it is characterised in that the composition pesticide
Dosage form is missible oil, aqueous emulsion, emulsifiable concentrate, wettable powder, oil-suspending agent.
6. composition pesticide according to claim 5, it is characterised in that the group of the missible oil weight percent becomes:It is living
Property ingredient 0.1%~95%, emulsifier 0.5%~30%, cosolvent 0%~30%, solvent make-up to 100%;
The group of the aqueous emulsion weight percent becomes:Active constituent 0.1%~95%, emulsifier 0.5~30%, cosolvent
0%~30%, solvent 1%~30%, antifreezing agent 0%~20%, thickener 0.1%~5%, water are supplemented to 100%;
The group of the oil-suspending agent weight percent becomes:Active constituent 0.1%~95%, increases emulsifier 0.1%~30%
Thick dose 0.01%~30%, oil complement to 100%;
The group of the emulsifiable concentrate weight percent becomes:Active constituent 0.1%~95%, emulsifier 1%~20%, cosolvent
1%~30%, antifreezing agent 1%~20%, thickener 0.01%~5%, water is supplemented to 100%.
7. composition pesticide described in -4 any claims according to claim 1, it is characterised in that the composition pesticide can
To be provided in the form of finished product preparation, i.e., each substance has mixed in composition;It can also be provided with independent dosage form, before use
It is voluntarily mixed in bucket or tank, concentrate is usually mixed to get the concentration of required active material with water.
8. composition pesticide according to claim 5, it is characterised in that the composition is for preventing and kill off corn, beet, sweet
Annual and perennial broadleaf weeds and/or gramineae weed in sugarcane, orchard the crop fields.
9. composition pesticide according to claim 8, it is characterised in that the annual and perennial broadleaf weeds and standing grain
The weeds of undergraduate course weeds are:Piemarker, Siberian cocklebur, summer cypress, herba stellariae mediae, black nightshade, Veronica, datura, salsola collina, willow leaf thorn smartweed, lady's thumb,
Beggar-ticks, Amaranthus retroflexus, purslane, acalypha copperleaf, barnyard grass, herba eleusines indicae, shepherd's purse, smallflower galinsoga herb, Chenopodiaceae, small Chenopodiaceae, rat-tail amur foxtail, Bao Gai
Grass, herba digitariae, knucklegrass, millet, semen euphorbiae, herba setariae viridis, big herba setariae viridis grass.
10. composition pesticide described in -4 any claims according to claim 1, it is characterised in that the composition pesticide is also
It can be used in mixed way with the herbicide of other compound especially cauline leaf process with weeding, desinsection or bactericidal property, it can also
It is used in mixed way with nematicide, protective agent, growth regulator, nutrient for plants or soil conditioner.
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CN201710332335.7A CN108849928A (en) | 2017-05-12 | 2017-05-12 | The composition pesticide of isoxaflutole and its application |
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CN201710332335.7A CN108849928A (en) | 2017-05-12 | 2017-05-12 | The composition pesticide of isoxaflutole and its application |
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CN201710332335.7A Pending CN108849928A (en) | 2017-05-12 | 2017-05-12 | The composition pesticide of isoxaflutole and its application |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1131379A (en) * | 1994-08-01 | 1996-09-18 | 罗纳-普朗克农业有限公司 | New herbicidal compositions |
WO1997034486A1 (en) * | 1996-03-15 | 1997-09-25 | Rhone-Poulenc Agrochimie | Herbicidal compositions |
CN1213272A (en) * | 1996-03-15 | 1999-04-07 | 诺瓦提斯公司 | Herbicidal synergistic composition and method of weed control |
CN101773142A (en) * | 2010-02-25 | 2010-07-14 | 北京颖泰嘉和科技股份有限公司 | Herbicide composition containing glufosinate and oxadiazon and application thereof |
-
2017
- 2017-05-12 CN CN201710332335.7A patent/CN108849928A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1131379A (en) * | 1994-08-01 | 1996-09-18 | 罗纳-普朗克农业有限公司 | New herbicidal compositions |
WO1997034486A1 (en) * | 1996-03-15 | 1997-09-25 | Rhone-Poulenc Agrochimie | Herbicidal compositions |
CN1213272A (en) * | 1996-03-15 | 1999-04-07 | 诺瓦提斯公司 | Herbicidal synergistic composition and method of weed control |
CN101773142A (en) * | 2010-02-25 | 2010-07-14 | 北京颖泰嘉和科技股份有限公司 | Herbicide composition containing glufosinate and oxadiazon and application thereof |
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