CN103518739A - Herbicide containing topramezone and atrazine - Google Patents

Herbicide containing topramezone and atrazine Download PDF

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Publication number
CN103518739A
CN103518739A CN201310460550.7A CN201310460550A CN103518739A CN 103518739 A CN103518739 A CN 103518739A CN 201310460550 A CN201310460550 A CN 201310460550A CN 103518739 A CN103518739 A CN 103518739A
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China
Prior art keywords
atrazine
azoles humulone
benzene azoles
killer herbicide
weed killer
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Pending
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CN201310460550.7A
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Chinese (zh)
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王玉梅
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Individual
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Individual
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Priority to CN201310460550.7A priority Critical patent/CN103518739A/en
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Abstract

The invention relates to a herbicide containing topramezone and atrazine. The herbicide is a two-member herbicide composition with topramezone and atrazine as effective components, wherein the weight ratio of the effective component topramezone to the effective component atrazine is 1:15; the herbicide can be prepared into any allowed dosage forms in agriculture. The herbicide is used for preventing and removing weeds in corn fields, has significant synergic effect compared with alone application of the components, can broaden weed killing spectrum, reduces preventing and removing cost, retards generation of weed resistance, and has good safety to crops.

Description

A kind of weed killer herbicide that contains benzene azoles humulone and atrazine
Technical field
The present invention relates to a kind of herbicidal composition for Control Weeds in Maize Field, be specifically related to a kind of for preventing and kill off the weed killer herbicide that contains benzene azoles humulone and atrazine of corn field grassy weed, broad leaved weed.
Background technology
Corn is important cereal crops, is also important forage crop.In recent years, along with the development of the industries such as livestock breeding, food processing, wine-making industry and biodiesel, the market demand of corn constantly increases.China is the country that has throughout the year corn growth, North gets ,Nan Dao Hainan Province, Heilongjiang Province, has corn planting, and 2010 Annual planting areas reach 3,000 ten thousand hectares, is only second to paddy rice, wheat planting area.Continuous expansion along with maize sown area, nonirrigated farmland crop smothering also day by day expands, and in recent years, Chemical Weeding in Maize Field has become the important technical links of guaranteeing corn safety in production, but because drug of choice is improper or operation technique is not in place, control efficiency is undesirable or produce the phenomenons such as poisoning and occur repeatedly.Thereby medicinal herb grower just need to select a kind of high activity, herbicide wide ranges and the weed killer herbicide to plant height safety.
In use, atrazine dosage is large, and herbicide spectrum is wide not, poor to many grassy weed preventive effects, and its lasting period is longer, during large usage quantity, second stubble crop wheat and other broad leaf crops is had to certain influence.Benzene azoles humulone activity is high, and consumption is low, uses optimum period wide after seedling, uses flexibly, and broad weed-killing spectrum, can prevent and kill off annual gramineous weed and broad leaved weed, but cost is high while using separately, is unfavorable for spread.Therefore, benzene azoles humulone, atrazine are carried out to rational mixture, to reach the object of synergy, reduction consumption and cost, expansion herbicide spectrum.
Summary of the invention
The object of this invention is to provide a kind of weed killer herbicide that contains benzene azoles humulone and atrazine that is applicable to corn field, can prevent and kill off grassy weed and can prevent and kill off broad leaved weed again, and can reduce medicament usage amount and to corn safety.
The present invention is achieved by the following technical solutions: a kind of weed killer herbicide that contains benzene azoles humulone and atrazine, and its active ingredient is benzene azoles humulone and atrazine, the weight ratio of described benzene azoles humulone and atrazine is: 1:15; Weight percentage in herbicidal composition is 80%, and surplus is one or more in the upper acceptable insecticides adjuvant of the agriculturals such as carrier, solvent, emulsifier, wetting agent, dispersant, thickener, defoamer, antifreezing agent.
According to different uses, need or applying environment, herbicidal composition of the present invention can be prepared into any formulation allowing in multi-form agricultural by conventional at present pesticide producing mode, and herbicidal composition most preferred dosage form of the present invention is oil suspending agent.
Benzene azoles humulone is benzoylpyrazole herbicides, after seedling, cauline leaf is processed, by root, seedling and leaf, absorb, in plant Xiang Ding, to base, be transmitted to meristematic tissue, suppress p-hydroxyl oxygen phenylacetone acid esters dual oxide enzyme (4-HPPL), suppress plastoquinone and indirectly suppress the biosynthesis of carotenoid, make chloroplast synthesize suppressed and dysfunction.Chlorophyllous oxidative degradation causes the susceptible weeds albefaction of germinateing, and follows growth inhibition, and under photosynthesis, its symptom of being injured is like chlorotic necrosis, and bleaching symptom appears in responsive target weeds after processing in 2~5 days, and in 14 days, plant is dead.Its broad weed-killing spectrum, prevents and kill off corn field annual gramineous weed and broad leaved weed effective, and the lasting period is long, normally uses crop safety.
Atrazine is selectivity inner-adsorption conduction-type herbicide, by root system and cauline leaf, is absorbed, and conducts to rapidly plant meristematic tissue and leaf portion, suppresses weeds photosynthesis, makes grass cutting blade flavescence, hungry dead.In the resistance crop bodies such as corn, medicament can be resolved into innocuous substance by corn ketolase, so to crop safety.Atrazine is water-soluble larger, has larger mobility in soil, easily by rain, is arrived compared with deep layer, causes some deep-rootedness weeds is had to inhibitory action.
In described insecticides adjuvant, carrier can be one or more in white carbon, kaolin, diatomite, bentonite, precipitated calcium carbonate, gypsum, attapulgite, soluble starch, urea, amine fertilizer, glucose, maltose, sucrose, citric acid, natrium carbonicum calcinatum, Carbon Dioxide hydrogen potassium, anhydrous sodium sulfate, anhydrous sodium bicarbonate, Anhydrous potassium carbonate, or other this area common carrier.
In described insecticides adjuvant, solvent can be one or more in water, benzene,toluene,xylene, methyl alcohol, ethanol, isopropyl alcohol, butanols, cyclohexanone, cyclohexanol, oxolane, tetrahydrofurfuryl alcohol, carrene, chloroform, dimethyl formamide, dioxane, 1-METHYLPYRROLIDONE, ethyl acetate, acetone, butanone, ether, epoxidized soybean oil, plant soybean oil, liquid wax, lubricating oil.
In described insecticides adjuvant, emulsifier can be phenethyl phenol polyethenoxy polyethenoxy ether, styryl fluosite PULLRONIC F68 block type polyethers, aliphatic acid polyethenoxy ether, dibenzyl xenyl APEO, glyceryl monolaurate APEO, styrylphenol polyoxyethylene ether, ethoxy castor oil APEO, alkyl phenol polyoxyethylene polyoxypropylene ether, secondary octyl phenol polyethenoxy ether, polyoxyethylene nonylphenol ether, aliphatic alcohol polyoxyethylene sulfonate, polyoxyethylene alkylphenol formaldehyde condensation products, dodecyl sodium sulfonate calcium, decyl alcohol polyoxyethylene ether sulfosuccinic acid sodium, alkylphenol polyoxyethylene succinate monoester sulfonate, alkylphenol-polyethenoxy phosphate, alkylphenol polyoxyethylene sulfosuccinates, one or more in fatty acid polyethylene glycol ester.
In described insecticides adjuvant, dispersant can be one or more in alkylnaphthalene sulfonate, polycarboxylate, sodium lignin sulfonate, sodium metnylene bis-naphthalene sulfonate, calcium lignosulfonate, Sodium Polyacrylate, alkyl naphthalene sulfonic acid condensation polymer sodium salt, sodium methylene bis-naphthalene sulfonate formaldehyde condensation products.
In described insecticides adjuvant, wetting agent is selected from one or more in Negel, lauryl sodium sulfate, Teepol, neopelex, fatty alcohol polyglycol ether sulphate, fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether, sorbitan fatty acid ester APEO, Fluhyzon formaldehyde condensation products, alkylnaphthalene sulfonate.
Thickener in described insecticides adjuvant can be xanthans, polyvinyl alcohol, sodium alginate, diatomite, starch, kaolin or organobentonite etc., can also be other conventional thickeners of this area.
Antifreezing agent in described insecticides adjuvant can be propane diols, ethylene glycol, glycerine or urea etc., can also be other conventional antifreezing agents of this area.
The weed killer herbicide that contains benzene azoles humulone and atrazine of the present invention is mainly used in Control Weeds in Maize Field, as lady's-grass, barnyard grass, green foxtail, eleusine indica, wild millet, hill wolf tail, difformed galingale herb, cyperus iria, kitchen garden, knotweed, lamb's-quarters, Siberian cocklebur, black nightshade, sandbur, piemarker, Thorn-Apple, amaranth, iron amaranth, amur foxtail etc., but be not limited to above-mentioned weeds.
The present invention has following beneficial effect: 1, herbicidal composition provided by the invention, show obvious synergistic effect, and the herbicidal effect of composition is significantly improved than single dose.Reduced pesticide cost and the adverse effect to ecotope, it applies huge Social benefit and economic benefit.2, this herbicidal composition adopts the use that is mixed of benzene azoles humulone and atrazine, this two components mechanism of action is different, benzene azoles humulone has made up the shortcoming that atrazine is low to grassy weed preventive effect and dosage is large, so there is wider herbicide spectrum and more excellent synergy control efficiency, only need just Control Weeds in Maize Field effectively of a drug, while not only using, to corn growth safety, also can delay or overcome the drug-fast generation of corn field weed, be conducive to agricultural synthesis and administer.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
Take 5% benzene azoles humulone, 75% atrazine, 3% Negel formaldehyde condensation products, 2% alkylphenol-polyethenoxy ichthyodin, 4% white carbon, 11% diatomite.The frequent regulation of above-mentioned raw materials, for the i.e. front mixing of method, air-flow crushing, the rear mixing of wetting powder, obtains described 80% benzene azoles humulone atrazine wetting powder.
Embodiment 2
Take 5% benzene azoles humulone, 75% atrazine, 4% alkylphenol polyoxyethylene phosphate, 3% alkylsulfonate, 1% ethylene glycol, 12% anhydrous sodium sulfate.The frequent regulation of above-mentioned raw materials is that high speed shear is disperseed, sand milling is pulverized, is in harmonious proportion for the method for suspending agent, obtains described 80% benzene azoles humulone atrazine suspending agent.
Embodiment 3
Take 5% benzene azoles humulone, 75% atrazine, 4% triphen ethyl-phenol polyoxy ethyl ether, 1% alkyl phenol polyoxy ethyl ether, 0.2% xanthans, 14.8% methyl oleate oil.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, after pulverizing, be in harmonious proportion, makes described 80% benzene azoles humulone atrazine oil suspending agent with sand mill sand milling.

Claims (5)

1. a weed killer herbicide that contains benzene azoles humulone and atrazine, is characterized in that, this weed killer herbicide contains benzene azoles humulone and two kinds of active ingredients of atrazine and usual auxiliaries, and the weight ratio of described active ingredient benzene azoles humulone and atrazine is: 1:15.
2. a kind of weed killer herbicide that contains benzene azoles humulone and atrazine according to claim 1, is characterized in that, active ingredient benzene azoles humulone and the mass percent of atrazine in herbicidal composition are 80%.
3. a kind of weed killer herbicide that contains benzene azoles humulone and atrazine according to claim 1, it is characterized in that, described usual auxiliaries is one or more in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, thickener, defoamer, antifreezing agent, disintegrant, binding agent, filler, filler, deionized water.
4. a kind of weed killer herbicide that contains benzene azoles humulone and atrazine according to claim 1, is characterized in that, can be mixed with the upper any formulation allowing of agricultural during described weed killer herbicide practical application.
5. according to a kind of weed killer herbicide that contains benzene azoles humulone and atrazine described in claim 1-4, it is characterized in that, this weed killer herbicide is used for preventing and kill off corn field weeds.
CN201310460550.7A 2013-10-08 2013-10-08 Herbicide containing topramezone and atrazine Pending CN103518739A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104521983A (en) * 2014-12-22 2015-04-22 京博农化科技股份有限公司 Topramezone-flurtamone weeding composition
CN104872162A (en) * 2015-05-15 2015-09-02 陕西上格之路生物科学有限公司 Topramezone-containing corn field weed control composition
CN105360140A (en) * 2015-11-25 2016-03-02 山东滨农科技有限公司 Corn field herbicide composition containing topramezone
CN105394053A (en) * 2015-11-25 2016-03-16 山东滨农科技有限公司 Herbicide composition containing topramezone and applied to corn fields
CN115363036A (en) * 2021-05-20 2022-11-22 四川利尔作物科学有限公司 Herbicide composition containing topramezone and application thereof
CN115918650A (en) * 2023-03-10 2023-04-07 山东德浩化学有限公司 Dispersible oil suspension containing topramezone and atrazine and preparation process and application thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104521983A (en) * 2014-12-22 2015-04-22 京博农化科技股份有限公司 Topramezone-flurtamone weeding composition
CN104872162A (en) * 2015-05-15 2015-09-02 陕西上格之路生物科学有限公司 Topramezone-containing corn field weed control composition
CN105360140A (en) * 2015-11-25 2016-03-02 山东滨农科技有限公司 Corn field herbicide composition containing topramezone
CN105394053A (en) * 2015-11-25 2016-03-16 山东滨农科技有限公司 Herbicide composition containing topramezone and applied to corn fields
CN115363036A (en) * 2021-05-20 2022-11-22 四川利尔作物科学有限公司 Herbicide composition containing topramezone and application thereof
CN115918650A (en) * 2023-03-10 2023-04-07 山东德浩化学有限公司 Dispersible oil suspension containing topramezone and atrazine and preparation process and application thereof

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