CN108823612A - A kind of inner hole of workpiece hard chrome electroplating solution and its electroplating technology - Google Patents

A kind of inner hole of workpiece hard chrome electroplating solution and its electroplating technology Download PDF

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Publication number
CN108823612A
CN108823612A CN201810706030.2A CN201810706030A CN108823612A CN 108823612 A CN108823612 A CN 108823612A CN 201810706030 A CN201810706030 A CN 201810706030A CN 108823612 A CN108823612 A CN 108823612A
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China
Prior art keywords
workpiece
inner hole
hard chrome
electroplating
current density
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CN201810706030.2A
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Chinese (zh)
Inventor
蒋卫红
曾鹏
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CHANGSHA DALISHEN HYDRAULIC ENGINEERING CO LTD
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CHANGSHA DALISHEN HYDRAULIC ENGINEERING CO LTD
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Priority to CN201810706030.2A priority Critical patent/CN108823612A/en
Publication of CN108823612A publication Critical patent/CN108823612A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/04Electroplating: Baths therefor from solutions of chromium
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/10Electroplating with more than one layer of the same or of different metals
    • C25D5/12Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
    • C25D5/14Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Electroplating And Plating Baths Therefor (AREA)

Abstract

The invention discloses a kind of inner hole of workpiece hard chrome electroplating solution, constitutive material includes H2SO4、CrO3And Cr3+, the H2SO4With CrO3Ratio is 0.8~1.2: 100;The present invention also provides a kind of inner hole of workpiece hard chrome electroplating technologies, include the following steps:(1) workpiece pre-treatment;(2) it preheats;(3) it anti-carves;(4) it activates;(5) chromium plating;(6) workpiece goes out slot and recovery and rinsing;(7) extension and polishing are unloaded;(8) it is electroplated for second;(9) inspection is handed over.A kind of inner hole of workpiece hard chrome electroplating solution and electroplating technology provided by the invention keep layers of chrome upper and lower side deposition velocity close, Cr after ingredient and the ratio adjustment of electroplating solution3+Formation speed relative drop, electroplating technology adjustment after, improve product quality, meet design requirement.

Description

A kind of inner hole of workpiece hard chrome electroplating solution and its electroplating technology
Technical field
The present invention relates to electroplating technology field, especially a kind of inner hole of workpiece hard chrome electroplating solution and its electroplating technology.
Background technique
Inner hole hard chrome electroplating technology currently on the market, there is also following disadvantages:(1) chamfer site has ingotism (chromium slag) or burn phenomenon;(2) hard chromium layers are in uneven thickness, since deposition velocity is uneven everywhere for inner hole.
SO in inner hole hard chrome electroplating solution currently on the market4 2-With Cro3Ratio is 1~2:100, accelerate Cr3+Life At SO4 2-Higher, covering power is poor, and formation tolerance dimension is big, and inner hole upper and lower side deposition velocity differs greatly, so that we are in life Produce the cost for not being able to and needing plus 40%, it is difficult to meet product design requirement.
Summary of the invention
The purpose of the present invention is to provide a kind of inner hole of workpiece hard chrome electroplating solution and its electroplating technology, electroplating solution at Divide with after ratio adjustment, keeps layers of chrome upper and lower side deposition velocity close, Cr3+Formation speed relative drop, electroplating technology adjustment after, Product quality is improved, design requirement is met.
The technical scheme is that:A kind of inner hole of workpiece hard chrome electroplating solution, constitutive material include H2SO4、CrO3With Cr3+, the H2SO4With CrO3Ratio is 0.8~1.2:100.
Preferably, the H2SO4、CrO3And Cr3+Ingredient be respectively 200~230g/L, 1.6~2.5g/L, 1~8g/L.
Preferably, the H2SO4、CrO3And Cr3+Ingredient be respectively 210 ± 10g/L, 1.6~2.5g/L, 5 ± 3g/L.
A kind of inner hole of workpiece hard chrome electroplating technology, includes the following steps,
(1) workpiece pre-treatment:Workpiece successively carry out it is inside and outside slightly wash, plate before inspection, fine purifiation oil removing, fill extension, electrochemical deoiling, clearly Water rinses pre-treatment;
(2) it preheats:Workpiece is placed in coating into slot and impregnates preheating;
(3) it anti-carves;After preheating, corresponding current density is inputted on control cabinet touch screen and is anti-carved, wherein electric current is close It spends and anti-carves time control and be suitable for;
(4) it activates:After anti-carving, corresponding current density is inputted on control cabinet touch screen and is activated, wherein electric current is close Degree and activation time control are being suitable for;
(5) chromium plating;Corresponding current density is inputted on control cabinet touch screen and carries out chromium plating, wherein current density, plating Time and the control of electroplating solution temperature are being suitable for;
(6) workpiece goes out slot and recovery and rinsing;Hanger hook is tangled with traveling crane band slowly to sling workpiece, after slinging out slot, The washing of level-one adverse current is respectively adopted, second level adverse current is washed, three-level adverse current washing carries out recovery and rinsing to workpiece;
(7) extension and polishing are unloaded;Workpiece and hanger are unloaded from winged bar, and uses and is directly thrown to manual polishing machine Light;
(8) it is electroplated for second;Corresponding current density is inputted on control cabinet touch screen and carries out chromium plating, and wherein electric current is close Degree, electroplating time and the control of electroplating solution temperature are being suitable for;
(9) inspection is handed over.
Preferably, 10min is preheated in the step (2).
Preferably, it is 15 ± 1A/dm that current density is anti-carved in the step (3)2, described to anti-carve the time as 30~90s.
Preferably, activation current density is 5 ± 0.5A/dm in the step (4)2, the activation time is 3~5min.
Preferably, chromium plating current density is 30 ± 1A/dm in the step (5)2, electroplating time 4h, electroplating solution temperature Degree control is at 57 ± 1 DEG C.
Preferably, started in the step (6) driving will be carried out respectively in workpiece transfer to rinsing bowl level-one adverse current washing, The washing of second level adverse current, three-level adverse current are washed, washing trough inner water adverse current.
Preferably, polishing wheel uses 120 mesh in the step (7).
Preferably, chromium plating current density is 30 ± 1A/dm in the step (8)2, electroplating time 6h, electroplating solution temperature Degree control is at 57 ± 1 DEG C.
Compared with prior art, the present invention has the advantages that:
(1) electroplating cost, energy saving are reduced;
(2) stablize layers of chrome upper and lower side deposition velocity;
(3) product quality is improved, design requirement is met.
Detailed description of the invention
Fig. 1 is the chromium plating deposition velocity schematic diagram of existing inner hole of workpiece each position.
Fig. 2 is the chromium plating deposition velocity schematic diagram of inner hole of workpiece each position of the invention.
Specific embodiment
With reference to the accompanying drawing and specific embodiment, the present invention will be further described.
As shown in Figure 1 to Figure 2, a kind of inner hole of workpiece hard chrome electroplating solution, constitutive material include H2SO4、CrO3And Cr3+, The H2SO4With CrO3Ratio is 0.8~1.2:100.
Preferably, H2SO4、CrO3And Cr3+Ingredient be respectively 200~230g/L, 1.6~2.5g/L, 1~8g/L.It is more excellent Ground, H2SO4、CrO3And Cr3+Ingredient be respectively 210 ± 10g/L, 1.6~2.5g/L, 5 ± 3g/L.
A kind of inner hole of workpiece hard chrome electroplating technology, includes the following steps,
(1) workpiece pre-treatment:Workpiece successively carry out it is inside and outside slightly wash, plate before inspection, fine purifiation oil removing, fill extension, electrochemical deoiling, clearly Water rinses pre-treatment;Specifically:
(1.1) cleaning solution using 15~25g/L of sodium hydroxide, 10~15ml/L of dish washing liquid, cleaning 3 are slightly washed inside and outside workpiece ~5 minutes;
(1.2) it is checked before plating
(1.21) process inspection:First confirm that whether plating piece is approved by preceding process inspection person;
(1.22) dimensional gaughing:Self-test is plated preceding size and is made a record;
(1.23) visual examination:The defects of being answered Ra < 0.2, smooth, non-threaded line, scratch, pit, the non-top gem of a girdle-pendant to rise by surfacing: The welding defects such as answer pore-free, pit, be mingled in all welding positions.The preceding technical requirements of plating should be met by plating surface roughness;
(1.24) inspection item should notify inspector or Production Supervisor at once if any exception, execute by handling suggestion;
(1.3) fine purifiation oil removing:After passed examination, oil water removal is stained with scouring pad and carefully wipes inner hole oral area, removes outer surface Greasy dirt;
(1.4) dress is hung:Corresponding frock clamp is selected according to specification of workpieces, frock clamp is using preceding reply conductive contact The oxide skin at position is cleared up, and work piece holder is considering the insulation of part and the installation of shielding using preceding reply;
(1.5) electrochemical deoiling:Degreasing powder carry out electrochemical deoiling, degreasing powder concentration be 50~75g/L, the oil removing time be 3~ 5min, except oil temperature is 55~65 DEG C;
(1.6) clear water rinses:10~15s is rinsed using cold water wash.
(2) it preheats:Workpiece is placed in coating into slot and impregnates preheating 10min.
(3) it anti-carves;After preheating, corresponding electric current is inputted on control cabinet touch screen according to (conveying cylinder is electroplated into parameter list) Density is anti-carved, wherein anti-carving current density is 15 ± 1A/dm2, anti-carving the time is 30~90s.
(4) it activates:After anti-carving, corresponding electric current is inputted on control cabinet touch screen according to (conveying cylinder is electroplated into parameter list) Density is activated, and wherein activation current density is 5 ± 0.5A/dm2, activation time is 3~5min.
(5) chromium plating;Inputted on control cabinet touch screen according to (conveying cylinder be electroplated into parameter list) corresponding current density into Row chromium plating, wherein chromium plating current density is 30 ± 1A/dm2, electroplating time 4h, the control of electroplating solution temperature is at 57 ± 1 DEG C.
Lifting/lowering is in staged, every 5min up/down current 5A/dm on electric current2To required electroplating current density.It preheats, is anti- Quarter, activation, chromium plating carry out in electroplating bath, and the temperature control of electroplating solution uses the installation temperature control on the inner wall of electroplating bath to fill Set (for example electric heater and temperature sensor, temperature sensor and control cabinet are electrically connected, and send temperature signal to control Cabinet, control cabinet and electric heater are electrically connected, control cabinet controls the unlatching of electric heater) it adjusts.Control cabinet, ammeter, electricity Heater, temperature sensor are using model conventional in the industry.
(6) workpiece goes out slot and recovery and rinsing;Hanger hook is tangled with traveling crane band slowly to sling workpiece;
After slinging out slot, the washing of level-one adverse current, two stage countercurrents will be carried out respectively by starting driving in workpiece transfer to rinsing bowl Washing, three-level adverse current are washed, and washing trough inner water adverse current carries out recovery and rinsing.
(7) extension and polishing are unloaded;Workpiece and hanger are unloaded from winged bar, and uses and is directly thrown to manual polishing machine Light, polishing wheel use 120 mesh.
(8) it is electroplated for second;Corresponding electric current is inputted on control cabinet touch screen according to (conveying cylinder is electroplated into parameter list) Density carries out chromium plating, and wherein chromium plating current density is 30 ± 1A/dm2, electroplating time 6h, the control of electroplating solution temperature 57 ± 1℃。
(9) inspection is handed over:Workpiece is examined to conform to quality requirements.
A kind of inner hole of workpiece hard chrome electroplating solution provided by the invention, has adjusted H2SO4With CrO3Ratio is 0.8~1.2: 100, SO4 2-Lower, covering power is good, and formation tolerance dimension is small, keeps layers of chrome upper and lower side deposition velocity close, Cr3+Formation speed Relative drop, specific Fig. 1 is the layers of chrome deposition velocity schematic diagram of existing inner hole of workpiece each position as shown in Figs. 1-2, wherein 0.25,0.27,0.27,0.29,0.33,0.26 be inner hole of workpiece each position deposition velocity, some places are high, some places It is low, cause salient point;And Fig. 2 be inner hole of workpiece each position of the present invention layers of chrome deposition velocity schematic diagram, wherein 0.25,0.25, 0.26,0.27,0.28,0.27 be inner hole of workpiece each position deposition velocity, deposition velocity is close, avoids salient point.
A kind of inner hole of workpiece hard chrome electroplating technology provided by the invention, it is final it is electroplated after workpiece product, have following Excellent performance characteristic:
(1) layers of chrome crystallize careful light smooth, no point, pit, peeling, peeling, piebald, chromium tumor machine locally without coating or Surface chromium-free layer etc. allows bad pinhole number and chromium eye number≤8Pc/m2, pin hole directly passes through≤0.3mm, do not concentrate and without feel;
(2) layers of chrome guarantees product size after plating, coating hardness >=800HV with a thickness of 0.14~0.17mm;
(3) layers of chrome thickness difference≤0.02mm.
The above embodiments are merely a preferred embodiment of the present invention, and cannot limit interest field of the invention with this, because This is still within the scope of the present invention according to modification, equivalent variations, improvement etc. made by scope of the present invention patent.

Claims (10)

1. a kind of inner hole of workpiece hard chrome electroplating solution, it is characterised in that:Its constitutive material includes H2SO4、CrO3And Cr3+, described H2SO4With CrO3Ratio is 0.8~1.2: 100.
2. a kind of inner hole of workpiece hard chrome electroplating solution according to claim 1, it is characterised in that:The H2SO4、CrO3With Cr3+Ingredient be respectively 200~230g/L, 1.6~2.5g/L, 1~8g/L.
3. a kind of inner hole of workpiece hard chrome electroplating solution according to claim 1, it is characterised in that:The H2SO4、CrO3With Cr3+Ingredient be respectively 210 ± 10g/L, 1.6~2.5g/L, 5 ± 3g/L.
4. a kind of inner hole of workpiece hard chrome electroplating technology, it is characterised in that:Include the following steps,
(1) workpiece pre-treatment:Workpiece successively carry out it is inside and outside slightly wash, plate before inspection, fine purifiation oil removing, fill extension, electrochemical deoiling, clear water and rush Wash pre-treatment;
(2) it preheats:Workpiece is placed in coating into slot and impregnates preheating;
(3) it anti-carves;After preheating, corresponding current density is inputted on control cabinet touch screen and is anti-carved, wherein current density and Anti-carving time control is being suitable for;
(4) it activates:After anti-carving, corresponding current density is inputted on control cabinet touch screen and is activated, wherein current density and Activation time control is suitable;
(5) chromium plating;Corresponding current density is inputted on control cabinet touch screen and carries out chromium plating, wherein current density, electroplating time And the control of electroplating solution temperature is being suitable for;
(6) workpiece goes out slot and recovery and rinsing;It tangles hanger hook with traveling crane band slowly to sling workpiece, after slinging out slot, respectively Recovery and rinsing is carried out to workpiece using the washing of level-one adverse current, the washing of second level adverse current, three-level adverse current washing;
(7) extension and polishing are unloaded;Workpiece and hanger are unloaded from winged bar, and uses and is directly polished to manual polishing machine;
(8) it is electroplated for second;Corresponding current density is inputted on control cabinet touch screen and carries out chromium plating, wherein current density, electricity It plates the time and the control of electroplating solution temperature is being suitable for;
(9) inspection is handed over.
5. a kind of inner hole of workpiece hard chrome electroplating technology according to claim 4, it is characterised in that:It is anti-in the step (3) Quarter current density is 15 ± 1A/dm2, described to anti-carve the time as 30~90s.
6. a kind of inner hole of workpiece hard chrome electroplating technology according to claim 4, it is characterised in that:It is living in the step (4) Galvanic current density is 5 ± 0.5A/dm2, the activation time is 3~5min.
7. a kind of inner hole of workpiece hard chrome electroplating technology according to claim 4, it is characterised in that:Plating in the step (5) Chromium current density is 30 ± 1A/dm2, electroplating time 4h, the control of electroplating solution temperature is at 57 ± 1 DEG C.
8. a kind of inner hole of workpiece hard chrome electroplating technology according to claim 4, it is characterised in that:It is opened in the step (6) Dynamic driving will carry out respectively the washing of level-one adverse current, second level in workpiece transfer to rinsing bowl countercurrently washing, three-level adverse current are washed, washing Trough inner water adverse current.
9. a kind of inner hole of workpiece hard chrome electroplating technology according to claim 4, it is characterised in that:It is thrown in the step (7) Halo uses 120 mesh.
10. a kind of inner hole of workpiece hard chrome electroplating technology according to claim 4, it is characterised in that:Plating in the step (8) Chromium current density is 30 ± 1A/dm2, electroplating time 6h, the control of electroplating solution temperature is at 57 ± 1 DEG C.
CN201810706030.2A 2018-06-29 2018-06-29 A kind of inner hole of workpiece hard chrome electroplating solution and its electroplating technology Pending CN108823612A (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN112226796A (en) * 2020-08-31 2021-01-15 江苏友富薄板科技有限公司 Chromium plating method for roller

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CN112226796A (en) * 2020-08-31 2021-01-15 江苏友富薄板科技有限公司 Chromium plating method for roller

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Application publication date: 20181116