CN108822708A - A kind of solvent-free elastic polyaspartic ester urea elastic floor coatings - Google Patents
A kind of solvent-free elastic polyaspartic ester urea elastic floor coatings Download PDFInfo
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- CN108822708A CN108822708A CN201810429179.0A CN201810429179A CN108822708A CN 108822708 A CN108822708 A CN 108822708A CN 201810429179 A CN201810429179 A CN 201810429179A CN 108822708 A CN108822708 A CN 108822708A
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- Prior art keywords
- component
- solvent
- elastic
- aspartic acid
- floor coatings
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/02—Polyureas
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The embodiment of the invention discloses a kind of solvent-free elastic polyaspartic ester urea elastic floor coatings, it is made of the component A and B component being mutually used in combination, wherein, component A is to be made of aspartate resin as matrix resin component, and B component is to be made of the prepolymer that the nco value that HMDI or IPDI is synthesized with end hydroxy polyether is 3-7% as host component.The characteristics of present invention uses resilient polyurea coating design scheme, on the one hand plays excellent polyurea materials elasticity, color inhibition, combines property easy for construction and material environmental-protecting performance.
Description
Technical field
The present invention relates to technical field of paint preparation, more particularly to a kind of solvent-free elastic polyaspartic ester urea elasticity
Floor coatings.
Background technique
Current conventional use of elastic terrace material has two major classes.One kind is preformed elastic PVC roll material, and another kind of is bullet
Property polyurethane coating.It is first to brush one layer of glue on the ground when PVC roll material site operation, then directly pastes PVC roll material
It goes to complete, construct very convenient, while PVC roll material itself can make the color and decorative pattern of various beauties during fabrication,
Decorative effect is fine.But then, PVC roll material is there is also some defects, and first, the body material polyvinyl chloride of PVC roll material
There are problems that plasticity is strong, poor flexibility, feel is bad, and second, polyvinyl chloride is easy jaundice discoloration, aging, even if indoor environment
PVC roll material is also easy to turn to be yellow, and causes apparent effect to be deteriorated, especially repairing area, and the color of new and old material is seriously inconsistent,
There are splicing seams in third, construction requirement is high, splices bad easily rise and rouses delamination, after time longer (3 years), handover
The slowly aging of the hot melt adhesive of seam leads to local crimping and plays drum problem.
The two-component or moisturecuring one-component coating that Elastic polyurethane is made of the pure and mild isocyanates of polyether polyols,
Elastic effect is good, comfortable foot feeling, but this kind of material product stability is not high, the reason is that raw material in air humidity and raw material itself
Moisture content is very sensitive, is easy to cause irregular foaming, causes construction to fail, while plasticizer, steric hindrance amine in system
Matter content is very high, there is larger smell and genotoxic potential, and this kind of material is usually applied to playing field terrace, few high-quality
This kind of material can reach and meet the standard for being applied to the higher occasion of environmental friendly indoors requirement such as hospital, classroom, aisle and want
It asks.
Therefore, the prior art need further to develop.
Summary of the invention
In view of the above technical problems, the embodiment of the invention provides a kind of solvent-free elastic polyaspartic ester urea elasticity
Floor coatings, to solve the problems, such as that existing elastic terrace material cannot meet weatherability, simplified construction and environmental requirement simultaneously.
A kind of solvent-free elastic polyaspartic ester urea elastic floor coatings, wherein by the component A that is mutually used in combination and
B component composition, wherein component A is to be made of aspartate resin as matrix resin component, B component for by HMDI or
The prepolymer that the nco value that IPDI is synthesized with end hydroxy polyether is 3-7% is constituted as host component.
The described solvent-free elastic polyaspartic ester urea elastic floor coatings, wherein the component A and B component
Active equivalents ratio is A：B=1:1.05~1.1.
The solvent-free elastic polyaspartic ester urea elastic floor coatings, wherein component A Mid-Heaven Gate aspartic acid ester
Resin is N, N'- (methylene two -4,1- hexamethylene diyl) two aspartic acid tetra-ethyl esters or component A Mid-Heaven Gate aspartic acid ester
Resin is by N, N'- (two -4,1- hexamethylene diyl of methylene) two aspartic acid tetra-ethyl esters and N, N'- (two -4,1- hexamethylene of methylene
Alkane diyl) two aspartic acids four butyl ester composition.
4, solvent-free elastic polyaspartic ester urea elastic floor coatings according to claim 3, feature exist
By mass in, component A Mid-Heaven Gate aspartic acid ester resin, including following component：
N, N'- (two -4,1- hexamethylene diyl of methylene) two aspartic acid tetra-ethyl esters：20~50；
Four butyl ester of N, N'- (two -4,1- hexamethylene diyl of methylene) two aspartic acid：0~30.
The described solvent-free elastic polyaspartic ester urea elastic floor coatings, wherein component A by mass, including
Following component：
The solvent-free elastic polyaspartic ester urea elastic floor coatings, wherein point of the end hydroxy polyether
Son amount is 2000-6000.
The described solvent-free elastic polyaspartic ester urea elastic floor coatings, wherein the B component by mass,
Including following component：
Wherein HMDI and IPDI content is not 0 simultaneously, and polyethers 5000 and polyethers 2000 are not 0 simultaneously.
Solvent-free elastic polyaspartic ester urea elastic floor coatings provided in an embodiment of the present invention, meet extremely low VOC
Volatilization, the environmental requirement without harmful heavy metal, without phthalic ester plasticizer and all kinds of bulky amines, have construction is simple
(can brush by hand), insensitive to construction environment humidity (90% or less humidity environment), moderate (Shao's A hardness 75- of hardness
90A) the characteristics of comfortable foot feeling, while by the design of construction technology, it can accomplish terrace beauty, Integral decoration effect after coating
It is excellent, and using aliphatic isocyanates as curing agent raw material components, yellowing resistance is good, and it is beautiful lasting, it is durable.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, art technology
Personnel's every other embodiment obtained without creative efforts, shall fall within the protection scope of the present invention.
The solvent-free elastic polyaspartic ester urea elastic floor coatings of the present invention are the painting of environment-friendly double-component elastic terrace
Material uses matrix resin component of the rate of drying in 30 minutes to 60 minutes aspartate resins as component A, mentions
For suitable operable time and physical strength.The prepolymer synthesized using HMDI, IPDI with end hydroxy polyether is as curing agent
Host component, i.e. B component main body are provided suitable elasticity and hardness, while avoiding the original being more toxic using HDI, TDI etc.
Material.
Wherein, the present invention selects aspartate resin N, N'- (methylene two -4,1- hexamethylene diyl) two asparagus fern ammonia
Sour tetra-ethyl ester and N, four butyl ester of N'- (methylene two -4,1- hexamethylene diyl) two aspartic acid, while suitable levelling is added
Agent, defoaming agent, water absorbing agent, pigments and fillers etc. are prepared into component A.
One or more copolyreaction of 3 functional groups and 2 functional groups of HMDI or IPDI and molecular weight 2000-6000,
Nco value is obtained in the prepolymer of 3-7%, as curing agent B component, by active equivalents ratio A when use：B=1:1.05~1.1.
Specifically, component A is by mass, it is formulated as follows：
B component by mass, is formulated as follows：
The present invention uses resilient polyurea coating design scheme.On the one hand play that polyurea materials elasticity is excellent, spy of color inhibition
Point combines property easy for construction and material environmental-protecting performance.
Below by the embodiment technical solution that the present invention is further explained.
Embodiment 1
Component A by mass, is formulated following (A1)：
B component curing agent synthetic method is as follows：
HMDI 20g is put into 250ml four-hole boiling flask, and 60 DEG C of constant temperature, 3 functions of molecular weight 5000 are added dropwise while stirring
Polyethers 90g, drips off for 2 hours, is then warming up to 80 DEG C and keeps the temperature 2 hours, and measurement nco value is down to 3.72 ± 0.1 qualifications.Solidified
Agent B1.
According to A1:B1=100:210 proportions use.
Embodiment 2
Component A by mass, is formulated following (A2)：
B component curing agent synthetic method is as follows：
IPDI 20g is put into 250ml four-hole boiling flask, and 60 DEG C of constant temperature, 2 functions of molecular weight 2000 are added dropwise while stirring
Polyethers 80g, drips off for 2 hours, is then warming up to 80 DEG C and keeps the temperature 2 hours, and measurement nco value is down to 4.20 ± 0.1 qualifications.Solidified
Agent B2.
According to A2:B2=100:180 proportions use.
Embodiment 3
Component A is formulated following (A3)：
B component curing agent synthetic method is as follows：
IPDI 12g is put into 250ml four-hole boiling flask, 60 DEG C of constant temperature, molecular weight is added dropwise in HMDI2.3g while stirring
2000 2 functional polyethers 5.7g, 5000 molecular weight, 3 official's polyethers 80g, drip off for 2 hours, are then warming up to 80 DEG C and keep the temperature 2 hours, survey
Determine nco value and is down to 3.0 ± 0.1 qualifications.Obtain curing agent B3.
According to A3:B3=100:260 proportions use.
Embodiment 4
Component A is formulated following (A4)：
B component curing agent synthetic method is as follows：
IPDI 4.9g is put into 250ml four-hole boiling flask, 60 DEG C of constant temperature, molecular weight is added dropwise in HMDI20g while stirring
5000 molecular weight, 3 official's polyethers 75.9g, drips off for 2 hours, is then warming up to 80 DEG C and keeps the temperature 2 hours, and measurement nco value is down to 6.0 ±
0.1 is qualified.Obtain curing agent B4.
According to A4:B4=100:130 proportions use.
Testing result is as follows：
It can be seen that the solvent-free elastic polyaspartic ester urea elastic floor coatings of the present invention from the above detection data.
Meet extremely low VOC volatilization, the environmental requirement without harmful heavy metal, without phthalic ester plasticizer and all kinds of bulky amines, and
It has the characteristics that the moderate comfortable foot feeling of hardness, while by the design of construction technology, terrace is beautiful, whole after can accomplishing coating
Body decorative effect is excellent, and using aliphatic isocyanates as curing agent raw material components, yellowing resistance is good, and beauty is held
Long, durable.
It, can according to the technique and scheme of the present invention and this hair it is understood that for those of ordinary skills
Bright design is subject to equivalent substitution or change, and all these changes or replacement all should belong to the guarantor of appended claims of the invention
Protect range.
Claims (7)
1. a kind of solvent-free elastic polyaspartic ester urea elastic floor coatings, which is characterized in that by the A group being mutually used in combination
Divide and B component forms, wherein component A is to be made of aspartate resin as matrix resin component, and B component is served as reasons
The prepolymer that the nco value that HMDI or IPDI is synthesized with end hydroxy polyether is 3-7% is constituted as host component.
2. solvent-free elastic polyaspartic ester urea elastic floor coatings according to claim 1, which is characterized in that institute
The active equivalents ratio for stating component A and B component is A：B=1:1.05~1.1.
3. solvent-free elastic polyaspartic ester urea elastic floor coatings according to claim 1, which is characterized in that A
Component Mid-Heaven Gate aspartic acid ester resin is N, N'- (methylene two -4,1- hexamethylene diyl) two aspartic acid tetra-ethyl esters or A
Component Mid-Heaven Gate aspartic acid ester resin is by N, N'- (two -4,1- hexamethylene diyl of methylene) two aspartic acid tetra-ethyl esters and N, N'-
Four butyl ester of (two -4,1- hexamethylene diyl of methylene) two aspartic acid composition.
4. solvent-free elastic polyaspartic ester urea elastic floor coatings according to claim 3, which is characterized in that A
Component Mid-Heaven Gate aspartic acid ester resin by mass, including following component：
N, N'- (two -4,1- hexamethylene diyl of methylene) two aspartic acid tetra-ethyl esters：20~50；
Four butyl ester of N, N'- (two -4,1- hexamethylene diyl of methylene) two aspartic acid：0~30.
5. solvent-free elastic polyaspartic ester urea elastic floor coatings according to claim 4, which is characterized in that A
Component by mass, including following component：
N, N'- (two -4,1- hexamethylene diyl of methylene) two aspartic acid tetra-ethyl esters：20~50；
Four butyl ester of N, N'- (two -4,1- hexamethylene diyl of methylene) two aspartic acid：0~30；
6. solvent-free elastic polyaspartic ester urea elastic floor coatings according to claim 1, which is characterized in that institute
The molecular weight for stating end hydroxy polyether is 2000-6000.
7. solvent-free elastic polyaspartic ester urea elastic floor coatings according to claim 6, which is characterized in that institute
State B component by mass, including following component：
Wherein HMDI and IPDI content is not 0 simultaneously, and polyethers 5000 and polyethers 2000 are not 0 simultaneously.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810429179.0A CN108822708A (en) | 2018-05-08 | 2018-05-08 | A kind of solvent-free elastic polyaspartic ester urea elastic floor coatings |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810429179.0A CN108822708A (en) | 2018-05-08 | 2018-05-08 | A kind of solvent-free elastic polyaspartic ester urea elastic floor coatings |
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| CN108822708A true CN108822708A (en) | 2018-11-16 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109705720A (en) * | 2018-12-30 | 2019-05-03 | 青岛海洋新材料科技有限公司 | A kind of polyurethane damping floor material and preparation method thereof |
| CN111440287A (en) * | 2020-04-24 | 2020-07-24 | 顺缔高新材料江苏有限公司 | Preparation method of epoxy floor spraying material |
| CN112852250A (en) * | 2021-01-12 | 2021-05-28 | 大厂金隅涂料有限责任公司 | Solvent-free quick coating floor material and preparation method thereof |
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| CN102925041A (en) * | 2012-10-19 | 2013-02-13 | 中华制漆（深圳）有限公司 | Terrace coating and preparation method thereof |
| CN103820014A (en) * | 2014-03-03 | 2014-05-28 | 深圳市威尔地坪材料有限公司 | Elastic waterproof polyurea coating as well as preparation method and application method thereof |
| CN107474712A (en) * | 2017-08-18 | 2017-12-15 | 深圳飞扬骏研新材料股份有限公司 | A kind of asparagus fern polyurea waterproof coating material of high intensity and preparation method thereof |
| CN107522845A (en) * | 2017-08-31 | 2017-12-29 | 深圳飞扬骏研新材料股份有限公司 | A kind of polyaspartic ester urea adhesive and its construction technology |
-
2018
- 2018-05-08 CN CN201810429179.0A patent/CN108822708A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925041A (en) * | 2012-10-19 | 2013-02-13 | 中华制漆（深圳）有限公司 | Terrace coating and preparation method thereof |
| CN103820014A (en) * | 2014-03-03 | 2014-05-28 | 深圳市威尔地坪材料有限公司 | Elastic waterproof polyurea coating as well as preparation method and application method thereof |
| CN107474712A (en) * | 2017-08-18 | 2017-12-15 | 深圳飞扬骏研新材料股份有限公司 | A kind of asparagus fern polyurea waterproof coating material of high intensity and preparation method thereof |
| CN107522845A (en) * | 2017-08-31 | 2017-12-29 | 深圳飞扬骏研新材料股份有限公司 | A kind of polyaspartic ester urea adhesive and its construction technology |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109705720A (en) * | 2018-12-30 | 2019-05-03 | 青岛海洋新材料科技有限公司 | A kind of polyurethane damping floor material and preparation method thereof |
| CN109705720B (en) * | 2018-12-30 | 2021-07-30 | 青岛海洋新材料科技有限公司 | Polyurethane damping terrace material and preparation method thereof |
| CN111440287A (en) * | 2020-04-24 | 2020-07-24 | 顺缔高新材料江苏有限公司 | Preparation method of epoxy floor spraying material |
| CN112852250A (en) * | 2021-01-12 | 2021-05-28 | 大厂金隅涂料有限责任公司 | Solvent-free quick coating floor material and preparation method thereof |
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Application publication date: 20181116 |