CN108813761A - PVC slip-proof glove and its production technology with open cells structure - Google Patents
PVC slip-proof glove and its production technology with open cells structure Download PDFInfo
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- CN108813761A CN108813761A CN201810456293.2A CN201810456293A CN108813761A CN 108813761 A CN108813761 A CN 108813761A CN 201810456293 A CN201810456293 A CN 201810456293A CN 108813761 A CN108813761 A CN 108813761A
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- slip
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- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 238000005516 engineering process Methods 0.000 title claims description 18
- 229920005989 resin Polymers 0.000 claims abstract description 40
- 239000011347 resin Substances 0.000 claims abstract description 40
- 239000000463 material Substances 0.000 claims abstract description 35
- 239000003381 stabilizer Substances 0.000 claims abstract description 22
- 229920001807 Urea-formaldehyde Polymers 0.000 claims abstract description 13
- 239000003094 microcapsule Substances 0.000 claims abstract description 13
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004014 plasticizer Substances 0.000 claims abstract description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 10
- 239000011575 calcium Substances 0.000 claims abstract description 10
- 239000011701 zinc Substances 0.000 claims abstract description 10
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 10
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims abstract description 9
- 229920000053 polysorbate 80 Polymers 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims abstract description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 88
- 239000004800 polyvinyl chloride Substances 0.000 claims description 88
- 238000003756 stirring Methods 0.000 claims description 65
- 239000007788 liquid Substances 0.000 claims description 52
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 27
- 239000004744 fabric Substances 0.000 claims description 14
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 238000007598 dipping method Methods 0.000 claims description 11
- 238000010792 warming Methods 0.000 claims description 11
- 229920000742 Cotton Polymers 0.000 claims description 8
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 7
- 206010011732 Cyst Diseases 0.000 claims description 6
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 claims description 6
- 239000011162 core material Substances 0.000 claims description 6
- 208000031513 cyst Diseases 0.000 claims description 6
- 229950011008 tetrachloroethylene Drugs 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229920000136 polysorbate Polymers 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- 238000010411 cooking Methods 0.000 description 3
- 238000009940 knitting Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002775 capsule Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0006—Gloves made of several layers of material
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
- A41D19/0058—Three-dimensional gloves
- A41D19/0065—Three-dimensional gloves with a textile layer underneath
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
Abstract
The invention discloses a kind of gloves with open cells structure PVC anti-slip material, wherein including：One glove body inner wall is covered with a glove interior layer, and the gloves outer layer uses open cells structure PVC anti-slip material, and the open cells structure PVC anti-slip material includes：PVC paste resin：25 parts；Plasticizer DOP：25 parts；Calcium zinc stabilizer：0.5 part；0.2 part of pigment；Dehydrated alcohol：18-25 parts；N-hexane：10-16 parts, urea-formaldehyde resin microcapsule：1-6 parts, Tween 80：2 parts.Outer layer of the present invention is porous structure, the slip-proof glove can be in its use, on the one hand increase the frictional force between grasping object by its coarse porous surface structure, on the other hand due to the foam structure of its surface open, make it that there is effect identical with sucker when contacting article, it can be increased in dry, wet structure adhesive force, to increase its antiskid effect.
Description
Technical field
The present invention relates to a kind of protective articles gloves more particularly to a kind of PVC slip-proof gloves with open cells structure
And its production technology.
Background technique
PVC leaching modeling gloves are impregnated using fingerprint and after using paste PVC resin and plasticizer and related auxiliary agent as raw material
Continuous high temperature plasticizing forming forms, and has many advantages, such as that at low cost, acid and alkali-resistance, comfortable feel, protection effect are good, is widely used in and builds
It builds, fishery, scientific research, the fields such as medical treatment.
However existing PVC glove surface is smooth, coefficient of friction is small, is easy to happen cunning in wearing gloves clawing thing product
It falls, to influence its using effect.Although gloves can be increased by increasing concave-convex antiskid particles in PVC glove surface
Antiskid effect, but on wet and slippery surface, the antiskid effect of this gloves is still poor.
Summary of the invention
The invention discloses a kind of PVC slip-proof gloves and its production technology with open cells structure, existing to solve
There is gloves coefficient of friction in technology small, the problem of skid resistance difference.
Above-mentioned purpose of the invention is achieved through the following technical solutions：
A kind of PVC slip-proof glove with open cells structure, wherein including：One glove body inner wall is covered with a gloves
Internal layer, the gloves outer layer use open cells structure PVC anti-slip material, and the open cells structure PVC anti-slip material includes：
PVC paste resin：25 parts；Plasticizer DOP：25 parts；Calcium zinc stabilizer：0.5 part；0.2 part of pigment；Dehydrated alcohol：18-25 parts；Just
Hexane：10-16 parts, urea-formaldehyde resin microcapsule：1-6 parts, Tween 80：2 parts.
PVC slip-proof glove as described above with open cells structure, wherein the glove interior layer is using coating PVC
Base fabric in the knitted interlining of resin.
The PVC slip-proof glove with open cells structure as described above, wherein the material of the PVC resin is：PVC
Paste resin：25 parts；Plasticizer DOP：20 parts；Calcium zinc stabilizer：0.5 part.
PVC slip-proof glove as described above with open cells structure, wherein base fabric uses cotton in the knitted interlining
Seamless knitted material.
The PVC slip-proof glove with open cells structure as described above, wherein the urea-formaldehyde resin microcapsule includes：
Cyst wall, core material, the core material use n-hexane and tetrachloro-ethylene, the volume ratio 1 of n-hexane and tetrachloro-ethylene:1, the cyst wall material
Material is Lauxite.
A kind of production technology of the PVC slip-proof glove with open cells structure, wherein step 1：Prepare the PVC of liquid
It is spare that resin is put into the first hopper；
Step 2：The open cells structure PVC anti-slip material of liquid is prepared, including：25 parts of DOP is added in a stirring kettle
Stirring puts into the PVC paste resin of 25 powder, then 0.5 part of calcium zinc stabilizer is added into stirred tank, continues stirring to feed liquid temperature
Stop stirring after being warming up to set temperature, 18-25 parts of dehydrated alcohol, 10- is added into feed liquid after feed liquid is cooled to room temperature
16 parts of n-hexane and 2 parts of Tween 80 stop after carrying out eccentric stirring, the 1-6 parts of micro- glue of Lauxite are added into feed liquid
Continuing to stir after capsule, is completing that material is put into stand for standby use in the second hopper after stirring；
Step 3：The polyvinyl chloride resin that the fingerprint for being cased with base fabric in knitted interlining is immersed to liquid carries out first time dipping, plasticizing；
Step 4：The fingerprint for completing to impregnate, be plasticized for the first time is put into the open cells structure PVC anti-slip material of liquid
In, carry out secondary dipping, plasticizing；
Step 5：It will complete second of fingerprint cooling, the demoulding for impregnating, being plasticized.
The production technology of PVC slip-proof glove as described above with open cells structure, wherein preparation solution in step 2
The open cells structure PVC anti-slip material of state specifically includes：25 parts of DOP is added in a stirring kettle, opens stirring, revolving speed is
Then 1000-1100r/min puts into the PVC paste resin of 25 powder, be added 0.5 part after high-speed stirred 15 minutes into stirred tank again
Calcium zinc stabilizer, continue stirring be warming up to 40 DEG C to feed liquid temperature after stop stirring, to feed liquid after feed liquid is cooled to room temperature
Middle addition 18-25 parts of dehydrated alcohol, 10-16 parts of n-hexane and 2 parts of Tween 80,1000r/min bias stir 25 points
Stop stirring after clock, stirs 10 minutes, be put under 200r/min revolving speed after 1-6 parts of urea-formaldehyde resin microcapsules are added into feed liquid
Stand for standby use in hopper.
The production technology of PVC slip-proof glove as described above with open cells structure, wherein in step 1, first
Drop of hanging down is carried out after secondary dipping, fingerprint is put into progress first time plasticizing in baking oven later, and being plasticized baking oven baking temperature for the first time is
170-190 DEG C, baking time 1min.
The production technology of PVC slip-proof glove as described above with open cells structure, wherein in step 2, second
Drop of hanging down is carried out after secondary dipping, fingerprint is put into baking oven carries out second of plasticizing later, and being plasticized baking oven baking temperature for the second time is
170-190 DEG C, baking time 15min.
The production technology of PVC slip-proof glove as described above with open cells structure, wherein preparation solution in step 1
The polyvinyl chloride resin of state includes：20 parts of DOP is added in a stirring kettle, opens stirring, then revolving speed 1000-1100r/min is thrown
The PVC paste resin for entering 25 powder is added 0.5 part of calcium zinc stabilizer into stirred tank again, continues to stir after high-speed stirred 15 minutes
Stop stirring after being warming up to 40 DEG C to feed liquid temperature.
In conclusion the slip-proof glove can be by adopting the above-described technical solution, outer layer of the present invention is porous structure
On the one hand it is in use, increase the frictional force between grasping object by its coarse porous surface structure, on the other hand due to it
The foam structure of surface open makes it have effect identical with sucker when contacting article, can increase it in dry, wet structure
Adhesive force, to increase its antiskid effect.
Specific embodiment
Following example is described further the present invention：
The invention discloses a kind of PVC slip-proof gloves with open cells structure, wherein including：One glove body inner wall
It is covered with a glove interior layer, gloves outer layer uses open cells structure PVC anti-slip material, open cells structure PVC anti-slip material
Including：PVC paste resin：25 parts；Plasticizer DOP：25 parts；Calcium zinc stabilizer：0.5 part；0.2 part of pigment；Dehydrated alcohol：18-25
Part；N-hexane：10-16 parts, urea-formaldehyde resin microcapsule：1-6 parts, Tween 80：2 parts.
Further, glove interior layer is using base fabric in the knitted interlining of coating polyvinyl chloride resin.Base fabric is that cotton is seamless in knitted interlining
Weave internal layer gloves.
Further, the material of polyvinyl chloride resin is：PVC paste resin：25 parts；Plasticizer DOP：20 parts；Calcium zinc stabilizer：
0.5 part.
Further, base fabric uses cotton seamless knitted material in knitted interlining.
Further, urea-formaldehyde resin microcapsule includes：Cyst wall, core material, core material use n-hexane and tetrachloro-ethylene, n-hexane
With the volume ratio 1 of tetrachloro-ethylene:1, cyst material is Lauxite.
A kind of production technology of the PVC slip-proof glove with open cells structure, wherein step 1：Prepare the PVC of liquid
It is spare that resin is put into the first hopper；
Step 2：The open cells structure PVC anti-slip material of liquid is prepared, including：25 parts of DOP is added in a stirring kettle
Stirring puts into the PVC paste resin of 25 powder, then 0.5 part of calcium zinc stabilizer is added into stirred tank, continues stirring to feed liquid temperature
Stop stirring after being warming up to set temperature, 18-25 parts of dehydrated alcohol, 10- is added into feed liquid after feed liquid is cooled to room temperature
16 parts of n-hexane and 2 parts of Tween 80 stop after carrying out eccentric stirring, the 1-6 parts of micro- glue of Lauxite are added into feed liquid
Continuing to stir after capsule, is completing that material is put into stand for standby use in the second hopper after stirring；
Step 3：The polyvinyl chloride resin that the fingerprint for being cased with base fabric in knitted interlining is immersed to liquid carries out first time dipping, plasticizing；
Step 4：The fingerprint for completing to impregnate, be plasticized for the first time is put into the open cells structure PVC anti-slip material of liquid
In, carry out secondary dipping, plasticizing；
Step 5：It will complete second of fingerprint cooling, the demoulding for impregnating, being plasticized.
Further, the open cells structure PVC anti-slip material that liquid is prepared in step 2 specifically includes：In a stirring kettle
25 parts of DOP is added, opens stirring, revolving speed is 1000-1100 r/min, then puts into the PVC paste resin of 25 powder, high-speed stirred
0.5 part of calcium zinc stabilizer is added after 15 minutes into stirred tank again, continues to stop after stirring is warming up to 40 DEG C to feed liquid temperature
18-25 parts of dehydrated alcohol, 10-16 parts of n-hexane and 2 parts is added in stirring after feed liquid is cooled to room temperature into feed liquid
Tween 80,1000r/min bias stir 25 minutes after stop stirring, into feed liquid be added 1-6 parts of urea-formaldehyde resin microcapsules after
It is stirred 10 minutes under 200r/min revolving speed, is put into stand for standby use in hopper.
Further, in step 1, drop of hanging down is carried out after impregnating for the first time, fingerprint is put into baking oven carries out for the first time later
Plasticizing, being plasticized baking oven baking temperature for the first time is 170-190 DEG C, baking time 1min.
Further, in step 2, drop of hanging down is carried out after second of dipping, fingerprint is put into baking oven carries out second later
Plasticizing, it is 170-190 DEG C that second, which is plasticized baking oven baking temperature, baking time 15min.
Further, the polyvinyl chloride resin of preparation liquid includes in step 1：20 parts of DOP is added in a stirring kettle, unlatching is stirred
It mixes, revolving speed 1000-1100r/min, the PVC paste resin of 25 powder is then put into, after high-speed stirred 15 minutes again into stirred tank
0.5 part of calcium zinc stabilizer is added, continues to stop stirring after stirring is warming up to 40 DEG C to feed liquid temperature.
Embodiment (one)
Open cells structure PVC anti-slip material includes：
PVC paste resin：25 parts；Plasticizer DOP：25 parts；Calcium zinc stabilizer：0.5 part；0.2 part of black pigment；Anhydrous second
Alcohol：22 parts；N-hexane：15 parts, urea-formaldehyde resin microcapsule：4 parts, Tween 80：2 parts.
The material of polyvinyl chloride resin is：PVC paste resin：25 parts；Plasticizer DOP：20 parts；Calcium zinc stabilizer：0.5 part；The needle
Knitting lining base fabric is the cotton seamless knitted internal layer gloves using the program-controlled braider production of Japan SHIMA SEIKI 13G.
The production technology of PVC slip-proof glove with open cells structure, includes the following steps：
1) internal layer PVC coat feed proportioning：20 parts of DOP is added in a stirring kettle, opens stirring, revolving speed 1000-
Then 1100r/min puts into the PVC paste resin of 25 powder, 0.5 part of calcium zinc is added after high-speed stirred 15 minutes into stirred tank again
Stabilizer continues to stop stirring after stirring is warming up to 40 DEG C to feed liquid temperature, is put into stand for standby use in hopper.
2) feed proportioning of the PVC anti-slip layer with open cells structure：25 parts of DOP is added in a stirring kettle, opens
Then stirring, revolving speed 1000-1100r/min put into the PVC paste resin of 25 powder, again to stirred tank after high-speed stirred 15 minutes
The middle calcium zinc stabilizer for being added 0.5 part continues to stop stirring after stirring is warming up to 40 DEG C to feed liquid temperature, is cooled to room to feed liquid
22 parts of dehydrated alcohol, 15 parts of n-hexane and 2 parts of Tween 80, the stirring of 1000r/min bias are added in warm backward feed liquid
Stop stirring after 25 minutes, stirred 10 minutes under 200r/min revolving speed after 4 parts of urea-formaldehyde resin microcapsules are added into feed liquid,
It is put into stand for standby use in hopper.
3) single-steeping, plasticizing：The fingerprint for being cased with cotton knitting base fabric, which is put into 60 DEG C of baking ovens, to be preheated after ten minutes, in step
Single-steeping is carried out in rapid 1 feed liquid configured, enters oven cooking cycle after dipping, drop of hanging down；Baking temperature is 170-190 DEG C, is dried
Roasting time 1min；
4) double-steeping, plasticizing：To be impregnated through step 3, the fingerprint of plastics processing be put into the feed liquid that step 2 is configured into
Row double-steeping, at 80-90 DEG C, fingerprint enters oven cooking cycle after double-steeping, drop of hanging down for the temperature control of fingerprint before impregnating；
Baking temperature is 170-190 DEG C, baking time 15min；
5) it demoulds：After fingerprint leaves secondary plasticizing process, 50-60 DEG C of demoulding is naturally cooled in air.
Embodiment (two)
The material of polyvinyl chloride resin is：PVC paste resin：25 parts；Plasticizer DOP：20 parts；Calcium zinc stabilizer：0.5 part；Red face
0.2 part of material；Base fabric is the cotton seamless knitted internal layer using the program-controlled braider production of Japan SHIMA SEIKI 13G in knitted interlining
Gloves.
The production technology of PVC slip-proof glove with open cells structure, includes the following steps：
(1) PVC coat feed proportioning：20 parts of DOP is added in a stirring kettle, opens stirring, revolving speed 1000-
Then 1100r/min puts into the PVC paste resin of 25 powder, 0.5 part of calcium zinc is added after high-speed stirred 15 minutes into stirred tank again
Stabilizer continues to stop stirring after stirring is warming up to 40 DEG C to feed liquid temperature, is put into stand for standby use in hopper.
(2) it impregnates, be plasticized：The fingerprint for being cased with cotton knitting base fabric, which is put into 60 DEG C of baking ovens, to be preheated after ten minutes, in step
It impregnated in 1 feed liquid configured, enter oven cooking cycle after drop of hanging down；Baking temperature is 170-190 DEG C, baking time 15min；
(3) it demoulds：After fingerprint leaves plasticizing process, 50-60 DEG C of demoulding is naturally cooled in air.
Non-skid property test is carried out in glass surface to the leaching of PVC prepared by embodiment one and embodiment two modeling gloves, is surveyed
Try canonical reference GB10006-88.
Claims (10)
1. a kind of PVC slip-proof glove with open cells structure, which is characterized in that including：One glove body inner wall is covered with one
Glove interior layer, the gloves outer layer use open cells structure PVC anti-slip material, the open cells structure PVC anti-slip material
Including：PVC paste resin：25 parts；Plasticizer DOP：25 parts；Calcium zinc stabilizer：0.5 part；0.2 part of pigment；Dehydrated alcohol：18-25
Part；N-hexane：10-16 parts, urea-formaldehyde resin microcapsule：1-6 parts, Tween 80：2 parts.
2. the PVC slip-proof glove according to claim 1 with open cells structure, which is characterized in that in the gloves
Layer is using base fabric in the knitted interlining of coating polyvinyl chloride resin.
3. the PVC slip-proof glove according to claim 2 with open cells structure, which is characterized in that the polyvinyl chloride resin
Material be：PVC paste resin：25 parts；Plasticizer DOP：20 parts；Calcium zinc stabilizer：0.5 part.
4. the PVC slip-proof glove according to claim 2 with open cells structure, which is characterized in that the knitted interlining
In base fabric use cotton seamless knitted material.
5. the PVC slip-proof glove according to claim 1 with open cells structure, which is characterized in that the ureaformaldehyde tree
Grease microcapsule includes：Cyst wall, core material, the core material use n-hexane and tetrachloro-ethylene, the volume ratio of n-hexane and tetrachloro-ethylene
1:1, the cyst material is Lauxite.
6. a kind of production technology of the PVC slip-proof glove with open cells structure, which is characterized in that step 1：Prepare liquid
Polyvinyl chloride resin to be put into the first hopper spare；
Step 2：The open cells structure PVC anti-slip material of liquid is prepared, including：The DOP for being added 25 parts in a stirring kettle is stirred
It mixes, puts into the PVC paste resin of 25 powder, then 0.5 part of calcium zinc stabilizer is added into stirred tank, continue stirring to feed liquid temperature liter
Stop stirring after temperature to set temperature, 18-25 parts of dehydrated alcohol, 10-16 is added into feed liquid after feed liquid is cooled to room temperature
The n-hexane and 2 parts of Tween 80 of part stop after carrying out eccentric stirring, 1-6 parts of urea-formaldehyde resin microcapsules are added into feed liquid
Continuing to stir afterwards, is completing that material is put into stand for standby use in the second hopper after stirring；
Step 3：The polyvinyl chloride resin that the fingerprint for being cased with base fabric in knitted interlining is immersed to liquid carries out first time dipping, plasticizing；
Step 4：The fingerprint that will complete to impregnate, be plasticized for the first time is put into the open cells structure PVC anti-slip material of liquid, into
The secondary dipping of row, plasticizing；
Step 5：It will complete second of fingerprint cooling, the demoulding for impregnating, being plasticized.
7. the production technology of the PVC slip-proof glove according to claim 6 with open cells structure, which is characterized in that
The open cells structure PVC anti-slip material that liquid is prepared in step 2 specifically includes：25 parts of DOP is added in a stirring kettle, opens
Stirring is opened, then revolving speed 1000-1100r/min puts into the PVC paste resin of 25 powder, again to stirring after high-speed stirred 15 minutes
0.5 part of calcium zinc stabilizer is added in kettle, continues to stop stirring after stirring is warming up to 40 DEG C to feed liquid temperature, is cooled to feed liquid
18-25 parts of dehydrated alcohol, 10-16 parts of n-hexane and 2 parts of Tween 80,1000r/min is added after room temperature into feed liquid
Bias stirring stopped stirring after 25 minutes, stirred under 200r/min revolving speed after 1-6 parts of urea-formaldehyde resin microcapsules are added into feed liquid
It mixes 10 minutes, is put into stand for standby use in hopper.
8. the production technology of the PVC slip-proof glove according to claim 6 with open cells structure, which is characterized in that
In step 1, drop of hanging down is carried out after impregnating for the first time, fingerprint is put into progress first time plasticizing in baking oven later, plasticizing is dried for the first time
Case baking temperature is 170-190 DEG C, baking time 1min.
9. the production technology of the PVC slip-proof glove according to claim 6 with open cells structure, which is characterized in that
In step 2, drop of hanging down is carried out after second of dipping, fingerprint is put into baking oven be plasticized for the second time later, plasticizing is dried for the second time
Case baking temperature is 170-190 DEG C, baking time 15min.
10. the production technology of the PVC slip-proof glove according to claim 6 with open cells structure, which is characterized in that
The polyvinyl chloride resin of preparation liquid includes in step 1：20 parts of DOP is added in a stirring kettle, opens stirring, revolving speed 1000-
Then 1100r/min puts into the PVC paste resin of 25 powder, 0.5 part of calcium zinc is added after high-speed stirred 15 minutes into stirred tank again
Stabilizer continues to stop stirring after stirring is warming up to 40 DEG C to feed liquid temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810456293.2A CN108813761A (en) | 2018-05-14 | 2018-05-14 | PVC slip-proof glove and its production technology with open cells structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810456293.2A CN108813761A (en) | 2018-05-14 | 2018-05-14 | PVC slip-proof glove and its production technology with open cells structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108813761A true CN108813761A (en) | 2018-11-16 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109944079A (en) * | 2019-03-13 | 2019-06-28 | 嘉兴市博尔新材料有限公司 | A kind of wear-resisting, ageing-resistant PVC artificial leather |
| CN113402821A (en) * | 2021-04-27 | 2021-09-17 | 南京瑞润新材料科技有限公司 | Medical antibacterial gloves and preparation method thereof |
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| US20010011387A1 (en) * | 2000-01-31 | 2001-08-09 | Shinzo Yamashita | Method for producing rubber glove |
| JP2005076153A (en) * | 2003-09-01 | 2005-03-24 | Mie Kagaku Kogyo Kk | Method for producing non-slip processed glove |
| CN101361602A (en) * | 2007-08-10 | 2009-02-11 | 淄博蓝帆塑胶制品有限公司 | Color plastic rubber protection gloves and manufacturing method thereof |
| CN101564208A (en) * | 2009-06-01 | 2009-10-28 | 上海瑞斯达防护制品有限公司 | Anti-skid ventilation type back-open PVC hyperelastic protective glove |
| CN102430371A (en) * | 2011-08-25 | 2012-05-02 | 华东理工大学 | Urea-formaldehyde resin microcapsule material with capsule core half-filled structure and preparation method thereof |
| CN105666909A (en) * | 2016-02-29 | 2016-06-15 | 江苏杰盛手套有限公司 | Preparation method for environment-friendly plasticized polyvinyl chloride glove |
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| US20010011387A1 (en) * | 2000-01-31 | 2001-08-09 | Shinzo Yamashita | Method for producing rubber glove |
| JP2005076153A (en) * | 2003-09-01 | 2005-03-24 | Mie Kagaku Kogyo Kk | Method for producing non-slip processed glove |
| CN101361602A (en) * | 2007-08-10 | 2009-02-11 | 淄博蓝帆塑胶制品有限公司 | Color plastic rubber protection gloves and manufacturing method thereof |
| CN101564208A (en) * | 2009-06-01 | 2009-10-28 | 上海瑞斯达防护制品有限公司 | Anti-skid ventilation type back-open PVC hyperelastic protective glove |
| CN102430371A (en) * | 2011-08-25 | 2012-05-02 | 华东理工大学 | Urea-formaldehyde resin microcapsule material with capsule core half-filled structure and preparation method thereof |
| CN105666909A (en) * | 2016-02-29 | 2016-06-15 | 江苏杰盛手套有限公司 | Preparation method for environment-friendly plasticized polyvinyl chloride glove |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109944079A (en) * | 2019-03-13 | 2019-06-28 | 嘉兴市博尔新材料有限公司 | A kind of wear-resisting, ageing-resistant PVC artificial leather |
| CN113402821A (en) * | 2021-04-27 | 2021-09-17 | 南京瑞润新材料科技有限公司 | Medical antibacterial gloves and preparation method thereof |
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Application publication date: 20181116 |