CN107337966A - The preparation method and its footwear liner of a kind of impregnation footwear coordinate emulsion - Google Patents

The preparation method and its footwear liner of a kind of impregnation footwear coordinate emulsion Download PDF

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Publication number
CN107337966A
CN107337966A CN201710602201.2A CN201710602201A CN107337966A CN 107337966 A CN107337966 A CN 107337966A CN 201710602201 A CN201710602201 A CN 201710602201A CN 107337966 A CN107337966 A CN 107337966A
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China
Prior art keywords
emulsion
footwear
impregnation
coordinates
preparation
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CN201710602201.2A
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Chinese (zh)
Inventor
戴国达
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Century Special Protective Equipment Technology (jiangsu) Co Ltd
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Century Special Protective Equipment Technology (jiangsu) Co Ltd
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Priority to CN201710602201.2A priority Critical patent/CN107337966A/en
Publication of CN107337966A publication Critical patent/CN107337966A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/02—Copolymers with acrylonitrile
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00—Footwear characterised by the material
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00—Footwear characterised by the material
    • A43B1/10—Footwear characterised by the material made of rubber
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00—Footwear characterised by the material
    • A43B1/14—Footwear characterised by the material made of plastics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D107/00—Coating compositions based on natural rubber
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65—Salts of oxyacids of nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • D06N3/144—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethane and polymerisation products, e.g. acrylics, PVC
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc

Abstract

Coordinate emulsion and the preparation method of impregnation footwear the invention provides a kind of, the raw material proportioning of emulsion is coordinated by designing, cooperation emulsion is fully infiltrated into footwear liner, the impregnation footwear of preparation are light and handy, comfortable, anti-skidding, ventilative, wear-resisting.

Description

The preparation method and its footwear liner of a kind of impregnation footwear coordinate emulsion
Technical field
The invention belongs to shoes production field, and in particular to the preparation method and its footwear liner of a kind of impregnation footwear coordinate breast Liquid.
Background technology
Conventional shoe on the market is not suitable for wearing indoors at present, heavier, wears, de- inconvenience；In order to not by ash Dust lane enters interior, and shoe cover can be put by getting in sometimes, can influence the comfort of pin, also brings along handicapped；Summary Consider, JP sends out this impregnation footwear.
The content of the invention
In order to solve the above technical problems, the invention provides a kind of footwear liner to coordinate emulsion and the preparation method of impregnation footwear, Coordinate the raw material proportioning of emulsion by designing, cooperation emulsion is fully infiltrated into footwear liner, the impregnation footwear of preparation are light and handy, comfortable, anti- It is sliding, ventilative, wear-resisting.
A kind of footwear liner coordinates emulsion, and the footwear liner cooperation emulsion includes the raw material of following percentage by weight meter：
The percentage by weight sum of above each component is 100wt%.
The emulsion be NBR latex, styrene-butadiene latex, polychloroprene latex, Heveatex, polyaminoester emulsion, acrylic emulsion, Styrene-acrylic emulsion, PVC emulsions, vinylpyridine emulsion, styrene-butadiene emulsion, butylbenzene pyrrole emulsion, one kind in chlorosulfonated polyethylene emulsion or It is several.
The pH adjusting agent is the one or more in potassium hydroxide solution, ammoniacal liquor, triethanolamine, sodium hydroxide solution.
The surfactant be Aerosol OT, neopelex, nekal, One or more in dodecyl phenenyl sulfate, ferric tri-dodecanesulfonate.
The vulcanization accelerator is PZ, zinc diethyl dithiocarbamate, dibutyl One or more in zinc dithiocarbamate, TMTD, diphenylguanidine.
The vulcanization accelerator additive is the one or more in zinc oxide, stearic acid.
The antioxidant be antioxidant 2246, antioxidant 4426-s, antioxidant 264, antioxidant 1010, antioxidant 1706, One or more in antioxidant 300.
PH adjusting agent is added into latex by raw material proportioning, surfactant, sulphur, vulcanization accelerator, vulcanization promotion help Agent, antioxidant, pigment, cooperation emulsion is uniformly mixing to obtain, stands, then emulsion is got blisters and even bubble, then into emulsion Adding thickener thickens emulsion, obtains coordinating emulsion；
Preferably, the time of repose is more than 10h；
Preferably, it is described get blisters for：Gas is passed through to coordinating in emulsion, is got blisters；
Preferably, the gas flow that is passed through is：The 2~30% of bubbles volume control emulsion volume caused by making；
Preferably, thickener is added into emulsion makes the viscosity of emulsion increase to 100~10000mPas.
The preparation method of the impregnation footwear is：
(1) deployment and conjugation emulsion；
(2) footwear liner is placed on mould, after the pre-heat treatment, impregnation footwear inner bag is immersed into permeability-reducing admixture and preparation successively Cooperation emulsion in, footwear liner outer surface formed coating；
(3) on-slip, drying process are carried out to not solidified coating surface；
(4) impregnation footwear are obtained after gallbladder channel foam washing, vulcanization and demoulding processing in the impregnation footwear after step (3) processing.
Preferably, the preheating temperature is 40~60 DEG C, and preheating time is 10~30min；
Preferably, the permeability-reducing admixture is at least two in methanol, isopropanol, calcium nitrate, calcium chloride, glacial acetic acid or benzoic acid The mass ratio of the mixed solution of the mixed solution of composition, more preferably methanol and calcium nitrate, wherein methanol and calcium nitrate is 100:(1~5), more preferably 100:2；
Preferably, the air-dry time is 80~200s, more preferably 150s；
Preferably, the metacarpus of impregnation footwear inner bag is immersed in the macromolecule emulsion prepared.
Preferably, the temperature dried described in step (3) is 40~60 DEG C, and drying time is 10~30min；
Preferably, it is 60~120min to wash the time with bubble in step (4), and temperature is 40~60 DEG C；
Preferably, curing temperature is 100~120 DEG C in step (4), and cure time is 90~120min.
Obtained anti-skidding, ventilative, wear-resisting impregnation footwear.
In the preparation method of above-mentioned impregnation footwear, after dipping takes out, it can also be prevented on the footwear lining coating surface of footwear Sliding processing, it is anti-skidding to increase frictional force.
Impregnation footwear obtained above need to heat vulcanization.
Every double footwear liner impregnation depth are 20~300mm.
The footwear liner is that yarn braiding forms.
Compared with prior art, in the present invention, emulsion is coordinated to soak footwear liner using footwear liner of the present invention Glue, not only save material, environmental protection, reduce cost, and lightly, it is comfortable, anti-skidding, and improve the wearability of shoes, stickiness.
Embodiment
Embodiment 1：
A kind of preparation method of anti-skidding, ventilative, wear-resisting impregnation footwear is present embodiments provided, methods described process is as follows：
(1) deployment and conjugation emulsion：
KOH, neopelex, sulphur, diethyl are added into NBR latex by the raw material proportioning described in table 1 Zinc dithiocarbamate (ZDC), ZnO, antioxidant 2246, black pigment, are uniformly mixing to obtain cooperation emulsion, stand 18~ 20h, gas is then passed through into emulsion, is got blisters, make caused by bubbles volume control emulsion volume 2~30%, even bubble, then Sodium Polyacrylate is added into emulsion to be made emulsion be thickened to 800 ± 50mPas (to use rotor viscosimeter：No. 3 rotors, 60 rotating speeds Measurement), obtain coordinating emulsion；
Table 1：Macromolecule emulsion raw material proportioning table in embodiment 1
Composition Solid content (wt%) Percentage by weight (wt%)
NBR latex 45 82.5
KOH 5 0.8
Neopelex - 1.0
Sulphur - 1.0
ZDC - 0.5
ZnO - 2.5
Antioxidant 2246 - 1.0
Sodium Polyacrylate 7~10 5.0
Black pigment - 3.5
(2) footwear liner is placed on mould, 10~20min is preheated at 50~60 DEG C, then soak the permeability-reducing admixture (antiseepage Agent is the mixed solution of methanol and calcium nitrate, and wherein the mass ratio of methanol and calcium nitrate is 100:2) 110s or so, is air-dried, then Footwear liner is immersed in the cooperation emulsion prepared in step (1), forms coating；
(3) and then to coating surface carry out curing process (curing agent is the mixed solution of methanol and calcium nitrate, wherein The mass ratio of methanol and calcium nitrate is 100:10), then it is carried out at 45 DEG C and dries 15~20min, then with temperature is 45 DEG C Foam washing 80min is carried out to dried coating；
(4) the impregnation footwear after step (3) processing dry 35min at 85 DEG C, vulcanize 100min at 110 DEG C, then Impregnation footwear are obtained after the demoulding is handled.
Embodiment 2：
A kind of preparation method of anti-skidding, ventilative, wear-resisting impregnation footwear impregnation footwear is present embodiments provided, methods described process is such as Under：
(1) macromolecule emulsion is prepared：
KOH, neopelex, sulphur, dimethyl are added into Heveatex by the raw material proportioning described in table 2 Zinc dithiocarbamate, ZnO, antioxidant 2246, mineral black, cooperation emulsion is uniformly mixing to obtain, stands 12~16h, then Gas is passed through into emulsion, is got blisters, make caused by bubbles volume control emulsion volume 15~20%, even bubble, then to emulsion Middle addition Sodium Polyacrylate makes emulsion be thickened to 500 ± 50mPas (to use rotor viscosimeter：No. 3 rotors, 60 tachometric surveies), Obtain macromolecule and coordinate emulsion；
Table 2：Macromolecule emulsion raw material proportioning table in embodiment 2
Composition Solid content (wt%) Percentage by weight (wt%)
Heveatex 60 81
KOH - 0.5
Neopelex - 2.5
Sulphur - 0.5
ZDC - 1
ZnO - 2
Antioxidant 2246 - 1.5
Sodium Polyacrylate 7~10 5
Mineral black - 2
(2) impregnation footwear liner is placed on mould, 10~20min is preheated at 55~60 DEG C, it is (described then to soak permeability-reducing admixture Permeability-reducing admixture is the mixed solution of methanol and calcium nitrate, and wherein the mass ratio of methanol and calcium nitrate is 100:1) 80s or so, is air-dried, Then impregnation footwear liner is immersed in the cooperation emulsion prepared in step (1), forms coating；
(3) to the sodium sulfate crystal that not solidified coating surface sprinkling mesh number is 20~40 mesh, sodium chloride crystal, which absorbs, to be applied Moisture in layer, makes coating be solidified because of dehydration, is then carried out at 40 DEG C and dries 20min, then with temperature is 40 DEG C of hot water The sodium sulfate crystal of coating surface is dissolved into 60min；
(4) the impregnation footwear after step (3) processing dry 40min at 80 DEG C, vulcanize 120min at 100 DEG C, then Impregnation footwear are obtained after the demoulding is handled.
Embodiment 3：
A kind of preparation method of anti-skidding, ventilative, wear-resisting impregnation footwear impregnation footwear is present embodiments provided, methods described process is such as Under：
(1) macromolecule emulsion is prepared：
KOH, neopelex, sulphur, two are added into styrene-butadiene latex successively by the raw material proportioning described in table 3 Zine dimethyldithiocarbamate, ZnO, antioxidant 2246, mineral black, cooperation emulsion is uniformly mixing to obtain, stands 20~24h, Then gas is passed through into emulsion, is got blisters, make caused by bubbles volume control emulsion volume 10~15%, even bubble, then to Thickener is added in emulsion to be made emulsion viscosify to 900mPas (to use rotor viscosimeter：No. 3 rotors, 60 tachometric surveies), obtain Macromolecule coordinates emulsion；
Table 3：Macromolecule emulsion raw material proportioning table in embodiment 3
Composition Solid content (wt%) Percentage by weight (wt%)
Styrene-butadiene latex 58 70
KOH - 1
Neopelex - 3
Sulphur - 0.8
ZDC - 1.2
ZnO - 5
Antioxidant 2246 - 1.8
Sodium Polyacrylate 7~10 8
Black pigment - 3.6
(2) metacarpus of impregnation footwear liner is placed on mould, 10~20min is preheated at 50~60 DEG C, then soaks antiseepage (permeability-reducing admixture is the mixed solution of methanol and calcium nitrate, and wherein the mass ratio of methanol and calcium nitrate is 100 for agent:5), air-dry 120s or so, then impregnation footwear inner bag is immersed in the cooperation emulsion prepared in step (1), form coating；
(3) to the calcium nitrate crystal that not solidified coating surface sprinkling mesh number is 80~100 mesh, sodium chloride crystal, which absorbs, to be applied Moisture in layer, makes coating be solidified because of dehydration, is then carried out at 50 DEG C and dries 10min, then with temperature is 50 DEG C of hot water By the calcium nitrate dissolution of crystals 100min on polymeric coating layer surface；
(4) the impregnation footwear after step (3) processing dry 30min at 90 DEG C, vulcanize 90min, Ran Houjing at 120 DEG C Impregnation footwear are obtained after demoulding processing.
Embodiment 4：
A kind of preparation method of anti-skidding, ventilative, wear-resisting impregnation footwear is present embodiments provided, except coordinating breast in methods described The consumption proportion of liquid is that unclassified stores dosage is in the same manner as in Example 1 with preparation method shown in table 4, and Skidproof ventilated leaching is made Rubber overshoes product.
Table 4：Macromolecule emulsion raw material proportioning table in embodiment 4
Composition Solid content (wt%) Percentage by weight (wt%)
Polyaminoester emulsion 45 90
KOH - 0.3
Neopelex - 1
Sulphur - 0.5
ZDC - 0.3
ZnO - 2
Antioxidant 2246 - 1
Tea Saponin - 0.2
Citrate - 2.2
Sodium Polyacrylate 7~10 1.5
Black pigment - 1
As known by the technical knowledge, the present invention can pass through the embodiment party of other essence without departing from its spirit or essential feature Case is realized.Therefore, embodiment disclosed above, for each side, all it is merely illustrative, is not only.Institute Have within the scope of the present invention or be included in the invention in the change being equal in the scope of the present invention.

Claims (15)

1. a kind of preparation method of impregnation footwear, it is characterised in that the preparation method comprises the following steps：
(1) deployment and conjugation emulsion；
(2) footwear liner is placed on mould, after the pre-heat treatment, impregnation footwear inner bag is immersed into permeability-reducing admixture successively and matched somebody with somebody with what is prepared Close in emulsion, coating is formed in footwear liner outer surface；
(3) on-slip, drying process are carried out to not solidified coating surface；
(4) impregnation footwear are obtained after gallbladder channel foam washing, vulcanization and demoulding processing in the impregnation footwear after step (3) processing.
2. the preparation method of impregnation footwear according to claim 1, it is characterised in that 20~300mm of impregnation depth.
3. the preparation method of impregnation footwear according to claim 1, it is characterised in that the footwear liner is yarn, fiber volume Knit and form.
4. a kind of footwear liner coordinates emulsion, it is characterised in that the footwear liner coordinates emulsion to include following percentage by weight meter Raw material：
The percentage by weight sum of above each component is 100wt%.
5. footwear liner according to claim 4 coordinates emulsion, it is characterised in that the emulsion is NBR latex, butadiene-styrene rubber Breast, polychloroprene latex, Heveatex, polyaminoester emulsion, acrylic emulsion, styrene-acrylic emulsion, PVC emulsions, vinylpyridine emulsion, butylbenzene One or more in emulsion, butylbenzene pyrrole emulsion, chlorosulfonated polyethylene emulsion.
6. footwear liner according to claim 4 coordinates emulsion, it is characterised in that the pH adjusting agent is that potassium hydroxide is molten One or more in liquid, ammoniacal liquor, triethanolamine, sodium hydroxide solution.
7. footwear liner according to claim 4 coordinates emulsion, it is characterised in that the surfactant is that butanedioic acid two is different In dioctyl sodium sulfosuccinate, neopelex, nekal, dodecyl phenenyl sulfate, ferric tri-dodecanesulfonate One or more.
8. footwear liner according to claim 4 coordinates emulsion, it is characterised in that the vulcanization accelerator is DMDS It is blue for carbaminate, zinc diethyl dithiocarbamate, zinc dibutyl dithiocarbamate, tetramethyl curing autumn One or more in nurse, diphenylguanidine.
9. footwear liner according to claim 4 coordinates emulsion, it is characterised in that the vulcanization accelerator additive be zinc oxide, One or more in stearic acid.
10. footwear liner according to claim 4 coordinates emulsion, it is characterised in that the antioxidant is antioxidant 2246, resisted One or more in oxygen agent 4426-s, antioxidant 264, antioxidant 1010, antioxidant 1706, antioxidant 300.
11. footwear liner according to claim 4 coordinates emulsion, it is characterised in that the thickener is Silica hydrogel, fiber One or more in element, sodium carboxymethylcellulose, casein, gelatin or Sodium Polyacrylate.
12. footwear liner according to claim 4 coordinates emulsion, it is characterised in that the pigment is red pigment, yellow face One or more in material, viridine green, blue pigment or black pigment.
13. footwear liner according to claim 4 coordinates emulsion, it is characterised in that described footwear liner coordinates the system of emulsion Preparation Method is：
PH adjusting agent, surfactant, sulphur, vulcanization accelerator, vulcanization accelerator additive, anti-is added into latex by raw material proportioning Oxygen agent, pigment, cooperation emulsion is uniformly mixing to obtain, stands, then emulsion is got blisters and even bubble, then added and increase into emulsion Thick dose thickens emulsion, obtains coordinating emulsion；
The time of repose is more than 10h；
It is described get blisters for：Gas is passed through to coordinating in emulsion, is got blisters；
The gas flow that is passed through is：The 2~30% of bubbles volume control emulsion volume caused by making；
Thickener is added into emulsion makes the viscosity of emulsion increase to 100~10000mPas.
14. footwear liner according to claim 4 coordinates emulsion, it is characterised in that the preparation method of the impregnation footwear is：
(1) deployment and conjugation emulsion；
(2) footwear liner is placed on mould, after the pre-heat treatment, impregnation footwear inner bag is immersed into permeability-reducing admixture successively and matched somebody with somebody with what is prepared Close in emulsion, coating is formed in footwear liner outer surface；
(3) on-slip, drying process are carried out to not solidified coating surface；
(4) impregnation footwear are obtained after gallbladder channel foam washing, vulcanization and demoulding processing in the impregnation footwear after step (3) processing.
The preheating temperature is 40~60 DEG C, and preheating time is 10~30min；
The permeability-reducing admixture is the mixing of at least two compositions in methanol, isopropanol, calcium nitrate, calcium chloride, glacial acetic acid or benzoic acid Solution；
The air-dry time is 80~200s；
The metacarpus of impregnation footwear inner bag is immersed in the macromolecule emulsion prepared；
The temperature dried described in the step (3) is 40~60 DEG C, and drying time is 10~30min；
On-slip processing described in the step (3) is frosted, corrugation or solidification；
It is 60~120min to wash the time with bubble in the step (4), and temperature is 40~60 DEG C；
Curing temperature is 100~120 DEG C in the step (4), and cure time is 90~120min.
15. anti-skidding, ventilative, the wear-resisting impregnation footwear that the preparation method according to claim any one of 1-14 is prepared.
CN201710602201.2A 2017-07-21 2017-07-21 The preparation method and its footwear liner of a kind of impregnation footwear coordinate emulsion Pending CN107337966A (en)

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CN107857913A (en) * 2017-11-16 2018-03-30 广东泰强化工实业有限公司 A kind of water-based neoprene of stable storage and the storage method of water-based neoprene
CN109518469A (en) * 2018-11-09 2019-03-26 南通高桥体育用品有限公司 The preparation process of tire yarn gallbladder in a kind of sport ball

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CN105015140A (en) * 2015-08-06 2015-11-04 青岛天和清原科技有限公司 Degradable non-woven fabric glue dipping composite preparation technology and materials thereof
CN105199367A (en) * 2015-10-20 2015-12-30 南通强生安全防护科技有限公司 Water-based PU slurry and preparation method as well as application thereof
CN106072923A (en) * 2016-06-07 2016-11-09 东台世目防护用品有限公司 A kind of Skidproof ventilated Working gloves and preparation method thereof
CN106903935A (en) * 2017-02-27 2017-06-30 合肥中科富华新材料有限公司 A kind of shoe cover waterproof waterproof cloth and preparation method and application

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CN102863850A (en) * 2012-09-04 2013-01-09 福建农林大学 Disposable rain-proof antibacterial shoe covers and preparation method thereof
CN105015140A (en) * 2015-08-06 2015-11-04 青岛天和清原科技有限公司 Degradable non-woven fabric glue dipping composite preparation technology and materials thereof
CN105199367A (en) * 2015-10-20 2015-12-30 南通强生安全防护科技有限公司 Water-based PU slurry and preparation method as well as application thereof
CN106072923A (en) * 2016-06-07 2016-11-09 东台世目防护用品有限公司 A kind of Skidproof ventilated Working gloves and preparation method thereof
CN106903935A (en) * 2017-02-27 2017-06-30 合肥中科富华新材料有限公司 A kind of shoe cover waterproof waterproof cloth and preparation method and application

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CN109518469B (en) * 2018-11-09 2021-09-07 南通高桥体育用品有限公司 Preparation process of yarn liner of middle tire of sports ball

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