CN108807647A - A kind of manufacturing method of LED structure fluorescent film - Google Patents

A kind of manufacturing method of LED structure fluorescent film Download PDF

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Publication number
CN108807647A
CN108807647A CN201810614837.3A CN201810614837A CN108807647A CN 108807647 A CN108807647 A CN 108807647A CN 201810614837 A CN201810614837 A CN 201810614837A CN 108807647 A CN108807647 A CN 108807647A
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CN
China
Prior art keywords
fluorescent film
fluorescent
fluorescent powder
poured
color temperature
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Pending
Application number
CN201810614837.3A
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Chinese (zh)
Inventor
石岩
汪诗宇
庄一
陈亮
金尚忠
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China Jiliang University
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China Jiliang University
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Priority to CN201810614837.3A priority Critical patent/CN108807647A/en
Publication of CN108807647A publication Critical patent/CN108807647A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/50Wavelength conversion elements
    • H01L33/505Wavelength conversion elements characterised by the shape, e.g. plate or foil
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/50Wavelength conversion elements
    • H01L33/507Wavelength conversion elements the elements being in intimate contact with parts other than the semiconductor body or integrated with parts other than the semiconductor body
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2933/00Details relating to devices covered by the group H01L33/00 but not provided for in its subgroups
    • H01L2933/0008Processes
    • H01L2933/0033Processes relating to semiconductor body packages
    • H01L2933/0041Processes relating to semiconductor body packages relating to wavelength conversion elements

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Power Engineering (AREA)
  • Luminescent Compositions (AREA)

Abstract

The invention discloses a kind of preparation methods of LED structure fluorescent film, technical problem to be solved is to provide a kind of preparation method of structured fluorescent film, the method overcome existing technological deficiencies, pass through corresponding manufacture craft, the structured fluorescent film prepared is arranged in pairs or groups with array blue-light LED chip, the different luminous zone of two groups of colour temperatures can be obtained, regulated and controled by the current ratio to two groups of luminous zones, finally realize photochromic adjustable purpose.It is beneficial to the heat dissipation of LED using structured fluorescent film, is conducive to the consistency for improving LED product, is used cooperatively with array blue-light LED chip and can reach photochromic adjustable purpose.

Description

A kind of manufacturing method of LED structure fluorescent film
Technical field
The present invention relates to field of photoelectric technology, and in particular to a kind of LED structure fluorescence membrane preparation method.
Background technology
For a long time, white light LEDs receive people's concern, wherein photochromic adjustable LED is then the trend developed at present, for light Color is adjustable, and its maximum advantage realizes secondary energy-saving, and LED can be adjusted according to the physiology of people, the various situations such as psychology, People is given with the light environment of the most comfortable.Hereby it is achieved that it is photochromic accurate continuously adjustable, be conducive to the development in LED technology field.It passes The photochromic adjustable LED of system includes mainly 5 kinds of schemes:1, white light is generated by RGB monochromatic LED mixed lights;2, using multi-chip Integrated white light LED realizes adjustable color by chip portfolio and current regulation;3, by adjust white light LEDs, 3 blue-ray LEDs and Adjustable color is realized in the brightness of three branches of red-light LED;4, adjustable color is realized using white light and yellow light LED combination;5, by Low color temperature white light LED and high color temperature white light LEDs mixed light and brightness regulation realize adjustable color, i.e. changes in temperature white light colour mixture.However The above dimming mode is all the adjusting to LED progress colour temperature and brightness using the photochromic LED mixing of two or more differences, and with Raising photochromic mode, systematic comparison is complicated without exception, and integrated level is not high.
Current fluorescent film preparation process is that the fluorescent powder colloid formed is uniformly mixed with phosphor raw material by transparent colloid, Then it uses printing technology by fluorescent powder colloid even print in support light transmission grinding, and is thermally dried and fluorescence is made Film.But just current fluorescent film preparation process only accounts for solving light emission rate, luminous effect by preparing fluorescent film without exception The problems such as rate and uniformity, there is no consider the preparation process by fluorescent film finally to realize that LED light color is adjustable.
Invention content
For the above technical deficiency, technical problem to be solved by the present invention lies in provide a kind of system of structured fluorescent film Preparation Method, the method overcome existing technological deficiencies, by corresponding manufacture craft, the same battle array of structured fluorescent film prepared Row blue-light LED chip is arranged in pairs or groups, and the different luminous zone of two groups of colour temperatures can be obtained, and is regulated and controled by the current ratio to two groups of luminous zones, Finally realize photochromic adjustable purpose.
To solve the above-mentioned problems, the technical solution used in the present invention is:
A kind of manufacturing method of LED structure fluorescent film, it is characterised in that:Include the following steps:
(1)The transparent colloids such as the same epoxy resin of fluorescent powder original powder, silica gel are mixed, is hydrolyzed, is condensed chemical reaction, through old Gradually it polymerize between change micelle, forms fluorescent powder colloid;
(2)The fluorescent powder colloid prepared is poured into chessboard trellis structure mold, by the phosphor gel between each isolation Body obtains certain thickness fluorescent film using dry-pressing mode;
(3)It is finally dried, cures and be removed from the molds together with support transparent membrane, make structured fluorescent film.
Further, step(1)Described in the form of structured fluorescent film include a, two kinds of fluorescent powder alternating structures Fluorescent film, b, thickness structure fluorescent film.
Further, step(1)Used in fluorescent powder original powder be YAG yellow fluorescent powders, fluorescence original powder and transparent colloid The ratio of 1%-10% mixes.
Further, in step(2)Described in chessboard trellis structure mold include:Between the isolation of chessboard trellis(1)And support Transparent membrane(2);Wherein between the isolation of chessboard trellis(1)It is placed in support transparent membrane(2)Top, the two can fit closely;Chessboard Be length and width dimensions it is n × n between trellis isolation, is highly h, between a × a isolation, the length and width dimensions between being each isolated is equal for inside It is highly h for b × b, inner hollow between isolation is divided into high color temperature block region and low color temperature block region, and two groups between isolation Region is arranged alternately, and support transparent membrane length and width dimensions are m × m, and m >=n, thickness is g mm, supports transparent membrane and gridiron pattern Between shape isolation(1)It is bonded and can freely take out.
Further, two kinds of fluorescent powder alternating structure fluorescent films use following steps:It is prepared by two kinds Two kinds not the fluorescent colloid of concentration or different component be poured into respectively in chessboard trellis structure mold, by low concentration fluorescent powder colloid It is poured into high color temperature block region, phosphor concentration is a mol/L;High concentration fluorescent powder colloid is poured into low color temperature module Area, phosphor concentration are b mol/L, a<B is poured into the highly consistent of the fluorescent powder colloid of two groups of block regions.
Further, the thickness structure fluorescent film uses following steps:Fluorescent powder colloid is poured to chessboard trellis respectively In structure mold, prepared fluorescent powder colloid is poured into high color temperature block region, glimmering phosphor gel body liquid level is c Mm, by prepared fluorescent powder colloid is poured into low color temperature block region in advance, fluorescent powder colloid liquid level is d mm, low Fluorescent powder colloid height in colour temperature block region is higher than fluorescent powder colloid height in high color temperature block region, c>d.
The good effect that the present invention has on the basis of the above is:
1. a kind of LED structure fluorescence membrane preparation method provided by the invention, using structured fluorescent film far from LED chip surface Packaged type, far from LED chip heat source, ensure that the organic material of phosphor film layer will not be because of temperature compared with traditional handicraft The raising of degree and explain aging, improve the bloom efficiency of LED.
2. a kind of LED structure fluorescence membrane preparation method provided by the invention, with the identical a × a of quantity between same isolation A array blue-light LED chip sends out blue light excitation yellow light structure fluorescent film, generates the different white light area of two groups of colour temperatures, a high color Warm white light area and a low color temperature white light area control the current ratio in two groups of regions respectively, realize photochromic adjustable.
Description of the drawings
Fig. 1 is the chessboard trellis structure mold schematic diagram of the present invention.
Fig. 2 present invention makes the process flow chart of LED structure fluorescent film.
Fig. 3 is that invention prepares two kinds of fluorescent powder alternating structure fluorescent film schematic diagrames.
Fig. 4 is two kinds of fluorescent powder alternating structure fluorescent film schematic diagrames of the present invention.
Fig. 5 be the present invention prepare thickness structure fluorescent film schematic diagram.
Fig. 6 is the thickness structure fluorescent film schematic diagram of the present invention.
Specific implementation mode
In order to more fully understand the technology contents of the present invention, technical scheme of the present invention is made with reference to specific embodiment It is further described and illustrates.
As shown in Figure 1, a kind of chessboard trellis structure mold schematic diagram provided in this embodiment, including:Chessboard trellis is isolated Between 1, support transparent membrane 2;
1 is placed in 2 top of support transparent membrane wherein between the isolation of chessboard trellis, and the two can fit closely.
1 be length and width dimensions is n × n between the isolation of chessboard trellis, is highly h, and inside is between a × a isolation, between being each isolated Length and width dimensions be b × b, be highly h, isolation between inner hollow, high color temperature block region and low color will be divided between isolation Warm block region, and two groups of regions are arranged alternately, support 2 length and width dimensions of transparent membrane are m × m, and m >=n, thickness is g mm, support 1 is bonded and can freely take out between transparent membrane 2 can be isolated with chessboard trellis completely.
As shown in Fig. 2, the process flow chart provided in this embodiment for making LED structure fluorescent film, includes the following steps:
(1)The transparent colloids such as the same epoxy resin of fluorescent powder original powder, silica gel are mixed, is hydrolyzed, is condensed chemical reaction, through old Gradually it polymerize between change micelle, forms fluorescent powder colloid.
(2)The fluorescent powder colloid prepared is poured into above-mentioned chessboard trellis structure mold, between being each isolated in Fluorescent powder colloid certain thickness fluorescent film is obtained using dry-pressing mode.
(3)It is finally dried, cures and be removed from the molds together with support transparent membrane, make structured fluorescent Film.
As shown in figure 3, two kinds of fluorescent powder alternating structure fluorescent film schematic diagrames of preparation provided in this embodiment, two kinds are matched The fluorescence of the various concentration or different component that make is solidifying to be poured into respectively in chessboard trellis structure mold, by low concentration phosphor gel Body is poured into high color temperature block region, and phosphor concentration is a mol/L;High concentration fluorescent powder colloid is poured into low color temperature module Area, phosphor concentration are b mol/L (a<B), ensure the highly consistent of the fluorescent powder colloid for being poured into two groups of block regions, pass through It after dry-pressing, is finally dried, cures, fluorescent film will be attached on support transparent membrane, by support transparent membrane together with fluorescence Film takes out together, obtains two kinds of fluorescent powder alternating structure fluorescent films.
As shown in figure 4, two kinds of fluorescent powder alternating structures fluorescent film 3 provided in this embodiment, two kinds of fluorescent powders are alternately tied Structure fluorescent film 3 is attached to 2 on support transparent membrane, and the fluorescence that two groups of various concentrations or different component are presented is arranged alternately, point For high concentration region 31 and low concentration region 32, a × a array blue-light LED chip is divided into two groups, two groups of blue-light LED chip alternatings Arrangement excites high concentration region fluorescent film and low concentration region fluorescent film respectively, generates warm white warm area and cool white warm area, when respectively The current ratio for regulating and controlling Liang Ge different-colours area, realizes photochromic regulation and control.
As shown in figure 5, provided in this embodiment prepare thickness structure fluorescent film schematic diagram, fluorescent powder colloid is poured respectively It fills in chessboard trellis structure mold, prepared fluorescent powder colloid is poured into high color temperature block region, glimmering phosphor gel body fluid Face height is c mm, by prepared fluorescent powder colloid is poured into low color temperature block region, fluorescent powder colloid liquid level height in advance Degree is d mm, and the fluorescent powder colloid height in low color temperature block region is higher than fluorescent powder colloid height (c in high color temperature block region<D), After dry-pressing, be finally dried, cure, fluorescent film will be attached to support transparent membrane on, will support transparent membrane together with Fluorescent film takes out together, obtains thickness structure fluorescent film.
As shown in fig. 6, thickness structure fluorescent film 4 provided in this embodiment, fluorescent film thickness structure fluorescent film 4 attaches On support transparent membrane 2, the fluorescence that two groups of different-thickness are presented is arranged alternately, and is divided into high caliper zones 41 and low thickness area 42, A × a array blue-light LED chip is divided into two groups, two groups of blue-light LED chips are alternately arranged, and excite high caliper zones fluorescence respectively Film and low thickness area fluorescent film generate warm white warm area and cool white warm area, when the electric current for regulating and controlling Liang Ge different-colours area respectively Ratio realizes photochromic regulation and control.

Claims (6)

1. a kind of manufacturing method of LED structure fluorescent film, it is characterised in that:Include the following steps:
(1)The transparent colloids such as the same epoxy resin of fluorescent powder original powder, silica gel are mixed, is hydrolyzed, is condensed chemical reaction, through old Gradually it polymerize between change micelle, forms fluorescent powder colloid;
(2)The fluorescent powder colloid prepared is poured into chessboard trellis structure mold, by the phosphor gel between each isolation Body obtains certain thickness fluorescent film using dry-pressing mode;
(3)It is finally dried, cures and be removed from the molds together with support transparent membrane, make structured fluorescent film.
2. a kind of manufacturing method of LED structure fluorescent film according to claim 1, it is characterised in that:Step(1)Middle institute The form for the structured fluorescent film stated includes a, two kinds of fluorescent powder alternating structure fluorescent films, b, thickness structure fluorescent film.
3. a kind of manufacturing method of LED structure fluorescent film according to claim 2, it is characterised in that:Step(1)Middle institute Fluorescent powder original powder is YAG yellow fluorescent powders, the ratio mixing of fluorescence original powder and transparent colloid 1%-10%.
4. a kind of manufacturing method of LED structure fluorescent film according to claim 1, it is characterised in that:In step(2)In The chessboard trellis structure mold includes:Between the isolation of chessboard trellis(1)With support transparent membrane(2);Wherein chessboard trellis is isolated Between(1)It is placed in support transparent membrane(2)Top, the two can fit closely;Be length and width dimensions it is n × n between the isolation of chessboard trellis, height Degree is h, and inside is between a × a isolation, and the length and width dimensions between each isolation are b × b, are highly h, between isolation in inside Sky is divided into high color temperature block region and low color temperature block region between isolation, and two groups of regions are arranged alternately, and supports transparent membrane length and width Size is m × m, and m >=n, thickness is g mm, between support transparent membrane is isolated with chessboard trellis(1)It is bonded and can freely take out.
5. a kind of manufacturing method of LED structure fluorescent film according to claim 2, it is characterised in that:Described two kinds Fluorescent powder alternating structure fluorescent film uses following steps:The fluorescence of two kinds of prepared various concentrations or different component is coagulated and is divided It is not poured into chessboard trellis structure mold, low concentration fluorescent powder colloid is poured into high color temperature block region, phosphor concentration For a mol/L;High concentration fluorescent powder colloid is poured into low color temperature block region, phosphor concentration is b mol/L, a<B is poured Enter the highly consistent of the fluorescent powder colloid of two groups of block regions.
6. a kind of manufacturing method of LED structure fluorescent film according to claim 2, it is characterised in that:The thickness Structured fluorescent film uses following steps:Fluorescent powder colloid is poured respectively in chessboard trellis structure mold, it will be prepared glimmering Light arogel body is poured into high color temperature block region, and glimmering phosphor gel body liquid level is c mm, will prepared fluorescence in advance Arogel body is poured into low color temperature block region, and fluorescent powder colloid liquid level is d mm, the phosphor gel in low color temperature block region Body height is higher than fluorescent powder colloid height in high color temperature block region, c>d.
CN201810614837.3A 2018-06-14 2018-06-14 A kind of manufacturing method of LED structure fluorescent film Pending CN108807647A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111403573A (en) * 2020-03-27 2020-07-10 创维液晶器件(深圳)有限公司 L ED packaging structure and L ED packaging method
US11879607B2 (en) 2022-04-28 2024-01-23 Nichia Corporation Light-emitting device and manufacturing method thereof
CN118507607A (en) * 2024-07-16 2024-08-16 江西省兆驰光电有限公司 Fluorescent adhesive film and preparation method and application thereof

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CN103489991A (en) * 2013-09-27 2014-01-01 五邑大学 Partitioned COB LED fluorescent film with high color rendering
CN104752588A (en) * 2013-12-31 2015-07-01 晶能光电(江西)有限公司 Fluorescent glue coating method for flip chip
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Publication number Priority date Publication date Assignee Title
CN111403573A (en) * 2020-03-27 2020-07-10 创维液晶器件(深圳)有限公司 L ED packaging structure and L ED packaging method
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CN118507607A (en) * 2024-07-16 2024-08-16 江西省兆驰光电有限公司 Fluorescent adhesive film and preparation method and application thereof

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Application publication date: 20181113