CN108795245A - Oxygen wall covering is put in a kind of compression of novel environment friendly - Google Patents

Oxygen wall covering is put in a kind of compression of novel environment friendly Download PDF

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Publication number
CN108795245A
CN108795245A CN201810708096.5A CN201810708096A CN108795245A CN 108795245 A CN108795245 A CN 108795245A CN 201810708096 A CN201810708096 A CN 201810708096A CN 108795245 A CN108795245 A CN 108795245A
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CN
China
Prior art keywords
agent
wall covering
environment friendly
novel environment
oxygen wall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810708096.5A
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Chinese (zh)
Inventor
吴为天
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Changzhou Chao Dian Construction Technology Co Ltd
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Changzhou Chao Dian Construction Technology Co Ltd
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Publication date
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Priority to CN201810708096.5A priority Critical patent/CN108795245A/en
Publication of CN108795245A publication Critical patent/CN108795245A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/47Levelling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of compressions of novel environment friendly to put oxygen wall covering, and the metope water paint includes base's lotion, PE nano powders, blanc fixe, oil-removing cleaning agent, levelling agent, antifoaming agent, wetting agent, pH adjusting agent, fungicide, antifreezing agent, water and oxidant.Oxygen wall covering is put in novel environment friendly compression, design of material is more reasonable, it is more environmentally-friendly, the surface tension of the film of coating more balances, esters of acrylic acid levelling agent can not only promote flowing and the levelling of film, the ply adhesion of film is not interfered with also, and there is the effect defoamed, the use of modified poly ester wetting agent, by reducing its surface tension or interfacial tension, it allows the water to be deployed on solid material surface, or penetrate its surface, and solid material is soaked, it is mixed well convenient for plurality of raw materials in the water paint, the use of the potassium ferrate material of solid sheet, ensure that the coating has and puts oxygen function, it is more environmentally-friendly.

Description

Oxygen wall covering is put in a kind of compression of novel environment friendly
Technical field
The present invention relates to building material technical field, oxygen wall covering is put in specially a kind of novel environment friendly compression.
Background technology
Wall covering refer to be applied to metope rise protection, decoration material, be indispensable one in building and ornament materials Part.Wall covering can be divided into mud class, coating class, wallpaper, wall paper, artificial decoration plate, stone materials, ceramic-like, category of glass, gold Belong to class etc..
It is every with water as solvent or to make the coating of decentralized medium, it all can be described as water paint.According to adhesive in coating Classification, water paint are divided into two major classes:The natural water paint and artificial synthetic resin of natural materials or minerals) oil Chemical industry water paint.Water paint includes water soluble paint, water-reducible coating, 3 kinds of water-dispersible paint (latex paint).Water Soluble paint be using water-soluble resin as film forming matter, using polyvinyl alcohol and its various modifiers as representative, in addition to this also water Molten alkyd resin, water-soluble epoxy resin and inorganic polymer water-base resin etc., coating class belongs to one of wall covering of multiple types, Water paint is even more one kind important in numerous paint class wall covering, but existing water paint exists in actual use It is unreasonable design of material, the feature of environmental protection is poor;The surface tension of the film of coating is uneven, is easily reduced surface tension and influences The flowing of coating;Do not have the problem of function of putting oxygen.
Invention content
The purpose of the present invention is to provide a kind of compressions of novel environment friendly to put oxygen wall covering, to solve in above-mentioned background technology It is proposed that design of material is unreasonable, the feature of environmental protection is poor;The surface tension of the film of coating is uneven, is easily reduced surface tension and shadow Ring the flowing of coating;Do not have the problem of function of putting oxygen.
To achieve the above object, the technical solution of use is as follows by the present invention:
Oxygen wall covering is put in a kind of compression of novel environment friendly, it is characterised in that:Proportioning in the metope water paint is with matter Amount percentage is calculated as:Epoxy resin latex 30-60%, PE nano powder 10%-20%, blanc fixe 5%-10%, oil removing Cleaning agent 4%-8%, levelling agent 0.4%-0.8%, antifoaming agent 0.4%-0.8%, wetting agent 0.1%-0.6%, pH adjusting agent 0.2%-0.6%, fungicide 2%-6%, antifreezing agent 1%-5%, potassium ferrate particle 4%~8%;Surplus is deionized water.
Preferably, the novel environment friendly compression, which is put the proportioning in oxygen wall covering and is calculated in mass percent, is:Asphalt mixtures modified by epoxy resin Fat liquor 30-60%, PE nano powder 10%-20%, blanc fixe 5%-8%, oil-removing cleaning agent 4%-8%, levelling agent 0.5%-0.7%, antifoaming agent 0.5%-0.7%, wetting agent 0.1%-0.4%, pH adjusting agent 0.2%-0.5%, fungicide 3%-5%, antifreezing agent 1%-4%, potassium ferrate particle 5%~6%;Surplus is deionized water.
Further, the novel environment friendly compression, which is put the proportioning in oxygen wall covering and is calculated in mass percent, is:Epoxy Resin emulsion 40-50%, PE nano powder 10%-20%, blanc fixe 6%-7%, oil-removing cleaning agent 5%-7%, levelling agent 0.5%-0.6%, antifoaming agent 0.5%-0.6%, wetting agent 0.1%-0.4%, pH adjusting agent 0.2%-0.5%, fungicide 3%-5%, antifreezing agent 1%-3%, potassium ferrate particle 5%~6%;Surplus is deionized water.
Preferably, the levelling agent is esters of acrylic acid levelling agent.
Preferably, the antifoaming agent is Polyether Modified Polysiloxanes Defoaming Agent.
Preferably, the wetting agent is modified poly ester wetting agent.
Preferably, the fungicide can in coating common antiseptic ingredient, such as 1,2- benzisothiazoles- 3- ketone, isothiazolinone disinfecting agent etc..
Preferably, the antifreezing agent is dimethyl sulfoxide (DMSO) latex antifreezing agent.
Compared with prior art, the beneficial effects of the invention are as follows:Oxygen wall covering, design of material are put in novel environment friendly compression More rationally, more environmentally-friendly, the surface tension of the film of coating more balances, and esters of acrylic acid levelling agent can not only promote to apply The flowing of film and levelling do not interfere with the ply adhesion of film also, and also have the effect defoamed, foam can be prevented to aqueous The influence of coating improves the painting effect of coating;The use of modified poly ester wetting agent, by reducing its surface tension or interface Tension allows the water to be deployed on solid material surface, or penetrates its surface, and solid material is soaked, and is convenient for the water paint Middle plurality of raw materials mixes well, the use of the potassium ferrate material of solid sheet, it is ensured that the coating, which has, puts oxygen function, and energy Poisonous and hazardous volatile organic compounds in enough oxidation environments, it is more environmentally-friendly.
Specific implementation mode
Below will knot technical scheme in the embodiment of the invention is clearly and completely described is clearly and completely described, it is clear that described reality It is only a part of the embodiment of the present invention to apply example, instead of all the embodiments.Based on the embodiments of the present invention, this field is general The every other embodiment that logical technical staff is obtained without making creative work belongs to what the present invention protected Range.
The present invention is described in detail below in conjunction with specific embodiment:
Embodiment 1
Oxygen wall covering, epoxy resin latex 40%, PE nano powders 20%, blanc fixe are put in a kind of compression of novel environment friendly 6%, oil-removing cleaning agent 5%, levelling agent 0.6%, antifoaming agent 0.6%, wetting agent 0.4%, pH adjusting agent 0.4%, fungicide 3%, antifreezing agent 3%, deionized water 16%, potassium ferrate particle 5%.
Base's lotion is epoxy resin latex, and accounting 40% of the epoxy resin latex in metope water paint, than Example design is more reasonable, effectively raises the smearing quality of water paint and the feature of environmental protection of coating itself.
Levelling agent is esters of acrylic acid levelling agent, and flow control agent majority is line style resinous polymer, mainly there is acrylic acid Resin, Lauxite and melamine resin.The compatibility of these resins is limited in general system, they can be accumulated Gather to surface formed one layer of new resin film at, so that the surface tension of film is tended to balance, but they will not reduce surface tension, So not influencing the flowing of coating, esters of acrylic acid levelling agent can not only promote flowing and the levelling of film, not interfere with also The ply adhesion of film, and also have the effect defoamed.
Oil-removing cleaning agent selects Aksu BEROL 226SA oil-removing cleaning agents of Suzhou Yuan Tairun Chemical Co., Ltd.s.
Antifoaming agent is Polyether Modified Polysiloxanes Defoaming Agent, and organic silicon defoamer is by silicone grease, emulsifier, waterproofing agent, thickening Agent etc. is equipped with suitable quantity of water and is formed through machinery emulsification, its main feature is that surface tension is small, high surface activity, defoaming power is strong, and dosage is few, at This is low, has preferable thermal stability, can be used within the scope of 5 DEG C -150 DEG C broad temperature;Its chemical stability is preferable, difficult With other substance reactions, Polyether Modified Polysiloxanes Defoaming Agent is used in the water paint, foam can be prevented to water paint It influences, improves the painting effect of coating.
Wetting agent is modified poly ester wetting agent, and acting through for wetting agent reduces its surface tension or interfacial tension, make water It can be deployed on solid material surface, or penetrate its surface, and solid material is soaked, convenient for plurality of raw materials in the water paint Mix well.
Fungicide is isothiazolinone disinfecting agent, and isothiazolinone is mainly by the key by disconnecting bacterium and algae protein matter And play bactericidal effect.After isothiazolinone is contacted with microorganism, it promptly can irreversibly inhibit growth, so as to cause micro- The death of biological cell, therefore there is very strong inhibition and killing effect to common bacteria, fungi, algae etc., and then prevent micro- life Damage of the object to the coating and coating covering wall.
Antifreezing agent is dimethyl sulfoxide (DMSO) latex antifreezing agent, can prevent moisture in material from freezing, and ensures that coating is just under subzero temperature Often construction, reduces the freezing point of coating, makes the water paint that can be used when constructing during the cold season.
Oxidant is the potassium ferrate material of solid sheet, and the potassium ferrate material of the solid sheet is in the aqueous painting of metope Accounting in material is 5%, and potassium ferrate is sufficiently stable when state in 198 DEG C or less dry airs, is highly soluble in water into shallow Purplish red solution can decompose to give off oxygen after standing, and the alkalinity of solution increases with decomposition, quite steady in strong alkali solution Fixed, be fabulous oxidant has stronger oxidisability, it is ensured that the coating has with efficient disinfection than potassium permanganate It is standby to put oxygen function, it is more environmentally-friendly.
Embodiment 2
Oxygen wall covering, epoxy resin latex 50%, PE nano powders 10%, blanc fixe are put in a kind of compression of novel environment friendly 7%, oil-removing cleaning agent 7%, levelling agent 0.5%, antifoaming agent 0.5%, wetting agent 0.1%, pH adjusting agent 0.4%, fungicide 5%, antifreezing agent 1%, potassium ferrate particle 6% and deionized water 12.5%.
Comparative example 1:
Control 1 is selected from commercially available common interior wall coating;Control 2 is formulated
The performance comparison of the embodiment of the present invention 1,2 and control 1,2 is listed in table 1:
Table 1
Embodiment 1 Embodiment 2 Control 1
Hardness 3H 3H 2H
Washability (secondary) 2000 2000 600
Service life (year) 15~20 15~20 5~10
Put oxygen amount 0.04~0.05ml/m2 0.05~0.06ml/m2 0
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (8)

1. oxygen wall covering is put in a kind of novel environment friendly compression, it is characterised in that:Proportioning in the metope water paint is with quality Percentage is calculated as:Epoxy resin latex 30-60%, PE nano powder 10%-20%, blanc fixe 5%-10%, oil removing cleaning Agent 4%-8%, levelling agent 0.4%-0.8%, antifoaming agent 0.4%-0.8%, wetting agent 0.1%-0.6%, pH adjusting agent 0.2%-0.6%, fungicide 2%-6%, antifreezing agent 1%-5%, potassium ferrate particle 4% ~ 8%;Surplus is deionized water.
2. oxygen wall covering is put in a kind of novel environment friendly compression according to claim 1, it is characterised in that:The novel environment friendly Compression is put the proportioning in oxygen wall covering and is calculated in mass percent:Epoxy resin latex 30-60%, PE nano powder 10%- 20%, blanc fixe 5%-8%, oil-removing cleaning agent 4%-8%, levelling agent 0.5%-0.7%, antifoaming agent 0.5%-0.7%, Wetting agent 0.1%-0.4%, pH adjusting agent 0.2%-0.5%, fungicide 3%-5%, antifreezing agent 1%-4%, potassium ferrate Grain 5% ~ 6%;Surplus is deionized water.
3. oxygen wall covering is put in a kind of novel environment friendly compression according to claim 1, it is characterised in that:The novel environment friendly Compression is put the proportioning in oxygen wall covering and is calculated in mass percent:Epoxy resin latex 40-50%, PE nano powder 10%- 20%, blanc fixe 6%-7%, oil-removing cleaning agent 5%-7%, levelling agent 0.5%-0.6%, antifoaming agent 0.5%-0.6%, Wetting agent 0.1%-0.4%, pH adjusting agent 0.2%-0.5%, fungicide 3%-5%, antifreezing agent 1%-3%, potassium ferrate Grain 5% ~ 6%;Surplus is deionized water.
4. oxygen wall covering is put in a kind of novel environment friendly compression according to claim 1, it is characterised in that:The levelling agent is Esters of acrylic acid levelling agent.
5. oxygen wall covering is put in a kind of novel environment friendly compression according to claim 1, it is characterised in that:The antifoaming agent is Polyether Modified Polysiloxanes Defoaming Agent.
6. oxygen wall covering is put in a kind of novel environment friendly compression according to claim 1, it is characterised in that:The wetting agent is Modified poly ester wetting agent.
7. oxygen wall covering is put in a kind of novel environment friendly compression according to claim 1, it is characterised in that:The fungicide is Isothiazolinone disinfecting agent.
8. oxygen wall covering is put in a kind of novel environment friendly compression according to claim 1, it is characterised in that:The antifreezing agent is Dimethyl sulfoxide (DMSO) latex antifreezing agent.
CN201810708096.5A 2018-07-02 2018-07-02 Oxygen wall covering is put in a kind of compression of novel environment friendly Pending CN108795245A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109665797A (en) * 2019-01-25 2019-04-23 郑晓珊 A kind of energy conservation and environmental protection wall covering and its Preparation equipment

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102702907A (en) * 2012-06-22 2012-10-03 山东乐化漆业股份有限公司 Nanometer silicon wall paint for external wall
CN106189572A (en) * 2016-07-19 2016-12-07 芜湖昊轩环保新材料有限公司 Internal wall paint for cleaning room and preparation method thereof
CN107137742A (en) * 2017-05-05 2017-09-08 杨鹏 A kind of deodorizing method, deodorant
CN107903771A (en) * 2017-12-06 2018-04-13 佛山君帝环保科技有限公司 A kind of aqueous, environmental protective building coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102702907A (en) * 2012-06-22 2012-10-03 山东乐化漆业股份有限公司 Nanometer silicon wall paint for external wall
CN106189572A (en) * 2016-07-19 2016-12-07 芜湖昊轩环保新材料有限公司 Internal wall paint for cleaning room and preparation method thereof
CN107137742A (en) * 2017-05-05 2017-09-08 杨鹏 A kind of deodorizing method, deodorant
CN107903771A (en) * 2017-12-06 2018-04-13 佛山君帝环保科技有限公司 A kind of aqueous, environmental protective building coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109665797A (en) * 2019-01-25 2019-04-23 郑晓珊 A kind of energy conservation and environmental protection wall covering and its Preparation equipment

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Application publication date: 20181113