CN108794772A - A kind of hydrogel material preparation method for bionic fish bait - Google Patents
A kind of hydrogel material preparation method for bionic fish bait Download PDFInfo
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- CN108794772A CN108794772A CN201810705116.3A CN201810705116A CN108794772A CN 108794772 A CN108794772 A CN 108794772A CN 201810705116 A CN201810705116 A CN 201810705116A CN 108794772 A CN108794772 A CN 108794772A
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- 241000251468 Actinopterygii Species 0.000 title claims abstract description 41
- 239000011664 nicotinic acid Substances 0.000 title claims abstract description 25
- 239000000017 hydrogel Substances 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 20
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 15
- ODLHGICHYURWBS-LKONHMLTSA-N trappsol cyclo Chemical compound CC(O)COC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)COCC(O)C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1COCC(C)O ODLHGICHYURWBS-LKONHMLTSA-N 0.000 claims abstract description 9
- 239000012153 distilled water Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 14
- 241000212314 Foeniculum Species 0.000 claims description 12
- 235000004204 Foeniculum vulgare Nutrition 0.000 claims description 12
- 108010010803 Gelatin Proteins 0.000 claims description 12
- 241000206607 Porphyra umbilicalis Species 0.000 claims description 12
- 244000223014 Syzygium aromaticum Species 0.000 claims description 12
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 12
- 239000008273 gelatin Substances 0.000 claims description 12
- 229920000159 gelatin Polymers 0.000 claims description 12
- 235000019322 gelatine Nutrition 0.000 claims description 12
- 235000011852 gelatine desserts Nutrition 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 11
- 238000005507 spraying Methods 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000706 filtrate Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 6
- 238000004321 preservation Methods 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 206010001497 Agitation Diseases 0.000 claims description 5
- 229920000858 Cyclodextrin Polymers 0.000 claims description 5
- 241001417490 Sillaginidae Species 0.000 claims description 5
- 238000005703 Whiting synthesis reaction Methods 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 5
- 239000008280 blood Substances 0.000 claims description 5
- 210000004369 blood Anatomy 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000011010 flushing procedure Methods 0.000 claims description 5
- 238000004108 freeze drying Methods 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 238000004064 recycling Methods 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 2
- 235000014666 liquid concentrate Nutrition 0.000 claims description 2
- 238000009777 vacuum freeze-drying Methods 0.000 claims 1
- 230000008961 swelling Effects 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 230000009977 dual effect Effects 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract description 2
- 230000009182 swimming Effects 0.000 abstract description 2
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 230000000694 effects Effects 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 3
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 235000008504 concentrate Nutrition 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000001116 FEMA 4028 Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960004853 betadex Drugs 0.000 description 1
- 230000003592 biomimetic effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/075—Macromolecular gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K85/00—Artificial bait for fishing
- A01K85/01—Artificial bait for fishing with light emission, sound emission, scent dispersal or the like
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2489/00—Characterised by the use of proteins; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Environmental Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Animal Husbandry (AREA)
- Marine Sciences & Fisheries (AREA)
- Fodder In General (AREA)
- Feed For Specific Animals (AREA)
Abstract
The invention discloses a kind of hydrogel material preparation methods for bionic fish bait, it is interacted using fish scale, oyster shell whiting, hydroxypropyl-β-cyclodextrin, make that there is the oyster shell whiting of light-reflecting property to be adhered to fish scale surface, form dual reflective material, applied to bait, it on the one hand can be under irradiation by sunlight, send out star flash of light, play the role of that fish is attracted to pay attention to, rate is fished in raising on the other hand can be as the density and mechanical property of filler enhancing resulting materials, so that it is quickly submerged in water, avoids swimming in the water surface since density is too small；Hydrogel is applied to bionic fish bait field, hydrogel water absorption and swelling characteristic can be fully utilized, bait is dipped into water when fishing, the excellent swelling character of hydrogel material so that bionic fish bait rapidly expand by water suction, and surface is smooth wet viscous, fidelity is high, the self-healing properties of cooperation gained hydrogel, can achieve the purpose that recycle, cost-effective.
Description
Technical field
The invention belongs to bait preparing technical fields, and in particular to a kind of hydrogel material preparation side for bionic fish bait
Method.
Background technology
In order to improve the success rate fished, nowadays increasingly carrys out more people and begin to use Bionic fishing bait, Bionic fishing bait general
It is made of materials such as plastics or rubber, and synthetic bait available on the market is mostly by individual plastic casing and fish hook group
At, form is not stiff true to nature, and will not shine does not have food calling fragrance, thus cannot cause fish note that fishing effect is low, have
Bionic fishing bait in contain O-phthalic substance, have pollution to environment, do not meet yet environmental protection, sustainable development epoch
It is required that.
Invention content
In view of the above-mentioned problems, the present invention is intended to provide one kind can glisten, have food calling fragrance, form sense of touch true to nature, and
And it can be with the bionic fish bait hydrogel material preparation method of selfreparing after fishing damages.
The invention is realized by the following technical scheme：
A kind of hydrogel material preparation method for bionic fish bait is made of following steps：
（1）The fish scale of 10-15 recycling in parts by weight is rinsed with water totally, surface smut and watery blood is removed, is subsequently placed in
In 80-150 parts of dilute hydrochloric acid solutions, 10-30min is boiled, distilled water flushing 2-3 times after taking-up dries at 40-50 DEG C, uses ball milling
Fish scale is milled to a diameter of 100-500 μm of tablet by machine, is put it into blender, under the stirring of 300-400rpm,
Oyster shell whiting, the spraying of hydroxypropyl-β-cyclodextrin solution are sprayed, used time 3-5min is sprayed, is turned with 500-800rpm after spraying
Speed stirs 10-20min, is dried at 30-40 DEG C；
（2）3-5 parts of dried orange peels, 2-8 parts of laver ends, 1-2 portions of cloves, 3-4 parts of fennel powders are mixed into 5-10min in dry-mixed machine, so
It is transferred to afterwards in the distilled water of 20-30 times of its volume, 30-60min is boiled under 100-200rpm magnetic agitations, is filtered after filtering
Liquid concentrates the filtrate to original 1/2-1/3, then heats to 70-80 DEG C, appropriate amounts of gelatin is added thereto, be configured to concentration
It is cold at -40~-50 DEG C by acquired solution at -10~-15 DEG C after precooling 1-2h for the gelatin solution of 5-10mg/mL
Freeze 4-6h, the particle that grain size is 100-1000 μm is crushed to after freeze-drying；
（3）By step（1）Gains and step（2）Gains are dispersed in the distilled water of 30-100 times of its volume at 10-20 DEG C
In, using 40-60Hz, the ultrasonic wave added of 800-1500W disperses 10-30min, and 80-100 parts of acrylic acid and 1-2 parts are then added
Then ferric nitrate is cooled to 5-10 DEG C with the rotating speed stirring and dissolving 20-30min of 300-600rpm, raising speed to 800-1500rpm,
0.1-0.5 parts of ammonium persulfate initiators are added after stirring 1-2h, reduction of speed to 400-500rpm is stirred to react 3-5h, is subsequently poured into imitative
In the mold of raw bait, heat preservation stands 30-40h, demoulding.
Further, step（1）A concentration of 10-40% of dilute hydrochloric acid solution.
Further, step（1）The oyster shell whiting, hydroxypropyl-β-cyclodextrin solution are prepared as 10-20 parts of hydroxypropyls
Group-beta-cyclodextrin is dissolved in the water, and the solution of 30-60% is made, and 4-8 parts of oyster shell whitings, 5-10 parts of ethyl alcohol are then added, and utilizes
The supersound process 30-40min of 500-800W makes it be uniformly dispersed.
Further, step（2）The dried orange peel, laver end, cloves, fennel powder are true -10~-30 DEG C of dry-mixed preceding process
Vacuum freecing-dry processing, processing time 3-8h.
Beneficial effects of the present invention：The present invention is interacted using fish scale, oyster shell whiting, hydroxypropyl-β-cyclodextrin, makes to have
The oyster shell whiting of light-reflecting property is adhered to fish scale surface, forms dual reflective material, is applied to bait, on the one hand can be in sunlight
Under irradiation, star flash of light is sent out, plays the role of that fish is attracted to pay attention to, improves rate of fishing, on the other hand, filler can be used as to increase
The density and mechanical property of strong resulting materials avoid swimming in water since density is too small so that it can be quickly submerged in water
Face；By dried orange peel, laver end, cloves, fennel by rationally compounding, there is special fragrance, fish can be lured to rise to the bait, boiling carries
After taking, gelatin-compounded particle is made, can not only achieve the effect that sustained release, prolong the service life, while the presence of gelatin, also may be used
Using the strengthening part as resulting materials, the cross-link intensity and toughness of target hydrogel are improved；Hydrogel is applied to Biomimetic Fish
Hydrogel water absorption and swelling characteristic can be fully utilized, bait is dipped into water when fishing, hydrogel material by bait field
Excellent swelling character so that bionic fish bait rapidly expand by water suction, and surface is smooth wet viscous, and fidelity is high, cooperation gained water
The self-healing properties of gel can achieve the purpose that recycle, cost-effective；When preservation, hydrogel dehydration is reduced, not perishable
It is bad, and be easy to preserve.
Specific implementation mode
Illustrate the present invention with specific embodiment below, but is not limitation of the present invention.
Embodiment 1
A kind of hydrogel material preparation method for bionic fish bait is made of following steps：
（1）The fish scale of 10 recycling in parts by weight is rinsed with water totally, surface smut and watery blood is removed, is subsequently placed in 80 parts
In dilute hydrochloric acid solution, 10min is boiled, distilled water flushing 2 times after taking-up dry at 40 DEG C, are milled to fish scale directly with ball mill
The tablet that diameter is 100 μm, puts it into blender, under the stirring of 300rpm, spraying oyster shell whiting, hydroxy propyl-Beta-ring paste
Smart solution spraying, sprays used time 3min, stirs 10min with the rotating speed of 500rpm after spraying, is dried at 30 DEG C；
（2）3 parts of dried orange peels, 2 parts of laver ends, 1 portion of cloves, 3 parts of fennel powders are mixed into 5min in dry-mixed machine, are then transferred to its volume
In 20 times of distilled water, 30min is boiled under 100rpm magnetic agitations, filtrate is obtained after filtering, concentrates the filtrate to original 1/
2,70 DEG C are then heated to, appropriate amounts of gelatin is added thereto, is configured to the gelatin solution of a concentration of 5mg/mL, by acquired solution
At -10 DEG C after precooling 1h, 4h is freezed at -40 DEG C, and the particle that grain size is 100 μm is crushed to after freeze-drying；
（3）By step（1）Gains and step（2）Gains are dispersed at 10 DEG C in the distilled water of 30 times of its volume, are utilized
The ultrasonic wave added of 40Hz, 800W disperse 10min, and 80 parts of acrylic acid and 1 part of ferric nitrate is then added, and are stirred with the rotating speed of 300rpm
20min is dissolved, is then cooled to 5 DEG C, 0.1 part of ammonium persulfate initiator is added after stirring 1h in raising speed to 800rpm, and reduction of speed is extremely
400rpm is stirred to react 3h, is subsequently poured into the mold of bionic fish bait, and heat preservation stands 30h, demoulding.
Further, step（1）The dilute hydrochloric acid solution a concentration of 10%.
Further, step（1）The oyster shell whiting, hydroxypropyl-β-cyclodextrin solution are prepared as 10 parts of hydroxy propyl-Betas-
30% solution is made in water in cyclodextrin, and 4 parts of oyster shell whitings, 5 parts of ethyl alcohol are then added, utilize the supersound process of 500W
30min makes it be uniformly dispersed.
Further, step（2）The dried orange peel, laver end, cloves, fennel powder are cold in the vacuum of dry-mixed -10 DEG C of preceding process
Freeze and is dried, processing time 3h.
Embodiment 2
A kind of hydrogel material preparation method for bionic fish bait is made of following steps：
（1）The fish scale of 12 recycling in parts by weight is rinsed with water totally, surface smut and watery blood is removed, is subsequently placed in 110
In part dilute hydrochloric acid solution, 20min is boiled, and distilled water flushing 3 times after taking-up dry at 45 DEG C, fish scale are milled to ball mill
A diameter of 300 μm of tablet, puts it into blender, under the stirring of 350rpm, spraying oyster shell whiting, hydroxy propyl-Beta-ring
Dextrin solution is sprayed, and used time 4min is sprayed, and is stirred 15min with the rotating speed of 700rpm after spraying, is dried at 35 DEG C；
（2）4 parts of dried orange peels, 6 parts of laver ends, 2 portions of cloves, 4 parts of fennel powders are mixed into 7min in dry-mixed machine, are then transferred to its volume
In 25 times of distilled water, 40min is boiled under 150rpm magnetic agitations, filtrate is obtained after filtering, concentrates the filtrate to original 1/
3,75 DEG C are then heated to, appropriate amounts of gelatin is added thereto, is configured to the gelatin solution of a concentration of 7mg/mL, by acquired solution
At -12 DEG C after precooling 2h, 5h is freezed at -45 DEG C, and the particle that grain size is 500 μm is crushed to after freeze-drying；
（3）By step（1）Gains and step（2）Gains are dispersed at 15 DEG C in the distilled water of 70 times of its volume, are utilized
The ultrasonic wave added of 50Hz, 1200W disperse 20min, and 90 parts of acrylic acid and 2 parts of ferric nitrates are then added, are stirred with the rotating speed of 500rpm
Dissolving 25min is mixed, is then cooled to 7 DEG C, 0.3 part of ammonium persulfate initiator, reduction of speed is added after stirring 2h in raising speed to 1000rpm
It is stirred to react 4h to 450rpm, is subsequently poured into the mold of bionic fish bait, heat preservation stands 35h, demoulding.
Further, step（1）The dilute hydrochloric acid solution a concentration of 30%.
Further, step（1）The oyster shell whiting, hydroxypropyl-β-cyclodextrin solution are prepared as 15 parts of hydroxy propyl-Betas-
40% solution is made in water in cyclodextrin, and 6 parts of oyster shell whitings, 7 parts of ethyl alcohol are then added, utilize the supersound process of 700W
35min makes it be uniformly dispersed.
Further, step（2）The dried orange peel, laver end, cloves, fennel powder are cold in the vacuum of dry-mixed -20 DEG C of preceding process
Freeze and is dried, processing time 5h.
Embodiment 3
A kind of hydrogel material preparation method for bionic fish bait is made of following steps：
（1）The fish scale of 15 recycling in parts by weight is rinsed with water totally, surface smut and watery blood is removed, is subsequently placed in 150
In part dilute hydrochloric acid solution, 30min is boiled, and distilled water flushing 3 times after taking-up dry at 50 DEG C, fish scale are milled to ball mill
A diameter of 500 μm of tablet, puts it into blender, under the stirring of 400rpm, spraying oyster shell whiting, hydroxy propyl-Beta-ring
Dextrin solution is sprayed, and used time 5min is sprayed, and is stirred 20min with the rotating speed of 800rpm after spraying, is dried at 40 DEG C；
（2）5 parts of dried orange peels, 8 parts of laver ends, 2 portions of cloves, 4 parts of fennel powders are mixed into 10min in dry-mixed machine, are then transferred to its body
In the distilled water of 30 times of product, 60min is boiled under 200rpm magnetic agitations, filtrate is obtained after filtering, is concentrated the filtrate to original
1/3,80 DEG C are then heated to, appropriate amounts of gelatin is added thereto, is configured to the gelatin solution of a concentration of 10mg/mL, gained is molten
Liquid after precooling 2h, freezes 6h at -15 DEG C at -50 DEG C, and the particle that grain size is 1000 μm is crushed to after freeze-drying；
（3）By step（1）Gains and step（2）Gains are dispersed at 20 DEG C in the distilled water of 100 times of its volume, are utilized
The ultrasonic wave added of 60Hz, 1500W disperse 30min, and 100 parts of acrylic acid and 2 parts of ferric nitrates are then added, are stirred with the rotating speed of 600rpm
Dissolving 30min is mixed, is then cooled to 10 DEG C, 0.5 part of ammonium persulfate initiator, reduction of speed is added after stirring 2h in raising speed to 1500rpm
It is stirred to react 5h to 500rpm, is subsequently poured into the mold of bionic fish bait, heat preservation stands 40h, demoulding.
Further, step（1）The dilute hydrochloric acid solution a concentration of 40%.
Further, step（1）The oyster shell whiting, hydroxypropyl-β-cyclodextrin solution are prepared as 20 parts of hydroxy propyl-Betas-
60% solution is made in water in cyclodextrin, then adds 8 parts of oyster shell whitings, 10 parts of ethyl alcohol, utilizes the supersound process of 800W
40min makes it be uniformly dispersed.
Further, step（2）The dried orange peel, laver end, cloves, fennel powder are cold in the vacuum of dry-mixed -30 DEG C of preceding process
Freeze and is dried, processing time 8h.
Comparative example 1
The addition of fish scale and oyster shell whiting is omitted compared to embodiment 1 in this comparative example, and method and step in addition to this is homogeneous
Together.
Comparative example 2
The addition and extraction of dried orange peel, laver end, cloves, fennel powder is omitted compared to embodiment 1 in this comparative example, removes this
Except method and step all same.
Comparative example 3
The addition of gelatin is omitted compared to embodiment 1 in this comparative example, method and step all same in addition to this.
Experiment：
Tensile property is tested：It is tested with reference to GB/T1040-2006, a diameter of 6mm, length 60mm is made in each group sample
Cylindrical batten, gauge length 15mm, rate of extension 100mm/min.Test result is as shown in table 1：
As shown in Table 1, the bionic fish bait that prepared by the present invention is substantially increased with hydrogel material by the way that gelatin-compounded particle is added
The tensile resistance of resulting materials extends its service life, increases benefit.
Self-healing properties are tested：
Each group sample is cut from centre with knife, then section is stacked together again, is placed in sealed plastic bag, at room temperature
It places and observes selfreparing situation afterwards for 24 hours, and carry out tensile property test again, the results are shown in Table 2：
Table 2
As can be seen from Table 2, the bionic fish bait that prepared by the present invention has good selfreparing situation, selfreparing with hydrogel material
Rate is 100%, and after selfreparing although mechanical property, which has, a little reduces, but has no effect on and be applied to bionic fish bait progress
It fishes.
Claims (4)
1. a kind of hydrogel material preparation method for bionic fish bait, which is characterized in that be made of following steps：
（1）The fish scale of 10-15 recycling in parts by weight is rinsed with water totally, surface smut and watery blood is removed, is subsequently placed in
In 80-150 parts of dilute hydrochloric acid solutions, 10-30min is boiled, distilled water flushing 2-3 times after taking-up dries at 40-50 DEG C, uses ball milling
Fish scale is milled to a diameter of 100-500 μm of tablet by machine, is put it into blender, under the stirring of 300-400rpm,
Oyster shell whiting, the spraying of hydroxypropyl-β-cyclodextrin solution are sprayed, used time 3-5min is sprayed, is turned with 500-800rpm after spraying
Speed stirs 10-20min, is dried at 30-40 DEG C；
（2）3-5 parts of dried orange peels, 2-8 parts of laver ends, 1-2 portions of cloves, 3-4 parts of fennel powders are mixed into 5-10min in dry-mixed machine, so
It is transferred to afterwards in the distilled water of 20-30 times of its volume, 30-60min is boiled under 100-200rpm magnetic agitations, is filtered after filtering
Liquid concentrates the filtrate to original 1/2-1/3, then heats to 70-80 DEG C, appropriate amounts of gelatin is added thereto, be configured to concentration
It is cold at -40~-50 DEG C by acquired solution at -10~-15 DEG C after precooling 1-2h for the gelatin solution of 5-10mg/mL
Freeze 4-6h, the particle that grain size is 100-1000 μm is crushed to after freeze-drying；
（3）By step（1）Gains and step（2）Gains are dispersed in the distilled water of 30-100 times of its volume at 10-20 DEG C
In, using 40-60Hz, the ultrasonic wave added of 800-1500W disperses 10-30min, and 80-100 parts of acrylic acid and 1-2 parts are then added
Then ferric nitrate is cooled to 5-10 DEG C with the rotating speed stirring and dissolving 20-30min of 300-600rpm, raising speed to 800-1500rpm,
0.1-0.5 parts of ammonium persulfate initiators are added after stirring 1-2h, reduction of speed to 400-500rpm is stirred to react 3-5h, is subsequently poured into imitative
In the mold of raw bait, heat preservation stands 30-40h, demoulding.
2. a kind of hydrogel material preparation method for bionic fish bait according to claim 1, which is characterized in that
Step（1）A concentration of 10-40% of dilute hydrochloric acid solution.
3. a kind of hydrogel material preparation method for bionic fish bait according to claim 1, which is characterized in that
Step（1）The oyster shell whiting, hydroxypropyl-β-cyclodextrin solution be prepared as 10-20 parts of hydroxypropyl-β-cyclodextrins are dissolved in water
In, the solution of 30-60% is made, 4-8 parts of oyster shell whitings, 5-10 parts of ethyl alcohol are then added, utilize the supersound process 30- of 500-800W
40min makes it be uniformly dispersed.
4. a kind of hydrogel material preparation method for bionic fish bait according to claim 1, which is characterized in that
Step（2）The dried orange peel, laver end, cloves, fennel powder are at the vacuum freeze drying processing of -10~-30 DEG C of dry-mixed preceding process, place
The reason time is 3-8h.
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