CN108790351A - A kind of high gloss aluminium plating polyethylene label film and its production method - Google Patents

A kind of high gloss aluminium plating polyethylene label film and its production method Download PDF

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Publication number
CN108790351A
CN108790351A CN201810617286.6A CN201810617286A CN108790351A CN 108790351 A CN108790351 A CN 108790351A CN 201810617286 A CN201810617286 A CN 201810617286A CN 108790351 A CN108790351 A CN 108790351A
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CN
China
Prior art keywords
layer
density polyethylene
polyethylene
film
label film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810617286.6A
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Chinese (zh)
Inventor
韩铮
叶青松
汪学文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huangshan Novel Co Ltd
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Huangshan Novel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huangshan Novel Co Ltd filed Critical Huangshan Novel Co Ltd
Priority to CN201810617286.6A priority Critical patent/CN108790351A/en
Publication of CN108790351A publication Critical patent/CN108790351A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/406Bright, glossy, shiny surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/552Fatigue strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/04Polyethylene

Landscapes

  • Laminated Bodies (AREA)

Abstract

The present invention relates to a kind of high gloss aluminium plating polyethylene label film and its production methods.The label film includes polyethylene film layer and aluminium coated;Polyethylene film layer is made of corona layer, middle layer and printing layer, 14-25 μm of corona layer thickness, 35-44 μm of intermediate layer thickness, prints 14-25 μm of layer thickness;Corona layer includes that mass ratio is (38-50):The metallocene linear medium density polyethylene and linear low density polyethylene of (50-62), middle layer include that mass ratio is (40-55):The metallocene linear medium density polyethylene and low density polyethylene (LDPE) of (45-60), printing layer include that mass ratio is (38-50):The metallocene linear medium density polyethylene and low density polyethylene (LDPE) of (50-62).The label film has high glossiness, good metal-like, excellent physical mechanical property, uniform thickness degree, labeling body effect good, meets not brittle using not aging for a long time in the presence of a harsh environment.

Description

A kind of high gloss aluminium plating polyethylene label film and its production method
Technical field
The invention belongs to label field of membrane material, it is specifically related to a kind of high gloss aluminium plating polyethylene label film and its life Production method.
Background technology
With the raising of people's living standard, commodity are just gradually to superior, diversified development, and label is as biography It passs product information and attracts the important means of consumer's eyeball, be the core of product external packaging, be the important carrier of brand, also just It is strided forward toward superior.High brightness label with metallic luster can not only promote product specification, and can excite people couple The desire to buy of product.
However, traditional high gloss metal-like label material mostly be use metal composite film, using plastic film with Metal aluminum foil or metallized film are by MULTILAYER COMPOSITE membrane structure made of compound curing, and complex process is cumbersome, long preparation period, Drying curing, it is of high cost, layering break-off is susceptible to during use, urgent need seeks other materials to substitute.Therefore, it opens The metal-like label film for sending out high gloss a kind of is by the extensive concern of researcher.
Invention content
In order to solve the above technical problem, the present invention provides a kind of high gloss aluminium plating polyethylene label film and its producers Method.
In order to achieve the object of the present invention, present invention employs following technical schemes:
A kind of high gloss aluminium plating polyethylene label film, the label film include polyethylene film layer and aluminium coated, described poly- Vinyl film is made of corona layer, middle layer and printing layer, and the aluminium coated is supported on the corona layer surface, wherein the electricity Dizzy 14-25 μm of layer thickness, 35-44 μm of the intermediate layer thickness, 14-25 μm of the printing layer thickness;The corona layer includes matter Amount is than being (38-50):The metallocene linear medium density polyethylene resin and linear low density polyethylene resin of (50-62), it is described Middle layer includes that mass ratio is (40-55):The metallocene linear medium density polyethylene resin of (45-60) and low density polyethylene (LDPE) tree Fat, the printing layer include that mass ratio is (38-50):The metallocene linear medium density polyethylene resin and low-density of (50-62) Polyvinyl resin.
Preferred embodiment:20 μm of the corona layer thickness, 42 μm of the intermediate layer thickness, 20 μm of the printing layer thickness.
Preferred embodiment:The corona layer includes that mass ratio is 55:45 metallocene linear medium density polyethylene resin and line Property ldpe resin, the middle layer include mass ratio be 60:40 metallocene linear medium density polyethylene resin and Ldpe resin, the printing layer include that mass ratio is 60:40 metallocene linear medium density polyethylene resin and low Density Polyethylene Resin.
Further scheme:The metallocene linear medium density polyethylene trade mark in the corona layer is 2027G, the corona layer In the linear low density polyethylene trade mark be 2036P, the metallocene linear medium density polyethylene trade mark in the middle layer is XUS81841.27, the low density polyethylene (LDPE) trade mark in the middle layer are FT6230, in the metallocene linear in the printing layer The density polyethylene trade mark is 2027G, and the low density polyethylene (LDPE) trade mark in the printing layer is 2420H.
Further scheme:The OD values of the aluminium coated are 2.2-2.6.
Further scheme:The label film is to be born metallic aluminium by direct or transfer aluminum plated method under the conditions of vacuum sealing It is loaded in polyethylene based film and obtains.
A kind of production method of the high gloss aluminium plating polyethylene label film, includes the following steps:
Step 1, material contained in the corona layer, middle layer and printing layer is added respectively by said components proportion requirement Enter in coextrusion casting machine by it is three-layer co-extruded go out molding mode obtain the polyethylene film layer;
Step 2, under the conditions of vacuum sealing, metallic aluminium is supported in polyethylene film layer by direct or transfer aluminum plated method Obtain aluminium coated;
Step 3, label film is made in cooling and shaping.
The beneficial effects of the present invention are:
(1) polyethylene film of the present invention passes through the optimum choice to each layer formula particle and thickness so that through aluminizing Treated, and label film product has higher deflection, high glossiness, good metal-like, excellent Physical Mechanical Energy, the excellent thickness uniformity can be good at adapting to later stage gluing poster process, possess good gluing labeling effect, full Use for a long time is not brittle without aging in the presence of a harsh environment for foot.
(2) the OD values of metallic aluminum of the present invention can effectively improve the gloss of label film product in constant range Degree, phenomena such as preventing from leaking aluminium light transmission caused by aluminium layer became uneven one.
(3) preparation method of label film of the present invention is easy to operate, integrate with a plurality of steps of operation, and basement membrane synthesizes, is golden The shortcomings that belonging to the load of aluminium can carry out, abandon conventional metals texture label membrane preparation method successively, without additional compound place Science and engineering sequence.
Description of the drawings
Fig. 1 is label membrane structure diagram of the present invention.
The meaning respectively marked in attached drawing is as follows:
1- metallic aluminums;2- corona layers;3- middle layers;4- printing layers;5- polyethylene based films.
Specific implementation mode
The embodiment of the present invention is described below in detail.The embodiments described below is exemplary, and is only used for explaining this hair It is bright, and limiting the scope of the invention cannot be construed to.
The preparation method of the high gloss aluminium plating polyethylene label film, includes the following steps:
Step 1, material contained in the corona layer, middle layer and printing layer is separately added into altogether by component ratio requirement Squeeze in casting machine by it is three-layer co-extruded go out molding mode obtain the polyethylene film layer;The processing technology of the polyethylene film layer Parameter is as shown in table 1 below:
Table 1
Step 2, the corona layer surface by plasma technology in the polyethylene film layer under the conditions of vacuum sealing carries out Directly/transfer aluminum plated obtain the aluminium coated;The OD values of the aluminium coated are 2.2-2.6.Specific aluminum plating process can refer to Existing mature technology.
Step 3, label film is made in cooling and shaping.
Preparation method and characteristic that 3 embodiments illustrate label film of the present invention with it is set forth below.
The formula rate of the preparation difference according to the form below 2 of polyethylene based film carries out in the embodiment:
Table 2
The 3 kinds of label film performance parameters produced according to above method are as shown in table 3 below:
Table 3

Claims (7)

1. a kind of high gloss aluminium plating polyethylene label film, it is characterised in that:The label film includes polyethylene film layer and aluminizes Layer, the polyethylene film layer are made of corona layer, middle layer and printing layer, and the aluminium coated is supported on the corona layer surface, Wherein described 14-25 μm of the corona layer thickness, 35-44 μm of the intermediate layer thickness, 14-25 μm of the printing layer thickness;The electricity Dizzy layer includes that mass ratio is (38-50):The metallocene linear medium density polyethylene resin and linear low density polyethylene of (50-62) Resin, the middle layer include that mass ratio is (40-55):The metallocene linear medium density polyethylene resin of (45-60) and low close Polyvinyl resin is spent, the printing layer includes that mass ratio is (38-50):The metallocene linear medium density polyethylene tree of (50-62) Fat and ldpe resin.
2. high gloss aluminium plating polyethylene label film as described in claim 1, it is characterised in that:20 μ of corona layer thickness M, 42 μm of the intermediate layer thickness, 20 μm of the printing layer thickness.
3. high gloss aluminium plating polyethylene label film as described in claim 1, it is characterised in that:The corona layer includes quality Than being 55:45 metallocene linear medium density polyethylene resin and linear low density polyethylene resin, the middle layer include matter Amount is than being 60:40 metallocene linear medium density polyethylene resin and ldpe resin, the printing layer include quality Than being 60:40 metallocene linear medium density polyethylene resin and ldpe resin.
4. high gloss aluminium plating polyethylene label film as described in claim 1, it is characterised in that:Cyclopentadienyl gold in the corona layer The category linear density polyethylene trade mark is 2027G, and the linear low density polyethylene trade mark in the corona layer is 2036P, described The metallocene linear medium density polyethylene trade mark in middle layer is XUS81841.27, the low density polyethylene (LDPE) in the middle layer The trade mark is FT6230, and the metallocene linear medium density polyethylene trade mark in the printing layer is 2027G, low in the printing layer The density polyethylene trade mark is 2420H.
5. high gloss aluminium plating polyethylene label film as described in claim 1, it is characterised in that:The OD values of the aluminium coated are 2.2-2.6。
6. high gloss aluminium plating polyethylene label film as described in claim 1, it is characterised in that:The label film is in vacuum seal Under the conditions of closing, obtained by metallic aluminium is supported in polyethylene based film by direct or transfer aluminum plated method.
7. a kind of production method of high gloss aluminium plating polyethylene label film as claimed in any one of claims 1 to 6, feature It is to include the following steps:
Step 1, material contained in the corona layer, middle layer and printing layer is separately added into altogether by said components proportion requirement Squeeze in casting machine by it is three-layer co-extruded go out molding mode obtain the polyethylene film layer;
Step 2, under the conditions of vacuum sealing, metallic aluminium is supported in polyethylene film layer by direct or transfer aluminum plated method and is obtained Aluminium coated;
Step 3, label film is made in cooling and shaping.
CN201810617286.6A 2018-06-15 2018-06-15 A kind of high gloss aluminium plating polyethylene label film and its production method Pending CN108790351A (en)

Priority Applications (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112677605A (en) * 2020-12-23 2021-04-20 上海紫江彩印包装有限公司 Label film, aluminum-plated label film, and preparation method and application thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0724002A2 (en) * 1995-01-25 1996-07-31 Mobil Plastics Europe, Inc. Adhesive film
JPH10121011A (en) * 1996-10-16 1998-05-12 Oji Paper Co Ltd Pressure-sensitive adhesive tape
CN1668455A (en) * 2002-07-18 2005-09-14 优泊公司 Glossy film
CN202079881U (en) * 2011-05-18 2011-12-21 江阴宝柏包装有限公司 Ultra-thin label film
CN104476889A (en) * 2015-01-16 2015-04-01 永新股份(黄山)包装有限公司 PE film and preparation method thereof
CN204471990U (en) * 2015-01-22 2015-07-15 惠州市浩明科技股份有限公司 A kind of PE electroplates label film
US20160106686A1 (en) * 2002-08-30 2016-04-21 Alza Corporation Multilaminate backing construction

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0724002A2 (en) * 1995-01-25 1996-07-31 Mobil Plastics Europe, Inc. Adhesive film
JPH10121011A (en) * 1996-10-16 1998-05-12 Oji Paper Co Ltd Pressure-sensitive adhesive tape
CN1668455A (en) * 2002-07-18 2005-09-14 优泊公司 Glossy film
US20160106686A1 (en) * 2002-08-30 2016-04-21 Alza Corporation Multilaminate backing construction
CN202079881U (en) * 2011-05-18 2011-12-21 江阴宝柏包装有限公司 Ultra-thin label film
CN104476889A (en) * 2015-01-16 2015-04-01 永新股份(黄山)包装有限公司 PE film and preparation method thereof
CN204471990U (en) * 2015-01-22 2015-07-15 惠州市浩明科技股份有限公司 A kind of PE electroplates label film

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112677605A (en) * 2020-12-23 2021-04-20 上海紫江彩印包装有限公司 Label film, aluminum-plated label film, and preparation method and application thereof

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Application publication date: 20181113