CN108788531A - One kind 400 is ferritic stainless steel activated rosin flux - Google Patents
One kind 400 is ferritic stainless steel activated rosin flux Download PDFInfo
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- CN108788531A CN108788531A CN201811019539.6A CN201811019539A CN108788531A CN 108788531 A CN108788531 A CN 108788531A CN 201811019539 A CN201811019539 A CN 201811019539A CN 108788531 A CN108788531 A CN 108788531A
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- China
- Prior art keywords
- stainless steel
- ferritic stainless
- rosin flux
- activated rosin
- flux
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3601—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
- B23K35/3603—Halide salts
- B23K35/3605—Fluorides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/362—Selection of compositions of fluxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/18—Submerged-arc welding
Abstract
The present invention relates to scaling powder technical fields, and in particular to one kind 400 is ferritic stainless steel activated rosin flux.The raw material components of the type activated rosin flux include:Calcirm-fluoride, chrome green, aluminium oxide, silica, magnesia, titanium dioxide, alloy powder, nitrogen titanium aluminide, potassium fluoborate, heat absorbent, surplus are binder and inevitable impurity.Wherein, heat absorbent contains nano-calcium carbonate, bentonite or sodium bicarbonate;Binder is potassium-sodium water glass.The mass fraction of P element is less than 0.05% in impurity element;The mass fraction of S elements is less than 0.03%;Alloy powder is high copper-manganese-nickel;The type scaling powder for avoid welding material occur sensitization and embrittlement have extraordinary effect, be highly suitable for 400 be ferritic stainless steel submerged arc welding use.
Description
Technical field
The present invention relates to scaling powder technical fields, and in particular to one kind 400 is ferritic stainless steel activated rosin flux.
Background technology
Stainless steel is the abbreviation of stainless acid resistant steel, the weak corrosive medium such as resistance to air, steam, water or the steel grade with rustless property
Referred to as stainless steel;And the steel grade that medium resistant to chemical etching (chemical etchings such as acid, alkali, salt) corrodes is known as acid resisting steel.Due to two
Difference of the person in chemical composition and keep their corrosion resistance different, generally resistant to chemical media corrodes common stainless steel, and resistance to
Sour steel then generally has rustless property.Stainless steel does not refer to a type of steel not instead of singly, indicates that more than 100 kinds of industry is stainless
Steel, each the stainless steel capital developed are with good performance in its specific application field.Stainless steel has hardness height, wear-resisting
Good, the good corrosion resistance of property, the characteristics such as excellent appearance and long lifespan are therefore widely used in building, auto industry, make
The industries such as ship industry, marine device, mechanical equipment and chemical device.
400 be the alloy that stainless steel is a kind of iron, carbon, chromium.This stainless steel has martensitic structure and ferro element, therefore
With normal magnetic characteristic.400, which be stainless steel, has very strong oxidation-resistance property, and compared with carbon steel, physics is special
Property and mechanical property have further improvement.Common 400 be to have 430 types containing chromium 18% in stainless steel kind and contain chromium
The 13% stainless steel pattern number of 410 types and 420 class, wherein the stainless steel pattern number usage amount of 430 types is maximum.400 the characteristics of being stainless steel
It is cheap, coefficient of thermal expansion is small, resistance to chloride stress corrosion better than 300 is stainless steel kind;But shortcoming
It is that forming property, solderability and tensile strength are less than the stainless steel pattern number of 304 types, it is therefore, limited using field.In chrome content
Under same case, in the Oxidant as in air, fresh water and nitric acid, 400 be stainless steel kind corrosion resistance and 300
It is that stainless steel kind is identical, 400 be that stainless steel kind is currently fed trace niobium, titanium, copper and aluminium element and can improve its deep drawing quality
Energy, solderability, corrosion resistance and high temperature resistance intensity can partly replace the stainless steel pattern number of 304 types.
400 be stainless steel in the welding process, seam crossing will produce partial saturation by 1000 DEG C of Source,
Then martensitic structure can be formed in grain boundaries during being quickly cooled down, and the coarse grains of intergranular can be caused, and made
Obtaining weld material embrittlement and toughness reduces, and the final welding quality for influencing seam even will produce crackle when serious.In addition,
The high temperature of welding also results in the carbon of ferritic stainless steel, nitrogen compound is precipitated, and intercrystalline corrosion tendency is reinforced so that seam crossing material
There is chromium depletedization in material, and the corrosion resistance of material reduces, that is, generates sensitization.
There is this problem in the use of most of welding auxiliary agent currently on the market, routinely improve the weld defect
Method is to be preheated before welding, carries out the heat treatment such as being tempered after welding, and needs to select high chromium-nickel austenite stainless
Steel welding wire.
Invention content
It is ferritic stainless steel activated rosin flux the present invention provides one kind 400 for problems of the prior art,
The type scaling powder has extraordinary effect for avoiding welding material from sensitization and embrittlement occur, and it is iron to be highly suitable for 400
The submerged arc welding of ferritic stainless steel uses.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
One kind 400 is ferritic stainless steel activated rosin flux, according to mass percent, the raw material components packet of activated rosin flux
It includes:
Calcirm-fluoride 18.0-30.0%, chrome green 12.5-16.4%, aluminium oxide 6.5-10.0%, silica 6.0-
8.6%, magnesia 2.6-4.9%, titanium dioxide 8.7-11.5%, alloy powder 2.5-3%, nitrogen titanium aluminide 0.8-1.2%, fluorine
Potassium borate 4.6-7.5%, heat absorbent 12.5-14.5%, surplus are binder and inevitable impurity.
Preferably, according to mass percent, the raw material components of activated rosin flux include:
Calcirm-fluoride 22.0-24.0%, chrome green 14.5-15.3%, aluminium oxide 7.8-9.1%, silica 7.2-
8.1%, magnesia 3.7-4.1%, titanium dioxide 10.1-10.7%, alloy powder 2.7-2.9%, nitrogen titanium aluminide 0.9-
1.1%, potassium fluoborate 5.7-6.3%, heat absorbent 13.7-14.1%, surplus are binder and inevitable impurity.
It is further preferred that according to mass percent, the raw material components of activated rosin flux include:
Calcirm-fluoride 23.5%, chrome green 14.9%, aluminium oxide 8.3%, silica 7.7%, magnesia 3.9%, two
Titanium oxide 10.5%, alloy powder 2.8%, nitrogen titanium aluminide 1.0%, potassium fluoborate 6.1%, heat absorbent 13.9%, surplus are viscous
Tie agent and inevitable impurity.
Preferably, heat absorbent is nano-calcium carbonate.
It is further preferred that also containing bentonite and sodium bicarbonate in heat absorbent, the content of sodium bicarbonate is less than 15%;It is swollen
The content of profit soil is not higher than 30%.
Preferably, binder is potassium-sodium water glass.
Preferably, viscosity of the sodium potassium water glass when being for 20 DEG C is 800-900MpaS.
Preferably, the mass fraction of P element is less than 0.05% in impurity element;The mass fraction of S elements is less than 0.03%.
Preferably, alloy powder is high copper-manganese-nickel, and the content of nickel element is 7.5-8.5% in alloy powder.
Activated rosin flux provided by the invention is as the submerged arc sintered flux that 400 be ferritic stainless steel.
The present invention has following advantageous effect:
In the type activated rosin flux, the calcirm-fluoride used is a kind of salt of meta-alkalescence, and the fusing point of the component is relatively low, can reduce
Slag surface tension and raising slag fluidity;It is relatively more active at high temperature, and decomposing the fluorine gas of generation can reduce in electric arc
The partial pressure of hydrogen, to effectively reduce weld metal diffusible hydrogen content.Aluminium oxide and magnesia can adjust slag fusing point and viscosity
Active ingredient, can make slag that there is good mobility so that weld metal and base material transitions smooth improve the beauty of weld seam
Degree.Potassium fluoborate can improve slag fluidity, adjust the angle of wetting between weld seam and base material, while potassium ion therein is also steady
The effect of arc.Alloy powder, chrome green and nitrogen titanium aluminide three can generate synergistic effect, for adjusting weld metal
Corrosion resistance and toughness of material have remarkable result.
In addition, the heat absorbent in component can absorb partial heat in welding except initial stage, avoid welding except material temperature is fast
Speed increases, and prevents crystal phase structure from occurring excessively to change, after welding, can also discharge partial heat, avoid weld seam temperature
It quickly reduces, the problem of embrittlement is reduced with toughness is easy so as to improve weld seam.
S elements can cause grain boundaries that FeS is precipitated in commissure, and form eutectic with FeO, or form oxysulfide, carbon
Sulphur compound etc., these can all cause the corrosion resistance of seam and toughness to reduce;The effect of P is similar with S, therefore tight in solder flux
Lattice control the content of the above element.
In conclusion activated rosin flux provided by the invention lacks the welding improved in ferritic stainless steel welding process
It falls into, there is good effect, to which raising 400 is the solderability of stainless steel, promote the welding quality of stainless steel material.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
One kind 400 is ferritic stainless steel activated rosin flux, according to mass percent, the raw material components packet of activated rosin flux
It includes:
Calcirm-fluoride 18.0%, chrome green 12.5%, aluminium oxide 6.5%, silica 6.0%, magnesia 2.6%, two
Titanium oxide 8.7%, alloy powder 2.5%, nitrogen titanium aluminide 0.8%, potassium fluoborate 4.6%, heat absorbent 12.5%, surplus are to bond
Agent and inevitable impurity.
Wherein, heat absorbent is nano-calcium carbonate.
Binder is potassium-sodium water glass.
Viscosity of the sodium potassium water glass when being for 20 DEG C is 800-900MpaS.
The mass fraction of P element is less than 0.05% in impurity element;The mass fraction of S elements is less than 0.03%.
Alloy powder is high copper-manganese-nickel, and the content of nickel element is 7.5% in alloy powder.
Activated rosin flux provided in this embodiment is as the submerged arc sintered flux that 400 be ferritic stainless steel.
Embodiment 2
One kind 400 is ferritic stainless steel activated rosin flux, according to mass percent, the raw material components packet of activated rosin flux
It includes:
Calcirm-fluoride 30.0%, chrome green 16.4%, aluminium oxide 10.0%, silica 8.6%, magnesia 4.9%, two
Titanium oxide 11.5%, alloy powder 3%, nitrogen titanium aluminide 1.2%, potassium fluoborate 7.5%, heat absorbent 14.5%, surplus are to bond
Agent and inevitable impurity.
Wherein, heat absorbent is the mixture of nano-calcium carbonate, bentonite and sodium bicarbonate, and the content of sodium bicarbonate is
15%;Bentonitic content is 30%.
Binder is potassium-sodium water glass.
Viscosity of the sodium potassium water glass when being for 20 DEG C is 800-900MpaS.
The mass fraction of P element is less than 0.05% in impurity element;The mass fraction of S elements is less than 0.03%.
Alloy powder is high copper-manganese-nickel, and the content of nickel element is 8.5% in alloy powder.
Activated rosin flux provided in this embodiment is as the submerged arc sintered flux that 400 be ferritic stainless steel.
Embodiment 3
One kind 400 is ferritic stainless steel activated rosin flux, according to mass percent, the raw material components packet of activated rosin flux
It includes:
Calcirm-fluoride 23.5%, chrome green 14.9%, aluminium oxide 8.3%, silica 7.7%, magnesia 3.9%, two
Titanium oxide 10.5%, alloy powder 2.8%, nitrogen titanium aluminide 1.0%, potassium fluoborate 6.1%, heat absorbent 13.9%, surplus are viscous
Tie agent and inevitable impurity.
Wherein, heat absorbent is the mixture of nano-calcium carbonate, bentonite and sodium bicarbonate, and the content of sodium bicarbonate is
10%;Bentonitic content is 20%.
Binder is potassium-sodium water glass.
Viscosity of the sodium potassium water glass when being for 20 DEG C is 800-900MpaS.
The mass fraction of P element is less than 0.05% in impurity element;The mass fraction of S elements is less than 0.03%.
Alloy powder is high copper-manganese-nickel, and the content of nickel element is 8% in alloy powder.
Activated rosin flux provided in this embodiment is as the submerged arc sintered flux that 400 be ferritic stainless steel.
Performance test
1, it is welded using 430 type stainless steel model of the activating flux weld pair of the present embodiment, and detects welding quality, simultaneously
" the prosperous board of Shun " SJ102 types stainless steel flux of the sale of Tai'an Wen Yue building materials Co., Ltd in the market is set as a control group,
Carry out welding performance comparison;Wherein, the evaluation index of welding quality includes weld appearance, the bend test result of weld seam and weld seam
Kesternich test result.
Table 1:The performance test results of the present embodiment and control group scaling powder
It analyzes the above experimental result and finds that scaling powder provided by the invention when welding 430 type stainless steel, borrow by welding effect
Preferably, the smooth in appearance of weld seam is smooth, and compared with the control group, the weld defect of scaling powder of the present invention is less, and can keep
Preferable welding seam toughness reduces welding seam toughness, in addition, the type scaling powder also has preferable improving performance for the corrosion resistance of weld seam.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (10)
1. one kind 400 is ferritic stainless steel activated rosin flux, which is characterized in that according to mass percent, the activated rosin flux
Raw material components include:
Calcirm-fluoride 18.0-30.0%, chrome green 12.5-16.4%, aluminium oxide 6.5-10.0%, silica 6.0-8.6%, oxidation
Magnesium 2.6-4.9%, titanium dioxide 8.7-11.5%, alloy powder 2.5-3%, nitrogen titanium aluminide 0.8-1.2%, potassium fluoborate 4.6-
7.5%, heat absorbent 12.5-14.5%, surplus are binder and inevitable impurity.
2. according to claim 1 a kind of 400 be ferritic stainless steel activated rosin flux, which is characterized in that according to quality
The raw material components of percentage, the activated rosin flux include:
Calcirm-fluoride 22.0-24.0%, chrome green 14.5-15.3%, aluminium oxide 7.8-9.1%, silica 7.2-8.1%, oxidation
Magnesium 3.7-4.1%, titanium dioxide 10.1-10.7%, alloy powder 2.7-2.9%, nitrogen titanium aluminide 0.9-1.1%, potassium fluoborate 5.7-
6.3%, heat absorbent 13.7-14.1%, surplus are binder and inevitable impurity.
3. according to claim 2 a kind of 400 be ferritic stainless steel activated rosin flux, which is characterized in that according to quality
The raw material components of percentage, the activated rosin flux include:
Calcirm-fluoride 23.5%, chrome green 14.9%, aluminium oxide 8.3%, silica 7.7%, magnesia 3.9%, titanium dioxide
10.5%, alloy powder 2.8%, nitrogen titanium aluminide 1.0%, potassium fluoborate 6.1%, heat absorbent 13.9%, surplus is binder and can not keep away
The impurity exempted from.
4. according to claim 1 a kind of 400 be ferritic stainless steel activated rosin flux, it is characterised in that:The heat absorption
Agent is nano-calcium carbonate.
5. according to claim 4 a kind of 400 be ferritic stainless steel activated rosin flux, it is characterised in that:The heat absorption
Also contain bentonite and sodium bicarbonate in agent, the content of sodium bicarbonate is less than 15%;Bentonitic content is not higher than 30%.
6. according to claim 1 a kind of 400 be ferritic stainless steel activated rosin flux, it is characterised in that:The bonding
Agent is potassium-sodium water glass.
7. according to claim 6 a kind of 400 be ferritic stainless steel activated rosin flux, it is characterised in that:The sodium potassium
Viscosity of the waterglass when being for 20 DEG C is 800-900MpaS.
8. according to claim 1 a kind of 400 be ferritic stainless steel activated rosin flux, it is characterised in that:The impurity
The mass fraction of P element is less than 0.05% in element;The mass fraction of S elements is less than 0.03%.
9. according to claim 1 a kind of 400 be ferritic stainless steel activated rosin flux, it is characterised in that:The alloy
Micro mist is high copper-manganese-nickel, and the content of nickel element is 7.5-8.5% in alloy powder.
10. according to claim 1 a kind of 400 be ferritic stainless steel activated rosin flux, it is characterised in that:The activity
Solder flux is as the submerged arc sintered flux that 400 be ferritic stainless steel.
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CN201811019539.6A CN108788531A (en) | 2018-09-03 | 2018-09-03 | One kind 400 is ferritic stainless steel activated rosin flux |
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CN201811019539.6A CN108788531A (en) | 2018-09-03 | 2018-09-03 | One kind 400 is ferritic stainless steel activated rosin flux |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1472889A (en) * | 1973-12-28 | 1977-05-11 | Wacker Chemie Gmbh | Welding fluxes |
JPS5348035A (en) * | 1976-10-14 | 1978-05-01 | Nippon Steel Corp | Fused flux for submerged arc welding |
CN101585123A (en) * | 2009-06-01 | 2009-11-25 | 林肯电气合力(郑州)焊材有限公司 | Sintered flux for stainless steel |
CN102240871A (en) * | 2011-05-05 | 2011-11-16 | 河海大学常州校区 | Sintered flux for stainless steel submerged arc deposited metal nitrogen alloying |
CN102451962A (en) * | 2010-10-26 | 2012-05-16 | 北京新风机械厂 | Stainless steel active rosin flux and preparation method thereof |
CN102581518A (en) * | 2012-03-23 | 2012-07-18 | 北京金威焊材有限公司 | Sintered flux for stainless steel surfacing with band electrode |
CN103418938A (en) * | 2013-09-02 | 2013-12-04 | 湖北鸿路钢结构有限公司 | Active solder for welding ferritic stainless steel with fined grains and preparation method of active solder |
-
2018
- 2018-09-03 CN CN201811019539.6A patent/CN108788531A/en not_active Withdrawn
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1472889A (en) * | 1973-12-28 | 1977-05-11 | Wacker Chemie Gmbh | Welding fluxes |
JPS5348035A (en) * | 1976-10-14 | 1978-05-01 | Nippon Steel Corp | Fused flux for submerged arc welding |
CN101585123A (en) * | 2009-06-01 | 2009-11-25 | 林肯电气合力(郑州)焊材有限公司 | Sintered flux for stainless steel |
CN102451962A (en) * | 2010-10-26 | 2012-05-16 | 北京新风机械厂 | Stainless steel active rosin flux and preparation method thereof |
CN102240871A (en) * | 2011-05-05 | 2011-11-16 | 河海大学常州校区 | Sintered flux for stainless steel submerged arc deposited metal nitrogen alloying |
CN102581518A (en) * | 2012-03-23 | 2012-07-18 | 北京金威焊材有限公司 | Sintered flux for stainless steel surfacing with band electrode |
CN103418938A (en) * | 2013-09-02 | 2013-12-04 | 湖北鸿路钢结构有限公司 | Active solder for welding ferritic stainless steel with fined grains and preparation method of active solder |
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Application publication date: 20181113 |