CN108787724A - A kind of combined plant restorative procedure of cadmium pollution soil repair - Google Patents

A kind of combined plant restorative procedure of cadmium pollution soil repair Download PDF

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Publication number
CN108787724A
CN108787724A CN201810901759.5A CN201810901759A CN108787724A CN 108787724 A CN108787724 A CN 108787724A CN 201810901759 A CN201810901759 A CN 201810901759A CN 108787724 A CN108787724 A CN 108787724A
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soil
witloof
mus
cadmium
cadmium pollution
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肖智华
曾馨怡
李舒惠
吴玲
邹冬生
李龙城
张利青
王安岽
刘芬
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Hunan Agricultural University
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Hunan Agricultural University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/10Reclamation of contaminated soil microbiologically, biologically or by using enzymes
    • B09C1/105Reclamation of contaminated soil microbiologically, biologically or by using enzymes using fungi or plants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C2101/00In situ

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  • General Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Soil Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Cultivation Of Plants (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of combined plant restorative procedure of cadmium pollution soil repair, which includes the following steps:Witloof is planted in cadmium pollution soil with legume in a manner of work to cultivate, completes the reparation to cadmium pollution soil.Combined plant restorative procedure of the present invention, witloof cadmium pollution soil is planted in legume in a manner of work to cultivate, it can realize effective reparation to cadmium pollution soil, have many advantages, such as that repairing effect is good, income is high, also have many advantages, such as that small investment, maintenance cost are low, quantities is small, administrative skill requires physicochemical property that is low, easy to operate, can keeping even improveing soil, cadmium pollution soil can be taken into account simultaneously to produce when repairing, and have good environmental benefit, Social benefit and economic benefit.

Description

A kind of combined plant restorative procedure of cadmium pollution soil repair
Technical field
The invention belongs to heavy-metal contaminated soil Prevention Technique fields, are related to a kind of method of cadmium pollution soil repair, tool Body is related to a kind of combined plant restorative procedure of cadmium pollution soil repair.
Background technology
It is dug up mine and the comprehensive function of other pollution channels, heavy metal in soil pollution is increasingly severe, wherein heavy metal Cadmium pollution problem is the most prominent.According to《Standard of soil environment quality》(GB 15618-1995) is shown, cadmium content in acid soil More than 0.3mg/kg, i.e. there are pollution risks.Thus, heavy metal in soil cadmium pollution becomes limitation crop yield and quality Key, in addition, heavy metal cadmium health can also be brought by the enrichment of food chain it is potentially hazardous.Therefore, there is an urgent need for counterweights Metallic pollution soil is repaired, and especially to cadmium pollution soil repair seems particularly urgent.
Currently, phytoremediation technology be it is a kind of with it is economical, green, environmental-friendly and can the advantages such as in-situ immobilization with plant Recovery technique based on object is absorbed by root system of plant from soil when being repaired to heavy-metal contaminated soil using plant Heavy metal ion, and it is transported to each position of plant, to which the heavy metal in soil is transferred in plant, realization pair The reparation of heavy-metal contaminated soil, has been widely used for restoration of soil polluted by heavy metal.For cadmium pollution soil, plant roots System is primarily limited to the existing forms of cadmium in the soil to the assimilation effect of cadmium ion, as can the cadmium for being absorbed by plants accumulation is main Exist in the form of exchangeable species, however the content of exchangeable cadmium is relatively fewer, i.e. the content of soil available Cd is relatively low, leads Cause root system of plant that can not effectively absorb more cadmium ions so that plant is difficult to improve the repairing effect of cadmium pollution soil.One Aspect, in the method for existing activation cadmium pollution soil, although plant used can secrete organic acid, the organic acid kind of secretion Class is less, and the organic acid content secreted is relatively low, it is difficult to cadmium pollution soil is quickly and efficiently activated, as a result, activation effect It is poor, in some instances it may even be possible to which that the physicochemical property that can destroy soil makes soil lose recycle value.On the other hand, existing reparation cadmium is dirty In the method for contaminating soil, the planting season of plant (such as corn) used conflicts with industrial crops (such as rice, wheat), causes Land resource cannot reasonably be utilized, preferable repairing effect and economic benefit can not be obtained, and the plant products utilized it is low, Technical costs is big, plants enriched coefficient is small, bad to the extraction effect of cadmium.In fact, since cadmium has toxicity, plant can be inhibited Growth and development, make plant can not normal growth, be unfavorable for improving plant to the repairing effect of cadmium pollution soil, and can also reduce The yield of plant, causes economic benefit to reduce, or even due to the cadmium of plant kernel meeting enriched, causes seed super because of cadmium content It marks and cannot eat, substantially reduce the use value and economic benefit of phytoremediation, be unfavorable for reducing the cost of phytoremediation.Separately Outside, that there is also costs of investment is high, maintenance cost is high, quantities is big, administrative skill requirement for the method for existing cadmium pollution soil repair The problems such as high, complicated for operation, seriously limits the application value and application range of phytoremediation technology.As it can be seen that existing cadmium pollution There are still cost of investment height, maintenance cost height, quantities in the recovery technique of soil greatly, administrative skill requirement is high, operates again Miscellaneous, the problems such as repairing effect is poor, income is poor.Therefore, how to improve the above problem comprehensively, obtain that a kind of repairing effect is good, income The method of high cadmium pollution soil repair has for improving the application range that phytoremediation technology repairs field in cadmium pollution soil It is significant.
Invention content
The technical problem to be solved by the present invention is to overcome the deficiencies in the prior art, provide that a kind of repairing effect is good, income is high Cadmium pollution soil repair combined plant restorative procedure.
In order to solve the above technical problems, the technical solution adopted by the present invention is:
A kind of combined plant restorative procedure of cadmium pollution soil repair, the combined plant restorative procedure include following step Suddenly:Witloof is planted in cadmium pollution soil with legume in a manner of work to cultivate, cadmium pollution soil is repaiied in completion It is multiple.
Combinations of the above plant restoration method, further improved, the line-spacing between the witloof and legume is 20cm~40cm.
Combinations of the above plant restoration method, further improved, the witloof is to be broadcast chicory seed with drilling method Kind is in cadmium pollution soil;The sowing spacing in the rows of the chicory seed is 10cm~15cm.
Combinations of the above plant restoration method, further improved, the application rate of the witloof is 1kg/ mus~1.5kg/ Mu.
Combinations of the above plant restoration method, further improved, the legume is Vicia sativa, broad bean, pea, purple At least one of Yun Ying, white clover, Lupinus albus.
Combinations of the above plant restoration method, it is further improved, when the legume is broad bean, pea, with program request Mode sows seeds of leguminous plant in cadmium pollution soil;The sowing spacing in the rows of the seeds of leguminous plant is 10cm~20cm; The application rate of the broad bean is 5.5kg/ mus~7kg/ mus;The application rate of the pea is 5.5kg/ mus~8kg/ mus.
Combinations of the above plant restoration method, further improved, the legume is Vicia sativa, Chinese milk vetch, white vehicle When axis grass, Lupinus albus, seeds of leguminous plant is sowed in cadmium pollution soil with drilling method;The seeds of leguminous plant Sowing spacing in the rows is 10cm~20cm;The application rate of the Vicia sativa is 3kg/ mus~4kg/ mus;The application rate of the Chinese milk vetch is 1kg/ mus~2kg/ mus;The application rate of the white clover is 0.5kg/ mus~1kg/ mus;The application rate of the Lupinus albus is 3kg/ mus~4kg/ mus.
Combinations of the above plant restoration method, further improved, the initial concentration of cadmium is in the cadmium pollution soil 0.3mg/kg~5.0mg/kg.
Combinations of the above plant restoration method, further improved, the legume is in the fall or winter planting;It is described Culture is carried out according to plant nature growth pattern;It is maximum water-holding capacity that cadmium pollution soil water content is kept in the incubation 65%~75%;Further include applying composite fertilizer and organic fertilizer into cadmium pollution soil in the incubation.
Combinations of the above plant restoration method, it is further improved, the applied amount of the composite fertilizer is 25kg/ mus~ 35kg/ mus;N, P in the composite fertilizer2O5、K2The weight ratio of O is 15: 10: 10;The applied amount of the organic fertilizer is 450kg/ mus ~500kg/ mus.
In the present invention, witloof (Cichorium intybus L.) used also known as coffee grass belong to composite family, and perennial herb is planted Object.Witloof has the characteristics that grass yield is high, nutritive value is excellent, palatability is good, power of regeneration is strong, and be one kind having potentiality to be exploited very much High yield and high quality forage grass.
In the present invention, Vicia sativa (Vicia villosa Roth) used is that pulse family Vetch is annual or more year sward This plant, well developed root system, main root are apparent.Vicia sativa is the transitional type of spring habit and winter habit, but is biased to winter habit, and nutritive value is very It is high.
In the present invention, broad bean (Vicia faba L.) used, also known as broad bean, lima bean, lima bean etc., are pulse family open country peas Macroptilium annual herb plant.Resistance to -4 DEG C of low temperature of broad bean fears heat, and main root is short and thick, pogoniasis root, root nodule pink, intensive.Broad bean is Grain, vegetables and feed, green manure dual-purpose crop.
In the present invention, pea (Pisum sativum Linn) used, which is that pulse family Vetch is annual, climbs up by holding on to draft, and half Cold resistance crop likes the weather of mild and moist, intolerant to scorching dullness.
In the present invention, Chinese milk vetch (Astragalus sinicus L.) used also known as Chinese milk vetch, are pulse family Astragalus two Year raw herbaceous plant.Chinese milk vetch main root is looser, lateral root bury it is shallower, on the radicula of main root, lateral root and earth's surface can take root Tumor, with number in the majority in lateral root.Mostly set is sowed in late rice Chinese milk vetch in the fall, is made the base manure of early rice, is that China rice field is main Winter green manure crop.Chinese milk vetch nutritive value is quite high, in addition to as green manure, moreover it is possible to which directly or ensiling Chinese milk vetch makees feed.
In the present invention, white clover (Trifolium repens L.) used also known as Trifolium repense, white flower clover etc. are Pulse family Clover perennial herb, wide adaptability, heat resistanceheat resistant winter resistance is strong, can the vigorous growth in acid soil, also can be in sand It is grown in matter soil, there is certain ornamental value, be one of countries in the world Main Cultivation herbage.
In the present invention, Lupinus albus (Lupinus albus) used is pulse family Lupinus annual herb, relatively cold-resistant (- 5 DEG C or more), happy expression, which is waited, feels nice and cool, and well developed root system is drought-enduring, optimum sand loam soil.Lupinus albus can be used as feed and green manure, again It can make ornamental plant.
Compared with the prior art, the advantages of the present invention are as follows:
(1) the present invention provides a kind of combined plant restorative procedures of cadmium pollution soil repair, by chrysanthemum in a manner of work Lettuce is planted in cadmium pollution soil with legume and is cultivated, and realizes effective reparation to cadmium pollution soil.In the present invention, pulse family Plant (such as Vicia sativa, broad bean, pea, Chinese milk vetch, white clover, Lupinus albus) can normally give birth in cadmium pollution soil It is long, and yield keeps normal level, at the same the root system of these legumes can largely secrete a variety of secretion (such as organic acid, Including citric acid, malic acid, lactic acid), and the content of secretion is very high, is on the one hand improved by legume root rhizosphere secreta The physicochemical property of cadmium pollution soil is conducive to the growth of witloof and legume, is on the other hand secreted by legume rhizosphere Organic acid for activating cadmium pollution soil improve the available state of cadmium in soil to change the form or bio-toxicity of cadmium in soil Content achievees the purpose that improve soil available Cd content.On this basis, in the present invention by witloof and legume with The mode of work is planted in cadmium pollution soil, witloof can it is significantly more efficient absorb soil in available Cd, and then preferably The repairing effect to cadmium pollution soil is improved, realizes effective reparation to cadmium pollution soil.In addition, being trained in witloof and legume During supporting, (e.g., regulate and control planting mode (line-spacing, spacing in the rows and application rate), moisture pipe in conjunction with different agronomy regulation measures Reason, fertilizing management, Pest management etc.), on the one hand utilize witloof to extract the preferential absorption of cadmium, and it is logical to be transferred to overground part part Cross to overground part cutting carry out strange land centralized processing, reduce soil available content of beary metal, on the other hand by witloof with Reciprocal effects between legume, the cadmium that legume rhizosphere secretion organic acid can be in activating soil in cadmium pollution soil, Promote absorption of the witloof to cadmium in soil, while reducing the legume with witloof interaction to cadmium uptuke, to drop The content of cadmium in low legume is realized under the premise of not destroying farmland ecological environment and existing plantation function to cadmium pollution soil The in-situ immobilization of earth ensures the purpose of agricultural product security, while not influencing normal agricultural production, and the yield of witloof can be made to protect Normal level is held, and improves the yield of witloof and legume.In the present invention, by witloof and legume kind in a manner of work It is implanted in cadmium pollution soil, using legume to the activation of cadmium in cadmium pollution soil, improves legume rhizosphere soil The content of middle available Cd is reached the effect of activating soil cadmium, while being absorbed to the available Cd in soil using witloof, Uptake of the witloof to soil available Cd can not only be improved, improves repairing effect, and more soil are absorbed by witloof In available Cd can also reduce influence of the available Cd to legume growth and development, to ensure witloof and legume Under the premise of normal growth, the yield of witloof and legume is maintained.In the present invention, witloof is to make autumn and winter with legume Object is made between the two, additionally it is possible to improve land utilization ratio, improve soil nutrient structure, obtain better repairing effect.Of the present invention group Plant restoration method is closed, witloof is planted in cadmium pollution soil with legume in a manner of work cultivates, and can realize Effective reparation to cadmium pollution soil has many advantages, such as that repairing effect is good, income is high, also has that small investment, maintenance cost be low, work Journey amount is small, administrative skill requires low, easy to operate, the advantages that capable of keeping even improveing the physicochemical property of soil, while can It takes into account cadmium pollution soil to produce when repairing, there is good environmental benefit, Social benefit and economic benefit.
(2) in combined plant restorative procedure of the present invention, using witloof as enriching plant, belong to autumn and winter crop.The present invention with Witloof plants witloof as main plant object, using autumn and winter vacant field, public land, does not interfere with the normal production of rice crop, can either The normal volume of rice crop is maintained, and land utilization ratio can also be improved, improves soil nutrient structure.Witloof of the present invention is to cadmium Enrichment performance it is strong, the cadmium content in plant is apparently higher than soil background values, and concentration level is high, and strong to soil suitability, Ground biomass is big.
(3) in combined plant restorative procedure of the present invention, with Vicia sativa, broad bean, pea, Chinese milk vetch, white clover and Bai Yu It is legume to fan at least one of beans, they belong to autumn and winter crop, wherein Vicia sativa, broad bean, Chinese milk vetch, white axle After grass, this 5 kinds of Lupinus albus make cadmium pollution soil repair between legume and witloof, their yield are above pea.In addition, hair For sweet potato other than the nitrogen fixation of root nodule, its own unique root exudates is preferable to the improvement effect of the readily available nutrient of soil; Chinese milk vetch is larger to the concentration coefficient of cadmium, can also improve repairing effect.
(4) in combined plant restorative procedure of the present invention, witloof and legume can normal growth, the yield of witloof is also just Often, reach 5000kg/ mus~6000kg/667m2, economic benefit can be generated, rehabilitation cost is reduced.Meanwhile legume produces Amount is in normal level, and the yield of Vicia sativa is 1000kg/ mu~2500kg/ mus, the yield of broad bean for 150kg/ mus~ 280kg/ mus, the yield of pea is 150kg/ mus~200kg/ mus, and the yield of Chinese milk vetch is 6000kg/ mus~7500kg/ mus, in vain The yield of clover is 2500kg/ mus~3000kg/ mus, and the yield of Lupinus albus is 250kg/ mus~300kg/ mus, also can Preferable economic benefit is generated, rehabilitation cost is further decreased.
Specific implementation mode
Below in conjunction with specific preferred embodiment, the invention will be further described, but not thereby limiting the invention Protection domain.
Material and instrument employed in following embodiment are commercially available.In the embodiment of the present invention, unless otherwise noted, Following the data obtained is the average value of the above experiment three times.
Embodiment 1:
A kind of combined plant restorative procedure of cadmium pollution soil repair specially utilizes the combination reparation of witloof and Vicia sativa Cadmium pollution soil, wherein test site are located at Changsha, Hunan Liuyang City, soil cadmium concentration be respectively 0.5mg/kg and 1.0mg/kg, organic acid content is 113.14mg/kg, soil CaCl in the contaminated soil that cadmium concentration is 0.5mg/kg2- Cd contents For 0.08mg/kg, soil DTPA-Cd contents are 0.21mg/kg;Organic acid content in the contaminated soil that cadmium concentration is 1.0mg/kg For 121.20mg/kg, soil CaCl2- Cd contents are 0.45mg/kg, and soil DTPA-Cd contents are 0.39mg/kg, with work Mode cultivates witloof with Vicia sativa in both cadmium pollution soils, includes the following steps:
(1) October the previous year (autumn) carries out site preparation to cadmium pollution soil, and application promotes the root of witloof and Vicia sativa It is the nitrogen-phosphorus-potassium compound fertilizer (commercially available) and organic fertilizer (commercially available) of growth, the wherein applied amount of nitrogen-phosphorus-potassium compound fertilizer is 28kg/ mus, and N, P in nitrogen-phosphorus-potassium compound fertilizer2O5、K2The weight ratio of O is 15: 10: 10, and the applied amount of organic fertilizer is 450kg/ mus.
(2) by make in a manner of will witloof and Vicia sativa plantation in step (1) in apply fertilizer cadmium pollution soil in, chrysanthemum Line-spacing between lettuce and Vicia sativa is 20cm, and wherein witloof is sowed with drilling method, spacing in the rows 12cm, and application rate is 1.5kg/ mu;Vicia sativa is sowed with drilling method, spacing in the rows 12cm, and application rate is 3.5kg/ mus.According to growth side naturally Formula cycle growth periodically carries out water consumpation management, keeps soil moisture content the 70% of maximum water-holding capacity, until witloof and hair Sweet potato is ripe, completes the reparation to cadmium pollution soil.
Plant harvest period and harvesting method:Witloof and hair sweet potato are harvested respectively in May of next year by a repairing efficiency Sub- overground part.Weigh under witloof-Vicia sativa intercropping system the overground part fresh weight of witloof be 7426kg/ mu (0.5mg/kg cadmium dirts Contaminate soil) and 7361kg/ mus (1.0mg/kg cadmium pollution soils);The witloof aerial part of harvest and Vicia sativa aerial part (pod Fruit, stalk), and the total cadmium content of overground part is measured, as shown in table 1-1;Witloof Rhizosphere Soil and Vicia sativa Rhizosphere Soil are acquired respectively, are surveyed The total cadmium content of Rhizosphere Soil is determined, as shown in table 1-2.
Make Vicia sativa and the total cadmium content of nonoculture mode overground part between table 1-1 witloofs
Make Vicia sativa and nonoculture mode rhizosphere organic acid content and the total cadmium content of Rhizosphere Soil between table 1-2 witloofs
It can be seen that under witloof-Vicia sativa intercropping mode from table 1-1, the total cadmium content of witloof overground part is higher than nonoculture witloof, The total cadmium content of Vicia sativa overground part is then less than nonoculture Vicia sativa.It can be seen that under witloof-Vicia sativa intercropping mode from table 1-2, root Soil total cadmium content in border significantly reduces, and is below nonoculture witloof and nonoculture Vicia sativa, and rhizosphere organic acid content is above nonoculture Witloof and nonoculture Vicia sativa.Consolidated statement 1-1 and table 1-2 is it is found that witloof and Vicia sativa are planted in by the present invention in a manner of work In cadmium pollution soil, using Vicia sativa to the activation of cadmium in cadmium pollution soil, available state in Vicia sativa rhizosphere soil is improved The content of cadmium is reached the effect of activating soil cadmium, while being absorbed to the available Cd in soil using witloof, can not only be carried High witloof improves repairing effect to the uptake of soil available Cd, and is absorbed by witloof effective in more soil State cadmium can also reduce influence of the available Cd to Vicia sativa growth and development, to before ensureing witloof and Vicia sativa normal growth It puts, maintains the yield of witloof and Vicia sativa, have many advantages, such as that repairing effect is good, income is high, there is good environmental benefit, society Meeting benefit and economic benefit, this is demonstrated, and witloof-broad bean intercropping mode is strong to the activation capacity of Cadmium in Soil and extractability is strong, together When show that witloof-Vicia sativa intercropping mode has a high potential to cadmium pollution soil repair.
Embodiment 2:
A kind of combined plant restorative procedure of cadmium pollution soil repair specially utilizes the combination of witloof and broad bean to repair cadmium Contaminated soil, wherein test site are located at Changsha, Hunan Liuyang City, and soil cadmium concentration is respectively 1.0mg/kg and 3.0mg/ Kg, organic acid content is 121.20mg/kg, soil CaCl in the contaminated soil that cadmium concentration is 1.0mg/kg2- Cd contents are 0.45mg/kg, soil DTPA-Cd contents are 0.39mg/kg;Organic acid content is in the contaminated soil that cadmium concentration is 3.0mg/kg 110.03mg/kg soil CaCl2- Cd contents are 1.57mg/kg, and soil DTPA-Cd contents are 1.58mg/kg, with the side made Formula cultivates witloof with broad bean in both cadmium pollution soils, includes the following steps:
(1) October the previous year (autumn) carries out site preparation to cadmium pollution soil, and application promotes the root system of witloof and broad bean The nitrogen-phosphorus-potassium compound fertilizer and organic fertilizer of growth, the wherein applied amount of nitrogen-phosphorus-potassium compound fertilizer are 35kg/ mus, and in nitrogen-phosphorus-potassium compound fertilizer N、P2O5、K2The weight ratio of O is 15: 10: 10, and the applied amount of organic fertilizer (commercially available) is 450kg/ mus.
(2) by make in a manner of will witloof and broad bean plantation in step (1) in apply fertilizer cadmium pollution soil in, witloof Line-spacing between broad bean is 35cm, and wherein witloof is sowed with drilling method, spacing in the rows 15cm, and application rate is 1kg/ mus; Broad bean is sowed with a broadcast mode, spacing in the rows 15cm, and application rate is 6kg/ mus.It is fixed according to natural growth pattern cycle growth Phase carries out water consumpation management, keeps soil moisture content the 75% of maximum water-holding capacity, until witloof and broad bean are ripe, completion pair The reparation of cadmium pollution soil.
Plant harvest period and harvesting method:Witloof and broad bean are harvested respectively in May of next year by a repairing efficiency Plant above ground portion.Weigh under witloof-broad bean intercropping system the overground part fresh weight of witloof be 7404kg/ mu (1.0mg/kg cadmium dirts Contaminate soil) and 7342kg/ mus (3.0mg/kg cadmium pollution soils), harvest the aerial part of witloof and the aerial part (pod of broad bean Fruit, stalk), and the total cadmium content of aerial part is measured, as shown in table 2-1;Witloof Rhizosphere Soil and broad bean Rhizosphere Soil are acquired respectively, are surveyed The total cadmium content of Rhizosphere Soil is determined, as shown in table 2-2.
Table 2-1 witloofs Fababean Intercropping and the total cadmium content of nonoculture mode overground part
Table 2-2 witloofs Fababean Intercropping and nonoculture mode rhizosphere organic acid content and the total cadmium content of Rhizosphere Soil
It can be seen that under witloof-broad bean intercropping mode from table 2-1, the total cadmium content of witloof overground part is higher than nonoculture witloof, silkworm The total cadmium content of beans overground part is then less than nonoculture broad bean.It can be seen that under witloof-broad bean intercropping mode from table 2-2, the total cadmium of Rhizosphere Soil Content significantly reduces, and is below nonoculture witloof and nonoculture broad bean, and rhizosphere organic acid content is above nonoculture witloof and nonoculture Broad bean.Consolidated statement 2-1 and table 2-2 it is found that the present invention in a manner of making by witloof and broad bean in cadmium pollution soil, utilize silkworm Beans improve the content of broad bean rhizosphere soil available Cd, reach activating soil cadmium to the activation of cadmium in cadmium pollution soil Effect, while the available Cd in soil is absorbed using witloof, witloof can not only be improved to soil available Cd Uptake, improve repairing effect, and the available Cd in more soil is absorbed by witloof can also reduce available Cd pair The influence of broad bean growth and development, under the premise of ensureing witloof and broad bean normal growth, maintain the yield of witloof and broad bean, Have many advantages, such as that repairing effect is good, income is high, has good environmental benefit, Social benefit and economic benefit, this demonstrates chrysanthemum Lettuce-broad bean intercropping mode is strong to the activation capacity of Cadmium in Soil and extractability is strong, while showing witloof-broad bean intercropping mode to repairing Multiple cadmium pollution soil has a high potential.
Embodiment 3:
A kind of combined plant restorative procedure of cadmium pollution soil repair specially utilizes the combination of witloof and pea to repair cadmium Contaminated soil, wherein test site are located at Changsha, Hunan Liuyang City, and soil cadmium concentration is respectively 0.3mg/kg and 3.5mg/ Kg, organic acid content is 97.79mg/kg, soil CaCl in the contaminated soil that cadmium concentration is 0.3mg/kg2- Cd contents are 0.05mg/kg, soil DTPA-Cd contents are 0.17mg/kg;Organic acid content is in the contaminated soil that cadmium concentration is 3.5mg/kg 89.97mg/kg soil CaCl2- Cd contents are 1.77mg/kg, and soil DTPA-Cd contents are 1.85mg/kg, with the side made Formula cultivates witloof with pea in both cadmium pollution soils, includes the following steps:
(1) October the previous year (autumn) carries out site preparation to cadmium pollution soil, and application promotes the root system of witloof and pea The nitrogen-phosphorus-potassium compound fertilizer and organic fertilizer of growth, the wherein applied amount of nitrogen-phosphorus-potassium compound fertilizer are 35kg/ mus, and in nitrogen-phosphorus-potassium compound fertilizer N、P2O5、K2The weight ratio of O is 15: 10: 10, and the applied amount of organic fertilizer (commercially available) is 480kg/ mus.
(2) by make in a manner of will witloof and pea plantation in step (1) in apply fertilizer cadmium pollution soil in, witloof Line-spacing between pea is 25cm, and wherein witloof is sowed with drilling method, spacing in the rows 12cm, application rate 1.5kg/ Mu;Pea is sowed with a broadcast mode, spacing in the rows 12cm, and application rate is 7kg/ mus.According to natural growth pattern cycle growth, Water consumpation management is periodically carried out, keeps soil moisture content the 75% of maximum water-holding capacity, until witloof and pea are ripe, completes Reparation to cadmium pollution soil.
Plant harvest period and harvesting method:Witloof and pulse family are harvested respectively in May of next year by a repairing efficiency Plant above ground portion.Weigh witloof-pea witloof overground part fresh weight under intercropping system is 7460kg/ mu (0.3mg/kg cadmiums dirts Contaminate soil) and 7346kg/ mus (3.5mg/kg cadmium pollution soils);The aerial part (pod, stalk) of witloof and pea is harvested, and The total cadmium content of aerial part is measured, as shown in table 3-1;Witloof Rhizosphere Soil and Rhizosphere of Pea soil are acquired respectively, and it is total to measure Rhizosphere Soil Cadmium content, as shown in table 3-2.
Make pea and the total cadmium content of nonoculture mode overground part between table 3-1 witloofs
Make pea and nonoculture mode rhizosphere organic acid content and the total cadmium content of Rhizosphere Soil between table 3-2 witloofs
It can be seen that under witloof-pea intercropping pattern from table 3-1, the total cadmium content of witloof overground part is higher than nonoculture witloof, pea The total cadmium content of beans overground part is then less than nonoculture pea;It can be seen that under witloof-pea intercropping pattern from table 3-2, the total cadmium of Rhizosphere Soil Content significantly reduces, and is below nonoculture witloof and nonoculture pea, and rhizosphere organic acid content is above nonoculture witloof and nonoculture Pea.Consolidated statement 3-1 and table 3-2 is it is found that witloof and pea are planted in cadmium pollution soil by the present invention in a manner of making, profit With pea to the activation of cadmium in cadmium pollution soil, the content of Rhizosphere of Pea soil available Cd is improved, activated soil is reached The effect of earth cadmium, while the available Cd in soil is absorbed using witloof, witloof can not only be improved to effective in soil The uptake of state cadmium improves repairing effect, and absorb the available Cd in more soil by witloof to reduce available state Influence of the cadmium to pea growth and development, to ensureing witloof and under the premise of pea normal growth, maintain witloof and pea Yield has many advantages, such as that repairing effect is good, income is high, there is good environmental benefit, Social benefit and economic benefit, this verification Witloof-pea intercropping pattern is strong to the activation capacity of Cadmium in Soil and extractability is strong, while showing witloof-pea intercropping pattern It has a high potential to cadmium pollution soil repair.
Embodiment 4:
A kind of combined plant restorative procedure of cadmium pollution soil repair specially utilizes the combination reparation of witloof and Chinese milk vetch Cadmium pollution soil, wherein test site are located at Changsha, Hunan Liuyang City, soil cadmium concentration be respectively 1.2mg/kg and 3.6mg/kg, organic acid content is 108.1mg/kg, soil CaCl in the contaminated soil that cadmium concentration is 1.2mg/kg2- Cd contents For 0.31mg/kg, soil DTPA-Cd contents are 0.46mg/kg;Organic acid content in the contaminated soil that cadmium concentration is 3.6mg/kg For 107.05mg/kg, soil CaCl2- Cd contents are 1.85mg/kg, and soil DTPA-Cd contents are 1.82mg/kg, with work Mode cultivates witloof with Chinese milk vetch in both cadmium pollution soils, includes the following steps:
(1) October the previous year (autumn) carries out site preparation to cadmium pollution soil, and application promotes the root of witloof and Chinese milk vetch It is the nitrogen-phosphorus-potassium compound fertilizer and organic fertilizer of growth, wherein the applied amount of nitrogen-phosphorus-potassium compound fertilizer is 30kg/ mus, and nitrogen-phosphorus-potassium compound fertilizer Middle N, P2O5、K2The weight ratio of O is 15: 10: 10, and the applied amount of organic fertilizer (commercially available) is 450kg/ mus.
(2) by make in a manner of will witloof and Chinese milk vetch plantation in step (1) in apply fertilizer cadmium pollution soil in, chrysanthemum Line-spacing between lettuce and Chinese milk vetch is 20cm, and wherein witloof is sowed with drilling method, spacing in the rows 10cm, and application rate is 1.5kg/ mu;Chinese milk vetch is sowed with drilling method, spacing in the rows 10cm, and application rate is 1.5kg/ mus.According to growth side naturally Formula cycle growth periodically carries out water consumpation management, keeps soil moisture content the 65% of maximum water-holding capacity, until witloof and purple Cloud Yingcheng is ripe, completes the reparation to cadmium pollution soil.
Plant harvest period and harvesting method:Witloof and purple cloud are harvested respectively in May of next year by a repairing efficiency English overground part.Weigh the lower witloof overground part fresh weight of witloof-Chinese milk vetch processing be 7406kg/ mus (1.2mg/kg cadmium pollution soils) and 7396kg/ mus (3.6mg/kg cadmium pollution soils);The aerial part (stalk) of witloof and Chinese milk vetch is harvested, and measures aerial part Total cadmium content, as shown in table 4-1;Witloof Rhizosphere Soil and Chinese milk vetch Rhizosphere Soil are acquired respectively, measure the total cadmium content of Rhizosphere Soil, such as table Shown in 4-2.
Make Chinese milk vetch and the total cadmium content of nonoculture mode overground part between table 4-1 witloofs
Make Chinese milk vetch and nonoculture mode rhizosphere organic acid content and the total cadmium content of Rhizosphere Soil between table 4-2 witloofs
It can be seen that under witloof-Chinese milk vetch intercropping mode from table 4-1, the total cadmium content of witloof overground part is higher than nonoculture witloof, The total cadmium content of Chinese milk vetch overground part is then less than nonoculture Chinese milk vetch;It can be seen that under witloof-Chinese milk vetch intercropping mode from table 4-2, root Soil total cadmium content in border significantly reduces, and is below nonoculture witloof and nonoculture Chinese milk vetch, and rhizosphere organic acid content is above nonoculture Witloof and nonoculture Chinese milk vetch.Consolidated statement 4-1 and table 4-2 is it is found that witloof and Chinese milk vetch are planted in by the present invention in a manner of work In cadmium pollution soil, using Chinese milk vetch to the activation of cadmium in cadmium pollution soil, available state in Chinese milk vetch rhizosphere soil is improved The content of cadmium is reached the effect of activating soil cadmium, while being absorbed to the available Cd in soil using witloof, can not only be carried High witloof improves repairing effect to the uptake of soil available Cd, and is absorbed by witloof effective in more soil State cadmium can also reduce influence of the available Cd to Chinese milk vetch growth and development, to before ensureing witloof and Chinese milk vetch normal growth It puts, maintains the yield of witloof and Chinese milk vetch, have many advantages, such as that repairing effect is good, income is high, there is good environmental benefit, society Meeting benefit and economic benefit, this is demonstrated, and witloof-Chinese milk vetch intercropping mode is strong to the activation capacity of Cadmium in Soil and extractability is strong, Show that witloof-Chinese milk vetch intercropping mode has a high potential to cadmium pollution soil repair.
Embodiment 5:
A kind of combined plant restorative procedure of cadmium pollution soil repair, is specially repaiied using the combination of witloof and white clover Multiple cadmium pollution soil, wherein test site are located at Changsha, Hunan Liuyang City, soil cadmium concentration be respectively 0.3mg/kg with 2.5mg/kg, organic acid content is 97.79mg/kg, soil CaCl in the contaminated soil that cadmium concentration is 0.3mg/kg2- Cd contents For 0.05mg/kg, soil DTPA-Cd contents are 0.17mg/kg;Organic acid content in the contaminated soil that cadmium concentration is 2.5mg/kg For 122.73mg/kg, soil CaCl2- Cd contents are 1.32mg/kg, and soil DTPA-Cd contents are 1.61mg/kg, with work Mode cultivates witloof with white clover in both cadmium pollution soils, includes the following steps:
(1) October the previous year (autumn) carries out site preparation to cadmium pollution soil, and application promotes witloof and white clover The nitrogen-phosphorus-potassium compound fertilizer and organic fertilizer of root growth, the wherein applied amount of nitrogen-phosphorus-potassium compound fertilizer are 30kg/ mus, and N P and K is compound N, P in fertilizer2O5、K2The weight ratio of O is 15: 10: 10, and the applied amount of organic fertilizer (commercially available) is 480kg/ mus.
(2) by make in a manner of will witloof and white clover plantation in step (1) in apply fertilizer cadmium pollution soil in, Line-spacing between witloof and white clover is 20cm, and wherein witloof is sowed with drilling method, spacing in the rows 10cm, and application rate is 1.5kg/ mu;White clover is sowed with drilling method, spacing in the rows 10cm, and application rate is 1kg/ mus.According to growth side naturally Formula cycle growth, it is regular to carry out water consumpation management, keep soil moisture content the 65% of maximum water-holding capacity, up to witloof and in vain Clover is ripe, completes the reparation to cadmium pollution soil.
Plant harvest period and harvesting method:Witloof and Bai Che are harvested respectively in May of next year by a repairing efficiency Axis meadow top.It is 7411kg/ mus of (0.3mg/kg cadmium dirts to weigh witloof overground part fresh weight under witloof-white clover intercropping system Contaminate soil) and 7344kg/ mus (2.5mg/kg cadmium pollution soils);Aerial part (the straw of witloof and white clover are harvested respectively Stalk), and the total cadmium content of aerial part is measured, as shown in Table 5-1;The rhizosphere of the Rhizosphere Soil and white clover of acquisition witloof respectively Soil measures the total cadmium content of Rhizosphere Soil, as shown in table 5-2.
Make white clover and the total cadmium content of nonoculture mode overground part between table 5-1 witloofs
Make white clover and nonoculture mode rhizosphere organic acid content and the total cadmium content of Rhizosphere Soil between table 5-2 witloofs
It can be seen that under witloof-white clover intercropping mode from table 5-1, the total cadmium content of witloof overground part is higher than nonoculture chrysanthemum Lettuce, the total cadmium content of white clover overground part are then less than nonoculture white clover;Make between can be seen that witloof-white clover from table 5-2 Under pattern, the total cadmium content of Rhizosphere Soil significantly reduces, and is below nonoculture witloof and nonoculture white clover, and rhizosphere organic acid content It is above nonoculture witloof and nonoculture white clover.Consolidated statement 5-1 and table 5-2 it is found that the present invention by make in a manner of by witloof with White clover is planted in cadmium pollution soil, using white clover to the activation of cadmium in cadmium pollution soil, improves white axle The content of grass roots border soil available Cd reaches the effect of activating soil cadmium, while using witloof to the available state in soil Cadmium is absorbed, and uptake of the witloof to soil available Cd can not only be improved, and improves repairing effect, and inhale by witloof Influence of the available Cd to white clover growth and development can also be reduced by receiving the available Cd in more soil, to ensure witloof Under the premise of white clover normal growth, the yield of witloof and white clover is maintained, it is excellent to have that repairing effect is good, income is high etc. Point has good environmental benefit, Social benefit and economic benefit, this demonstrates witloof-white clover intercropping mode to soil The activation capacity of cadmium is strong and extractability is strong, while showing that witloof-white clover intercropping mode dives to cadmium pollution soil repair Power is huge.
Embodiment 6:
A kind of combined plant restorative procedure of cadmium pollution soil repair, is specially repaiied using the combination of witloof and Lupinus albus Multiple cadmium pollution soil, wherein test site are located at Changsha, Hunan Liuyang City, soil cadmium concentration be respectively 0.5mg/kg with 5.0mg/kg, organic acid content is 113.14mg/kg, soil CaCl in the contaminated soil that cadmium concentration is 0.5mg/kg2- Cd contents For 0.08mg/kg, soil DTPA-Cd contents are 0.21mg/kg;Organic acid content in the contaminated soil that cadmium concentration is 5.0mg/kg For 106.92mg/kg, soil CaCl2- Cd contents are 2.28mg/kg, and soil DTPA-Cd contents are 2.51mg/kg, with work Mode cultivates witloof with Lupinus albus in both cadmium pollution soils, includes the following steps:
(1) October the previous year (autumn) carries out site preparation to cadmium pollution soil, and application promotes witloof and Lupinus albus The nitrogen-phosphorus-potassium compound fertilizer and organic fertilizer of root growth, the wherein applied amount of nitrogen-phosphorus-potassium compound fertilizer are 30kg/ mus, and N P and K is compound N, P in fertilizer2O5、K2The weight ratio of O is 15: 10: 10, and the applied amount of organic fertilizer (commercially available) is 480kg/ mus.
(2) by make in a manner of will witloof and Lupinus albus plantation in step (1) in apply fertilizer cadmium pollution soil in, Line-spacing between witloof and Lupinus albus is 30cm, and wherein witloof is sowed with drilling method, spacing in the rows 15cm, and application rate is 1.5kg/ mu;Lupinus albus is sowed with drilling method, spacing in the rows 15cm, and application rate is 3.5kg/ mus.According to natural growth Mode cycle growth periodically carries out water consumpation management, keeps soil moisture content the 70% of maximum water-holding capacity, until witloof and Lupinus albus is ripe, completes the reparation to cadmium pollution soil.
Plant harvest period and harvesting method:After a repairing efficiency, witloof and Lupinus albus plant are harvested respectively Overground part.It is 7408kg/ mus of (0.5mg/kg cadmium pollution soil to weigh witloof overground part fresh weight under witloof-Lupinus albus intercropping system Earth) and 7260kg/ mus (5.0mg/kg cadmium pollution soils);Aerial part (pod, the straw of witloof and Lupinus albus are harvested respectively Stalk), and the total cadmium content of aerial part is measured, as shown in Table 6-1;Witloof Rhizosphere Soil and Lupinus albus Rhizosphere Soil are acquired respectively, are surveyed Fixed two kinds of total cadmium contents of Rhizosphere Soil, as shown in table 6-2.
Make Lupinus albus and the total cadmium content of nonoculture mode overground part between table 6-1 witloofs
Make Lupinus albus and nonoculture mode rhizosphere organic acid content and the total cadmium content of Rhizosphere Soil between table 6-2 witloofs
It can be seen that under witloof-Lupinus albus intercropping mode from table 6-1, the total cadmium content of witloof overground part is higher than nonoculture Witloof, the total cadmium content of Lupinus albus overground part are then less than nonoculture Lupinus albus;It can be seen that from table 6-2 in witloof-Lupinus albus Under intercropping mode, the total cadmium content of Rhizosphere Soil significantly reduces, and is below nonoculture witloof and nonoculture Lupinus albus, and rhizosphere organic acid Content is above nonoculture witloof and nonoculture Lupinus albus.Consolidated statement 6-1 and table 6-2 it is found that the present invention in a manner of making by chrysanthemum Lettuce is planted in Lupinus albus in cadmium pollution soil, using Lupinus albus to the activation of cadmium in cadmium pollution soil, improves white The content of available Cd in lupin rhizosphere soil reaches the effect of activating soil cadmium, while using witloof to having in soil Effect state cadmium is absorbed, and uptake of the witloof to soil available Cd can not only be improved, and improves repairing effect, and pass through chrysanthemum Lettuce, which absorbs the available Cd in more soil, can also reduce influence of the available Cd to Lupinus albus growth and development, to ensure Under the premise of witloof and Lupinus albus normal growth, the yield of witloof and Lupinus albus is maintained, has that repairing effect is good, income is high The advantages that, there are good environmental benefit, Social benefit and economic benefit, this demonstrates witloof-Lupinus albus intercropping mode pair The activation capacity of Cadmium in Soil is strong and extractability is strong, while showing witloof-Lupinus albus intercropping mode to cadmium pollution soil repair Have a high potential.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation Example.All technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It is noted that for the art Those of ordinary skill for, improvements and modifications without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (10)

1. a kind of combined plant restorative procedure of cadmium pollution soil repair, which is characterized in that the combined plant restorative procedure packet Include following steps:Witloof is planted in cadmium pollution soil with legume in a manner of work to cultivate, is completed to cadmium pollution The reparation of soil.
2. combined plant restorative procedure according to claim 1, which is characterized in that between the witloof and legume Line-spacing is 20cm~40cm.
3. combined plant restorative procedure according to claim 2, which is characterized in that the witloof is with drilling method by chrysanthemum Lettuce seed is sowed in cadmium pollution soil;The sowing spacing in the rows of the chicory seed is 10cm~15cm.
4. combined plant restorative procedure according to claim 3, which is characterized in that the application rate of the witloof is 1kg/ mus ~1.5kg/ mus.
5. combined plant restorative procedure according to claim 2, which is characterized in that the legume is Vicia sativa, silkworm At least one of beans, pea, Chinese milk vetch, white clover, Lupinus albus.
6. combined plant restorative procedure according to claim 5, which is characterized in that the legume is broad bean, pea When, seeds of leguminous plant is sowed in cadmium pollution soil with broadcast mode;The sowing spacing in the rows of the seeds of leguminous plant is 10cm~20cm;The application rate of the broad bean is 5.5kg/ mus~7kg/ mus;The application rate of the pea be 5.5kg/ mus~ 8kg/ mus.
7. combined plant restorative procedure according to claim 5, which is characterized in that the legume is Vicia sativa, purple When Yun Ying, white clover, Lupinus albus, seeds of leguminous plant is sowed in cadmium pollution soil with drilling method;The pulse family The sowing spacing in the rows of vegetable seeds is 10cm~20cm;The application rate of the Vicia sativa is 3kg/ mus~4kg/ mus;The Chinese milk vetch Application rate be 1kg/ mus~2kg/ mus;The application rate of the white clover is 0.5kg/ mus~1kg/ mus;The Lupinus albus Application rate be 3kg/ mus~4kg/ mus.
8. combined plant restorative procedure according to any one of claims 1 to 7, which is characterized in that the cadmium pollution soil The initial concentration of cadmium is 0.3mg/kg~5.0mg/kg in earth.
9. combined plant restorative procedure according to any one of claims 1 to 7, which is characterized in that the legume In the fall or winter planting;The culture is carried out according to plant nature growth pattern;Cadmium pollution soil is kept in the incubation Earth water content is the 65%~75% of maximum water-holding capacity;Further include applying composite fertilizer into cadmium pollution soil in the incubation And organic fertilizer.
10. combined plant restorative procedure according to claim 9, which is characterized in that the applied amount of the composite fertilizer is 25kg/ mus~35kg/ mus;N, P in the composite fertilizer2O5、K2The weight ratio of O is 15: 10: 10;The applied amount of the organic fertilizer is 450kg/ mus~500kg/ mus.
CN201810901759.5A 2018-08-09 2018-08-09 A kind of combined plant restorative procedure of cadmium pollution soil repair Pending CN108787724A (en)

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