CN108777233A - Chip polymer stack aluminum capacitor - Google Patents

Chip polymer stack aluminum capacitor Download PDF

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Publication number
CN108777233A
CN108777233A CN201810519504.2A CN201810519504A CN108777233A CN 108777233 A CN108777233 A CN 108777233A CN 201810519504 A CN201810519504 A CN 201810519504A CN 108777233 A CN108777233 A CN 108777233A
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CN
China
Prior art keywords
aluminium flake
shell
positive
cathode
out terminal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810519504.2A
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Chinese (zh)
Inventor
宋庆杰
袁坤阳
王慧卉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhuzhou Hongda Electronics Corp Ltd
Original Assignee
Zhuzhou Hongda Electronics Corp Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhuzhou Hongda Electronics Corp Ltd filed Critical Zhuzhou Hongda Electronics Corp Ltd
Priority to CN201810519504.2A priority Critical patent/CN108777233A/en
Publication of CN108777233A publication Critical patent/CN108777233A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/15Solid electrolytic capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/0029Processes of manufacture
    • H01G9/0032Processes of manufacture formation of the dielectric layer
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004Details
    • H01G9/008Terminals
    • H01G9/012Terminals specially adapted for solid capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004Details
    • H01G9/04Electrodes or formation of dielectric layers thereon
    • H01G9/042Electrodes or formation of dielectric layers thereon characterised by the material
    • H01G9/0425Electrodes or formation of dielectric layers thereon characterised by the material specially adapted for cathode
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004Details
    • H01G9/04Electrodes or formation of dielectric layers thereon
    • H01G9/048Electrodes or formation of dielectric layers thereon characterised by their structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/004Details
    • H01G9/08Housing; Encapsulation

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Primary Cells (AREA)

Abstract

Chip polymer stack aluminum capacitor of the present invention includes aluminium flake capacitor cell, adhesive layer, positive welding gasket, positive leading-out terminal, cathode leading-out terminal, shell, wherein, aluminium flake capacitor cell is multigroup, stacked arrangement is inside the shell, aluminium flake capacitor cell one end is connected with positive welding gasket, positive welding gasket is fixed inside the shell, positive leading-out terminal is connect with positive welding gasket, positive leads ends are formed across shell, for cathode leading-out terminal by being connect with the aluminium flake capacitor cell other end, cathode leading-out terminal passes through shell to form negative pin end.Products obtained therefrom of the present invention has the performance of safety and reliability, does not burn, while having smaller equivalent series resistance, more excellent Acclimation temperature performance is more suitable in the circuits such as various high-frequency circuits, CPU.

Description

Chip polymer stack aluminum capacitor
Technical field
The present invention relates to capacitor technology fields, refer in particular to chip polymer stack aluminum capacitor.
Background technology
An important component of the capacitor as electronic component, in recent years with science and technology rapidly development, Electronic product is towards slim, small-sized, surface mount manner rapid development, for capacitor, ultra-low equivalent series resistance, height Frequency characteristic, high temperature reliability etc. are its important development directions.Chip polymer stack aluminum capacitor is international in recent years, domestic One important R&D direction of Power capacitor industry, the product is polarized, patch type compared with traditional liquid aluminium electrolutic capacitor Capacitor.Traditional liquid aluminium electrolutic capacitor manufacture is relatively easy, and equipment and match materials are easy, therefore, the production unit cost Relative moderate.But change in resistance is big there is varying with temperature for the liquid electrolyte of the product, there is the security risk of leakage The defects of.And chip polymer stack aluminum capacitor, it is made due to the use of organic polymer cathode material, thus can be to avoid these Defect.
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of reliable pieces high, Acclimation temperature performance is good Formula polymer stack aluminum capacitor.
To achieve the above object, technical matters provided by the present invention is:
1), using the aluminium flake for the reaming for cutting completion in advance, be accurately located at stainless steel steel bar using the method for electric resistance welding On, it is equal to be welded on the distance between adjacent sheet on stainless steel steel bar;The Pureness control of aluminium in the aluminium flake material of the reaming 99.99% or more;
2), aluminium flake is immersed in certain phosphoric acid weak solution, conductivity is controlled in 2200 ~ 2800 μ s/ in production process Cm repairs the technique of alundum (Al2O3) dielectric layer by applying DC current and voltage;Initial electric energy supply maintains one Under a constant electric current, until reaching required voltage of energizing;Then the supply that electric energy is kept under constant voltage, is ensured with this The dielectric thickness being pre-designed is formed in the aluminum flake surface of reaming, then energized current is decayed;Time when energizing is 180 points Clock, between temperature is 80 ~ 85 degrees Celsius;
3) chemical polymerization, electrochemical polymerization or physics coating method is used to prepare conducting high polymers object as cathode;Chemistry is poly- Conjunction is most important one preparation method, its main technique mode is by recycling oxide impregnation agent and monomer, and certain In the environment of grow into fine and close, uniform polymer, ensure the stability of cathode layer with this.In practical procedures, need The rate of specific gravity 0.889 ~ 0.895 of monomer solution is strictly controlled using densimeter.
4), in macromolecule cathode polymerization layer surface carry out graphite linings covering, form anaerobic electronic contact, it is conductive to increase cathode Property and reduce product equivalent series resistance;The silver slurry layer of a floor height electric conductivity is covered in graphite linings, increases the electric conductivity of product And reliability;In the process, final aluminium flake thickness needs to control in 0.150 ~ 0.180mm;
5), according to the Capacity design of product require, in conjunction with the practical bulking value of the aluminium flake material of reaming, piecewise by the aluminium flake of reaming It stacks, while reaching every electrical performance indexes;In stacking technique, anode is handled by electric resistance welding and is connected, cathode By the bonding silver paste with high conductivity and applying certain temperature and pressure makes the aluminium flake of each reaming complete bonding;
6), with epoxide resin material product plastic packaging is got up to have the function that protective condenser.
Chip polymer stack aluminum capacitor includes aluminium flake capacitor cell, adhesive layer, positive welding gasket, anode extraction Terminal, cathode leading-out terminal, shell, wherein aluminium flake capacitor cell be it is multigroup, stacked arrangement inside the shell, neighbouring aluminium capacitance It being bonded by adhesive layer between unit, adhesive layer is bonded using silver paste, and aluminium flake capacitor cell one end is connected with positive welding gasket, Positive welding gasket is fixed inside the shell, and positive leading-out terminal one end is connect with positive welding gasket, and the other end passes through outer hull shape At positive leads ends, cathode leading-out terminal is connect with the aluminium flake capacitor cell other end, and the cathode leading-out terminal other end passes through shell Form negative pin end.
The aluminium flake capacitor cell includes aluminium flake, macromolecule cathode polymer layer, graphite linings, silver slurry layer, wherein aluminium Piece one end is connect with positive welding gasket, and the surface of the aluminium flake other end is coated with macromolecule cathode polymer layer, macromolecule cathode Polymer layer surface is equipped with graphite linings, and graphite layer surface is equipped with silver slurry layer.
The shell seals to be formed using epoxy resin.
The aluminum capacitor of this programme is highly suitable for the place of small size large capacity high reliability.If passing through porous aluminium flake Chip polymer stack aluminum capacitor is made in lamination, can obtain extremely low equivalent series resistance(ESR), this programme products obtained therefrom tool The performance for having safety and reliability, does not burn, while having smaller equivalent series resistance, more excellent Acclimation temperature performance, more Suitable for the circuits such as various high-frequency circuits, CPU.The actual capacity that product needs the number of plies stacked to depend in products application needs It asks, and depending on combination final design;First the positive gasket material of product is connected to using electric resistance welding on aluminium flake, and successively It is soldered to the pre-designed number of plies;Then, by every layer of aluminium flake capacitor cell of coated silver paste in advance, apply certain temperature and Pressure is completed to be bonded, finally, be protected capacitor plastic packaging using epoxy potting material in conjunction with cathode leading-out terminal, Form a complete capacitor.
Description of the drawings
Fig. 1 is the overall structure diagram of the present invention.
Fig. 2 is aluminium flake capacitor cell structural schematic diagram.
Specific implementation mode
With reference to all attached drawings, the invention will be further described, and presently preferred embodiments of the present invention is:Referring to 1 He of attached drawing Attached drawing 2, the technical matters described in the present embodiment are:
1), using the aluminium flake for the reaming for cutting completion in advance, be accurately located at stainless steel steel bar using the method for electric resistance welding On, it is equal to be welded on the distance between adjacent sheet on stainless steel steel bar;The Pureness control of aluminium in the aluminium flake material of the reaming 99.99% or more;
2), aluminium flake is immersed in certain phosphoric acid weak solution, conductivity is controlled in 2200 ~ 2800 μ s/ in production process Cm repairs the technique of alundum (Al2O3) dielectric layer by applying DC current and voltage;Initial electric energy supply maintains one Under a constant electric current, until reaching required voltage of energizing;Then the supply that electric energy is kept under constant voltage, is ensured with this The dielectric thickness being pre-designed is formed in the aluminum flake surface of reaming, then energized current is decayed;Time when energizing is 180 points Clock, between temperature is 80 ~ 85 degrees Celsius;
3) chemical polymerization, electrochemical polymerization or physics coating method is used to prepare conducting high polymers object as cathode;Chemistry is poly- Conjunction is most important one preparation method, its main technique mode is by recycling oxide impregnation agent and monomer, and certain In the environment of grow into fine and close, uniform polymer, ensure the stability of cathode layer with this.In practical procedures, need The rate of specific gravity 0.889 ~ 0.895 of monomer solution is strictly controlled using densimeter.
4), in macromolecule cathode polymerization layer surface carry out graphite linings covering, form anaerobic electronic contact, it is conductive to increase cathode Property and reduce product equivalent series resistance;The silver slurry layer of a floor height electric conductivity is covered in graphite linings, increases the electric conductivity of product And reliability;In the process, final aluminium flake thickness needs to control in 0.150 ~ 0.180mm;
5), according to the Capacity design of product require, in conjunction with the practical bulking value of the aluminium flake material of reaming, piecewise by the aluminium flake of reaming It stacks, while reaching every electrical performance indexes;In stacking technique, anode is handled by electric resistance welding and is connected, cathode By the bonding silver paste with high conductivity and applying certain temperature and pressure makes the aluminium flake of each reaming complete bonding;
6), with epoxide resin material product plastic packaging is got up to have the function that protective condenser.
Include aluminium flake capacitor cell 1, adhesive layer 2, just by the chip polymer stack aluminum capacitor of above-mentioned technique productions Pole welding gasket 3, positive leading-out terminal 4, cathode leading-out terminal 5, shell 6, wherein aluminium flake capacitor cell 1 is multigroup, stacking row It is listed in shell 6, shell 6 seals to be formed using epoxy resin;It is bonded, is glued by adhesive layer 2 between neighbouring aluminium capacitor cell 1 Tying layer 2 uses silver paste material, 1 one end of aluminium flake capacitor cell to be connected with positive welding gasket 3, and positive welding gasket 3 is fixed on outer In shell 6, positive leading-out terminal 4 is connect with positive welding gasket 3, and positive leads ends, cathode leading-out terminal 5 are formed across shell 6 It is connect with 1 other end of aluminium flake capacitor cell, cathode leading-out terminal 5 passes through shell 6 to form negative pin end.Aluminium flake capacitor cell 1 Include aluminium flake 7, macromolecule cathode polymer layer 8, graphite linings 9, silver slurry layer 10, wherein 7 one end of aluminium flake and positive welding gasket 3 connections, the surface of 7 other end of aluminium flake are coated with macromolecule cathode polymer layer 8, and 8 surface of macromolecule cathode polymer layer is equipped with Graphite linings 9,9 surface of graphite linings are equipped with silver slurry layer 10.The aluminum capacitor of this programme is highly suitable for small size large capacity high reliability Place.If chip polymer stack aluminum capacitor is made by the lamination of porous aluminium flake, extremely low equivalent series can be obtained Resistance(ESR), this programme products obtained therefrom has the performance of safety and reliability, does not burn, while having smaller equivalent series winding electricity Resistance, more excellent Acclimation temperature performance are more suitable in the circuits such as various high-frequency circuits, CPU.Product needs the number of plies stacked to take Actual capacity demand certainly in products application, and depending on combination final design;The positive gasket material of product is first used into electricity Welding resistance is welded to connect on aluminium flake, and is successively soldered to the pre-designed number of plies;Then, by every layer of coated silver paste in advance Aluminium flake capacitor cell applies certain temperature and pressure, completes to be bonded in conjunction with cathode leading-out terminal, finally, close using epoxy resin Closure material protects capacitor plastic packaging, forms a complete capacitor.
The upper embodiment is only the preferred embodiments of the invention, and but not intended to limit the scope of the present invention, therefore Change made by all shapes according to the present invention, principle, should all cover within the scope of the present invention.

Claims (3)

1. chip polymer stack aluminum capacitor, it is characterised in that:It includes aluminium flake capacitor cell(1), adhesive layer(2), just Pole welding gasket(3), positive leading-out terminal(4), cathode leading-out terminal(5), shell(6), wherein aluminium flake capacitor cell(1)For Multigroup, stacked arrangement is in shell(6)It is interior, neighbouring aluminium capacitor cell(1)Between pass through adhesive layer(2)Bonding, adhesive layer(2)It adopts With silver paste material, aluminium flake capacitor cell(1)One end is connected with positive welding gasket(3), positive welding gasket(3)It is fixed on shell (6)It is interior, positive leading-out terminal(4)With positive welding gasket(3)Connection passes through shell(6)Positive leads ends are formed, cathode is drawn Terminal(5)With aluminium flake capacitor cell(1)The other end connects, cathode leading-out terminal(5)Across shell(6)Form negative pin end.
2. capacitor according to claim 1, it is characterised in that:Aluminium flake capacitor cell(1)It include aluminium flake(7), high score Sub- cathode polymer layer(8), graphite linings(9), silver slurry layer(10), wherein aluminium flake(7)One end and positive welding gasket(3)Connection, Aluminium flake(7)The surface of the other end is coated with macromolecule cathode polymer layer(8), macromolecule cathode polymer layer(8)Surface is equipped with Graphite linings(9), graphite linings(9)Surface is equipped with silver slurry layer(10).
3. capacitor according to claim 1, it is characterised in that:Shell(6)It seals to be formed using epoxy resin.
CN201810519504.2A 2018-05-28 2018-05-28 Chip polymer stack aluminum capacitor Pending CN108777233A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810519504.2A CN108777233A (en) 2018-05-28 2018-05-28 Chip polymer stack aluminum capacitor

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Application Number Priority Date Filing Date Title
CN201810519504.2A CN108777233A (en) 2018-05-28 2018-05-28 Chip polymer stack aluminum capacitor

Publications (1)

Publication Number Publication Date
CN108777233A true CN108777233A (en) 2018-11-09

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112820546A (en) * 2020-12-31 2021-05-18 中国振华(集团)新云电子元器件有限责任公司(国营第四三二六厂) Capacitor, multilayer capacitor, and method for manufacturing multilayer capacitor
CN114220662A (en) * 2021-12-13 2022-03-22 上海永铭电子股份有限公司 Laminated solid aluminum electrolytic capacitor with low ESR (equivalent series resistance), high voltage and large capacity and preparation method thereof
CN114709081A (en) * 2022-04-12 2022-07-05 南通飞泰电子科技有限公司 High-capacity low-voltage chip type laminated aluminum capacitor and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107946075A (en) * 2017-11-18 2018-04-20 湖南艾华集团股份有限公司 Stacked capacitor
CN207409387U (en) * 2017-11-27 2018-05-25 福建国光电子科技股份有限公司 A kind of polymer chip-type laminated solid aluminum electrolytic capacitor of low ESR
CN208368360U (en) * 2018-05-28 2019-01-11 株洲宏达电子股份有限公司 Chip polymer stack aluminum capacitor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107946075A (en) * 2017-11-18 2018-04-20 湖南艾华集团股份有限公司 Stacked capacitor
CN207409387U (en) * 2017-11-27 2018-05-25 福建国光电子科技股份有限公司 A kind of polymer chip-type laminated solid aluminum electrolytic capacitor of low ESR
CN208368360U (en) * 2018-05-28 2019-01-11 株洲宏达电子股份有限公司 Chip polymer stack aluminum capacitor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112820546A (en) * 2020-12-31 2021-05-18 中国振华(集团)新云电子元器件有限责任公司(国营第四三二六厂) Capacitor, multilayer capacitor, and method for manufacturing multilayer capacitor
CN114220662A (en) * 2021-12-13 2022-03-22 上海永铭电子股份有限公司 Laminated solid aluminum electrolytic capacitor with low ESR (equivalent series resistance), high voltage and large capacity and preparation method thereof
CN114709081A (en) * 2022-04-12 2022-07-05 南通飞泰电子科技有限公司 High-capacity low-voltage chip type laminated aluminum capacitor and preparation method thereof

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Application publication date: 20181109

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