CN109087811A - A kind of surface attaching type solid-state aluminum electrolytic capacitor - Google Patents
A kind of surface attaching type solid-state aluminum electrolytic capacitor Download PDFInfo
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- CN109087811A CN109087811A CN201810974249.0A CN201810974249A CN109087811A CN 109087811 A CN109087811 A CN 109087811A CN 201810974249 A CN201810974249 A CN 201810974249A CN 109087811 A CN109087811 A CN 109087811A
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- 239000003990 capacitor Substances 0.000 title claims abstract description 61
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 36
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 239000003292 glue Substances 0.000 claims abstract description 11
- 230000001681 protective effect Effects 0.000 claims abstract description 11
- 238000005266 casting Methods 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- 238000007493 shaping process Methods 0.000 claims abstract description 5
- 238000010792 warming Methods 0.000 claims description 41
- 239000011888 foil Substances 0.000 claims description 18
- 230000032683 aging Effects 0.000 claims description 11
- 238000005470 impregnation Methods 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 9
- 230000005611 electricity Effects 0.000 claims description 6
- 238000005452 bending Methods 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000005476 soldering Methods 0.000 abstract description 5
- 238000004220 aggregation Methods 0.000 abstract description 3
- 230000002776 aggregation Effects 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 2
- 239000000376 reactant Substances 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 12
- 239000007787 solid Substances 0.000 description 9
- 239000000178 monomer Substances 0.000 description 8
- 239000007800 oxidant agent Substances 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 6
- 229920001940 conductive polymer Polymers 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 238000003763 carbonization Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000002322 conducting polymer Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 230000006355 external stress Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 description 1
- FLDCSPABIQBYKP-UHFFFAOYSA-N 5-chloro-1,2-dimethylbenzimidazole Chemical compound ClC1=CC=C2N(C)C(C)=NC2=C1 FLDCSPABIQBYKP-UHFFFAOYSA-N 0.000 description 1
- 239000001741 Ammonium adipate Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 235000019293 ammonium adipate Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- LWLURCPMVVCCCR-UHFFFAOYSA-N iron;4-methylbenzenesulfonic acid Chemical compound [Fe].CC1=CC=C(S(O)(=O)=O)C=C1 LWLURCPMVVCCCR-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- -1 nail is rolled up Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/15—Solid electrolytic capacitors
- H01G9/151—Solid electrolytic capacitors with wound foil electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/008—Terminals
- H01G9/012—Terminals specially adapted for solid capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/08—Housing; Encapsulation
Abstract
A kind of surface attaching type solid-state aluminum electrolytic capacitor, using carbon electrolytic paper is exempted from, lead is half-hard wire;Also contain outside core packet after coiled polymer and is soaked with one layer of casting glue protective film;It is rectangle or trapezoidal with a tight waist that the shell of capacitor and the contact site of rubber plug, which are provided with section,;A kind of manufacturing method of surface attaching type solid-state aluminum electrolytic capacitor, polymerization further include heating, and the final temperature of heating is higher than the operating temperature of subsequent reflow weldering.The beneficial effects of the invention are as follows; a protective film is first impregnated with after core packet aggregation, after it is sealed again, make capacitor that there is stronger resistivity when fighting the inevitable external force such as machine-shaping; simultaneously because polymerization temperature is higher than Reflow Soldering temperature, unreacted reactant is cleared up more thorough.
Description
Technical field
The present invention relates to aluminium electrolutic capacitor and its technologies of preparing, and in particular to a kind of surface attaching type solid-state aluminium electroloysis electricity
Container and preparation method thereof.
Background technique
Capacitor, is a kind of device for accommodating charge, and one of the electronic component largely used in electronic equipment is widely applied
Separated by direct communication, coupling, bypass, filtering, resonant tank, energy conversion, control in circuit etc..Using surface mount skill
Art can increase productivity without carrying out brill dress hole to printed board to reduce process.
Solid-state aluminum electrolytic capacitor, abbreviation solid capacitor, the maximum of it and conventional capacitive (i.e. liquid aluminum electrolytic capacitor)
Difference is to use conductive polymer material as dielectric material, so as to avoid the bulge and leakage of ordinary capacitor.
Solid capacitor has high frequency low-resistance, resistance to high ripple, wide temperature characteristics, many advantages, such as service life is long, is suitable for power filter or high frequency
In circuit, but one of its disadvantage, it is exactly that electric leakage is big.
External stress is to cause one of the reason of solid capacitor leaks electricity.Breakage can be repaired due to not containing in solid capacitor
The movable ion of oxidation film can not directly repair damaged oxidation film.Current programme " is repaired indirectly " to it.When encountering
When external force destroys its oxidation film, make solid state conductive polymer minor insulation using electric leakage Joule heat, with realization " self-regeneration ".
This method the problem is that, but when again by external force destroy macromolecular structure after, the electric leakage of product can generate rise.It leaks electricity a side
Face can cause capacitor internal temperature rise, accelerate electrolyte aging, shorten the capacitor service life;On the other hand downstream product can also be reduced
Reliability.
Other than external stress, thermal shock is also the main reason for causing capacity fall off to go up.For surface attaching type electricity
Sub- component common high temperature reflux welding technology when installing, since the temperature of traditional handicraft polymerization is lower, maximum temperature about 180
DEG C, and when the temperature of Reflow Soldering is higher, 220 DEG C, when being greater than polymerization temperature, solid capacitor is when by high temperature reflux weldering, core packet
Interior extra unreacted reactant cracks just now, and generates SO2Gas forms internal stress, sends a telegraph container casing or rubber plug protrusion becomes
Shape causes electric leakage.
In addition to this, capacitor factor itself is also to cause one of the reason of leaking electricity.
In general, the manufacturing method of solid capacitor are as follows: firstly, production anode foils, form dielectric layer oxygen on anode foils surface
Change film, one end extraction wire of anode foils forms the support portion of a thicker outer diameter as anode between conducting wire and anode foils;Its
It is secondary, with metallic aluminium make Cathode Foil, one end extraction wire as cathode, be again provided between conducting wire and Cathode Foil one compared with
The support portion of thick outer diameter;Finally, separation layer is arranged between anode foils and Cathode Foil, then by separation layer, anode foils and Cathode Foil
It winds together, forms winding-type capacitance core packet.
When production, at 60 ~ 90 DEG C, capacitance core packet is put into 2 ~ 10% ammonium adipate solution, electrochemical treatments 10 ~
30 minutes;Then it is toasted 60 ~ 180 minutes at 130 ~ 280 DEG C, separation layer is made to be carbonized;Capacitance core packet after carbonization temperature 20 ~
35 DEG C, immerse in the solution containing organic monomer and oxidant 10 ~ 40 minutes under normal pressure, polymerize under normal pressure after taking-up, 30 ~
At 210 DEG C, by 0.5 ~ 6 hour formation high conductivity organic polymer, polymeric residues are finally washed off again.
When assembling, capacitance core is first packaged into aluminum hull, is then filled with rubber plug, rubber plug is made to be completely covered by the upper of capacitance core packet
Side, the height of rubber plug are equivalent to the height of thicker support portion;By extruder tool, the nozzle of beam pressure aluminum hull upper end makes the upper end
Nozzle is completely closely sealed with rubber plug;The capacitor that finally completion is encapsulated aging process 0.5 ~ 10 hour at 105 ~ 145 DEG C, is made
Plug-in type solid-state aluminum electrolytic capacitor.
When surface attaching type solid-state aluminum electrolytic capacitor is made in plug-in type solid-state aluminum electrolytic capacitor, have using surface
The cover board of through-hole passes through anode stabilizer blade and cathode stabilizer blade, coats cover board completely and is fixed on above capacitor, then utilizes and covering
The preformed groove of plate surface is bent to 90 degree, is finally respectively implanted after so that anode stabilizer blade and cathode branch foot is passed through through-hole
In groove, that is, constitute surface attaching type solid-state aluminum electrolytic capacitor.
During producing existing solid capacitor, there is also problems in detail below: 1. conventional solid-state capacitor designs use
Carbonization technique, electrolytic paper increase through carbonization back aperture, and core pack arrangement is loose, and external force resistance ability is poor;2. core after common process polymerization
Packet is directly assembled, and core packet lacks protection;3. the lead of conventional solid-state capacitor is ordinary rigid conducting wire, using one-pass molding,
Therefore lead is flattened and when bending, and required active force is larger, is easy to pass to external force into core packet, causes capacitor internal conductive
Macromolecular structure is impaired.
Summary of the invention
The problem to be solved in the present invention is, by structure and process modification, a possibility that oxidation film is damaged to be reduced, to mention
Rise the external force resistance of capacitor and the ability of heat resistanceheat resistant punching.
In order to solve the above-mentioned technical problem, the invention adopts the following technical scheme:
A kind of surface attaching type solid-state aluminum electrolytic capacitor, which is characterized in that make capacitor with aluminum foil coil using carbon electrolytic paper is exempted from
Core packet;Core packet expoeridium after polymerization has protective film;The lead of the capacitor is half-hard wire.
It using the above method, be subjected to displacement aluminium foil will not because of the gap generated after electrolytic paper carbonization, core pack arrangement
Securely, external force resistance ability is strong.
According to the difference of copper covered steel wire intensity, referring concurrently to extending situation, by soft to can be divided into firmly: soft state (A), half-hard state
(M), hard state (HS), superhard state (EHS).Using half-hard wire, the hardness of lead is reduced, can make to flatten and work needed for clinched lead
Firmly reduce, to reduce the damage to capacitor internal conducting polymer, reduces capacitance core packet by the risk of external force.
It is packed into aluminum shell after conventional method core packet aggregation, capacitance core packet is easily made to receive damage.It is wrapped up using protective film, it can
To avoid the direct collision of core bud and shell, increase the ability of the anti-external stress of capacitance core packet, while conducting polymer knot can be made
Structure is stronger.
Preferably, the ingredient of the protective film is casting glue.
Casting glue is a kind of thermosetting polymer insulating materials.Casting glue belong to before uncured it is liquid, have flowing
Property, to avoid damaging core packet.
Preferably, the shell of the capacitor and the contact site of rubber plug be provided with it is with a tight waist, which is characterized in that it is described
Section with a tight waist is rectangle or trapezoidal.
Using the above method, it is possible to increase it is convex to reduce capacitor rubber plug when crossing Reflow Soldering for the contact area of rubber plug and shell
The risk risen, to increase the ability that capacitor resists external force.
A kind of manufacturing method of surface attaching type solid-state aluminum electrolytic capacitor, including nail is rolled up, chemical conversion, impregnation, polymerization, is protected
Shield, sealing, aging, machine-shaping, packaging, which is characterized in that the protection refers to is impregnated with an encapsulating for the core packet after polymerization again
Glue makes to form protective film outside core packet.
Preferably, the method for producing the surface attaching type solid-state aluminum electrolytic capacitor further includes lead bending,
It is characterized in that, 30 °, 60 °, 90 ° of lead bending point forms three times.
Using the above method, influence of the one-pass molding to interiors of products by external force is avoided.
Preferably, the polymerization of the surface attaching type solid-state aluminum electrolytic capacitor includes heating, 40 DEG C of temperature ~
250 DEG C, heating time 6 ~ 10 hours.
Preferably, the polymerization stage has 4 ~ 5 constant temperature gradients, and such as: (1) initial temperature 40 DEG C, when preheating
Between 2 hours, be warming up to 60 DEG C by 15 minutes, continue 1 hour, then be warming up to 80 DEG C through 15 minutes, continue 1 hour, then through 30
Minute is warming up to 150 DEG C, continues 30 minutes, then be warming up to 180 DEG C through 15 minutes, continues 30 minutes, then be warming up to through 30 minutes
220 DEG C, continue 10 minutes, takes out, natural cooling;Or 40 DEG C of (2) initial temperature, it preheating time 3 hours, heated up by 30 minutes
To 70 DEG C, continue 1 hour, then be warming up to 150 DEG C through 30 minutes, continue 30 minutes, then be warming up to 220 DEG C through 30 minutes, continues
10 minutes, then 250 DEG C were warming up to through 30 minutes, continue 5 minutes, takes out, natural cooling;Or 40 DEG C of (3) initial temperature, when preheating
Between 2 hours, be warming up to 50 DEG C by 15 minutes, continue 2 hours, then be warming up to 70 DEG C through 30 minutes, continue 1.5 hours, then pass through
It is warming up to 110 DEG C within 30 minutes, continues 1 hour, then be warming up to 150 DEG C through 30 minutes, continue 30 minutes, then be warming up to through 30 minutes
180 DEG C, continue 30 minutes, takes out, natural cooling.
Using the above method, the abundant reactive polymeric of conducting polymer can be made, the macromolecular structure of formation is stablized, and capacitor is avoided
It after device assembling, is cracked through remained unreacted object when Reflow Soldering high temperature and generates steam, cause product aluminum hull or rubber plug protrusion.
The invention has the advantages that surface attaching type solid-state aluminum electrolytic capacitor of the present invention, core packet aggregation
First be impregnated with a protective film afterwards, after it is sealed again, sealing part be additionally provided with it is with a tight waist reinforced, make capacitor in confrontation plus
There is stronger resistivity, while because polymerization temperature is higher than Reflow Soldering temperature when the inevitable external force such as work molding, not instead
Object is answered to clear up more thorough.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of capacitor of the present invention.
In figure: 1, shell, 2, rubber plug, 3, lead.
Specific embodiment
Below with reference to specific example, the present invention is further explained.
Embodiment 1
A kind of manufacturing method of surface attaching type solid-state aluminum electrolytic capacitor, includes the following steps:
S1. nail volume: by the anode foils with lead, the Cathode Foil with lead and exempt from carbon electrolytic paper by core packet up- coiler and be wound into core
Packet;The lead is the half-hard wire in CP wire;Exempt from carbon electrolytic paper between anode foils and Cathode Foil, and length ratio
The length of anode and cathode foil lap is longer.
S2. it is melted into: the core packet of winding is put into forming liquid, application DC voltage repair process, the processing time 15~
40 minutes;The oxidation film layer that the chemical conversion of core packet facilitates formed aluminum foil surface is repaired.
S3. it is impregnated with: the core packet after chemical conversion being subjected to monomer impregnation, after being impregnated with 30~70 seconds time;Place into oxidant
Middle impregnation 3~5 minutes;It can also be carried out before with oxidant containing monomer impregnation is immersed in.
In the present invention, the type of monomer is not particularly limited, monomer well known in the art can be used.Preferably,
Monomer be selected from thiophene, pyrroles, phenylethylene, aniline or above-mentioned high polymer monomer derivative, or any combination thereof;More preferably
Ground, the monomer are 20% butanol solution of 3,4-ethylene dioxythiophene.The type of oxidant is not specially limited, it can be with
Using oxidant well known in the art, it is highly preferred that the oxidant is molten for the n-butanol of 50~60% p-methyl benzenesulfonic acid iron
Liquid.The impregnation can choose normal pressure impregnation, can also carry out vacuum impregnation;It is preferred that vacuum impregnation, can make impregnation more abundant.
S4. it polymerize: the core packet being impregnated with is subjected to polymerization reaction, polymerization temperature is carried out according to gradient, and polymerization temperature is as follows: just
40 DEG C of beginning temperature, preheating time 2 hours, 60 DEG C were warming up to by 15 minutes, continues 1 hour, then be warming up to 80 DEG C through 15 minutes,
Continue 1 hour, then be warming up to 150 DEG C through 30 minutes, continue 30 minutes, then be warming up to 180 DEG C through 15 minutes, continues 30 minutes,
220 DEG C were warming up to through 30 minutes again, continues 10 minutes, is taken out, natural cooling.Solid high score is formed after polymerization reaction in core packet
Conducting layer.
S5. it protects: including to be immersed in casting glue by the core after the completion of polymerization reaction, be impregnated with 3 ~ 5 minutes, it is dry after taking-up,
Solidification forms protective film;The casting glue can use the casting glue of this field routine;It as an example, can be Henkel KGaA
The epoxy hardener ratio of the epoxy resin of model STYCAST 2651-40 and model C atalyst 11 mix under house flag, shape
At epoxy pouring sealant;Preferably, its mass ratio is 100 epoxy resin: 5 epoxy hardeners;The casting glue uses 125
DEG C hot setting, can also be solidified with ultraviolet light.
S6. it seals: the core after protection being packaged into aluminum hull, lead is passed through from the through-hole of rubber plug, then is sealed with rubber plug.
Preferably, the shell of the capacitor and the contact site of rubber plug be provided with it is with a tight waist, which is characterized in that it is described
Section with a tight waist is rectangle or trapezoidal.
S7. segmentation aging process aging: is carried out to packaged product: applying aging operating voltage when voltage is aging
1 ~ 1.15 times, not more than the 1.25 of aging operating voltage times, 125 DEG C of aging temperature, ageing time 120 minutes.
S8. machine-shaping: product carries out the processing such as following process, inspection, packaging.
Preferably, the following process includes that the lead of capacitor is flattened and bent, to make surface mount
Type capacitor uses.To avoid damage of the one-pass molding to interiors of products, when the bending, pin point is bent to 90 degree 3 times,
It respectively is 30 °, 60 °, 90 °.
Embodiment 2
Such as embodiment 1, difference is, the temperature gradient change of the S4 polymerization are as follows: 40 DEG C of initial temperature, preheating time 3 is small
When, 70 DEG C were warming up to by 30 minutes, continues 1 hour, then be warming up to 150 DEG C through 30 minutes, continues 30 minutes, then through 30 minutes
220 DEG C are warming up to, continues 10 minutes, then be warming up to 250 DEG C through 30 minutes, continues 5 minutes, is taken out, natural cooling.
Embodiment 3
Such as embodiment 1, difference is, the temperature gradient change of the S4 polymerization are as follows: 40 DEG C of initial temperature, preheating time 2 is small
When, 50 DEG C were warming up to by 15 minutes, continues 2 hours, then be warming up to 70 DEG C through 30 minutes, continues 1.5 hours, then through 30 minutes
110 DEG C are warming up to, continues 1 hour, then be warming up to 150 DEG C through 30 minutes, continues 30 minutes, then be warming up to 180 DEG C through 30 minutes,
Continue 30 minutes, takes out, natural cooling.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention
Within protection scope.
Claims (9)
1. a kind of surface attaching type solid-state aluminum electrolytic capacitor, which is characterized in that make electricity with aluminum foil coil using carbon electrolytic paper is exempted from
Rong Xin packet;Core packet expoeridium after polymerization has protective film;The lead of the capacitor is half-hard wire.
2. surface attaching type solid-state aluminum electrolytic capacitor as described in claim 1, which is characterized in that the ingredient of the protective film
For casting glue.
3. surface attaching type solid-state aluminum electrolytic capacitor as described in claim 1, contact of the shell of the capacitor with rubber plug
Position is provided with a tight waist, which is characterized in that the section with a tight waist is rectangle or trapezoidal.
4. a kind of manufacturing method of surface attaching type solid-state aluminum electrolytic capacitor, including follow closely and roll up, chemical conversion, impregnation, polymerization, protect,
Sealing, aging, machine-shaping, packaging, which is characterized in that the protection refers to is impregnated with a casting glue for the core packet after polymerization again,
Make to form protective film outside core packet.
5. a kind of manufacturing method of surface attaching type solid-state aluminum electrolytic capacitor as claimed in claim 4, the machine-shaping
Including being flattened and being bent to lead, which is characterized in that points of 3 times moldings of the bending, profile angle be followed successively by 30 °, 60 °,
90°。
6. a kind of manufacturing method of surface attaching type solid-state aluminum electrolytic capacitor as claimed in claim 4, which is characterized in that institute
The polymerization for stating capacitor includes heating, and 40 DEG C ~ 250 DEG C of heating temperature, heating time 6 ~ 10 hours.
7. a kind of manufacturing method of surface attaching type solid-state aluminum electrolytic capacitor as claimed in claim 6, which is characterized in that institute
State heating, heat cycles are as follows: 40 DEG C of initial temperature, preheating time 2 hours, be warming up to 60 DEG C by 15 minutes, it is small to continue 1
When, then 80 DEG C were warming up to through 15 minutes, continue 1 hour, then be warming up to 150 DEG C through 30 minutes, continues 30 minutes, then through 15 minutes
180 DEG C are warming up to, continues 30 minutes, then be warming up to 220 DEG C through 30 minutes, continues 10 minutes, is taken out, natural cooling.
8. a kind of manufacturing method of surface attaching type solid-state aluminum electrolytic capacitor as claimed in claim 6, which is characterized in that institute
State heating, heat cycles are as follows: 40 DEG C of initial temperature, preheating time 3 hours, be warming up to 70 DEG C by 30 minutes, it is small to continue 1
When, then 150 DEG C were warming up to through 30 minutes, continue 30 minutes, then be warming up to 220 DEG C through 30 minutes, continues 10 minutes, then through 30 points
Clock is warming up to 250 DEG C, continues 5 minutes, takes out, natural cooling.
9. a kind of manufacturing method of surface attaching type solid-state aluminum electrolytic capacitor as claimed in claim 6, which is characterized in that institute
State heating, heat cycles are as follows: 40 DEG C of initial temperature, preheating time 2 hours, be warming up to 50 DEG C by 15 minutes, it is small to continue 2
When, then 70 DEG C were warming up to through 30 minutes, continue 1.5 hours, then be warming up to 110 DEG C through 30 minutes, continues 1 hour, then through 30 points
Clock is warming up to 150 DEG C, continues 30 minutes, then be warming up to 180 DEG C through 30 minutes, continues 30 minutes, takes out, natural cooling.
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CN201810974249.0A CN109087811A (en) | 2018-08-24 | 2018-08-24 | A kind of surface attaching type solid-state aluminum electrolytic capacitor |
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CN201810974249.0A CN109087811A (en) | 2018-08-24 | 2018-08-24 | A kind of surface attaching type solid-state aluminum electrolytic capacitor |
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CN110634681A (en) * | 2019-10-15 | 2019-12-31 | 厦门法拉和信电子有限公司 | Impregnation preparation method of hybrid aluminum electrolytic capacitor |
CN111627710A (en) * | 2020-06-17 | 2020-09-04 | 肇庆绿宝石电子科技股份有限公司 | Solid polymer capacitor ignited by electronic detonator and manufacturing method thereof |
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