CN108766886A - A kind of forming method of fin formula field effect transistor structure - Google Patents

A kind of forming method of fin formula field effect transistor structure Download PDF

Info

Publication number
CN108766886A
CN108766886A CN201810509583.9A CN201810509583A CN108766886A CN 108766886 A CN108766886 A CN 108766886A CN 201810509583 A CN201810509583 A CN 201810509583A CN 108766886 A CN108766886 A CN 108766886A
Authority
CN
China
Prior art keywords
fin
effect transistor
field effect
semiconductor substrate
formula field
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810509583.9A
Other languages
Chinese (zh)
Inventor
曾绍海
李铭
陈张发
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai IC R&D Center Co Ltd
Original Assignee
Shanghai Integrated Circuit Research and Development Center Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Integrated Circuit Research and Development Center Co Ltd filed Critical Shanghai Integrated Circuit Research and Development Center Co Ltd
Priority to CN201810509583.9A priority Critical patent/CN108766886A/en
Publication of CN108766886A publication Critical patent/CN108766886A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66787Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel
    • H01L29/66795Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET

Abstract

The invention discloses a kind of forming methods of fin formula field effect transistor structure, include the following steps:Step S01:Semi-conductive substrate is provided, deposits one layer of metallic film on the semiconductor substrate;Step S02:Patterned metal film;Step S03:Using hydrofluoric acid and hydrogen peroxide as etching agent, the semiconductor substrate surface to being covered with metal thin-film pattern carries out full wafer etching, and relatively raised fin is formed between virgin metal film pattern position;Step S04:It is developed across the gate structure of fin at the top of fin and side wall;Wherein, by using metallic particles as local cathode and catalyst, local microscopic electrochemical occurs between the semiconductor substrate particle as local anode to react, the semiconductor substrate surface of metal thin-film pattern lower zone is preferentially corroded to formation recess, to form relatively raised fin between virgin metal film pattern position.The present invention can accurately control the width and height of fin.

Description

A kind of forming method of fin formula field effect transistor structure
Technical field
The present invention relates to integrated circuit technology manufacturing technology fields, more particularly, to a kind of fin formula field effect transistor The forming method of structure.
Background technology
With the continuous development of semiconductor technology, traditional planar device has been difficult to the need for meeting people to high performance device It asks.
Fin formula field effect transistor (Fin Field-Effect Transistor, FinFET) is a kind of solid type device, Including the fin vertically formed on substrate and the stacking gate intersected with fin.This design can greatly improve circuit control and subtract Few electric leakage mouth, while the lock that can also substantially shorten transistor is long.
Referring to Fig. 1, Fig. 1 is a kind of dimensional structure diagram of existing fin formula field effect transistor.As shown in Figure 1, Fin formula field effect transistor structure includes:Positioned at the semiconductor substrate 10 of bottom, it is formed in the semiconductor substrate 10 convex The fin 14 risen, fin 14 are obtained generally by being etched to semiconductor substrate 10;Dielectric layer 11 is covered in the semiconductor A part for 10 surface and the side wall of fin 14;Gate structure 12 across in the fin 14 top and side wall, grid Structure 12 includes gate dielectric layer (not shown) and the gate electrode (not shown) on gate dielectric layer.More about fin The introduction of formula field-effect transistor please refers to the United States Patent (USP) of Publication No. " US7868380B2 ".
The forming method of existing fin formula field effect transistor fin is first to deposit hard mask layer on a semiconductor substrate, so Self aligned Dual graphing (self-aligned double patterning, SADP) method is used afterwards, is sequentially etched hard Mask layer and semiconductor substrate, eventually form fin.However, the fin formed in this way, not to its height and width Good control;Also, it is formed by the edge of fin and the pattern lack of homogeneity of side wall.This can make fin formula field effect transistor Threshold voltage shifts, and influences the stability of fin formula field effect transistor.
So be badly in need of finding a kind of forming method of new fin formula field effect transistor, it is of the existing technology to eliminate It is insufficient.
Invention content
It is an object of the invention to overcome drawbacks described above of the existing technology, a kind of new fin field effect crystal is provided The forming method of pipe structure.
To achieve the above object, technical scheme is as follows:
A kind of forming method of fin formula field effect transistor structure, includes the following steps:
Step S01:Semi-conductive substrate is provided, deposits one layer of metallic film on the semiconductor substrate;
Step S02:Patterned metal film;
Step S03:Using hydrofluoric acid and hydrogen peroxide as etching agent, to be covered with the semiconductor substrate surface of metal thin-film pattern into Row full wafer etches, and relatively raised fin is formed between virgin metal film pattern position;
Step S04:It is developed across the gate structure of fin at the top of fin and side wall;
Wherein, by using metallic particles as local cathode and catalyst, with the semiconductor substrate as local anode The reaction of local microscopic electrochemical occurs between particle, the semiconductor substrate surface of metal thin-film pattern lower zone is preferentially corroded Recess is formed, to form relatively raised fin between virgin metal film pattern position.
Preferably, according to the relative mistake between semiconductor substrate surface and metal thin-film pattern surface on etch rate It is different, the width and height dimension of metal thin-film pattern are determined, to accurately control the width and height of the required fin formed.
Preferably, it in step S03, is corroded using metallic film clean as etching terminal.
Preferably, the metallic film material deposition thickness is 50nm~200nm.
Preferably, further include the steps that being cleaned to semiconductor substrate surface before step S04.
Preferably, when being cleaned, using deionized water as cleaning agent.
Preferably, it is carried out in cleaning self-stopping technology has etched 0~2 minute.
Preferably, the semiconductor substrate is silicon substrate.
Preferably, the metallic film material is Au, Ag or Pt.
Preferably, the gate structure includes gate dielectric layer and gate electrode.
It can be seen from the above technical proposal that the present invention is by using hydrofluoric acid and hydrogen peroxide as etching agent, to being covered with metal The semiconductor substrate surface of film pattern carries out full wafer etching, as local cathode and is urged using the metallic particles in metallic film Agent, generation local microscopic electrochemical reacts between the substrate grain of the semiconductor substrate surface as local anode, will be golden Belong to film pattern lower zone semiconductor substrate surface preferentially corrode formation recess, thus virgin metal film pattern position it Between form relatively raised fin.The present invention can accurately control the width and height of fin, improve the row of fin on substrate Cloth density;Meanwhile the present invention is compatible with conventional silicon substrate super large-scale integration manufacturing technology, has simply, convenient, the period is short The characteristics of, reduce process costs.
Description of the drawings
Fig. 1 is a kind of dimensional structure diagram of existing fin formula field effect transistor;
Fig. 2 is a kind of forming method flow signal of fin formula field effect transistor structure of a preferred embodiment of the present invention Figure;
Fig. 3~Fig. 8 is processing step signal when method according to fig. 2 forms a kind of fin formula field effect transistor structure Figure;
Fig. 9 is the etching principle schematic of the present invention.
Specific implementation mode
Below in conjunction with the accompanying drawings, the specific implementation mode of the present invention is described in further detail.
It should be noted that in following specific implementation modes, when embodiments of the present invention are described in detail, in order to clear Ground indicates the structure of the present invention in order to illustrate, spy does not draw to the structure in attached drawing according to general proportion, and has carried out part Amplification, deformation and simplified processing, therefore, should avoid in this, as limitation of the invention to understand.
In specific implementation mode of the invention below, referring to Fig. 2, Fig. 2 is one kind of a preferred embodiment of the present invention The forming method flow diagram of fin formula field effect transistor structure;Meanwhile Fig. 3~Fig. 8 is please referred to, Fig. 3~Fig. 8 is according to figure 2 method forms processing step schematic diagram when a kind of fin formula field effect transistor structure.As shown in Fig. 2, one kind of the present invention The forming method of fin formula field effect transistor structure, it may include following steps:
Step S01:Semi-conductive substrate is provided, deposits one layer of metallic film on the semiconductor substrate.
Please refer to Fig. 3.First, the general PVD process manufacturing method of industry can be used, deposit on a semiconductor substrate 100 Form one layer of metallic film 101.Wherein,
Silicon substrate etc. can be used in semiconductor substrate 100.The present embodiment is illustrated by taking silicon substrate as an example.
Au, Ag or Pt etc. can be used in 101 material of metallic film.The present embodiment is illustrated by taking Ag as an example.
The deposition thickness of 101 material of metallic film is 50nm~200nm.
Step S02:Patterned metal film.
Please refer to Fig. 4 and Fig. 5.Then, can be used the general technique manufacturing method of industry carry out photoetching, development and etching, The techniques such as cleaning, including elder generation is in 101 surface coating photoresist of metallic film;Then, by photoetching, development, the photoetching to coating Glue is patterned, and forms photoetching offset plate figure 102;Next, continuing with patterned photoresist 102 to be mask, to photoresist 101 material of metallic film of 102 lower section of figure performs etching, and forms corresponding metal thin-film pattern 101 ';It later, will be remaining Photoresist 102 removes, and is cleaned.
Step S03:Using hydrofluoric acid and hydrogen peroxide as etching agent, to be covered with the semiconductor substrate surface of metal thin-film pattern into Row full wafer etches, and relatively raised fin is formed between virgin metal film pattern position.
Please refer to Fig. 6.Then, hydrofluoric acid (HF) and hydrogen peroxide (H are passed through2O2) it is used as etching agent, to being covered with metallic film figure The semiconductor substrate surface of shape 101 ' carries out full wafer etching (corrosion).It includes lining that the object that (corrosion) is directed to is etched in the present embodiment Bottom silicon and the Ag films for being covered in substrate silicon surface.
In etching process, the height of metal 101 ' is because by hydrofluoric acid (HF) and hydrogen peroxide (H2O2) corrosiveness and it is continuous It reduces;Meanwhile etching speed of the substrate silicon below metal 101 ' because of etch rate much larger than 101 ' both side surface substrate silicon of metal Rate, so that constantly sinking and forming recess.
In this way after over etching (corrosion), relatively raised fin 103 is just formed between virgin metal film pattern position (please also refer to Fig. 7).
When silicon substrate to being covered with metal carries out full wafer etching, it is corroded using metallic film clean as etching terminal; Therefore, once metallic film is corroded totally, just stop etching technics.
The present invention manufacture fin formula field effect transistor basic principle be, substrate silicon surface deposition metal Ag particles and its Region, can occur the local cathode of local microscopic electrochemical reaction as silicon face, and become local cathode and local Anode (silicon particle of substrate surface and its region, can as occur local microscopic electrochemical reaction local anode) it Between charge transfer center;Simultaneously as the silver nano-grain formed has apparent catalytic activity for corrosion reaction, it can profit It uses Argent grain as catalyst, thus corrosion rate can be greatly increased.And the hole needed for pasc reaction can be by H2O2In silver Reduction at nano particle obtains.Total reaction equation is:
Si+H2O2+ 6HF=2H2O+H2SiF6+H2
Reaction process can be explained by Fig. 9:
1) at the surface metal (such as Au, Ag, Pt), oxidant H2O2(Ox) (Red) is restored by preferential catalysis, generates hole (+);
2) hole is injected by metallic particles (Metal) in the silicon contacted (Si);
3) in the interface that metal and silicon contact, silica is melted into silica by injected holes, and then, silica is molten Solution is in HF solution;
4) due to the local hole solubility highest that metal is contacted with silicon, corrosion rate is also most fast.Therefore, with metal contact zone The silicon in domain compares the silicon in no plated region, and the speed being corroded is faster.In this way, can will be below metal thin-film pattern The substrate silicon surface in region preferentially corrodes formation recess, to form relatively raised fin between virgin metal film pattern position Portion 103.
Compared with prior art, the fin formula field effect transistor of above method manufacture using the present invention, can be according to semiconductor Relative different between substrate surface and metal thin-film pattern surface on etch rate, determine metal thin-film pattern width and Height dimension, thus the width and height of the required fin formed can be accurately controlled, improve the arrangement density of fin on substrate; The technique of the present invention can be compatible with conventional silicon substrate super large-scale integration manufacturing technology simultaneously, has simply, and convenient, the period is short The characteristics of, reduce process costs.
Step S04:It is developed across the gate structure of fin at the top of fin and side wall.
Please refer to Fig. 7.Then, it needs to clean semiconductor substrate surface, to remove semiconductor substrate surface not phase The residual substance of prestige keeps the cleaning of semiconductor substrate surface.
It when being cleaned, can be used deionized water as cleaning agent, full wafer cleaning carried out to semiconductor substrate surface.
As preferred embodiment, above-mentioned cleaning answers self-stopping technology etching (by HF and H2O2After etching agent takes out) rise 0~ It is carried out in 2 minutes.
After washing with water, that is, forming fin formula field effect transistor has the fin 103 of strict width and height.
Please refer to Fig. 8.Next, the material and technique manufacturing method of the general formation grid of industry can be used, above-mentioned 103 surface deposition grid material of device and fin, and gate structure 104 is formed by photoetching, etching.Gate structure 104 can wrap Include the gate dielectric layer positioned at lower layer and the gate electrode on gate dielectric layer.
In addition, after completing the procedure, other techniques to form cmos device can be continued to execute, these processing steps can To be formed using method familiar to those skilled in the art, details are not described herein.
To sum up, the present invention is by the way that using hydrofluoric acid and hydrogen peroxide as etching agent, the semiconductor to being covered with metal thin-film pattern serves as a contrast Bottom surface carries out full wafer etching, and local cathode and catalyst are used as using the metallic particles in metallic film, and positive as local The reaction of local microscopic electrochemical occurs between the substrate grain of the semiconductor substrate surface of pole, by metal thin-film pattern lower zone Semiconductor substrate surface preferentially corrode formation recess, to form relatively raised fin between virgin metal film pattern position Portion.The present invention can accurately control the width and height of fin, improve the arrangement density of fin on substrate;Meanwhile the present invention It is compatible with conventional silicon substrate super large-scale integration manufacturing technology, have simple, convenient, period short feature reduces technique Cost.
Above-described to be merely a preferred embodiment of the present invention, the embodiment is not to be protected to limit the patent of the present invention Range, therefore equivalent structure variation made by every specification and accompanying drawing content with the present invention are protected, similarly should be included in In protection scope of the present invention.

Claims (10)

1. a kind of forming method of fin formula field effect transistor structure, which is characterized in that include the following steps:
Step S01:Semi-conductive substrate is provided, deposits one layer of metallic film on the semiconductor substrate;
Step S02:Patterned metal film;
Step S03:Using hydrofluoric acid and hydrogen peroxide as etching agent, the semiconductor substrate surface to being covered with metal thin-film pattern carries out whole Piece etches, and relatively raised fin is formed between virgin metal film pattern position;
Step S04:It is developed across the gate structure of fin at the top of fin and side wall;
Wherein, by using metallic particles as local cathode and catalyst, with the semiconductor substrate particle as local anode Between occur local microscopic electrochemical reaction, the semiconductor substrate surface of metal thin-film pattern lower zone is preferentially corroded to be formed Recess, to form relatively raised fin between virgin metal film pattern position.
2. the forming method of fin formula field effect transistor structure according to claim 1, which is characterized in that according to semiconductor Relative different between substrate surface and metal thin-film pattern surface on etch rate, determine metal thin-film pattern width and Height dimension, to accurately control the width and height of the required fin formed.
3. the forming method of fin formula field effect transistor structure according to claim 1, which is characterized in that in step S03, It is corroded using metallic film clean as etching terminal.
4. the forming method of fin formula field effect transistor structure according to claim 1, which is characterized in that the metal foil Membrane material deposition thickness is 50nm~200nm.
5. the forming method of fin formula field effect transistor structure according to claim 1, which is characterized in that in step S04 Before, further include the steps that being cleaned to semiconductor substrate surface.
6. the forming method of fin formula field effect transistor structure according to claim 5, which is characterized in that cleaned When, using deionized water as cleaning agent.
7. the forming method of fin formula field effect transistor structure according to claim 5, which is characterized in that cleaning self-stopping technology It is carried out in 0~2 minute etched.
8. the forming method of the fin formula field effect transistor structure according to claim 1-7 any one, which is characterized in that The semiconductor substrate is silicon substrate.
9. the forming method of the fin formula field effect transistor structure according to claim 1-7 any one, which is characterized in that The metallic film material is Au, Ag or Pt.
10. the forming method of fin formula field effect transistor structure according to claim 1, which is characterized in that the grid Structure includes gate dielectric layer and gate electrode.
CN201810509583.9A 2018-05-24 2018-05-24 A kind of forming method of fin formula field effect transistor structure Pending CN108766886A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810509583.9A CN108766886A (en) 2018-05-24 2018-05-24 A kind of forming method of fin formula field effect transistor structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810509583.9A CN108766886A (en) 2018-05-24 2018-05-24 A kind of forming method of fin formula field effect transistor structure

Publications (1)

Publication Number Publication Date
CN108766886A true CN108766886A (en) 2018-11-06

Family

ID=64005543

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810509583.9A Pending CN108766886A (en) 2018-05-24 2018-05-24 A kind of forming method of fin formula field effect transistor structure

Country Status (1)

Country Link
CN (1) CN108766886A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080073723A1 (en) * 2006-09-22 2008-03-27 Willy Rachmady Selective anisotropic wet etching of workfunction metal for semiconductor devices
CN103145090A (en) * 2011-12-06 2013-06-12 林清富 Technology for manufacturing large-area thin monocrystalline silicon
CN106328513A (en) * 2015-07-02 2017-01-11 中芯国际集成电路制造(上海)有限公司 Method of forming semiconductor structure
CN107706113A (en) * 2016-08-09 2018-02-16 中芯国际集成电路制造(上海)有限公司 A kind of FinFET and preparation method, electronic installation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080073723A1 (en) * 2006-09-22 2008-03-27 Willy Rachmady Selective anisotropic wet etching of workfunction metal for semiconductor devices
CN103145090A (en) * 2011-12-06 2013-06-12 林清富 Technology for manufacturing large-area thin monocrystalline silicon
CN106328513A (en) * 2015-07-02 2017-01-11 中芯国际集成电路制造(上海)有限公司 Method of forming semiconductor structure
CN107706113A (en) * 2016-08-09 2018-02-16 中芯国际集成电路制造(上海)有限公司 A kind of FinFET and preparation method, electronic installation

Similar Documents

Publication Publication Date Title
JP6092260B2 (en) Array substrate manufacturing method, array substrate, and display
CN108364867B (en) Deep silicon etching method
CN107039335B (en) The forming method of semiconductor structure
CN106328513B (en) The forming method of semiconductor structure
CN106783866B (en) The manufacturing method of flush memory device
CN107230678A (en) The manufacture method of flash memory
CN104078329B (en) The forming method of autoregistration multiple graphics
JP2000036495A (en) Manufacture of semiconductor device
CN113496949B (en) Method for improving electric leakage phenomenon after forming metal silicide layer on surface of gate structure
CN104701145B (en) The forming method of semiconductor structure
CN105668509A (en) Method for etching micron silicon through hole
CN108766886A (en) A kind of forming method of fin formula field effect transistor structure
CN105374680A (en) Method for forming semiconductor structure
CN103346126A (en) Method for forming flash memory storage unit
CN105826326A (en) Cell recess oxide etching method of improving deep-submicron flash memory device coupling rate
CN105513954A (en) Forming method of semiconductor device
CN102800587B (en) Process for producing schottky diode
KR100597619B1 (en) Method for fabricating semiconduntor device
CN115410991A (en) Contact hole forming method
CN105514044A (en) Semiconductor structure forming method
TW202139352A (en) Structure and method of producing the same
CN116133369B (en) Method for manufacturing semiconductor structure and structure thereof
CN1877798A (en) Silicon-base single electron device structure based on MOSFET process and method for fabricating same
CN106033719A (en) Formation method of semiconductor structure
CN104733377B (en) The method for realizing trench FET source contact groove self-alignment structure

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20181106