CN108753170A - A kind of environmental protection electrostatic spary coating type wood wax oil and its preparation method and application - Google Patents
A kind of environmental protection electrostatic spary coating type wood wax oil and its preparation method and application Download PDFInfo
- Publication number
- CN108753170A CN108753170A CN201810719209.1A CN201810719209A CN108753170A CN 108753170 A CN108753170 A CN 108753170A CN 201810719209 A CN201810719209 A CN 201810719209A CN 108753170 A CN108753170 A CN 108753170A
- Authority
- CN
- China
- Prior art keywords
- parts
- wood wax
- electrostatic
- wax oil
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002023 wood Substances 0.000 title claims abstract description 79
- 238000000576 coating method Methods 0.000 title claims abstract description 46
- 239000011248 coating agent Substances 0.000 title claims abstract description 42
- 230000007613 environmental effect Effects 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000003921 oil Substances 0.000 claims abstract description 81
- 235000019198 oils Nutrition 0.000 claims abstract description 81
- 239000001993 wax Substances 0.000 claims abstract description 81
- 229920002160 Celluloid Polymers 0.000 claims abstract description 23
- 239000002904 solvent Substances 0.000 claims abstract description 19
- 239000002253 acid Substances 0.000 claims abstract description 17
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 16
- 235000013871 bee wax Nutrition 0.000 claims abstract description 15
- 239000012166 beeswax Substances 0.000 claims abstract description 15
- 235000019438 castor oil Nutrition 0.000 claims abstract description 15
- 239000004359 castor oil Substances 0.000 claims abstract description 15
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 15
- 235000021388 linseed oil Nutrition 0.000 claims abstract description 15
- 239000000944 linseed oil Substances 0.000 claims abstract description 15
- 239000004203 carnauba wax Substances 0.000 claims abstract description 14
- 238000007664 blowing Methods 0.000 claims abstract description 12
- 239000007921 spray Substances 0.000 claims abstract description 7
- 229920001220 nitrocellulos Polymers 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- -1 polyol esters Chemical class 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 239000003760 tallow Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
- 229920005862 polyol Polymers 0.000 claims description 8
- 238000010790 dilution Methods 0.000 claims description 6
- 239000012895 dilution Substances 0.000 claims description 6
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 6
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 5
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000011435 rock Substances 0.000 claims description 3
- 235000021314 Palmitic acid Nutrition 0.000 claims description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 2
- 241000254173 Coleoptera Species 0.000 claims 1
- 235000019441 ethanol Nutrition 0.000 claims 1
- NYXHSRNBKJIQQG-UHFFFAOYSA-N methyl n-methylcarbamate Chemical compound CNC(=O)OC NYXHSRNBKJIQQG-UHFFFAOYSA-N 0.000 claims 1
- 238000007590 electrostatic spraying Methods 0.000 abstract description 12
- 238000001035 drying Methods 0.000 abstract description 5
- 238000004806 packaging method and process Methods 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000005507 spraying Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 241001050985 Disco Species 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- FJFOVISFRWPXDB-UHFFFAOYSA-N carbamoyloxymethyl carbamate Chemical compound NC(=O)OCOC(N)=O FJFOVISFRWPXDB-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/005—Drying oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to a kind of environmental protection electrostatic spary coating type wood wax oil and its preparation method and application, the environmental protection electrostatic spary coating type wood wax oil is grouped as by the group of following mass fraction：19~37 parts of environmentally friendly solvent, 15~20 parts of celluloid, 10~15 parts of Malin's acid resin, 20~30 parts of castor oil of blowing, 20~30 parts of linseed oil, 3~5 parts of Brazil wax, 3~5 parts of beeswax, 1~2 part of electrostatic auxiliary agent.Wood wax oil provided by the invention is realized is used for woodwork by wood wax oil in such a way that electrostatic spraying forms a film, the rapid-drying properties of wood wax oil on the one hand can be improved using electrostatic spraying, half can be improved does solid work speed, it is needed 2~3 hours from packaging is sprayed to only, and usual spray wood wax oil or solvent based coating, need could pack under normal circumstances within 6~12 hours.On the other hand, electrostatic spraying wood wax oil can save artificial and cost, accelerate the shipment amount of product, therefore have larger application value.
Description
Technical field
The present invention relates to wood wax oil fields, specifically, being related to a kind of environmental protection electrostatic spary coating type wood wax oil and preparation method thereof
And application.
Background technology
Wood wax oil, which is that vegetable oil Wax coatings are domestic, to be commonly called as, and is a kind of similar natural woodenware painted and be different from paint
Coating.It and that paint for being produced based on petrochemical industry class synthetic resin is entirely different at present, raw material mainly with refine linseed oil,
The crude vegetals such as palm wax and vegetable wax simultaneously coordinate some other natural component to merge.Since oil can penetrate into timber
Portion carries out deep layer to timber and moistens maintenance；Wax can combine closely with lumber fibre, enhancing case hardness, water proof anti-soil, therefore,
Wood wax oil can provide most outstanding beautification and protective effect.
Remain able to detect in part haze tallow oil product on the market at present the Elements in Organic Solvents such as toluene, dimethylbenzene with
And heavy metal, or it is added with chemical naval stores, it is not truly realized materials safety, environmental protection；And there is also product gloss
Difference, hardness is low, wearability and film forming are poor, it is incompatible between each ingredient caused by product stability it is poor the problems such as.In addition, at present
Do not occur also can be used for the wood wax oil of electrostatic spraying in the market, and wood wax oil can be significantly reduced using the spraying of electrostatic spraying form
Cost and drying time.
Therefore, it still needs to research and develop a kind of suitable for electrostatic spraying, environmental protection and the wood with performances such as excellent abrasive resistance, stability
Wax oil.
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of environmental protection electrostatic spary coating type wood wax oil, this hairs
The wood wax oil of bright offer is realized is used for woodwork by wood wax oil in such a way that electrostatic spraying forms a film, in the drying for improving wood wax oil
Cost is reduced while speed.
Another object of the present invention is to provide the preparation methods of above-mentioned environmental protection electrostatic spary coating type wood wax oil.
Another object of the present invention is to provide the application methods of above-mentioned environmental protection electrostatic spary coating type wood wax oil.
To achieve the above object, the present invention adopts the following technical scheme that：
A kind of environmental protection electrostatic spary coating type wood wax oil, the environmental protection electrostatic spary coating type wood wax oil are grouped by the group of following mass fraction
At：
19~37 parts of environmentally friendly solvent, 15~20 parts of celluloid, 10~15 parts of Malin's acid resin, 20~30 parts of castor oil of blowing, Asia
20~30 parts of edestan oil, 3~5 parts of Brazil wax, 3~5 parts of beeswax, 1~2 part of electrostatic auxiliary agent.
In the present invention, celluloid rises from dry bridging action, and Malin's acid resin, blowing castor oil and linseed oil rise to be contained admittedly
The effect of richness, Brazil wax and beeswax play feel, wax sense, velvet sense, scratch resistant, and Malin's acid resin also has
Have and increase hardness, richness effect, electrostatic auxiliary agent is used to adjust the electrostatic spraying electric conductivity of wood wax oil, plays electrostatic insulating effect.
Electrostatic spraying refers to making atomised coating bear electricity under high voltage direct current field action using principle of corona discharge, and inhale
Invest the coating process of lotus positive electricity substrate surface electric discharge.Wood wax oil provided by the invention can be widely applied to electrostatic spraying flowing water
Line such as disco spraying coating line, moves down spraying coating line.
Preferably, the environmental protection electrostatic spary coating type wood wax oil is grouped as by the group of following mass fraction：
28 parts of environmentally friendly solvent, 15 parts of celluloid, 10 parts of Malin's acid resin, 20 parts of castor oil of blowing, 20 parts of linseed oil, cohune
3 parts of palmitic acid wax, 3 parts of beeswax, 1 part of electrostatic auxiliary agent.
Preferably, the environmentally friendly solvent be absolute methanol, absolute ethyl alcohol, dimethyl carbonate, propylene glycol methyl ether acetate or
One or more of PCC polyol esters.
Preferably, the PCC polyol esters are methylene dicarbamate.
Preferably, the celluloid is grouped as by the group of following mass percent：
2/1 nitrocotton 30 ~ 40%, 1/4 nitrocotton 30 ~ 40%, 1/8 nitrocotton .10 ~ 20%, 1/16 nitrocotton 10 ~ 20%.
It is further preferable that the celluloid is grouped as by the group of following mass percent：
1/2 nitrocotton 30%, 1/4 nitrocotton 30%, 1/8 nitrocotton 20%, 1/16 nitrocotton 20%.
Preferably, the electrostatic auxiliary agent is amine salt compound.
The present invention protects the preparation method of above-mentioned environmental protection electrostatic spary coating type wood wax oil, the method as follows simultaneously：
S1：Celluloid is added into environmentally friendly solvent, 15~20min is dispersed with stirring under the conditions of 600~800rpm makes celluloid fill
Divide dissolving, Malin's acid resin, 20 ~ 25min of high speed dispersion is then added；
S2：Castor oil and linseed oil are added into mixture obtained by S1, it is dispersed with stirring 10 under the conditions of 300~400rpm ~
15min；
S3：Brazil wax and beeswax is added into mixture obtained by S2 and is dispersed with stirring 20 under the conditions of 1000~1200rpm
After~30min, electrostatic auxiliary agent is added and is stirred evenly under the conditions of 300~600rpm.
The application method of above-mentioned environmental protection electrostatic spary coating type wood wax oil also within protection scope of the present invention, the user
Method is as follows：
According to mass ratio it is 1 by the wood wax oil and haze tallow water:0.4~0.5 ratio is uniformly mixed, and then uses strainer filtering,
The wood wax oil after dilution is finally pumped into electrostatic sprayer to spray；
Wherein, the haze tallow water by absolute alcohol, dimethyl carbonate, propylene glycol methyl ether acetate and PCC polyol esters according to 20
~30:30~40:10~20:10~20 mass ratio composition.
Preferably, the mesh number of the strainer is 80~100 mesh.
Preferably, measure 50ml it is above-mentioned through dilution mix after wood wax oil and pour into rock field cup in, in 25 DEG C, 50~
Its viscosity is tested under the conditions of 75%RH；The viscosity of the wood wax oil is 15~20 seconds.
Compared with prior art, the present invention has the advantages that：
Wood wax oil provided by the invention has preferable electric conductivity, wearability, hardness, film forming, levelability and stability, simultaneously
The wood wax oil is without triphen, formaldehydeless, while heavy metal free lead, chromium, mercury, cadmium, for products obtained therefrom gloss and feel after woodwork
Preferably.
Wood wax oil provided by the invention is realized is used for woodwork by wood wax oil in such a way that electrostatic spraying forms a film, and use is quiet
On the one hand electrospray can improve the rapid-drying properties of wood wax oil, can improve half does solid work speed, from spray to packaging only and need 2~
3 hours, and usual spray wood wax oil or solvent based coating, need could pack under normal circumstances within 6~12 hours.On the other hand,
Electrostatic spraying wood wax oil can save artificial and cost, accelerate the shipment amount of product, therefore have larger application value.
Specific implementation mode
Further illustrated the present invention below in conjunction with specific embodiment, but embodiment the present invention is not done it is any type of
It limits.Unless stated otherwise, the present invention uses reagent, method and apparatus is the art conventional reagent, methods and apparatus.
Unless stated otherwise, agents useful for same and material of the present invention are purchased in market.
Embodiment 1
A kind of environmental protection electrostatic spary coating type wood wax oil, the environmental protection electrostatic spary coating type wood wax oil are grouped by the group of following mass fraction
At：
Absolute alcohol 5kg, 6 kg of dimethyl carbonate, PMA10 kg, 7 kg of PCC polyol esters, 15 kg of celluloid, Malin acid tree
10 kg of fat, 20 kg of blowing castor oil, 20 kg of linseed oil, 3 kg of Brazil wax, 3 kg of beeswax, 1 kg of electrostatic auxiliary agent；Its
In, the celluloid is grouped as by the group of following mass percent：1/2 nitrocotton 30%, 1/4 nitrocotton 30%, 1/8 nitrocotton
20%, 1/16 nitrocotton 20%.
The preparation method of the environmental protection electrostatic spary coating type wood wax oil is as follows：
S1：Celluloid is added into environmentally friendly solvent, 15~20min is dispersed with stirring under the conditions of 600~800rpm makes celluloid fill
Divide dissolving, Malin's acid resin, 20 ~ 25min of high speed dispersion is then added；
S2：Castor oil and linseed oil are added into mixture obtained by S1, it is dispersed with stirring 10 under the conditions of 300~400rpm ~
15min；
S3：Brazil wax and beeswax is added into mixture obtained by S2 and is dispersed with stirring 20 under the conditions of 1000~1200rpm
After~30min, electrostatic auxiliary agent is added and is stirred evenly under the conditions of 300~600rpm.
Embodiment 2
A kind of environmental protection electrostatic spary coating type wood wax oil, the environmental protection electrostatic spary coating type wood wax oil are grouped by the group of following mass fraction
At：
19 kg of environmentally friendly solvent, 20 kg of celluloid, 15 kg of Malin's acid resin, blowing castor oil 30 kg, 30 kg of linseed oil,
5 kg of Brazil wax, 5 kg of beeswax, 2 kg of electrostatic auxiliary agent.
The preparation method is the same as that of Example 1 for wood wax oil provided in this embodiment.
Embodiment 3
A kind of environmental protection electrostatic spary coating type wood wax oil, the environmental protection electrostatic spary coating type wood wax oil are grouped by the group of following mass fraction
At：
37 kg of environmentally friendly solvent, 15 kg of celluloid, 15 kg of Malin's acid resin, blowing castor oil 20 kg, 20 kg of linseed oil,
5 kg of Brazil wax, 3 kg of beeswax, 1 kg of electrostatic auxiliary agent.
The preparation method is the same as that of Example 1 for wood wax oil provided in this embodiment.
Embodiment 4
A kind of environmental protection electrostatic spary coating type wood wax oil, the environmental protection electrostatic spary coating type wood wax oil are grouped by the group of following mass fraction
At：
20 kg of environmentally friendly solvent, 16 kg of celluloid, 14 kg of Malin's acid resin, blowing castor oil 25 kg, 25 kg of linseed oil,
4 kg of Brazil wax, 4 kg of beeswax, 1 kg of electrostatic auxiliary agent.
The preparation method is the same as that of Example 1 for wood wax oil provided in this embodiment.
Embodiment 5
A kind of environmental protection electrostatic spary coating type wood wax oil, the environmental protection electrostatic spary coating type wood wax oil are grouped by the group of following mass fraction
At：
35 kg of environmentally friendly solvent, 18 kg of celluloid, 14 kg of Malin's acid resin, blowing castor oil 26 kg, 28 kg of linseed oil,
4 kg of Brazil wax, 5 kg of beeswax, 2 kg of electrostatic auxiliary agent.
The preparation method is the same as that of Example 1 for wood wax oil provided in this embodiment.
Embodiment 6
A kind of environmental protection electrostatic spary coating type wood wax oil, the environmental protection electrostatic spary coating type wood wax oil are grouped by the group of following mass fraction
At：
33 kg of environmentally friendly solvent, 15 kg of celluloid, 10 kg of Malin's acid resin, blowing castor oil 22 kg, 21 kg of linseed oil,
5 kg of Brazil wax, 3 kg of beeswax, 2 kg of electrostatic auxiliary agent.
The preparation method is the same as that of Example 1 for wood wax oil provided in this embodiment.
Comparative example 1
This comparative example is in addition to without celluloid, and other components and content are same as Example 1, and preparation method is referring to embodiment 1.
Comparative example 2
This comparative example is in addition to without Malin's acid resin, and other components are same as Example 1 with content, and preparation method is referring to implementation
Example 1.
Comparative example 3
This comparative example is in addition to without linseed oil, and other components are same as Example 1 with content, and preparation method is referring to embodiment
1。
It is used for the wood wax oil that above-described embodiment and comparative example are prepared to spray wooden articles, the user of the wood wax oil
Method is as follows：
According to mass ratio it is 1 by the wood wax oil and haze tallow water:0.4~0.5 ratio is uniformly mixed, and then uses strainer filtering,
The wood wax oil after dilution is finally pumped into electrostatic sprayer to spray；
Wherein, the haze tallow water by absolute alcohol, dimethyl carbonate, propylene glycol methyl ether acetate and PCC polyol esters according to 20
~30:30~40:10~20:10~20 mass ratio composition.
Wooden articles after the completion of spraying are tested for the property, test method is as follows, and test result sees below Tables 1 and 2.
（1）Wearability
With wooden articles after rag wiping spraying, the wearability of wood wax oil is determined according to resistance to wiping number；
（2）Hardness
With trolley type measuring pencil durometer；
（3）Viscosity
By the wood wax oil and haze tallow water according to 1：0.8~1.2 mass ratio is diluted, and it is above-mentioned through dilution mixing to measure 50ml
Wood wax oil after good is simultaneously poured into the cup of rock field, its viscosity is tested under the conditions of 25 DEG C, 50~75%RH, with manual time-keeping, with haze tallow
Subject to oil stream is complete.
（4）Gloss
Measurement of luster is carried out by BC-D512 glossometers；
（5）Benzene, toluene level detection
With reference to the requirement of limits of harmful substances in GB 18581-2009 indoor hardware fitting solvent wood coatings, sample is detected
The content of middle benzene, toluene.
（6）The heavy metal analysis of lead, cadmium, chromium, mercury, formaldehyde
With reference to the requirement of limits of harmful substances in GB 18581-2009 indoor hardware fitting solvent wood coatings, sample is detected
The content of middle dissoluble lead, chromium, cadmium and mercury.
（7）Electric conductivity
Using electric conductivity analyzer（1SO11713-2000）It is measured.
（8）Film forming
Using film formation at low temp analyzer（MFT-2）It is measured according to the requirement of GB/T9267-9 and regulation.
（9）Rapid-drying properties
It is tested using the method for ballotini（Subject to relative temperature 25oC. humidity 50 ~ 65%）If whole ballotinis can be brushed off
Then it is dry tack free without injured surface.
Above-described specific implementation mode has carried out further the purpose of the present invention, technical solution and advantageous effect
It is described in detail, it should be understood that the foregoing is merely the specific implementation mode of the present invention, is not intended to limit the present invention
Protection domain, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should all include
Within protection scope of the present invention.
Claims (10)
1. a kind of environmental protection electrostatic spary coating type wood wax oil, which is characterized in that the environmental protection electrostatic spary coating type wood wax oil is by following quality
The group of number is grouped as：
19~37 parts of environmentally friendly solvent, 15~20 parts of celluloid, 10~15 parts of Malin's acid resin, 20~30 parts of castor oil of blowing, Asia
20~30 parts of edestan oil, 3~5 parts of Brazil wax, 3~5 parts of beeswax, 1~2 part of electrostatic auxiliary agent.
2. environmental protection electrostatic spary coating type wood wax oil according to claim 1, which is characterized in that the environmental protection electrostatic spary coating type haze tallow
Oil is grouped as by the group of following mass fraction：
28 parts of environmentally friendly solvent, 15 parts of celluloid, 10 parts of Malin's acid resin, 20 parts of castor oil of blowing, 20 parts of linseed oil, cohune
3 parts of palmitic acid wax, 3 parts of beeswax, 1 part of electrostatic auxiliary agent.
3. environmental protection electrostatic spary coating type wood wax oil according to claim 1, which is characterized in that the environmentally friendly solvent is no water beetle
One or more of alcohol, absolute ethyl alcohol, dimethyl carbonate, propylene glycol methyl ether acetate or PCC polyol esters.
4. environmental protection electrostatic spary coating type wood wax oil according to claim 3, which is characterized in that the PCC polyol esters are methyl
Methyl carbamate.
5. environmental protection electrostatic spary coating type wood wax oil according to claim 1, which is characterized in that the celluloid is by following quality hundred
The group of ratio is divided to be grouped as：
2/1 nitrocotton 30 ~ 40%, 1/4 nitrocotton 30 ~ 40%, 1/8 nitrocotton .10 ~ 20%, 1/16 nitrocotton 10 ~ 20%.
6. environmental protection electrostatic spary coating type wood wax oil according to claim 1, which is characterized in that the electrostatic auxiliary agent is amine salt chemical combination
Object.
7. the preparation method of any environmental protection electrostatic spary coating type wood wax oil of claim 1~6, which is characterized in that the method
It is as follows：
S1：Celluloid is added into environmentally friendly solvent, 15~20min is dispersed with stirring under the conditions of 600~800rpm makes celluloid fill
Divide dissolving, Malin's acid resin, 20 ~ 25min of high speed dispersion is then added；
S2：Castor oil and linseed oil are added into mixture obtained by S1, it is dispersed with stirring 10 under the conditions of 300~400rpm ~
15min；
S3：Brazil wax and beeswax is added into mixture obtained by S2 and is dispersed with stirring 20 under the conditions of 1000~1200rpm
After~30min, electrostatic auxiliary agent is added and is stirred evenly under the conditions of 300~600rpm.
8. the application method of any environmental protection electrostatic spary coating type wood wax oil of claim 1~6, which is characterized in that the use
Method is as follows：
According to mass ratio it is 1 by the wood wax oil and haze tallow water:0.4~0.5 ratio is uniformly mixed, and then uses strainer filtering,
The wood wax oil after dilution is finally pumped into electrostatic sprayer to spray；
Wherein, the haze tallow water by absolute alcohol, dimethyl carbonate, propylene glycol methyl ether acetate and PCC polyol esters according to 20
~30:30~40:10~20:10~20 mass ratio composition.
9. application method according to claim 8, which is characterized in that the mesh number of the strainer is 80~100 mesh.
10. application method according to claim 8, which is characterized in that measure the above-mentioned haze tallows after dilution mixes of 50ml
Oil simultaneously pours into the cup of rock field, its viscosity is tested under the conditions of 25 DEG C, 50~75%RH；The viscosity of the wood wax oil is 15~20 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810719209.1A CN108753170B (en) | 2018-07-03 | 2018-07-03 | Environment-friendly electrostatic spraying type wood wax oil and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810719209.1A CN108753170B (en) | 2018-07-03 | 2018-07-03 | Environment-friendly electrostatic spraying type wood wax oil and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108753170A true CN108753170A (en) | 2018-11-06 |
| CN108753170B CN108753170B (en) | 2020-10-16 |
Family
ID=63975699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810719209.1A Active CN108753170B (en) | 2018-07-03 | 2018-07-03 | Environment-friendly electrostatic spraying type wood wax oil and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108753170B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113906181A (en) * | 2019-04-24 | 2022-01-07 | 帕帕克斯销售有限责任公司 | Barrier layer for cellulosic substrates |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006067959A (en) * | 2004-09-06 | 2006-03-16 | Rolling:Kk | Spray-type solid oil and fat |
| CN106978075A (en) * | 2017-05-11 | 2017-07-25 | 深圳市清弘环保科技有限公司 | White wood wax oil of a kind of environment-friendly spray coating type and its preparation method and application |
| CN106987207A (en) * | 2017-05-11 | 2017-07-28 | 深圳市清弘环保科技有限公司 | A kind of environment-friendly spray coating type wood wax oil and its preparation method and application |
-
2018
- 2018-07-03 CN CN201810719209.1A patent/CN108753170B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006067959A (en) * | 2004-09-06 | 2006-03-16 | Rolling:Kk | Spray-type solid oil and fat |
| CN106978075A (en) * | 2017-05-11 | 2017-07-25 | 深圳市清弘环保科技有限公司 | White wood wax oil of a kind of environment-friendly spray coating type and its preparation method and application |
| CN106987207A (en) * | 2017-05-11 | 2017-07-28 | 深圳市清弘环保科技有限公司 | A kind of environment-friendly spray coating type wood wax oil and its preparation method and application |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113906181A (en) * | 2019-04-24 | 2022-01-07 | 帕帕克斯销售有限责任公司 | Barrier layer for cellulosic substrates |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108753170B (en) | 2020-10-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106243966B (en) | A kind of double-component aqueous woodenware white finish paint of composite multifunction and preparation method thereof | |
| CN102120910B (en) | Environmentally-friendly solvent type woodware coating with formaldehyde-absorbing function and preparation method thereof | |
| CN104263214B (en) | The transparent woodenware combination paints of PU and its coating process | |
| CN102604489B (en) | Water-based environment-friendly nitrolacquer and construction method for same | |
| CN110003790A (en) | A kind of high matte varnish and preparation method thereof thoroughly of PU ordor removing | |
| CN103614062A (en) | Environment-friendly coating for leather surface finishing and preparation method thereof | |
| CN106634544A (en) | Low-VOC (Volatile Organic Compound) sound-insulation PU (Polyurethane) matte white finish paint | |
| CN106987207B (en) | A kind of environment-friendly spray coating type wood wax oil and its preparation method and application | |
| CN108753170A (en) | A kind of environmental protection electrostatic spary coating type wood wax oil and its preparation method and application | |
| US20070101902A1 (en) | Low VOC solvent useful with paints and coatings | |
| CN106833268B (en) | A kind of aqueous sealing primer and preparation method thereof for high fat content ground | |
| CN104327698B (en) | The polyurethane-modified matte varnish of net taste benzene-free acrylic | |
| CN106978075B (en) | A kind of environment-friendly spray coating type white wood wax oil and its preparation method and application | |
| CN107022308B (en) | A kind of UV hardening types wood wax oil and its preparation method and application | |
| CN101747838A (en) | Preparation method of natural transparent paint | |
| CN106519840B (en) | A kind of plastic paint and preparation method thereof | |
| CN102533110A (en) | Preparation method of alcohol water-soluble paint | |
| WO2017088086A1 (en) | Aqueous brightening treatment agent for synthetic leather and preparation method for same | |
| CN108753168A (en) | Environmentally friendly erasing type hard wood wax oil with stain resistance and the preparation method and application thereof | |
| CN108485452A (en) | A kind of water paint and preparation method thereof suitable for woodwork | |
| CN108912982A (en) | A kind of anti-sag PU transparent priming and preparation method thereof | |
| CN107446491A (en) | A kind of anti-flake bubble Thief zone prevents sagging polyurethane woodenware priming paint | |
| CN103184003A (en) | Super waterproof water-borne wood paint and preparation method thereof | |
| CN103254749A (en) | Water-based blackboard paint | |
| CN111117354A (en) | Water-based propylene marker ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240416 Address after: 516000, No. 49, Changzhong Third Lane, Futian Town, Boluo County, Huizhou City, Guangdong Province Patentee after: Huizhou Qinghong Environmental Protection Technology Co.,Ltd. Country or region after: China Address before: No. 49, Changzhong Third Lane, Futian Town, Boluo County, Huizhou City, Guangdong Province, 516100 Patentee before: Qiu Pingliang Country or region before: China Patentee before: SHENZHEN QINGHONG ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. |
|
| TR01 | Transfer of patent right |